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Etude et simulation du bruit des boîtes de transmission principales d'hélicoptères / Study and simulation of helicopters main gearboxes noisesRoulois, Guillaume 26 May 2011 (has links)
La boîte de transmission principale (BTP) est une des principales sources dubruit perçu dans les cabines d’hélicoptères et pénalise fortement le confort acoustique deséquipages et passagers. Afin de réduire l’impact de cette source, les phénomènes acoustiqueset vibratoires mis en jeu par les boîtes de transmission à engrenages doivent être compris etsimulés durant les phases de développement. De cette façon, le comportementvibroacoustique des BTP pourra être amélioré dès la conception, réduisant ainsi le coût, lamasse et les difficultés d’intégration des solutions d’insonorisation. Ce travail présente lesBTP d’hélicoptères ainsi que le bruit qu’elles génèrent. Il présente également nosdéveloppements concernant la modélisation du comportement dynamique des BTP afin d’encalculer le bruit. Nous avons développé un code éléments finis permettant d’effectuer desétudes paramétriques afin d’ajuster le design des boîtes de transmission lors des phases dedéveloppement. Notre modèle est capable de calculer les efforts dynamiques aux paliers detransmissions composées de plusieurs engrenages cylindriques et spiro-coniques. Enfin, nousanalysons des mesures acoustiques et vibratoires effectuées autour de deux BTP pourplusieurs conditions de couple et vitesse. Ces mesures nous permettent de mieux comprendrele comportement vibroacoustique des BTP et de confirmer certaines tendances observées avecnotre modèle / Main gearbox (MGB) is one of the main noise sources in helicopter cabinsand it strongly penalizes acoustic comfort of crews and passengers. In order to reduce theimpact of this source, acoustic and vibration mechanisms of gearboxes have to be understoodand simulated during the development phases. By this way, MGB vibroacoustic behaviourcould be improved by design, thus reducing cost, additional weight and integration difficultiesof sound-proofing solutions. This work presents helicopters MGB and the noise they generate.It also presents our developments regarding the modelling of MGB dynamic behaviour fornoise computation. We have developed a finite elements code allowing to conduct parametricstudies to tune the gearboxes design in early development phases. Our model is able tocompute dynamic loads on bearings of any transmission composed of several cylindrical andspiral bevel gears. At last, we analyse acoustic and vibration measurements done around twoMGB for several conditions of torque and speed. These measurements allow to betterunderstand MGB vibroacoustic behaviour and to confirm some trends observed with ourmodel
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Isolierung und Strukturaufklärung neuer Naturstoffe aus Bakterien und endophytischen Pilzen durch chemisches Screening / Isolation and structure elucidation of new natural products from bacteria and endophytic fungi by chemical screeningBitzer, Jens 29 June 2005 (has links)
No description available.
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Hole Transport Materials for Solid-State Mesoscopic Solar CellsYang, Lei January 2014 (has links)
The solid-state mesoscopic solar cells (sMSCs) have been developed as a promising alternative technology to the conventional photovoltaics. However, the device performance suffers from the low hole-mobilities and the incomplete pore filling of the hole transport materials (HTMs) into the mesoporous electrodes. A variety of HTMs and different preparation methods have been studied to overcome these limitations. There are two types of sMSCs included in this doctoral thesis, namely solid-state dye-sensitized solar cells (sDSCs) and organometallic halide perovskite based solar cells. Two different types of HTMs, namely the small molecule organic HTM spiro-OMeTAD and the conjugated polymer HTM P3HT, were compared in sDSCs. The photo-induced absorption spectroscopy (PIA) spectra and spectroelectrochemical data suggested that the dye-dye hole conduction occurs in the absence of HTM and appears to be of significant importance to the contribution of hole transport. The PIA measurements and transient absorption spectroscopy (TAS) indicated that the oxidized dye was efficiently regenerated by a small molecule organic HTM TPAA due to its excellent pore filling. The conducting polymer P3HT was employed as a co-HTM to transfer the holes away from TPAA to prohibit the charge carrier recombination and to improve the hole transport. An alternative small molecule organic HTM, MeO-TPD, was found to outperform spiro-OMeTAD in sDSCs due to its more efficient pore filling and higher hole-mobility. Moreover, an initial light soaking treatment was observed to significantly improve the device performance due to a mechanism of Li+ ion migration towards the TiO2 surface. In order to overcome the infiltration difficulty of conducting polymer HTMs, a state-of-the-art method to perform in-situ photoelectrochemical polymerization (PEP) in an aqueous micellar solution of bis-EDOT monomer was developed as an environmental-friendly alternative pathway with scale-up potential for constructing efficient sDSCs with polymer HTMs. Three different types of HTMs, namely DEH, spiro-OMeTAD and P3HT, were used to investigate the influence of HTMs on the charge recombination in CH3NH3PbI3 perovskite based sMSCs. The photovoltage decay measurements indicate that the electron lifetime (τn) of these devices decreases by one order of magnitude in the sequence τspiro-OMeTAD > τP3HT > τDEH.
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