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Grouting techniques have been in used for many years, but several new grout materials have surfaced in recent decades that have re-defined the boundaries of the limitations of grouting programs. Typically these applications are used for seepage control in earthen impoundments, but strength of these earthen impoundments should be considered where there is potential for movement in the grouted soil mass. This study investigated initial conditions that could affect grout application effectiveness. The initial conditions in question were soil grain size and in situ moisture content. Two grouts were used, ultrafine and acrylate, and variations in pure grout properties were studied. An apparatus was developed so that a uniform grout could penetrate the pore spaces of a soil specimen. The rate of penetration of the grout into the soil was studied. The unconfined compressive strength of the resulting grouted soil was then analyzed. In testing neat ultrafine grout, it was shown that increased water-to-cement ratios had negative effects on the stability of the grout. Increasing the water-to-cement ratio from 0.5 to 2.5 resulted in a decrease in strength by a factor of 100. An inhibitor chemical was used to increase the time for reaction in the acrylate grout. During the chemical reaction, the curing temperature and gel times were monitored. A grout mix was selected for the acrylate grout that achieved appropriate gel times. In general, this study found that the grout penetrations rates into the soil increased as the initial moisture was increased from dry conditions to a gravimetric moisture content of nine percent. In each study, increased initial moisture decreased the grouted soil strength, with decreases in strength exceeding 50 percent. Empirical relationships were realized when compared to the initial matric suction of the soil. This suggests initial matric suction may be a useful initial condition for estimating increases in soil strength upon implementation of a grouting program for both the acrylate and ultrafine grouts.

Surface mining of oil sands results in extensive land disturbance, earth movement and water usage. After mining, the disturbed landscapes must be reconstructed and reclaimed as natural landforms. There are numerous challenges associated with understanding the responses of these landforms over time, including a need to track and characterize water movement through closure landforms to understand the hydrological responses of these landforms over time. This study attempted to use natural stable isotopes of water (δD and δ18O) to identify and characterize source waters from various closure landforms at an oil sands mine site. The study area is Syncrude‟s Mildred Lake mine, an open pit oil sands mine located in northern Alberta. A variety of groundwater, surface water and soil samples from a variety of landforms (overburden dumps, composite and mature fine tailings areas, tailings sand structures and freshwater reservoirs) were collected in an attempt to fully represent the isotopic distribution of waters across the mine site. Laboratory analysis of δD and δ18O was done on all samples. The local meteoric water line first established by Hilderman (2011) was redeveloped with additional precipitation data and calculated to be δD=7.0(δ18O) -18.6‰. A natural evaporation line having a slope of 5.3 was calculated for the mine site with samples collected from three surface water ponds on the mine site. Five primary source waters were identified on the mine site: process affected water/tailings, rainfall, snow, interstitial shale water and Mildred Lake water. It was found that these sources of water generally have unique natural stable water isotope signatures. Process affected water at the site generally had an enriched signature compared to other mine waters. The enrichment was attributed to fractionation from the recycle water circuit and natural evaporation. The characterizations of these source waters were then used in several hydrogeological examples to demonstrate that natural stable water isotopes can be applied to water balance estimates and to identify water movement processes related to closure landforms.

Biofilms are significant contributors to primary production, nutrient cycling, bio-stabilization and the food web of wetland ecosystems. Photoautotrophic biomass (PB) and primary production (PP) were determined for biofilms exposed to various treatments and materials in wetlands near Fort McMurray. Biofilm additions and oil sands process-affected materials were expected to increase the microbial colonization rates on treated substrates and subsequently PB and PP of biofilms over time as compared to controls and unaffected materials. Biofilms survived the transfers and colonized new substrates immediately. Oil sands process affected materials were found to increase PB and PP throughout the first year. A strong decreasing trend for both PB and PP in treatment microcosms occurred in year two, eventually coalescing with control conditions at a lower equilibrium. Transferred biofilms and treatment materials, therefore, increased overall wetland productivity during the initial stages of wetland development when growing conditions are most limiting. / Land Reclamation and Remediation

Bitumen recovery by the water-based extraction process produces waste streams known as tailings. When discharged into the tailing ponds, the coarse solids in the tailings stream settle out quickly, while the fine solids accumulate over years of settling to a solids content of 30-35% by weight. The formed fluid fine solids sludge, known as mature fine tailings (MFT), traps 1-3% by weight hydrocarbons within its stable slurry structure. The remediation of these mature fine tailings is one of the major challenges facing the oil sands industry. This study was intended to investigate the recovery of residual hydrocarbons in the MFT by froth flotation process. Using a laboratory Denver flotation cell operated in a batch mode, the effect of MFT dilution ratio by process water or tap water, the flotation hydrodynamics and aeration rate on hydrocarbon recovery kinetics was studied. It was found that at 1:2 dilution by weight of the MFT with process water, increasing aeration rate has a more favourable effect on recovering more than 85% of the hydrocarbons from the MFT. The hydrocarbon-rich froth produced was treated by naphtha and was found to produce a hydrocarbon product similar to diluted bitumen obtained in bitumen extraction process, suitable for upgrading. Similar approach was applied to the hydrocarbon-rich tailings from the Tailings Solvent Recovery Unit of paraffinic froth treatment. Satisfactory recovery of hydrocarbons from the MFT was obtained using a flotation column operated in a continuous mode, confirmed the results obtained from the batch tests. The tailings produced from the continuous flotation experiments were treated with polymer flocculants such as Magnafloc-1011 and Al-PAM to study the effect of hydrocarbon recovery on the remediation of the MFT. The results from initial tests showed that both flocculants were not as effective on flocculating MFT solids following the recovery of hydrocarbons by froth flotation. / in Chemical Engineering

The technique of Inverse Gas Chromatography (IGC) was employed for the study of the interactions between various organic solvents with various types of the major inorganic materials (clay minerals and sand) found in Albertas oil sands. Heat of adsorption (-H) was measured for each solvent with respect to each of the four studied inorganic materials. The calculation we used was based on the Infinite Dilution Thermodynamics approach used by Katsanos et. al. [Journal of Chromatography A. 795, 133-184 (1998)]. Retention time data is converted into Retention Volume; H is then obtained by a plot vs. 1/T. The solvents studied were straight chain, branched and cyclic alkanes, alkenes, aromatics, and ketones. The inorganic materials studied were kaolinite, illite, illite-smectite mixed layer, and sand. Our results show that solvents had significantly less affinity for sand when compared to the three types of clay studied. Additionally, solvent affinity to illite had appreciable difference when compared to kaolinite and the mixed layer of illite-smectite. Furthermore, increase in carbon number leads to increased adsorption to the clay. Branched or cyclic alkanes have slightly lower adsorption to clay when compared to straight chain alkane of the same carbon number. Double bonds significantly increase solvent affinity to clay, but have no effect on sand. Lastly, alcohols and ketones have very high affinity to clay that no elution occurred when either solvent was injected into the GC and only ketone eluted when sand was the stationary phase in the GC column. / Chemical Engineering

Densification of tailings slurries to mature fine tailings (MFT) is important in the oil sands industry for tailings inventory reduction, pore water recovery and tailings reclamation. The cause of methane release from the tailings pond of Shell Albian Sands (Albian) and the effects this process has on densification of Albian tailings was investigated. Citrate, added to tailings with polyacrylamide and hydrocarbon-diluent, was identified as the methanogenic substrate. Bacterial and Archaeal 16S rRNA gene sequences in Albian MFT were dominated by matches to Rhodoferax, some Clostridia and sulfate-reducing bacteria, and acetoclastic methanogens. Citrate-, diluent-, and polyacrylamide-amendments to Albian MFT did not cause a microbial shift over a 10-month laboratory incubation period. A potential pathway for microbial methane production in Albian MFT is proposed. Methane production and release from citrate-amended Albian MFT correlated to accelerated densification. Though diluent and polyacrylamide did not affect methanogenesis, they potentially affect gas bubble formation and release. / Microbiology and Biotechnology

In 1997, Rogner published a paper containing an estimate of the natural gas in place in unconventional reservoirs for 11 world regions. Rogner's work was assessing the unconventional gas resource base, and is now considered to be very conservative. Very little is known publicly about technically recoverable unconventional gas resource potential on a global scale. Driven by a new understanding of the size of gas shale resources in the United States, we estimated original gas in place (OGIP) and technically recoverable resource (TRR) in highly uncertain unconventional gas reservoirs, worldwide. We evaluated global unconventional OGIP by (1) developing theoretical statistic relationships between conventional hydrocarbon and unconventional gas; (2) fitting these relationships to North America publically available data; and (3) applying North American theoretical statistical relationships to evaluate the volume of unconventional gas resource of the world. Estimated global unconventional OGIP ranges from 83,300 (P10) to 184,200 (P90) Tcf. To assess global TRR from unconventional gas reservoirs, we developed a computer program that we call Unconventional Gas Resource Assessment System (UGRAS). In the program, we integrated a Monte Carlo technique with an analytical reservoir simulator to estimate the original volume of gas in place and to predict production performance. We used UGRAS to evaluate the probabilistic distribution of OGIP, TRR and recovery factor (RF) for the most productive unconventional gas formations in the North America. The P50 of recovery factor for shale gas, tight sands gas and coalbed methane is 25%, 79% and 41%, respectively. Finally, we applied our global OGIP assessment and these distributions of recovery factor gained from our analyses of plays/formations in the United States to estimate global technically recoverable unconventional gas resource. Global technically recoverable unconventional gas resource is estimated from 43,000 (P10) to 112,000 (P90) Tcf.

During oil-sands mining all vegetation cover, soil, overburden and oil-sand is removed, leaving pits several kilometres wide and hundreds of metres deep. These pits are reclaimed by a variety of treatments using mineral soil or a mixed peat and mineral soil as the capping layer and planted with trees with natural colonisation from adjacent sites. A number of reclamation treatments covering different age classes were compared with a range of natural forest ecotypes to identify the age at which the treatments become similar to a natural site with respect to vegetation composition and key soil attributes relevant to nutrient cycling. Ecosystem function was estimated from plant community composition, litter decomposition, development of an organic layer and bio-available nutrients. Key response variables including moisture, pH, C:N ratios, bio-available nutrients and ground-cover were analysed by non-metric multidimensional scaling and cluster analysis to discover which reclamation treatments were moving towards or merging with natural forest ecotypes and at what age this occurs. On reclaimed sites, bio-available nutrients including nitrate generally were above the natural range of variability but ammonium, phosphorus, potassium, sodium and manganese were generally very low and limiting to ecosystem development. Plant diversity was similar to natural sites from 5 years to 30 years after reclamation, but declined as reclaimed sites approached canopy closure. Grass and forb leaf litters decomposed faster than aspen or pine in the first year, but decomposition on one reclamation treatment fell below the natural range of variability. Development of an organic layer appeared to be facilitated by the presence of shrubs, while forbs correlated negatively with first-year decomposition of aspen litter. The better restoration amendments for tailings sands involved repeated fertilisation of peat: mineral mixtures in the early years of plant establishment, these became similar to a target ecotype at about 25 years. Good results were also shown by subsoil laid over non-saline overburden and fertilised once, these became similar to a target ecotype at about 15 years. Other treatments receiving a single application of fertiliser remain entrenched in the early reclamation phase for up to 25 years.