Proefschrift--Utrecht. / "Stellingen" ([2] p.) inserted. Bibliography: p. [141]-143.

Proefschrift--Utrecht. / "Stellingen" ([2] p.) inserted. Bibliography: p. [141]-143.

The description of a novel device to measure the spectral direct normal irradiance is presented. The solar spectral irradiance meter (SSIM) was designed at the University of Ottawa as a cost-effective alternative to a prohibitively expensive field spectroradiometer (FSR). The latter measures highly-varying and location-dependent solar spectrum, which is essential for accurate characterization of a concentrating photovoltaic system’s performance. The SSIM measures solar spectral irradiance in several narrow wavelength bands with a combination of photodiodes with integrated interference filters. This device performs spectral measurements at a fraction of the cost of a FSR, but additional post-processing is required to deduce the solar spectrum. The model was developed to take the SSIM’s inputs and reconstruct the solar spectrum in 280–4000 nm range. It resolves major atmospheric processes, such as air mass changes, Rayleigh scattering, aerosol extinction, ozone and water vapour absorptions. The SSIM was installed at the University of Ottawa’s CPV testing facility in September, 2013. The device gathered six months of data from October, 2013 to March, 2014. The mean difference between the SSIM and the Eppley pyrheliometer was within ±1.5% for cloudless periods in October, 2013. However, interference filter degradation and condensation negatively affected the performance of the SSIM. Future design changes will improve the longterm reliability of the next generation SSIMs.

A parametric model of granulation employing a small number of parameters was developed. Synthetic spectra calculated using this model closely match observed spectra and, in particular, reproduce the asymmetries observed in spectral lines. Both the microturbulent motions and the large-scale flow velocity decrease exponentially with a scale height of 368 km as the height within the photosphere increases. The model agrees with observations of the solar granulation (from which it was derived). The horizontal motions associated with granulation were found and used to calculate spectra emergent away from disk centre. These calculated spectra were compared to observed spectra, with the agreement supporting the accuracy of the granular model. Also in the course of this work, the Brueckner-O'Mara damping theory was found to predict damping constants accurately. The photospheric abundances of a number of elements were determined. The abundance obtained for iron agrees with the meteoric iron abundance. Astrophysical f-values for some lines were also determined.

Orientadores: Maria Angela Fagnani / Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Agricola / Made available in DSpace on 2018-08-07T22:58:20Z (GMT). No. of bitstreams: 1 Leite_CiceroAlexandre_D.pdf: 5359491 bytes, checksum: 85d9823bcfcf799676c4fee678ed8746 (MD5) Previous issue date: 2006 / Doutorado / Agua e Solo / Doutor em Engenharia Agrícola

Philosophiae Doctor - PhD / The main aim of this study was to prepare band gap-engineered graphene quantum dot (GQD) structures which match the different energies of the visible region in the solar spectrum. These band gap-engineered graphene quantum dot structures were used as donor materials in rainbow Schottky junction solar cells, targeting all the energies in the visible region of the solar spectrum for improved solar-to-electricity power conversion efficiency. Structural characterisation of the prepared nanomaterials under solid-state nuclear magnetic resonance spectroscopy (SS-NMR) showed appearance of bands at 40 ppm due to the presence of sp3 hybridised carbon atoms from the peripheral region of the GQD structures. Other bands were observed at 130 ppm due to the presence of polycyclic aromatic carbon atoms from the benzene rings of the GQD backbone, and around 180 ppm due to the presence of carboxylic acid carbons from oxidation due to moisture. Fourier-transform infrared resonance (FTIR) spectroscopy further confirmed the presence of aromatic carbon atoms and oxidised carbons due to the presence of C=O, C=C and -OH functional groups, concurrent with SS-NMR results. / 2023-12-01

This thesis describes and documents the design and construction of a light source which is tunable and has the ability to mimic the spectral output of the sun in the photosynthetic active radiation range (400 - 700 nm). To adjust the spectral output at different wavelengths different types of LEDs were chosen and combined. This thesis describes the design, construction, testing, and suggestions for further improvements to this light source. The light source is comprised of 900 LEDs with 26 different peak wavelengths within the photosynthetically active radiation range. The light source is made tunable through the use of a control system utilizing pulse width modulation. This unique light source will allow studies to be performed to understand spectral influences on microalgae and lipid production as well as other photosynthetic organisms.

Dans un contexte de fort déploiement du Photovoltaïque (PV), de plus en plus de recherches sont menées pour assurer une certaine fiabilité et prédictibilité de la production provenant du PV. Les investisseurs se plaignent d’un manque de visibilité dans cette filière et hésitent à investir dans le PV (surtout avec les baisses régulières des tarifs de rachats). Il est donc nécessaire pour le développement de la filière PV de faire des efforts pour étudier, comprendre les systèmes PV en fonctionnement et ainsi donner plus de visibilité pour l’amélioration des systèmes, leur monitoring, une plus grande fiabilité et pouvoir prédire plus précisément le productible PV en améliorant les modèles de prédiction du productible PV déjà existants.C’est dans ce cadre que s’inscrit cette thèse qui a pour but de caractériser les modules PV en conditions réelles d’utilisation en fonction des différentes technologies. Nous étudions, dans cette thèse, les facteurs extérieurs qui influent sur le comportement des modules de différentes filières, pour tenter de rendre le PV plus fiable et prédictible. C’est donc un axe de recherche qui vient en complément de la caractérisation en laboratoire qui a pour objectif l’amélioration des rendements des cellules.Pour y parvenir il est nécessaire, dans un premier temps, de connaitre les paramètres extérieurs qui influent sur le fonctionnement du module et savoir comment les étudier. Une partie de la thèse est par conséquent consacrée à l'étude des facteurs météorologiques et atmosphériques ayant un impact sur le comportement électrique du module ainsi que la mise en place d'instruments et méthodes pour les mesurer. On présente également les avantages et inconvénients de la caractérisation en extérieur.Après avoir exposé tous les paramètres à prendre en compte, on décrit l'installation de plusieurs plateformes de caractérisation de modules PV entièrement automatisées que l'on a monté au cours de cette thèse au LGEP ainsi qu'à l'École Polytechnique et qui ont toutes un objectif particulier.Ce manuscrit montre par la suite les différentes applications et utilités que peuvent avoir de telles plateformes en analysant les données enregistrées régulièrement (toutes les minutes en moyenne) sur des périodes allant de quelques jours à plusieurs mois. On compare, par la même occasion, les données constructeur prises en conditions standard de test et les performances mesurées dans de nombreuses conditions de modules PV. Les résultats obtenus peuvent servir à la fois pour la recherche, l'aide à la compréhension du comportement des modules, par conséquent aide à la prévision du productible d'installation PV et peuvent avoir un rôle pédagogique dans l'enseignement du PV.Enfin, une dernière partie est dédiée à la description et à la démonstration de faisabilité d'une carte qui permet d'obtenir les caractéristiques principales de n'importe quel module PV en les extrayant de la courbe I(V) mesurée. Cette carte, développée au LGEP, a d'autres utilités telles que la recherche du point de fonctionnement maximale du module (MPPT). / Nowadays, photovoltaic (PV) keeps growing fast and an increasing number of studies is require in order to assure the reliability and predictability of the PV-produced electricity. The lack of visibility concerning this field is a continuous source of complaints from the investors who hesitate to commit to PV projects (especially after the decrease of buying prices in Europe). Therefore, to assure the successful increase of PV energy, it is necessary to provide studies aiming at better understanding PV systems in real operations conditions, that means in outdoor conditions.The goal of this doctoral work has been to characterize different PV module technologies in their real use conditions. The outdoor parameters that influence the behavior of different module technologies have been investigated. The goal was to obtain useful information which could make PV-produced electricity more reliable. Therefore, these studies can efficiently complete standard laboratory characterization tests made under a single condition, the purpose of which is usually to determine the efficiency of the different solar cells technologies.To achieve this goal, first it has been necessary to define the outdoor parameters that mainly influence the modules and the most suitable methods to be used for their investigation. For this reason, part of this doctoral work has been devoted to the study of weather and atmospheric factors affecting the electrical behavior of the modules, as well as setting up instruments and methods to measure them. Additionally, advantages and disadvantages of outdoors characterizations have been addressed.Then, after multiple fully automated PV platforms, mounted at the LGEP and at Ecole Polytechnique, thanks to a collaboration with the Laboratoire de Méteorologie Dynamique (LMD). The different applications and uses of these platforms have been highlighted by analyzing data recorded periodically (every minute on average) over periods ranging from days to several months. Manufacturer data, which are acquired in standard test conditions, and the performance measured in several conditions are compared. These results can be used for both research, understanding the behavior of the modules, help in predicting the energy yield of PV system and also to stress the educational role in teaching PV.Finally, the feasibility of an electric card that provides the main characteristics of any PV module by extracting the measured I(V) curve is described. Such electric card, developed at the LGEP, has other uses such as the determination of the maximum operating point.

Planetários e observatórios oferecem a possibilidade de desenvolver um ensino contextualizado de Astronomia, permitindo a realização de atividades educativas que proporcionam acesso a uma ciência escolar mais autêntica. Com isso em vista, esta pesquisa consistiu no desenvolvimento, aplicação e análise de minicursos sobre o Sol, para o ensino fundamental e física solar, para o ensino médio em um espaço não formal de educação, o Observatório Astronômico do CDCC/USP. Tópicos como a composição química, temperatura e evolução estelar foram ensinados a partir de experimentos clássicos em uma sala totalmente dedicada ao Sol, a Sala Solar com equipamentos de baixo custo. Os cursos enfatizaram atividades práticas, observacionais e questionadoras, como discussões sobre a natureza do Sol, manchas solares e proeminências, estimativas da temperatura da fotosfera, observaçã do espectro solar na região do visível e identicação das linhas de absorção entendendo como são produzidas e que tipo de informações podem ser extraídas a partir delas. O objetivo do curso do ensino fundamental foi mostrar que o Sol e um astro dinâmico e que influencia a Terra de diversas maneiras, além de contextualizar o conteúudo ensinado com atividades práticas. O objetivo do curso do ensino médio foi compreender o papel chave desempenhado pela espectroscopia na astrofísica e permitir abordagens interdisciplinares incluíndo física moderna e química no ensino de Astronomia. A metodologia de pesquisa consistiu de uma abordagem qualitativa com a realização de questionários escritos, entrevistas semi-estruturadas e lmagens. Antes dos cursos, muitos alunos concebiam o Sol como sendo uma esfera quente de fogo, as manchas solares como sendo buracos no Sol e as proeminências como magma expelido por vulcões. Após a realizaçã dos cursos os alunos apresentaram ideias sobre o Sol e aspectos de física solar mais próximas das aceitas hoje em dia pela comunidade cientca. Esta pesquisa não ficou restrita aos ganhos cognitivos dos alunos após a realização dos minicursos, pois considerou a interação de diferentes contextos responsáveis pela aprendizagem em museus de ciências. Isso foi possível pelo referencial teórico adotado: o Modelo Contextual de Aprendizagem de Falk e Dierking. Trabalhar conteudos astronômicos de forma interdisciplinar e ao mesmo tempo de maneira ativa e questionadora traz alguns desafios para as equipes de instituições como o Observatório. As atividades elaboradas nos centros de ciências devem ter como principal objetivo despertar o interesse do aprendiz pela ciência, mas também destacamos a necessidade da oferta de minicursos para voluntários, pois a linguagem, conteúdos e metodologias em atividades mais longas podem facilitar abordagens interdisciplinares e integradoras da Astronomia com outras áreas do conhecimento científico pouco exploradas nas salas de aula. Isso pode ocorrer quando o projeto pedagógico da escola é construído coletivamente, envolvendo museus de ciências, professores, escola e alunos buscando conciliar propostas de um ensino de ciências que considere o contexto fora da escola e que ao mesmo tempo tenha relação com o que o aluno está estudando em sala de aula. / Observatories and planetariums offer the possibility of developing contextualized astronomy teaching by fostering educational activities that provide access to a more authentic school science. Thus, this research consisted in developing, applying and evaluating courses about the Sun for middle, junior high school students and solar physics for high school students in an informal educational space, the CDCC/USP Astronomical Observatory. Topics of chemical composition, temperature and stellar evolution were taught in a room totally dedicated to the study of the Sun, a Solar Room, designed with simple and inexpensive equipment. The course strongly emphasized practical, observational and inquirybased activities, such as estimation of the solar surface temperature, observation of the visible solar spectrum, identication of solar absorption lines, understanding how they are produced, and what kind of information can be extracted from the observed spectral lines. Some of the course goals were to foster the comprehension of the key role played by spectroscopy in astrophysics, to contextualize contents with practical activities, and to allow interdisciplinary approaches including modern physics and chemistry in physics teaching. The research methodology consisted of a qualitative approach by fillming the whole course and performing written questionnaires and semi-structured interviews. Before the courses were applied most students conceived the Sun as a hot sphere composed of fire, sunspots as holes in the Sun and solar prominences as magma expelled by volcanoes. After the courses students presented ideas about the Sun and solar physics more closely related to the ones accepted by contemporary science. This research was not restricted to students\' cognitive gains after concluding the courses, since it considered the interaction of different contexts responsible for learning in science museums. This was possible due to the theoretical framework adopted: The Contextual Model of Learning of Falk and Dierking. Some challenges have to be faced by institutions such as the Astronomical Observatory in order to teach astronomy in an interdisciplinary form and with inquiry-based activities The activities developed at science centers must have as their main objective to motivate the public towards science, but it is also important to offer courses for volunteers, since language, contents and methodologies in longer activities can facilitate interdisciplinary approaches of Astronomy with other areas of scientic knowledge seldom explored in classrooms. This can happen when the school\'s educational project is collectively constructed including science museums, teachers, school and students by seeking to enhance teaching proposals that consider the out of school context and is related to contents taught in the classroom.

Au cours des dernières années, la communauté scientifique s'est intéressée de plus en plus à l'acquisition de sources d'énergie renouvelables vertes et propres par rapport aux combustibles fossiles traditionnels. Le rayonnement solaire est une source particulièrement abondante d'énergie renouvelable qui a été largement utilisée dans les véhicules, les machines et les bâtiments, entre autres. Il y a généralement deux manières différentes d'utiliser l'énergie solaire: la chaleur et l'électricité. La principale motivation de ce travail de thèse est d'utiliser cette abondante source d'énergie pour produire une petite fraction de la tension et du courant continu de sortie. Puisque le spectre solaire se situe dans les longueurs d'onde à l'échelle nanométrique ou dans la bande térahertz, les antennes optiques seront utilisées comme une nouvelle technologie de nanotechnologie pour capter et récolter l'énergie solaire. Les antennes optiques ont des propriétés similaires à celles de leurs homologues micro-ondes, mais leur avantage réside dans des moyens sans précédent pour adapter les champs électromagnétiques dans tous leurs aspects et applications. Par conséquent, avec les détails mentionnés ci-dessus, l'idée principale de cette thèse est de capturer le rayonnement infrarouge solaire et l'utiliser pour produire une tension continue de sortie. La première partie de cette thèse est consacrée à la compréhension du fonctionnement de la collecte d'énergie par radiofréquence (RF) et à la présentation d'un concept de rectenna. La deuxième partie traite de l'introduction et de la simulation d'antennes optiques à base de résonateurs diélectriques (DR) car elles offrent moins de pertes à la bande THz. Deux conceptions de DR différentes sont proposées fonctionnant à la fréquence centrale de 193,5 THz (longueur d'onde 1550 nm). La troisième partie traite de la contribution principale à ce travail en termes de conception, simulation et fabrication d'une antenne optique Yagi-uda à haut gain et large bande. La technique de lithographie par faisceau d'électrons est utilisée pour réaliser la structure proposée. En dehors de la conception de l'élément unique Yagi-uda, diverses configurations de réseau ont été simulées avec la réalisation d'un réseau d'éléments 100 x 100 fabriqué sur un substrat de silicium. Pour produire une certaine quantité de tension de sortie, deux techniques ont été utilisées pour tester le réseau d'antennes optiques Yagi-uda. La première technique impliquait l'intégration du réseau Yagi-uda avec une diode fermionique du commerce qui produisait une tension de sortie de 0,15 V par excitation à partir d'une lumière visible et de 0,52 V par excitation directe à partir d'un laser à 1550 nm. La deuxième technique est basée sur la dissipation thermique entre des métaux dissemblables produisant une tension de sortie. Quatre lasers à longueurs d'onde différents (532 nm, 650 nm, 940 nm et 1550 nm) ont excité trois conceptions de nantenna réalisées. Parmi ces conceptions, la tension de sortie maximale de 0,82 V a été produite par le réseau Yagi-uda lorsqu'il est excité via un laser de 1550 nm. / Recent years have witnessed an increased interest by the scientific community to acquire green and clean renewable sources of energy compared to traditional fossil fuels. Solar radiation is one particular abundant source of renewable energy that has been widely applied in vehicles, machines, and buildings, among others. There are generally two different ways in which solar energy is used – heat and electricity. The main motivation of this thesis work is to utilize that abundant source of energy in producing a small fraction of output DC voltage and current. Since the solar spectrum lies in the nano scale wavelengths or terahertz band, optical antennas as a novel nano fabrication technology will be used to capture and harvest the solar energy. Optical antennas have properties similar to their microwave counterparts, but the advantage they have is in terms of unprecedented means to tailor electromagnetic fields in all its aspects and applications. Therefore, with the aforementioned details, the main idea of this thesis is to capture the solar infrared radiation and utilize it for producing output DC voltage. The first part of this thesis is dedicated to understanding the working of radio frequency (RF) energy harvesting and presenting a rectenna design. The second part deals with the introduction and simulation of optical antennas based of dielectric resonators (DR) as they offer fewer losses at the THz band. Two different DR designs are proposed working at the center frequency of 193.5 THz (1550 nm wavelength). The third part discusses the main contribution to this work in terms of design, simulation and fabrication of a high gain and wideband Yagi-uda optical antenna. E-beam lithography technique is used to realize the proposed structure. Apart for the single element Yagi-uda design, various array configurations have been simulated with realization of a 100 x 100 elements array fabricated on a silicon substrate. To produce a certain amount of output voltage, two techniques were deployed in testing the realized Yagi-uda optical antenna array. The first technique involved integration of the Yagi-uda array with a commercial fermionic diode that produced output voltage of 0.15 V via excitation from a visible light and 0.52 V with direct excitation from a 1550 nm laser. The second technique is based on thermal dissipation among dissimilar metals producing an output voltage. Four different wavelength (532 nm, 650 nm, 940 nm and 1550 nm) lasers excited three realized nantenna designs. Among these designs, the maximum output voltage of 0.82 V was produced by the Yagi-uda array when excited via 1550 nm laser.