This thesis investigates how benthic fluxes of phosphorus (P), nitrogen (N), and silicon (Si) change upon oxygenation of anoxic soft bottoms in the brackish, eutrophicated Baltic Sea. Direct measurements in situ by benthic landers demonstrated that fluxes of dissolved inorganic P (DIP) from anoxic bottom sediments in the Eastern Gotland Basin are higher than previously thought (Paper I). It is argued that the benthic DIP flux has a much larger influence on the DIP inventory in the Baltic proper than the external sources. Similarly, benthic fluxes of DIP and dissolved inorganic N (DIN) from anoxic sediment in the coastal Kanholmsfjärden Basin, Stockholm archipelago, were sufficiently high to renew the pools of these nutrients below the upper mixed layer in roughly one year (Paper II). A natural inflow of oxygen rich water into the deep, and previously long-term anoxic part of Kanholmsfjärden Basin, increased the P content in the sediment by 65% and lowered DIP and dissolved silica (DSi) concentrations in the pore water. These changes, as well as the large increases in benthic effluxes of these solutes following de-oxygenation of the bottom water, suggest that they are influenced similarly by changing oxygen conditions. Experimental results in papers III and IV show that common benthic macrofauna species in the Baltic Sea can stimulate benthic release of DIN and DSi, as well as dissolved organic and particulate bound nutrients. Thus, if benthic oxygen conditions would improve in the Baltic, initial effects on benthic–pelagic nutrient coupling will change due to animal colonisation of currently azoic soft bottoms. A new box corer was designed (Paper V) which can be used to obtain highly needed virtually undisturbed samples from soft bottom sediments – if lowered slowly and straight into the bottom strata – as demonstrated by in situ videography and turbidimetry. The commonly used USNEL box corer caused severe biasing during sediment collection. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 2: Manuscript. Paper 4: Manuscript. Paper 5: Manuscript.</p> / Baltic oxygenation project

Agricultural land use near streams frequently results in long-term disturbance to woody riparian vegetation and an alteration of reach scale geomorphic structure. Such disturbances often result in increased fine sediment input to the stream along with direct changes in channel structure. The study described here was designed to quantify stream geomorphic changes associated with agriculture and their influence on reach scale transient storage hydraulics and sediment biological function. Six small streams in the Appalachian Mountains of western North Carolina were selected to compare 3 reaches with active near-stream agriculture to 3 forested reference reaches. The study site categories differed significantly in many structural and hydraulic properties including slope, sinuosity, sediment size, and transient storage extent. However, differences cannot be attributed to land use alone. Distinct disparity in slope suggests that many of the categorical differences between stream types may also reflect valley scale structure. Despite these larger scale controls, the abundance of suspendable fines varied substantially among agricultural stream substrates, possibly due to varied land-use practices. Suspendable fine sediments and valley slope explained 91 % of variability in transient storage exchange, and abundance of inorganic fine sediments explained 77 % of variability in sediment microcosm nitrate production. This study supports conclusions that reach-scale influence of fine sediments occurred within the context of larger-scale valley structure, with implications on stream hydraulics and biogeochemistry. / Master of Science