This research involves design and implementation of computer program for simulation of a wastewater treatment plant. The program has the capability to be interfaced with an existing analog wastewater plant process flow training board which is equipped with meter readouts of key process variables and adjustable control valves. It is planned that the total system simulator could be used to train wastewater treatment plant operators to afford them hands-on dynamic experience in plant operations. The wastewater treatment process modeled is the activated sludge process. Beginning with the known plant design stead-state equations for this particular process an algorithm was developed to simulate the treatment process through probable system dynamics. All assumptions are presented in a logical manner and used to develop the necessary transient equations. The success of this project demonstrates that a simulation program which emulates a waste treatment process is possible; however, it is suggested that further research is needed to provide deeper insight into variable changes during system transients.

Design considerations and operating procedures were investigated for nitrogen removal in an extended aeration-denitrification facility. Both past and present removal efficiencies were evaluated for the facility, along with capital and operating cost data. The findings of this research indicate that at very long detention times, significant nitrification and denitrification occurred in the plant without the use of chemicals. Overall nitrogen, BOD5, and suspended solids removals were extremely high. The significance of this research is that future plants may achieve high rates of nitrogen removal through innovative design and operating procedures without the use of costly chemicals. However, capital costs needed to achieve longer detention items will have to be evaluated for the individual plant.

Land application of domestic wastewater effluent by rapid rate infiltration (i.e., percolation ponds) is a very successful and cost-effective method for wastewater management. Municipal percolation pond systems have been successfully operated in the United States for about 100 years. The disposal concept depends on a relatively high rate of secondary wastewater effluent infiltration into the soil by rapid percolation, either vertically or horizontally, away from the application surface area. This study was accomplished to determine infiltration rates at two working percolation pond systems and the variability of these rates, to compare the operating results with the initial design, and to create a stochastic computer based simulation program for design and operation. The initial study site was located west of Orlando, Florida, and consisted of a system of two percolation ponds. Daily readings were obtained on evaporation, rainfall, flow to the ponds, pond depth and groundwater table elevations. A mass balance inventory equation was formulated and the infiltration parameter was determined. A frequency distribution was created for the rainfall, evaporation and calculated infiltration from the initial site, and then a stochastic computer based simulation program was written with this data. The program calculated results which compared favorably with the design for this initial percolation pond site. A second site was chosen, also located in the Orlando area, to confirm the usefulness of the program and its operational capabilities.

No description available.

Utilization of the activated sludge process is widespread although many of the mechanisms that make it work are still relatively misunderstood. Recent studies have indicated that dual substrate limitations may occur in the process. Several misconceptions in the basic fundamentals regarding the rates and mechanisms involved in oxygen transfer to wastewater systems also exist. This research investigation examined the effects of the mean cell residence time and wastewater stoichiometry on the operation of the completely mixed activated sludge process under a dual substrate limitation. At low mean cell residence times (θ_c) the system was growth C limited with respect to carbon and at high mean cell residence times the system was oxygen limited. Oxygen transfer studies were conducted to ascertain the relationship between the steady state oxygen transfer coefficient (K_La) and the oxygen uptake rate of the mixed liquor (R). The objectives of this research were accomplished by operating two continuous flow bench scale activated sludge units at COD:TKN ratios of 6.07:1 and 0.65:1. Reactor-1 was operated at a COD:TKN = 6.07:1 and was always growth limited with respect to organic carbon while Reactor-2 was operated at a COD:TKN = 0.65:1 and was carbon limited at low mean cell residence times and oxygen limited at high θ_c values. Mean cell residence time served as the primary control parameter during the laboratory studies and was varied form approximately 2.5 to 21.0 days. Theoretical studies were also conducted in which biokinetic and stoichiometric equations were used to develop a model to simulate the process operating under carbon and oxygen limitations. The model was found to yield results that were similar to the actual experimental data collected. Further refinement of the model by including inhibition functions would result in a model with better predictability. Examination of the experimental data collected during the laboratory study revealed several interesting conclusions. Operation of the activated sludge process at a low COD:TKN ratio (0.65:1) and under an oxygen limitation at high mean cell residence times can result in high levels of free ammonia and nitrite that will lead to a deterioration in effluent quality. Increased removal efficiencies for COD, TKN and NH₃-N can be achieved by operating the process at a high COD:TKN ratio (6.07:1). Steady state oxygen transfer coefficients determined in the mixed liquor of the reactors indicated there was a direct relationship to the oxygen uptake rate of the activated sludge (R). This observation is quite significant since standard aeration theory states that K_La is constant for a given aeration device. Nonsteady state K_La values determined on the effluent from each reactor indicated that K_La was a constant. Alpha and beta coefficients determined from nonsteady state tests on wastewater effluent from each reactor showed no trend with the mean cell residence time. / Ph. D.

This study compared the sludge characteristics of a lab-scale Air Products (A/O) and a conventional activated sludge system. The sludges were analyzed for operational properties and the exocellular biopolymers of each sludge was characterized. Operational analysis mainly consisted of measurements of settling (SVI) and dewatering (specific resistance, CST) parameters at each sludge age. Biopolymers were measured using pH extraction followed by gel filtration and subsequent analysis for carbohydrate and protein concentrations. The results showed a high degree of similarity between the two systems both operationally and with respect to biopolymer characteristics. The A/0 system did produce a lower effluent soluble COD at sludge ages below 5 days. Also, the A/O system showed some consistent differences in the distribution of bound and unbound fractions of protein and carbohydrate ECP but these had no discernible· effect on sludge operational characteristics. In addition relationships between unbound ECP and effluent BOD, bound HMW ECP and SVI, and phosphorus and Mg uptake were observed, with varying degrees of consistency, in this study. / Master of Science

Experiments were performed on samples of alum, anaerobically digested, and aerobically digested sludges to determine optimum polymer dosages for various mixing intensities produced during conditioning by a high-stress mixing unit. Mean velocity gradient (G) values were established for each of the mixing speeds used ranging from 250 sec-1 to 4,000 sec-1. Using the optimum conditioning dosages determined each mixing speed, batches of optimally, conditioned sludge were introduced into a pilot scale plate and frame filter press. Filtrate volume per unit time and final cake solids were used to characterize the press performance. Results indicated that filter press, performance can be optimized by selecting mixing. speeds during conditioning that simulate the shear conditions produced in the filter press during operation. It was shown that press performance was substantially reduced using sludge conditioned at a mixing speed of 200 rpm, corresponding to a Gt equal to 17,000. Tests using mixing speeds of 400 rpm and 1800 rpm corresponding to Gt values of 32,000 and 230,000, respectively indicated better performance and, thus, the filter press is thought to generate Gt values within this range. A substantial increase in polymer requirements is shown for sludge conditioned at a mixing speed of 1800 rpm, and therefore, it was concluded that sludge conditioned at mixing speed of 400 rpm best characterized the filter press producing optimum operational conditions. It was also postulated that the filter press may not be characterized by a single Gt value, but, by a range of values dependent on press run time. / Master of Science

A study of the anaerobically digested sludge form a full-scale biological phosphorus removal (BPR) plant (York River Wastewater Treatment Plant, York River, Va.) was conducted to determine the effects of BPR on sludge characteristics and conditioning requirements. Data collected from the plant indicated that both the total and soluble phosphorus (P) concentrations in the anaerobically digested sludge increased dramatically with the initiation of BPR. Accompanying this increase in total P was an increase in the total concentrations of magnesium and potassium content of the sludge, supporting the observations that these ions are co-transported with P during the accumulation and release of P by P accumulating organisms. The majority of the phosphate present in the pre- and post- BPR anaerobically digested sludges was bound by calcium, magnesium, and iron phosphorus precipitates including hydroxyapatite, struvite, and vivianite. Calcium phosphorus precipitates were the most prevalent in both sludges, but the percentage of magnesium phosphorus precipitates increased with the onset of BPR. Cationic organic polymer conditioning dosages needed to achieve acceptable sludge dewatering rates for the post-BPR sludge were similar to those required by the pre-BPR sludge. The cationic organic polymer used to condition these sludges was ineffective in removing excess phosphate; therefore, the addition of either one or both of the inorganic chemicals ferric chloride and calcium hydroxide was required to remove soluble phosphorus. Conditioning with either ferric chloride or calcium hydroxide alone was not effective in achieving acceptable dewatering rates; however, when used together the chemicals produced acceptable dewatering rates and soluble P removal from the post-BPR sludge. / Master of Science

The dewatering characteristics of sludges produced by water and wastewater treatment plants bear heavily on the methods chosen to treat and dispose of the sludge, as well as on the costs associated with handling the large volumes of sludge produced at these facilities. This study investigated why different sludges dewater to different dry solids concentrations, how sludge structure affects dewatering, and how sludge structure changes during gravity thickening and during different types of mechanical dewatering. It is generally thought that sludge can be described as having a three-tiered structure: (1) primary particles, (2) floc particles, and (3) aggregate particles. To investigate sludge structure in relation to sludge dewatering, this study has defined sludge structure using several sludge particle micro properties. A laboratory technique incorporating isopycnic centrifugation in gradients of Percoll^R media was developed to measure one micro property known as floc particle density. Six field and laboratory sludges were subjected to a series of dewatering tests: gravity thickening, centrifugation, and vacuum filtration. Each sludge was analyzed for macro- and micro properties through each stage of dewatering. It was concluded that improvements in thickening and dewatering characteristics were heavily dependent upon increases in sludge floc density and decreases in aggregate water content. / Master of Science

Treatability studies were performed on oily wastewaters produced by petroleum and canning industries. Chlorine dioxide was used for the removal of phenolic compounds from these oily wastewaters. Most of phenolic compounds can be destroyed by chlorine dioxide within 15 minutes if CI02-to-phenol ratios of higher than 5.0 are provided. Factors such as pH, temperature, and COD have little effect on phenol removal. The effectiveness of chlorine dioxide treatment depends critically on the performance of the chlorine dioxide generator. High yields of chlorine dioxide generation can be achieved by maintaining the pH between 2.5 and 3.5, and by controlling the concentration of feed chemicals. For small treatment plants, chlorine dioxide treatment may be an economical process because no expensive equipment is required. / Master of Science