Orientador: Rosângela Barros Zanoni Lopes Moreno / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecânica e Instituto de Geociências / Made available in DSpace on 2018-08-22T07:30:06Z (GMT). No. of bitstreams: 1 EspinosaLeon_Carlos_M.pdf: 5382010 bytes, checksum: fdf960a158541b21f9deb9c7f4593f44 (MD5) Previous issue date: 2013 / Resumo: A molhabilidade tem sido reconhecida como um fator importante controlando a localização microscópica, distribuição e escoamento de fluidos em um meio poroso. Afeta a saturação de água irredutível e de óleo residual assim como as curvas de permeabilidade relativa e pressão capilar do meio poroso, impactando significativamente na recuperação final de óleo. Evidencias de estudos de laboratório têm mostrado que as rochas carbonáticas são de molhabilidade mista a preferencialmente molhadas por óleo. Estas condições são desfavoráveis para a embebição espontânea da água e, portanto, para projetos de injeção de água como método de recuperação. Conforme estudos sobre interações óleo/água/rocha, a composição e propriedades da água injetada podem alterar as propriedades de molhabilidade das rochas durante processos de injeção de água, melhorando a recuperação de petróleo. O principal objetivo deste trabalho é caracterizar a molhabilidade de um bloco de coquinas de afloramento provenientes da Formação Coqueiro Seco - Bacia Sergipe-Alagoas, que são equivalentes às rochas dos reservatórios do pré sal. As medidas do índice de molhabilidade foram realizadas pelo método de Amott, que combina a embebição espontânea e forçada de fluidos para determinar a molhabilidade média das amostras carbonáticas. Óleo mineral e soluções aquosas com salinidade variando de 10000 a 140000 ppm de NaCl foram usadas para representar o óleo e a água de injeção, respectivamente. Os resultados obtidos dos testes realizados neste estudo evidenciam que este tipo de rocha é de molhabilidade mista a preferencialmente molhadas por óleo / Abstract: Wettability has been recognized as an important factor controlling the microscopic location, distribution and fluid flow through a porous medium. It affects the irreducible water saturation and residual oil saturation as well as the relative permeability curves and capillary pressure impacting the ultimate recovery oil. Evidence from laboratory studies have shown that carbonate rocks are mixed wettability to preferentially oil wet which are unfavorable conditions for spontaneous imbibition of water and therefore in the design of a waterflooding process as a recovery method. As studies on oil/water/rock interactions the composition and properties of the injected water can alter the wetting properties of rocks during a waterflooding improving oil recovery. The main objective of this work is to measure the wettability of coquina outcrops from the Coqueiro Seco Formation - Sergipe-Alagoas Basin, which are equivalent to pre-salt reservoir rocks. Wettability index measurements were carried out with the Amott method which combines spontaneous and forced imbibition of fluids to determine the average wettability of carbonate cores. Mineral oil and brines with salinity ranging from 10.000 to 140.000 ppm of NaCl were used to represent crude oil and the injection brine respectively. The results of the tests addressed in this study provided evidences that these rocks are mixed-wet to preferentially oil-wet / Mestrado / Reservatórios e Gestão / Mestre em Ciências e Engenharia de Petróleo

The growth of fossil fuel production in North Dakota has resulted in numerous releases of brine. Brine releases cause vegetation mortality as well as the deterioration of soil structural and edaphic properties. Little research to date has been dedicated to the germination response of plant species grown in North Dakota to brine-induced salinity. Through the exposure of plant seeds to increasing levels of brine and NaCl-induced salinity, it was determined that the graminoid species Elymus hoffmannii (AC Saltlander) and Pascopyrum smithii (Western Wheatgrass) exhibited the greatest germination at high salinities. Current remediation technologies for brine-impacted lands often produce mixed results, requiring further research and testing. In two laboratory experiments, the ability of materials to wick salts from brine-contaminated soils was tested. The results of these studies show that some materials reduced Na concentrations in sandy loam, loam, and silty clay soils by upwards of 88, 89.5, 38.4% respectively.

Soil salinity is a widespread problem that affects crop productivity. We expect that saline soils also have altered microbial community structure, soil food webs and related soil properties. To test this, we sampled field soils across four farms in eastern North Dakota that host salinity gradients. We evaluated microbial biomass carbon, phospholipid fatty acid analysis and nematode counts in moderately saline and low saline soils. Additionally, we measured soil properties that represent potential food sources and habitat characteristics that influence microbial communities. We found higher microbial group abundance in moderately saline soils than in the lower saline soils. In contrast, we found lower nematode abundances in the moderately saline soils. We also observed increased labile carbon, nitrogen, phosphorus, and water content in the moderately saline soils. Based on our results, saline soils appear to have unique soil biological characteristics, which have implications for overall soil function along salinity gradients.

Magister Scientiae (Biodiversity and Conservation Biology) - MSc (Biodiv and Cons Biol) / Randomized block experiments were conducted to examine the putative amelioratory effects of kinetin or gibberellic acid at concentrations (0, 4, 12.5, 40, and 125 μM) in Erucastrum strigosum plants subjected to a salinity series (0, 100, 200, 300, and 400 mM NaCl) in the greenhouse. When the highest salinity concentration (increased stepwise) was reached, growth effects in relation to water and cation content of the plants were evaluated. Growth and water content were reduced progressively with salinity treatments. Na+ concentration accumulated with salinity treatments to levels that were much higher than that of other cations (K+, Ca2+ and Mg2+) in both organs. However, it is noteworthy that Na+ distribution was more in shoots than in roots. In kinetin treated plants, shoot growth decreased whilst root growth increased with moderate hormonal treatments.

Due to the flocculation process, suspended mud aggregates carried by rivers and streams can undergo changes in their size, shape, and settling velocity in response to environmental drivers such as turbulence, sediment concentration, organic matter (OM), and salinity. Some have assumed that salt is necessary for floc formation, and that mud, therefore, reaches the estuary unflocculated. Yet mud flocs exist in freshwater systems long before the estuarine zone, likely due to the presence of OM and ions in the water that facilitate binding and aggregation of mud particles. This research aimed to examine the flocculation state of mud over the fluvial as well as fluvial to marine transition (FtMT) zones of the Mississippi River basin and how salinity, or the ion concentration of water, and organic matter independently and together affect flocculation. Suspended mud was found to be mostly flocculated in the headwaters of the Mississippi River in southwest Virginia, USA. However, increasing the ion concentration of water samples to levels measured following winter storms changed the size distribution of suspended particles, led to more of the mud existing in large flocs, and resulted in an overall increase in average size by about 40%, thereby increasing the settling rate of the mud relative to the suspensions without salt. These results suggested that potential negative effects of road salts on mud deposition should be investigated further. Additional experiments were used to examine the flocculation of a natural mud sample with and without OM showed that the rate of floc growth and equilibrium size both increase with salinity regardless of the presence or absence of OM. However, the response of both to salinity was stronger when OM was present. In deionized water, natural sediment with OM was seen to produce large flocs. However, the size distribution of the suspension tended to be bimodal. With the addition of salt, increasing amounts of unflocculated material became bound within flocs, producing a more unimodal size distribution. Here, the enhancing effects of salt were noticeable at even 0.5 ppt, and increases in salinity past 3 to 5 ppt only marginally increased the floc growth rate and final size. A salinity-dependent model to account for changes in floc growth rate and equilibrium size was presented. Laboratory experiments on the sediment suspended in the lower reaches of the Mississippi River were used to provide further insight on the mud flocs behavior in the FtMT. Turbulence shear rate, a proxy for the river hydrodynamics, was found to be the most influential factor in mud floc size. While artificial increase in salinity by adding of salts did not lead to considerable increase in floc size, addition of water collected from the Gulf of Mexico enhanced the flocculation. These effects were speculated to originate from the biomatter composition of the Gulf water, particularly where the nutrient-rich Mississippi River water reaches the marine water. / Doctor of Philosophy / Rivers bring a substantial amount of mud to coastal regions. Where this mud deposits is important in shaping the coastal land and nutrient dynamics. Mud particles are different from sand and gravel in that they can form aggregates known as flocs that constantly change shape and size under different conditions. As they change size, they change how fast they sink, and this influences where they deposit. Due to their small size, mud particles are also considered a pollutant as they can clog up fish gills and destroy freshwater habitats. Findings of this dissertation showed that the roadway deicing salts that make their way to streams can enhance the aggregation of mud particles, causing them to sink faster. This can be harmful to the species that live on streambeds. While salts are known to enhance flocculation, there is ample evidence that flocs exist in rivers before reaching the sea. It is possible, therefore, that flocs in estuaries are due to biological matter acting as a glue to bind mud particles together and may not be influenced by salt. This dissertation looked at the effects of saltwater on mud flocculation when biological matter is present and when it is absent. Findings showed that salinity increased the size of mud flocs, even more so than when organic matter was absent. However, organic matter was needed for flocs to reach sizes often found in nature. An equation was also provided to aid in the prediction of floc size under different salinities. Observations on the lower Mississippi River flocs showed that the turbulence of water was the most influential factor in determining the size of flocs.

Dormancy is a plausible strategy for bacteria to overcome the effects of temporal fluctuations in resources or stresses and await more “optimal” conditions to resume metabolic activity and growth. Seasonal changes in environmental conditions force microbes to adjust their metabolic activity accordingly, and community composition drastically shifts. In extreme environments, however, the overriding effects of a constant stress may constrain the need or benefit of bacteria entering dormancy. In hypersaline lakes, high metabolic activity is required to maintain adaptations that permit survival. Sampling from six lakes on a salinity gradient (0.05% – 30.3%), we measured seasonal fluctuations in bacterial dormancy patterns in summer, fall, winter, and spring of 2013-14. Dormancy was calculated based on ratios of OTU recovery between 16S rRNA-based communities (only the active bacteria) and 16S rRNA gene-based communities (all bacteria present in the community) from lake water. Dormancy was linked to lake chemistry shifts through time. We found that salinity was strongly related to relative bacterial dormancy. There was a negative linear relationship (R2 = .89 P <0.01) between total dormancy and salinity. Total phosphorus (R2 = .63, P < .001) and relative community contribution by rare taxa (R2 = .89, P < .001) were also important in structuring dormancy. Our findings suggest that temporal nutrient flux is highly influential on bacterial community composition and activity, but that the presence of an extreme variable decreases change in both through time.

<p> A detailed study of sponge boring morphotypes within the molluscan fauna of Upper Cretaceous estuarine sediments near Drumheller, Alberta provides information relevant to the depositional environment. Problems with regard to utilizing Entobia as a paleoenvironmental indicator and as an indicator of salinity do not appear to be insurmountable.</p> <p> Distributions and characteristics of associated marine organisms (phoronid worms, gastropods and encrusting bryozoa) suggest that sponge colonies were affected by salinity and sedimentation. Boring networks in Ostrea glabra suggest that more than one species of sponge were present. Sponge distribution patterns, changes in papilla and chamber sizes and preferential occurrence of sponge borings on certain shell thicknesses provide good evidence for responses to salinity and sedimentation.</p> / Thesis / Bachelor of Science (BSc)

Thesis advisor: Christopher Kenaley / Bergmann’s rule predicts a change in body size with latitude, with larger members of a taxonomic group occurring further from the equator. This pattern has been described for many groups of organisms; however, no study has assessed this relationship across a substantial number of ray-finned fish species, the largest group of vertebrates. I performed Bayesian phylogenetic modeling using maximum length and latitude data for 3021 species of actinopterygians to assess Bergmann’s rule in the group. The impact of salinity tolerance on the relationship between length and latitude was also considered. Maximum length and salinity tolerance data were obtained from FishBase, and latitude data were obtained from museum records. I found that, overall, Bergmann’s rule holds and is not significantly affected by salinity tolerance except when not considering phylogeny, in which case only marine species show the trend. / Thesis (BA) — Boston College, 2023. / Submitted to: Boston College. College of Arts and Sciences. / Discipline: Departmental Honors. / Discipline: Biology.

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Biochar amendment to agricultural soils has been promoted for use in agricultural systems, both to mitigate global warming by increasing long-term soil carbon (C) sequestration and to enhance soil fertility and crop productivity. The objective of this study was to evaluate the effects of a single biochar application from peanut shell (Arachis hypogea L.) and mixed pine (Pinus spp.) wood to a Typic Hapludults in Blacksburg (VA, USA) and from peanut shell and eucalyptus (Eucalyptus camaldulensis) wood to a tropical, sandy, salt-affected soil in Ndoff (Fatick, Senegal) at 0, 10, and 20 Mg ha⁻¹ on soil chemical properties, inorganic nitrogen supply, and pearl millet production responses under field conditions for two growing seasons (2014 and 2015). Biochar application to temperate soils (Blacksburg) significantly increased total soil carbon, nitrogen, and plant available potassium in both years. In addition, pearl millet yields significant increased (53%) at the 20 Mg ha⁻¹ rate of peanut shell biochar in 2014 but did not persist in year 2. Beneficial effects largely appeared due to nutrient additions. Biochar treatment to tropical, sandy, salt-affected soils (Ndoff) had no effect on soil chemical properties. These results suggest that biochar application could improve soil fertility and crop productivity in temperate soils but had limited effects on tropical, sandy, salt-stressed soils in this study. The disparate results between these two field studies could be explained by differences in soil properties and climate, biomass feedstock, pyrolysis processes, and biochar handling, as well as experimental set-up. / Master of Science