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The effects of doping Sb on properties of CuInSe2 thin-film solar cellsWu, Wan-Ling 25 July 2001 (has links)
none
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Simulation and Analysis on Physical Vapor Deposition of CuInSe2 Thin FilmChen, Yu-Ting 04 July 2002 (has links)
Abstract
The objective of this proposed study is to develop the new material CuInSe2 for larger area, low cost and high efficiency commercial CuInSe2 based solar cell for the solar resource in Taiwan. Recently, The¢¹-¢»-¢¾2 ternary chalcopyrite semiconductors, CuMX2(M=In, Ga; X=Se, S) have received considerable potential for nonlinear optics and photovoltaic applications such as a promising material for solar cell. For the request of large area homogeneousness, the electrochemical atomic layer epitaxy (ECALE) and molecular beam epitaxy (MBE) are used to deposit and adjust the composition. The combination of the advantages of MBE and ECALE could produce the large area epitaxial layer and get the precise compositions of CuInSe2 films to obtain a high conversion efficiency for commercial solar cell applications.
For the study of large area CuInSe2 substrate, first, the electrochemical atomic layer epitaxy (ECALE) was applied to deposit a layer of CuInSe2 thin film on ITO substrate, and then the physical vapor deposition was applied for the annealing process to adjust the composition wanted. At last, a CuInSe2 epitaxial film was grown on the top of substrate under the MBE process. In addition, under the conditions of fixed In molecular beam flux and excess Se molecular beam flux, we can control the Cu/In composition ratio by changing Cu molecular beam flux to get stoichiometric and In-rich or Cu-rich epitaxial films, and predict the type of conductivity. It could be possible to obtain the high reproducibility and stability of the composition and properties of epilayers by controlling the growth parameters carefully.
Finally, We hope it can be used in the manufacture of solar cell and get large area high conversion efficiency.
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Silicon nanowires for photovoltaic applications /Parlevliet, David Adam. January 2008 (has links)
Thesis (Ph.D.)--Murdoch University, 2008. / Thesis submitted to the Faculty of Minerals and Energy. Includes bibliographical references (leaves 238-246)
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Charge dynamics in new architectures for dye-sensitized solar cellsMartinson, Alex Brandon Fletcher. January 1900 (has links)
Thesis (Ph.D.)--Northwestern University, 2008. / Adviser: Hupp, Joseph T. Includes bibliographical references.
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Doping dependence of surface and bulk passivation of multicrystalline silicon solar cellsBrody, Jed, January 2003 (has links) (PDF)
Thesis (Ph. D.)--School of Electrical and Computer Engineering, Georgia Institute of Technology, 2004. Directed by Ajeet Rohatgi. / Vita. Includes bibliographical references (leaves 203-211).
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Wire array solar cells fabrication and photoelectrochemical studies /Spurgeon, Joshua Michael. Lewis, Nathan Saul. Lewis, Nathan Saul, January 1900 (has links)
Thesis (Ph. D.) -- California Institute of Technology, 2010. / Title from home page (viewed 03/04/2010). Advisor and committee chair names found in the thesis' metadata record in the digital repository. Includes bibliographical references.
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Phthalocyanine based organic solar cells /Kwong, Chung-yin, Calvin. January 2001 (has links)
Thesis (M. Phil.)--University of Hong Kong, 2002. / Includes bibliographical references (leaves 97-102).
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Performance improvement of organic solar cells incorporated with metallic nanoparticlesFung, Dat-shun, Dixon., 馮達信. January 2011 (has links)
Organic solar cells (OSCs) have shown great promise in becoming the next
generation of renewable energy due to its low cost, simple manufacturing process and
flexibility. A method of efficiency improvement in OSCs is by incorporating metallic
nanoparticles (NPs). While various reports have reported that incorporation of NPs
improve OSC efficiencies due to the Localized Surface Plasmon Resonance (LSPR)
effect, the investigations have lacked depth and a detailed investigation is necessary to
fully understand the device mechanisms of these OSCs.
In this thesis, we first investigate OSCs incorporating Au NPs into the hole
collection Poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS)
layer. Our theoretical and experimental results show that the very strong near field
around Au NPs due to LSPR mainly distributes laterally along the PEDOT:PSS rather
than vertically into the adjacent active layer, leading to minimal enhancement of light
absorption in the active layer. With optical effects proven to be minor contributors to
device performance improvements, we investigate the electrical properties of the
OSCs and obtain insights into the detailed device mechanisms. Improvements in
power conversion efficiency (PCE) of solar cells are found to originate from the
enlarged active layer/PEDOT:PSS interfacial area and improved PEDOT:PSS
conductivity. At high NP concentrations, reduced exciton quenching at donor/acceptor
junctions is found to cause PCE deterioration.
Next, the effects of Au NPs incorporated into the active layer of OSCs with a
newly synthesized donor polymer are investigated in detail. Our experimental and
theoretical results both show that LSPR introduced by the NPs can enhance the light
absorption in the active layer of OSCs because the strong LSPR near field mainly
distributes laterally along the active layer. Combined with our previous study, our
results strongly suggest that NPs have to be incorporated in the active layer in order to
harvest light by the LSPR effect. Meanwhile, our results show that the electrical
properties of NPs improve at low concentration of NPs. When NP concentration is
increased, the electrical properties deteriorates and counter-diminish the optical
enhancement from LSPR and reduces the overall performance improvement.
Finally, we demonstrate efficiency improvement in OSCs by ~22% through
incorporating Au NPs into all polymer layers. Au NPs are found to have distinct
mechanisms in improving device performance when incorporated in different polymer
layers. Our results indicate that the efficiency improvement is the accumulated effects
of incorporating NPs in the individual layers and that coupling is not observed in this
device configuration.
On the whole, our findings highlight the importance that both optical and
electrical properties need to be studied and optimized simultaneously for achieving
enhancement in PCE of OSCs. We have carried out a detailed study on incorporating
NP in various layers and our results are highly useful for the design of high efficiency
OSCs incorporating metallic NPs. / published_or_final_version / Electrical and Electronic Engineering / Master / Master of Philosophy
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Polymer blend film for photovoltaic applications optical characterization and solar cell performanceNg, Annie, 吳玥 January 2013 (has links)
Sunlight is sustainable, clean and readily available energy source, which is one of the potential alternatives to the traditional energy sources. Recently, the organic photovoltaics (OPVs), in particular polymer solar cells (PSCs), have attracted increasing attention owing to their outstanding properties such as low cost, lightweight, flexible, allowing vacuum-free fabrication process and thin-film architecture. These advantageous material and manufacturing features of PSCs provide the opportunities for many novel applications. However, the lower power conversion efficiencies (PCEs) of PSCs compared to inorganic solar cells hinder their competition in the marketplace.
This thesis covers the basic principles of the PSC, strategies for enhancing PCEs as well as the recent development of PSCs. The importance of the source materials has been also demonstrated and discussed. Due to a large number of possibilities, limited resources and time, it is not feasible to do all the work experimentally. Therefore, for continuing advance development of PSCs, the device performance should be modeled as a function of material parameters, which requires the knowledge of material properties, in particular the complex index of refraction N= n - ik. Accurate determination of the optical functions of the active layers and light trapping layers commonly used in PSCs by using the spectroscopic ellipsometry (SE) has been demonstrated. In order to acquire reliable solutions, the methodology including multiple sample analysis, combinations of different measurement techniques, selection of models, the rigorous fitting procedures and the independent verification have been proposed. The obtained information can be used in the simulation to optimize device architectures, model device performance as well as characterize novel materials. / published_or_final_version / Physics / Doctoral / Doctor of Philosophy
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Optical design of organic solar cells by 3-D modeling of device structuresChen, Lüzhou, 陈绿洲 January 2013 (has links)
Organic solar cells (OSCs) have attracted intense attention in recent years due to their advantages of low cost, easy fabrication, and high flexibility compared to its inorganic counterparts. However, due to the conflicts between the short diffusion length of excitons and long absorption length of incident photons, the thickness of OSCs is typically thin, and thus power conversion efficiency (PCE) is generally lower than traditional silicon solar cells. Therefore, an exquisite design of light trapping schemes is essential to the PCE improvement. Generally, physical guideline of light trapping involves two main approaches: geometric optics methods and wave optics methods. The former aims at elongating optical path inside the photoactive layer and thus enhancing photon absorption. For organic thin film solar cells with typical active layer thickness of 100 nm-200 nm, which is in subwavelength scale, we cannot investigate light harvesting mechanism simply by the geometric optics methods and instead wave optics properties should be considered.
In this thesis, two different light trapping enhancement designs are proposed. In order to simulate these structures, we built up programs for absorption power calculation based on scattering matrix method (SMM) by rigorously solving Maxwell’s equations. It is worth to point out that, different from the widely-used calculation method by Absorption = 1-Transmission-Reflection, our algorithm can extract the net optical absorption of the active layer rather than the whole OSCs. This improvement is very important because metal absorption, which does not contribute to exciton generation, can be excluded from the result.
In Chapter 3, design of organic solar cell incorporating periodically arranged gradient type active layer is presented. This design can enhance light harvesting with patterned organic materials themselves (i.e. self-enhanced active layer design) to avoid degrading electrical performance in contrast to introducing inorganic concentrators into the active layers such as silicon and metallic nanostructures. Our numerical results show that the OSC with a self-enhanced active layer, compared with the conventional planar active layer configuration, has broadband and wide-angle range absorption enhancement due to better geometric impedance matching and prolonged optical path.
In Chapter 4, OSC with interstitial lattice patterned metal nanoparticles (NPs) is proposed, which can improve the light blocking of traditional square lattice patterned NPs structure and achieve broadband absorption enhancement. Compared to square lattice design, the plasmonic mode couplings between individual NPs in the interstitial lattice are more versatile and much stronger. Moreover, plasmonic modes can couple to the guided modes, resulting in large enhancement factor at some wavelengths. These works provide a theoretical foundation and engineering reference for high performance OSC designs. / published_or_final_version / Electrical and Electronic Engineering / Doctoral / Doctor of Philosophy
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