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The measurement of phosphorus which is available to plants is a problem closely related to the forms and amounts of phosphorus present in soils. The fractionation of soil phosphorus, based on a series of extractions, is a procedure that has been utilized by many investigators. In this study, this scheme was utilized in an attempt to improve and evaluate the effectiveness of some methods employed in the measurement of available phosphorus to plants. / Ph. D.

Lai, Yuk Fo. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2007. / Includes bibliographical references (leaves 169-191). / Abstracts in English and Chinese. / Abstract --- p.i / Abstract (in Chinese) --- p.iv / Dedication --- p.v / Acknowledgement --- p.vi / Table of contents --- p.viii / List of tables --- p.xii / List of figures --- p.xiii / List of plates --- p.xv / List of symbols and abbreviations --- p.xvi / Chapter Chapter One --- Introduction / Chapter 1.1 --- Introduction --- p.1 / Chapter 1.2 --- Research background --- p.1 / Chapter 1.2.1 --- Wetlands and water quality --- p.1 / Chapter 1.2.2 --- The role of sediments in eutrophication control --- p.3 / Chapter 1.2.3 --- Wetlands in ecological mitigation --- p.4 / Chapter 1.2.4 --- Previous studies of wetland pollution in Hong Kong --- p.6 / Chapter 1.3 --- Conceptual framework --- p.8 / Chapter 1.4 --- Objectives of the study --- p.12 / Chapter 1.5 --- Significance of study --- p.13 / Chapter 1.6 --- Organization of the thesis --- p.14 / Chapter Chapter Two --- Literature Review / Chapter 2.1 --- Introduction --- p.15 / Chapter 2.2 --- Quantification of phosphorus retention in wetlands --- p.16 / Chapter 2.2.1 --- Input-output concentration approach --- p.16 / Chapter 2.2.2 --- Mass balance approach --- p.18 / Chapter 2.2.3 --- Phosphorus removal efficiency --- p.19 / Chapter 2.3 --- Phosphorus sorption by wetland sediments --- p.20 / Chapter 2.3.1 --- Sorption and its significance --- p.20 / Chapter 2.3.2 --- Phosphorus sorption maxima --- p.22 / Chapter 2.3.3 --- Adsorption-desorption equilibrium --- p.23 / Chapter 2.3.4 --- Phosphorus sorption kinetics --- p.24 / Chapter 2.4 --- Phosphorus exchange across the sediment-water interface --- p.24 / Chapter 2.4.1 --- Phosphorus mobilization and transport mechanisms --- p.25 / Chapter 2.4.2 --- Phosphorus flux from aquatic sediments --- p.26 / Chapter 2.5 --- Phosphorus fractionation in wetland sediments --- p.29 / Chapter 2.5.1 --- Major sediment phosphorus fractions --- p.29 / Chapter 2.5.2 --- Phosphorus fractionation methods --- p.30 / Chapter 2.5.3 --- Relationships between phosphorus fractions and bioavailability . --- p.32 / Chapter 2.6 --- Factors affecting sediment-water phosphorus exchange --- p.33 / Chapter 2.6.1 --- pH --- p.34 / Chapter 2.6.2 --- Redox potential --- p.34 / Chapter 2.6.3 --- Temperature --- p.35 / Chapter 2.6.4 --- Salinity --- p.35 / Chapter 2.6.5 --- Sediment properties --- p.36 / Chapter Chapter Three --- Methodology / Chapter 3.1 --- Overall study approach --- p.38 / Chapter 3.2 --- Geographical setting of Hong Kong --- p.41 / Chapter 3.2.1 --- Climate --- p.42 / Chapter 3.2.2 --- Geology and landform --- p.44 / Chapter 3.2.3 --- Soil --- p.45 / Chapter 3.2.4 --- Vegetation --- p.45 / Chapter 3.3 --- Study sites --- p.46 / Chapter 3.3.1 --- Site selection --- p.46 / Chapter 3.3.2 --- Site description --- p.48 / Chapter 3.3.2.1 --- The Hong Kong Wetland Park --- p.48 / Chapter 3.3.2.2 --- Mai Po Marshes Nature Reserve --- p.50 / Chapter 3.4 --- Sampling strategy --- p.53 / Chapter 3.4.1 --- Sampling locations --- p.53 / Chapter 3.4.2 --- Sampling dates --- p.57 / Chapter 3.4.3 --- Sample collection and treatment --- p.58 / Chapter 3.5 --- Sample analysis --- p.60 / Chapter 3.5.1 --- Analysis of sediment samples --- p.61 / Chapter 3.5.1.1 --- Sediment texture --- p.61 / Chapter 3.5.1.2 --- Sediment pH --- p.61 / Chapter 3.5.1.3 --- Redox potential --- p.61 / Chapter 3.5.1.4 --- Sediment moisture --- p.62 / Chapter 3.5.1.5 --- Organic matter --- p.62 / Chapter 3.5.1.6 --- Total Kjeldahl nitrogen --- p.63 / Chapter 3.5.1.7 --- "Total Fe, Al, and P" --- p.63 / Chapter 3.5.1.8 --- "Oxalate-extractable Fe, Al, and P" --- p.63 / Chapter 3.5.2 --- Analysis of water samples --- p.64 / Chapter 3.5.2.1 --- "Water pH, conductivity, salinity, turbidity, temperature and DO" --- p.64 / Chapter 3.5.2.2 --- Orthophosphate --- p.64 / Chapter 3.5.2.3 --- Total nitrogen and phosphorus --- p.65 / Chapter 3.5.3 --- Determination of phosphorus exchange characteristics --- p.65 / Chapter 3.6 --- Statistical analysis --- p.65 / Chapter Chapter Four --- Phosphorus Fractionation in Wetland Sediments in Hong Kong / Chapter 4.1 --- Introduction --- p.67 / Chapter 4.2 --- Methodology --- p.68 / Chapter 4.2.1 --- Sample collection and analysis --- p.68 / Chapter 4.2.2 --- Phosphorus fractionation --- p.69 / Chapter 4.2.3 --- Statistical analysis --- p.72 / Chapter 4.3 --- Results and discussion --- p.72 / Chapter 4.3.1 --- Physico-chemical properties of sediments --- p.72 / Chapter 4.3.2 --- Physico-chemical properties of overlying water --- p.78 / Chapter 4.3.3 --- Phosphorus fractionation in sediments --- p.82 / Chapter 4.3.3.1 --- Phosphorus fractions in sediments of the Hong Kong Wetland Park --- p.82 / Chapter 4.3.3.2 --- Phosphorus fractions in sediments of the Mai Po Marshes --- p.89 / Chapter 4.3.3.3 --- Phosphorus fractions in relation to mobility and bioavailability --- p.96 / Chapter 4.4 --- Conclusions --- p.100 / Chapter Chapter Five --- Phosphorus Sorption by Wetland Sediments in Hong Kong / Chapter 5.1 --- Introduction --- p.103 / Chapter 5.2 --- Methodology --- p.104 / Chapter 5.2.1 --- Sample collection and analysis --- p.104 / Chapter 5.2.2 --- Batch incubation experiments --- p.105 / Chapter 5.2.3 --- Sorption kinetics --- p.106 / Chapter 5.2.4 --- Effects of selected environmental factors on phosphorus sorption --- p.106 / Chapter 5.2.5 --- Estimation of sorption parameters --- p.107 / Chapter 5.2.6 --- Statistical analysis --- p.109 / Chapter 5.3 --- Results and discussion --- p.109 / Chapter 5.3.1 --- Phosphorus sorption parameters of wetland sediments --- p.109 / Chapter 5.3.1.1 --- Phosphorus adsorption isotherms --- p.109 / Chapter 5.3.1.2 --- The role of sediments in phosphate buffering --- p.116 / Chapter 5.3.1.3 --- Relationships between phosphorus sorption parameters and physico-chemical properties of sediments --- p.121 / Chapter 5.3.2 --- Kinetics of phosphorus adsorption --- p.124 / Chapter 5.3.3 --- Effects of environmental factors on phosphorus sorption --- p.128 / Chapter 5.3.3.1 --- Effects of pH --- p.128 / Chapter 5.3.3.2 --- Effects of salinity --- p.131 / Chapter 5.3.3.3 --- Effects of temperature --- p.133 / Chapter 5.4 --- Conclusions --- p.136 / Chapter Chapter Six --- Phosphorus Flux from Wetland Sediments in Hong Kong / Chapter 6.1 --- Introduction --- p.139 / Chapter 6.2 --- Methodology --- p.140 / Chapter 6.2.1 --- Sample collection and analysis --- p.140 / Chapter 6.2.2 --- Core incubation experiments --- p.141 / Chapter 6.2.3 --- Estimation of phosphorus flux --- p.142 / Chapter 6.2.4 --- Statistical analysis --- p.142 / Chapter 6.3 --- Results and discussion --- p.143 / Chapter 6.3.1 --- Phosphorus flux from wetland sediments --- p.143 / Chapter 6.3.1.1 --- Phosphorus flux from sediments in the Hong Kong Wetland Park --- p.143 / Chapter 6.3.1.2 --- Phosphorus flux from sediments in the Mai Po Marshes --- p.147 / Chapter 6.3.2 --- Effects of redox conditions on sediment phosphorus flux --- p.152 / Chapter 6.4 --- Conclusions --- p.156 / Chapter Chapter Seven --- Conclusion / Chapter 7.1 --- Introduction --- p.159 / Chapter 7.2 --- Summary of major findings --- p.159 / Chapter 7.3 --- Limitations of study --- p.166 / Chapter 7.4 --- Suggestions for future study --- p.166 / References --- p.169

Call number: LD2668 .T4 1984 G73 / Master of Science

Call number: LD2668 .T4 1984 M93 / Master of Science

Call number: LD2668 .T4 1966 N562 / Master of Science

Modern urban stormwater infrastructure includes vegetated bioretention facilities (BRFs) that are designed to detain water and pollutants. Phosphorus (P) is a pollutant in stormwater which can be retained in BRF soils in mineral, plant, and microbial pools. We explored soil properties and phosphorus forms in the soils of 16 operational BRFs in Portland, OR. Since soil hydrology can significantly impact P retention, we selected BRFs along an infiltration rate (IR) gradient. We conducted sequential fractionation and tests of P pools and measured P release in a subset of soils after drying and flooding samples for ten days. We hypothesized that mineral or organic soil P forms would be correlated with IR, and that vulnerability to P release would depend on the interaction of drying and flooding treatments with P forms and pools. IR did not significantly explain differences in P forms. Soil TP was elevated across all sites, compared with TP in agriculturally-impacted wetlands and was substantially composed of soil organic matter (OM)-associated P. Phosphorus sorbed to mineral Fe and Al oxides- was variable but positively correlated with water-extractable P. The concentration gradient of water-extractable P was primarily controlled by overall P pools. Experimentally induced P releases were seen in 5 of 6 soils exposed to drying conditions, presumably released through microbial mineralization of OM. Only one site showed significant P release following the flooding treatment. Our measurements supported the idea that Fe and Al oxides provide P sorption capacity in these BRF soils. Variable inputs of P to BRFs through stormwater and litterfall may contribute to variability in P profiles and P release vulnerability across sites. Design specifications and management decisions relating to bioretention soils (e.g. establishment of acceptable soil test P levels, focusing on P forms known to influence vulnerability of P release) may benefit from detailed biogeochemical investigations.

Thesis (MSc. Agriculture (Soil Science)) -- University of Limpopo, 2014 / Phosphorus (P) runoff from agricultural sites and the subsequent loading into surface water bodies contribute to eutrophication. Environmental concerns associated with P loading in soil have motivated the need for the development of a proper tool that will allow farmers to identify agricultural areas or management practices that have the greatest potential to accelerate eutrophication. The objective of the study was to determine the spatial variability of soil test P, soil loss potential of the farm, P application rate and methods, and map P runoff risk across the field. This study was conducted in Vierfontein Boerdery in Kriel, Mpumalanga province, South Africa (longitude 29.11258833 and latitude -26.27104340). The field was under dryland cultivation and planted to yellow maize that was rotated with soybeans. Soil samples were taken at georeferenced locations in a 100 x 100 m grid for soil analysis. Spatial layers of soil P distribution, soil loss potential as well as application rate and method were created in ArcGIS software. These layers were used as input factors in a P index model to identify areas in the farm that are vulnerable to P runoff. Results indicated a variation in soil test P. Although soil test P variation was not statistically different at P≤0.05, variation had both agronomic and environmental implications. This variation could be attributed to differences in site-specific conditions and management practices. Furthermore, soil loss potential across the study site predicted by the Revised Universal Soil Loss Equation (RUSLE) showed variation with a range of 3-15 tons/ha/yr. This variation was attributed to differences in topographic variations in the study site. There is a need for best management practices that control soil erosion to minimize P runoff into water bodies. KEYWORDS: Eutrophication, Geographic Information System, Phosphorus best management practises, Phosphorus runoff index, Soil erosion, Site-specific management.

"September 2001" Includes bibliographical references (leaves 206-230)