Organic matter which is insoluble in common solvents and non-oxidising acids often comprises the quantitatively most important fraction of organic matter in sediments. This operationally defined material is usually simply termed 'insoluble organic matter' (IOM) or 'kerogen' when it is isolated from ancient sediments. Indeed, kerogen is regarded as the most abundant form of carbon on the planet. The molecular character of this generic material has not been fully elucidated, principally because of its insolubility which limits instrumental methods of analysis to those applicable to solid substrates. This thesis describes the quantitative isolation of IOM from lacustrine and marine sediments and two species of methanogenic bacteria using a sequential isolation procedure. A range of synthetic IOMs (melanoidins) was also prepared. The dissolution of IOM and melanoidins obtained in this manner was then attempted using the acidic ionic liquid l-ethyl-3- methylimidazolium chloride-aluminium (III) chloride. Two synthetic dendrimers containing similar functional groups to those observed in sedimentary IOM were used to try and assess the mode of action of the ionic liquid. Ionic liquid treatment of the DCM soluble dendrimers resulted in the formation of 7 - 62 % of material that was no longer soluble in DCM, whilst the soluble components had been substantially altered. The ionic liquid was found to non-quantitatively promote ether cleavage, protonation and rearrangement reactions. IOM was isolated from lacustrine Rostherne Mere, UK, sediments (7 - 3 0 % dry weight), Kimmeridge Clay, Dorset (11 - 12 %) and methanogenic bacteria (Methanococcus jannaschii, 3 %; Methanobacterium thermoaiitotrophicum, 0.1 %) using a time-consuming isolation procedure involving over forty separate chemical manipulations. Monitoring of the sequential isolation of IOM and characterisation of the final isolates was carried out using solid-state NMR, IR, elemental analysis, pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS), scanning electron microscopy, and the newer surface sensitive technique of time of flight-secondary ion mass spectrometry (ToF-SIMS). Less than 1 % of sedimentary IOM and 5 % of Kimmeridge Clay IOM was soluble in DCM following ionic liquid treatment, whilst alkyl chains were lost from the insoluble portion which also increased in aromaticity. The poor yield recovered following ionic liquid treatment of M. jannaschii IOM (5 %) was attributed to loss of volatile material during hydrolysis. Following ionic liquid treatment 93 - 96 % of the melanoidins remained insoluble in DCM although their character had been altered, becoming more condensed. This ionic liquid dissolution procedure has not provided the substantial progress in elucidating the molecular character of IOM promised by earlier reports.

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Much research effort is focused on the development of reliable empirical and numerical models for the prediction of sand transport. Confidence in these models depends on good agreement between predicted and measured transport rates for controlled conditions and, in the case of process-driven numerical models, good agreement between measured and predicted "sub-processes", such as time-dependent concentration and velocity profiles. The purpose of this project was to conduct experiments that measure these transport "sub-processes" in full-scale sinusoidal and asymmetric oscillatory sheet-flow conditions for well-sorted and graded sands. Detailed measurements have been obtained of concentrations, velocities, total and fractional transport rates and particles sizes in bed samples and in suspended and transported sands. The range and level of detail in the new concentration measurements makes it possible to interrogate concentration behaviour much more rigorously than previously possible. A new equation is presented which characterises time-dependent concentration profiles in the sheet-flow layer. The equation is based on time-dependent erosion depth and reference concentration. Analysis of the dependence of these parameters on flow and bed conditions is presented. The new velocity measurements extend "deeper" into the oscillatory boundary layer than previously possible and the results show classic features of oscillatory boundary layer flow. The product of the measured velocity and concentration data gives time-dependent sediment flux profiles. Analysis of the flux profiles reveals the detailed transport processes. The effects of unsteady behaviour and the effects of interactions between different size fractions in graded beds are evident in the sediment transport results. Unsteady effects act to reduce net transport and result in a strong offshore-directed transport in the case of fine sand. There is strong interaction between size fractions in graded beds. The mobility of the finer fractions is suppressed by the presence of coarser sands whilst the mobility of the coarser fractions is increased by the presence of finer sands.

The lower continental slope of Morocco’s west coast consists of Triassic-age salt manifested in the form of diapirs, tongues, sheets, and canopies, and both extensional and compressional structures that result from salt movements. Salt diapirism and regional tectonics greatly influenced a broad spectrum of depositional processes along the margin. Mapping of a 1064-km2 (411-mi2) seismic survey acquired in the Safi Haute Mer area reveals that Jurassic to Holocene salt mobilization has induced sedimentation that manifests itself in gravity slumps and slides and debris flows. An east-west–trending structural anticline located downdip of the salt-influenced region, was activated during the Atlas uplift (latest Cretaceous) and shaped much of the lower continental slope morphology from Tertiary time until present. The largest of the mass transport deposits (MTC) is a 500-m (1640-ft)-thick Cretaceous-age unit that spans an area of up to 20,000 km2 (7722 mi2). Seismic facies composing the MTC are (1) chaotic, mounded reflectors; (2) imbricated continuous to discontinuous folded reflector packages interpreted to represent internal syn-depositional thrusts; and (3) isolated, thick packages of continuous reflectors interpreted to represent transported megablocks (3.3 km2 [1.3 mi2]). The latter show well preserved internal stratigraphy. The MTCs originated from an upslope collapse of a narrow shelf during the earliest phases of the Alpine orogeny. Seismic geomorphologic analysis of the non-salt-deformed sections reveal numerous linear features that are interpreted as migrating Mesozoic-age deepmarine sediment waves. Three styles of sediment waves have been identified. These include: (1) type J1—small (less than 17 m thick) and poorly imaged, Jurassic in age, ridges that have wavelengths of up to 12 km and crest-to-crest separations of less than 1 km; (2) type K1—early Aptian constructional sediment waves (~110 m thick) that appear to show some orientation and size variations which suggest an influence on currents by salt-influenced seafloor topography, and (3) type K2—latest Albian and earliest post-Albian sediment waves exhibiting wave heights of 40 m and crest-to-crest separations of 1 km, that are continuous across the entire study area and show evidence of up-slope migration.

The lower continental slope of Morocco’s west coast consists of Triassic-age salt manifested in the form of diapirs, tongues, sheets, and canopies, and both extensional and compressional structures that result from salt movements. Salt diapirism and regional tectonics greatly influenced a broad spectrum of depositional processes along the margin. Mapping of a 1064-km2 (411-mi2) seismic survey acquired in the Safi Haute Mer area reveals that Jurassic to Holocene salt mobilization has induced sedimentation that manifests itself in gravity slumps and slides and debris flows. An east-west–trending structural anticline located downdip of the salt-influenced region, was activated during the Atlas uplift (latest Cretaceous) and shaped much of the lower continental slope morphology from Tertiary time until present. The largest of the mass transport deposits (MTC) is a 500-m (1640-ft)-thick Cretaceous-age unit that spans an area of up to 20,000 km2 (7722 mi2). Seismic facies composing the MTC are (1) chaotic, mounded reflectors; (2) imbricated continuous to discontinuous folded reflector packages interpreted to represent internal syn-depositional thrusts; and (3) isolated, thick packages of continuous reflectors interpreted to represent transported megablocks (3.3 km2 [1.3 mi2]). The latter show well preserved internal stratigraphy. The MTCs originated from an upslope collapse of a narrow shelf during the earliest phases of the Alpine orogeny. Seismic geomorphologic analysis of the non-salt-deformed sections reveal numerous linear features that are interpreted as migrating Mesozoic-age deepmarine sediment waves. Three styles of sediment waves have been identified. These include: (1) type J1—small (less than 17 m thick) and poorly imaged, Jurassic in age, ridges that have wavelengths of up to 12 km and crest-to-crest separations of less than 1 km; (2) type K1—early Aptian constructional sediment waves (~110 m thick) that appear to show some orientation and size variations which suggest an influence on currents by salt-influenced seafloor topography, and (3) type K2—latest Albian and earliest post-Albian sediment waves exhibiting wave heights of 40 m and crest-to-crest separations of 1 km, that are continuous across the entire study area and show evidence of up-slope migration.

The lower continental slope of Morocco’s west coast consists of Triassic-age salt manifested in the form of diapirs, tongues, sheets, and canopies, and both extensional and compressional structures that result from salt movements. Salt diapirism and regional tectonics greatly influenced a broad spectrum of depositional processes along the margin. Mapping of a 1064-km2 (411-mi2) seismic survey acquired in the Safi Haute Mer area reveals that Jurassic to Holocene salt mobilization has induced sedimentation that manifests itself in gravity slumps and slides and debris flows. An east-west–trending structural anticline located downdip of the salt-influenced region, was activated during the Atlas uplift (latest Cretaceous) and shaped much of the lower continental slope morphology from Tertiary time until present. The largest of the mass transport deposits (MTC) is a 500-m (1640-ft)-thick Cretaceous-age unit that spans an area of up to 20,000 km2 (7722 mi2). Seismic facies composing the MTC are (1) chaotic, mounded reflectors; (2) imbricated continuous to discontinuous folded reflector packages interpreted to represent internal syn-depositional thrusts; and (3) isolated, thick packages of continuous reflectors interpreted to represent transported megablocks (3.3 km2 [1.3 mi2]). The latter show well preserved internal stratigraphy. The MTCs originated from an upslope collapse of a narrow shelf during the earliest phases of the Alpine orogeny. Seismic geomorphologic analysis of the non-salt-deformed sections reveal numerous linear features that are interpreted as migrating Mesozoic-age deepmarine sediment waves. Three styles of sediment waves have been identified. These include: (1) type J1—small (less than 17 m thick) and poorly imaged, Jurassic in age, ridges that have wavelengths of up to 12 km and crest-to-crest separations of less than 1 km; (2) type K1—early Aptian constructional sediment waves (~110 m thick) that appear to show some orientation and size variations which suggest an influence on currents by salt-influenced seafloor topography, and (3) type K2—latest Albian and earliest post-Albian sediment waves exhibiting wave heights of 40 m and crest-to-crest separations of 1 km, that are continuous across the entire study area and show evidence of up-slope migration.

The lower continental slope of Morocco’s west coast consists of Triassic-age salt manifested in the form of diapirs, tongues, sheets, and canopies, and both extensional and compressional structures that result from salt movements. Salt diapirism and regional tectonics greatly influenced a broad spectrum of depositional processes along the margin. Mapping of a 1064-km2 (411-mi2) seismic survey acquired in the Safi Haute Mer area reveals that Jurassic to Holocene salt mobilization has induced sedimentation that manifests itself in gravity slumps and slides and debris flows. An east-west–trending structural anticline located downdip of the salt-influenced region, was activated during the Atlas uplift (latest Cretaceous) and shaped much of the lower continental slope morphology from Tertiary time until present. The largest of the mass transport deposits (MTC) is a 500-m (1640-ft)-thick Cretaceous-age unit that spans an area of up to 20,000 km2 (7722 mi2). Seismic facies composing the MTC are (1) chaotic, mounded reflectors; (2) imbricated continuous to discontinuous folded reflector packages interpreted to represent internal syn-depositional thrusts; and (3) isolated, thick packages of continuous reflectors interpreted to represent transported megablocks (3.3 km2 [1.3 mi2]). The latter show well preserved internal stratigraphy. The MTCs originated from an upslope collapse of a narrow shelf during the earliest phases of the Alpine orogeny. Seismic geomorphologic analysis of the non-salt-deformed sections reveal numerous linear features that are interpreted as migrating Mesozoic-age deepmarine sediment waves. Three styles of sediment waves have been identified. These include: (1) type J1—small (less than 17 m thick) and poorly imaged, Jurassic in age, ridges that have wavelengths of up to 12 km and crest-to-crest separations of less than 1 km; (2) type K1—early Aptian constructional sediment waves (~110 m thick) that appear to show some orientation and size variations which suggest an influence on currents by salt-influenced seafloor topography, and (3) type K2—latest Albian and earliest post-Albian sediment waves exhibiting wave heights of 40 m and crest-to-crest separations of 1 km, that are continuous across the entire study area and show evidence of up-slope migration.

The lower continental slope of Morocco’s west coast consists of Triassic-age salt manifested in the form of diapirs, tongues, sheets, and canopies, and both extensional and compressional structures that result from salt movements. Salt diapirism and regional tectonics greatly influenced a broad spectrum of depositional processes along the margin. Mapping of a 1064-km2 (411-mi2) seismic survey acquired in the Safi Haute Mer area reveals that Jurassic to Holocene salt mobilization has induced sedimentation that manifests itself in gravity slumps and slides and debris flows. An east-west–trending structural anticline located downdip of the salt-influenced region, was activated during the Atlas uplift (latest Cretaceous) and shaped much of the lower continental slope morphology from Tertiary time until present. The largest of the mass transport deposits (MTC) is a 500-m (1640-ft)-thick Cretaceous-age unit that spans an area of up to 20,000 km2 (7722 mi2). Seismic facies composing the MTC are (1) chaotic, mounded reflectors; (2) imbricated continuous to discontinuous folded reflector packages interpreted to represent internal syn-depositional thrusts; and (3) isolated, thick packages of continuous reflectors interpreted to represent transported megablocks (3.3 km2 [1.3 mi2]). The latter show well preserved internal stratigraphy. The MTCs originated from an upslope collapse of a narrow shelf during the earliest phases of the Alpine orogeny. Seismic geomorphologic analysis of the non-salt-deformed sections reveal numerous linear features that are interpreted as migrating Mesozoic-age deepmarine sediment waves. Three styles of sediment waves have been identified. These include: (1) type J1—small (less than 17 m thick) and poorly imaged, Jurassic in age, ridges that have wavelengths of up to 12 km and crest-to-crest separations of less than 1 km; (2) type K1—early Aptian constructional sediment waves (~110 m thick) that appear to show some orientation and size variations which suggest an influence on currents by salt-influenced seafloor topography, and (3) type K2—latest Albian and earliest post-Albian sediment waves exhibiting wave heights of 40 m and crest-to-crest separations of 1 km, that are continuous across the entire study area and show evidence of up-slope migration.

The lower continental slope of Morocco’s west coast consists of Triassic-age salt manifested in the form of diapirs, tongues, sheets, and canopies, and both extensional and compressional structures that result from salt movements. Salt diapirism and regional tectonics greatly influenced a broad spectrum of depositional processes along the margin. Mapping of a 1064-km2 (411-mi2) seismic survey acquired in the Safi Haute Mer area reveals that Jurassic to Holocene salt mobilization has induced sedimentation that manifests itself in gravity slumps and slides and debris flows. An east-west–trending structural anticline located downdip of the salt-influenced region, was activated during the Atlas uplift (latest Cretaceous) and shaped much of the lower continental slope morphology from Tertiary time until present. The largest of the mass transport deposits (MTC) is a 500-m (1640-ft)-thick Cretaceous-age unit that spans an area of up to 20,000 km2 (7722 mi2). Seismic facies composing the MTC are (1) chaotic, mounded reflectors; (2) imbricated continuous to discontinuous folded reflector packages interpreted to represent internal syn-depositional thrusts; and (3) isolated, thick packages of continuous reflectors interpreted to represent transported megablocks (3.3 km2 [1.3 mi2]). The latter show well preserved internal stratigraphy. The MTCs originated from an upslope collapse of a narrow shelf during the earliest phases of the Alpine orogeny. Seismic geomorphologic analysis of the non-salt-deformed sections reveal numerous linear features that are interpreted as migrating Mesozoic-age deepmarine sediment waves. Three styles of sediment waves have been identified. These include: (1) type J1—small (less than 17 m thick) and poorly imaged, Jurassic in age, ridges that have wavelengths of up to 12 km and crest-to-crest separations of less than 1 km; (2) type K1—early Aptian constructional sediment waves (~110 m thick) that appear to show some orientation and size variations which suggest an influence on currents by salt-influenced seafloor topography, and (3) type K2—latest Albian and earliest post-Albian sediment waves exhibiting wave heights of 40 m and crest-to-crest separations of 1 km, that are continuous across the entire study area and show evidence of up-slope migration.