This thesis addresses the tensile capacity and load-deflection behavior of wedge-type expansion and undercut anchors in concrete affected by alkali-silica reaction (ASR). ASR is a chemical reaction that occurs between alkalis in the cement and silica in the aggregates. The reaction occurs with the presence of moisture, forming a gel which expands and causes micro-cracking in the concrete. Researchers conducted 85 static unconfined tensile tests on control and ASR-affected specimens. The results indicate that anchors in concrete cracked due to ASR perform like anchors in concrete cracked due to other mechanisms. Up to a threshold value of the Comprehensive Crack Index (CCI) of at least 1.5 mm/m, all cracking, regardless of cause, has the same effect on the tensile breakout capacity of mechanical and undercut anchors. / text

Although concrete is widely considered a very durable material, if conditions are such, it can be vulnerable to deterioration and early distress development. Alkali-Silica Reaction (ASR) is a major durability problem in concrete structures. It is a chemical reaction between the reactive silica existent in some types of rocks and alkali hydroxides in the concrete pore water. The product of this reaction is a gel that is hygroscopic in nature. When the gel absorbs moisture, it swells leading to tensile stresses in concrete. When those stresses exceed the tensile strength of concrete, cracks occur. The main objective of this study was to address a method of testing concrete materials as a combination to assist engineers to effectively mitigate ASR in concrete. The research approach involved capturing the combined effects of concrete materials (water cement ratio, porosity, supplementary cementitious materials, etc.) through a method of testing to allow the formulation of mixture combinations resistant to ASR leading to an increase in the life span of concrete structures. To achieve this objective, a comprehensive study on different types of aggregates of different reactivity was conducted to formulate a robust approach that takes into account the factors affecting ASR; such as, temperature, moisture, calcium concentration and alkalinity. A kinetic model was proposed to determine aggregate ASR characteristics which were calculated using the System Identification Method. Analysis of the results validates that ASR is a thermally activated process and therefore, the reactivity of an aggregate can be characterized in terms of its activation energy (Ea) using the Arrhenius equation. Statistical analysis was conducted to determine that the test protocol is highly repeatable and reliable. To relate the effect of material combinations to field performance, concrete samples with different w/cm?s and fly ash contents using selective aggregates were tested at different alkalinities. To combine aggregate and concrete characteristics, two models were proposed and combined. The first model predicts the Ea of the aggregate at levels of alkalinity similar to field conditions. The second model, generated using the Juarez- Badillo transform, connects the ultimate expansion of the concrete and aggregate, the water cement ratio, and the fly ash content to the Ea of the rock. The proposed models were validated through laboratory tests. To develop concrete mixtures highly resistant to ASR, a sequence of steps to determine threshold total alkali in concrete were presented with examples. It is expected that the knowledge gained through this work will assist government agencies, contractors, and material engineers, to select the optimum mixture combinations that fits best their needs or type of applications, and predict their effects on the concrete performance in the field.

<p>Microorganisms inhabiting silica solute-rich environments often show various degrees of Si02 mineralization as a consequence of exposure to SiOrsaturated waters. As such, it has been thought that microorganisms exert a prominent role in the immobilization of amorphous silica phases. While this intimate spatial relationship of microorganisms and amorphous Si02 phases are almost always observed in hot springs, the exact mechanisms by which microbes affect Si02 secondary mineral precipitation is still poorly understood. Further, available laboratory investigations to date consistently showed that microbes do not significantly impact Si02 immobilization, suggesting that microbial silicification is a mere consequence of exposure to a largely abiogenically-driven Si02 precipitation. </p> <p>This study demonstrates that discernible microbially-mediated silicification can occur under conditions where the potential for microbial opportunity to biomineralize is promoted. Identification of the key geochemical requirements for biosilicification to occur include thermodynamically favorable, but sluggish silica reaction kinetics associated with acidic conditions, and the necessity for colloidal silica rather than dissolved silicic acid species. This work provides the first results to bridge the apparent literature discrepancy between widespread, in-situ observations of microbial silicification, and the inability to demonstrate a detectable microbial effect in this process under well-constrained laboratory conditions.</p> <p>Acid conditions promote microbial silicification by overriding the dominant repulsive forces arising from charge similarities between Si02 and cell surfaces, via neutralization of deprotonated surface silanol and carboxylic groups, respectively. Mechanistic consideration for Si02 coordination to cell surfaces suggests direct chemical bonding of silanol to carboxylic groups forming stable inner-sphere complexes largely insensitive to environmental perturbations. This result indicates that microbially immobilized Si02 are more tenaciously-coordinated on cell surfaces and not simply electrostatically-held.</p> <p>Surface-dependent silicification showed higher Si02 mineralization propensities for unmineralized microbial cells compared to silica-encrusted cell matrices. Moreover, the extent and style of microbial Si02 mineralization is impacted by cellular level of metabolic activity. These results suggest that a biological overlay may be discernible in microbially induced biosilicification. </p> / Thesis / Doctor of Philosophy (PhD)

The undesirable expansion of concrete because of a reaction between alkalis and certain type of reactive siliceous aggregates, known as alkali-silica reactivity (ASR), continues to be a major problem across the entire world. The renewed interest to minimize distress resulting from ASR has emphasized the need to develop predictable modeling of concrete ASR behavior under field conditions. Current test methods are either incapable or need long testing periods in which to only offer rather limited predictive estimates of ASR behavior in a narrow and impractical band of field conditions. Therefore, an attempt has been made to formulate a robust performance approach based upon basic properties of aggregate and concrete ASR materials derived from dilatometry and a kinetic-based mathematical expressions for ASR behavior. Because ASR is largely an alkali as well as a thermally activated process, the use of rate theory (an Arrhenius relationship between temperature and the alkali solution concentration) on the dilatometer time-expansion relationship, provides a fundamental aggregate ASR material property known as “activation energy.” Activation energy is an indicator of aggregate reactivity which is a function of alkalinity, particle size, crystallinity, calcium concentration, and others. The studied concrete ASR material properties represent a combined effects of mixture related properties (e.g., water-cementitious ratio, porosity, presence of supplementary cementitious materials, etc.) and maturity. Therefore, the proposed performance-based approach provides a direct accountability for a variety of factors that affect ASR, such as aggregate reactivity (activation energy), temperature, moisture, calcium concentration, solution alkalinity, and water-cementitious material ratio. Based on the experimental results, the following conclusion can be drawn concerning the performance-based approach to evaluate ASR potential of aggregate and concrete using dilatometer method; (i) the concept of activation energy can be used to represent the reactivity of aggregate subjected to ASR, (ii) the activation energy depends on the reactivity of aggregate and phenomenological alkalinity of test solution, and (iii) The proposed performance-based model provides a means to predict ASR expansion development in concrete.

Alkali silica reaction (ASR), a reaction which occurs between reactive siliceous mineral components in the aggregate and the alkaline pore solution in concrete, is responsible for substantial damage to concrete structures in the U. S. and across the world. Lithium admixtures, including lithium nitrate (LiNO3), have been demonstrated to mitigate ASR damage, and are of particular interest for use in concrete airfield pavement construction, where ASR damage has been recently linked to the use of certain de-icing chemicals. Although the effectiveness of lithium admixtures at ASR-mitigation is well-researched, relatively less is known regarding the potential effects, including negative effects, on overall concrete behavior. The goal of this research is to better understand the influence of LiNO3 admixture on early age concrete behavior, and to determine if a maximum dosage rate for its use exists. Isothermal calorimetry, rheology and bleed water testing, time of setting, chemical shrinkage, autogenous shrinkage, free and restrained concrete shrinkage, and compressive and flexural strength were measured for pastes and concretes prepared with a range of LiNO3 dosages (i.e., 0, 50, 100, 200, and 400% of the recommended dosage). In addition, the interaction of LiNO3 with cement was evaluated by comparing results obtained with six cements of varying alkali and tricalcium aluminate (C3A) contents. Additionally, one of these cements, was examined alone and with 20% by weight Class F fly ash replacement. Results indicate that the hydration of the tricalcium silicate and tricalcium aluminate components of cement are accelerated by the use of LiNO3, and that low alkali cements (typically specified to avoid damage by ASR) may be particularly susceptible to this acceleration. However, inclusion of Class F fly ash at 20% by weight replacement of cement (also common in applications where ASR is a concern) appears to diminish these possibly negative effects of LiNO3 on early age hydration acceleration and heat generation. Dosages higher than the current standard dosage of LiNO3 may have minor effects on fresh concrete workability, causing slight decreases in Bingham yield stress, corresponding to slightly higher slump. Fresh concrete viscosity may also be affected, though more research is necessary to confirm this effect. LiNO3 had no effect on quantity of bleed water in the mixes tested. Generally, LiNO3 had no effect on initial and final setting times, although increasing dosages caused faster set times in the lowest alkali (Na2Oeq = 0.295%) cement examined. In shrinkage testing, higher LiNO3 dosages appeared to cause initial expansion in some sealed paste specimens, but in all cases the highest dosage led to greater autogenous shrinkage after 40 days. In concrete specimens, however, the restraining effect of aggregates diminished shrinkage, and no effect of the LiNO3 was apparent. In no cases, with any dosage of lithium tested, with or without fly ash replacement, did restrained shrinkage specimens show any cracking. Strength testing produced mixed results, with laboratory specimens increasing in 28-day compressive strength, but companion specimens cast in the field and tested by an outside laboratory, exhibited lower 28-day compressive strength, with increasing lithium dosages. Flexural specimens, also cast in the field and tested by an outside laboratory, appeared to show an increase in 28-day flexural strength with increasing lithium dosages. However, because of the conflicting results when comparing the various strength data, further research is necessary for conclusive evidence of LiNO3 effects on concrete strength.

The undesirable expansion of concrete because of a reaction between alkalis and certain type of reactive siliceous aggregates, known as alkali-silica reactivity (ASR), continues to be a major problem across the entire world. The renewed interest to minimize distress resulting from ASR has emphasized the need to develop predictable modeling of concrete ASR behavior under field conditions. Current test methods are either incapable or need long testing periods in which to only offer rather limited predictive estimates of ASR behavior in a narrow and impractical band of field conditions. Therefore, an attempt has been made to formulate a robust performance approach based upon basic properties of aggregate and concrete ASR materials derived from dilatometry and a kinetic-based mathematical expressions for ASR behavior. Because ASR is largely an alkali as well as a thermally activated process, the use of rate theory (an Arrhenius relationship between temperature and the alkali solution concentration) on the dilatometer time-expansion relationship, provides a fundamental aggregate ASR material property known as “activation energy.” Activation energy is an indicator of aggregate reactivity which is a function of alkalinity, particle size, crystallinity, calcium concentration, and others. The studied concrete ASR material properties represent a combined effects of mixture related properties (e.g., water-cementitious ratio, porosity, presence of supplementary cementitious materials, etc.) and maturity. Therefore, the proposed performance-based approach provides a direct accountability for a variety of factors that affect ASR, such as aggregate reactivity (activation energy), temperature, moisture, calcium concentration, solution alkalinity, and water-cementitious material ratio. Based on the experimental results, the following conclusion can be drawn concerning the performance-based approach to evaluate ASR potential of aggregate and concrete using dilatometer method; (i) the concept of activation energy can be used to represent the reactivity of aggregate subjected to ASR, (ii) the activation energy depends on the reactivity of aggregate and phenomenological alkalinity of test solution, and (iii) The proposed performance-based model provides a means to predict ASR expansion development in concrete.

The effects of using alkali-silica reaction (ASR) affected recycled concrete aggregate (ASR-RCA) in hot mix asphalt (HMA) were investigated in this study. Dilatometer and modified beam tests were performed to determine the possibility of new ASR occurring in reactive aggregates within the HMA or re-expansion of existing gel. The Lottman test and micro-calorimeter were used to determine the moisture susceptibility of HMA made with ASR-RCA. A differential scanning calorimeter (DSC) with thermogravimetric analysis (TGA) was used to evaluate the drying of an artificial gel and x-ray diffraction (XRD) was used to check for the potential presence of gel in the filler fraction of the ASR-RCAs. Micro-deval and freeze-thaw tests were evaluated for their potential to indicate the presence of excess micro-cracks or ASR gel. Expansion testing indicated that both ASR-RCAs were still reactive with 0.5 N NaOH solution saturated with calcium hydroxide (CH) at 60 degrees C. Dilatometer testing of HMA specimens in NaOH CH solution at 60 degrees C indicated a reaction between the asphalt binder and the solution, but little, if any, ASR. The lack of expansion in the modified beam test supports the binder-solution interaction. However, dilatometer testing in deicer solution at the same temperature indicated that some ASR may have occurred along with the primary binder-solution interaction. The volume change characteristics associated with the binder-solution interaction with and without ASR was supported by the change in pH and alkali concentration of the test solution. DSC/TGA testing indicated that the artificial gel dehydrated at approximately 100 degrees C. XRD analysis of the filler indicated that some gel may have accumulated in this fraction. Moisture damage testing indicated good resistance to moisture damage by HMA mixtures made with ASR-RCA especially compared to a virgin siliceous aggregate. Micro-deval and freeze-thaw tests can detect the presence of micro-cracks due to ASR in ASR-RCAs as higher mass loss than the virgin aggregate. The potential distress mechanisms that may occur when using ASR-RCA in an HMA pavement were identified. Results obtained using accelerated laboratory conditions were extrapolated based on anticipated field conditions. Guidelines for the mitigation of potential distresses in HMA made with ASR-RCA are presented.

Fly ash has been used extensively to control deleterious alkali-silica reaction in concrete. The majority of fly ashes can be used to control ASR induced expansion. Fly ashes with high CaO contents are less effective at reducing expansion and fly ashes with high alkali contents can be counter active. Class C fly ashes are less effective at reducing the pH of the pore solution because they are less pozzolanic. The pozzolanic reaction in Class F fly ashes enhances the ability for the hydration products to bind alkalis. This prevents the availability of these alkalis for ASR. This project aims to characterize fly ash in a way that best predicts how it will perform in concrete with an emphasis on ASR. Fly ashes with a variety of chemical compositions were evaluated using a range of analytical and characterization techniques. Research data from several universities were used to correlate their long term data with this project’s accelerated tests. This research aimed at evaluating the mineralogical, chemical, and physical characteristics that most affect the ability of a given fly ash to prevent ASR-induced expansion and cracking. / text

Alkali-silica reaction (ASR) and delayed ettringite formation (DEF) deterioration have been a problem for the concrete infrastructure in the state of Texas and around the world in recent decades. A great deal of research into the causes and mechanisms of the deterioration has helped to prevent the formation of ASR and DEF in new construction, but the evaluation and maintenance of existing structures remains a problem. The goal of this research is to investigate the use of several nondestructive testing (NDT) methods to evaluate the level of ASR and DEF deterioration in a structural element. Based on the results, recommendations are made as to which NDT methods have the most potential to be incorporated into the evaluation process. / text

Fly Ash was tested in relation to its ability to mitigate alkali-silica reaction, its contribution to strength, electrical resistance and heat release with the aim of recommending improvements to fly ash specifications. ASTM C 1567 accelerated mortar bar test results were in agreement with an expansion limit of 0.10 % at 14 days. A non-standard alkali leaching test showed that with high alkali fly ashes as replacement level increases the amount of alkalis leached increases while prism expansions decrease. Measures of pozzolanic activity can be improved by measuring against non-pozzolanic fillers, This requires high replacement levels to reduce statistical variability. Isothermal calorimetry tests showed that high calcium fly ashes can lead to delays in hydration, these delays can be reduced by calcium hydroxide additions. Calcium sulphate additions can also improve hydration.