L'eau est un constituant essentiel de l'atmosphère de supergéantes rouges (RSG), mais dont l'influence reste mal comprise. Le spectre observé de l'eau de ces étoiles ne peut être reproduit que par l'ajout d'une coquille de gaz moléculaire, les MOLsphères. Cependant, l'hypothèse des MOLsphères reste fragile et sujette à caution. Dans le but de mieux interpréter les spectres observés, la synthèse de spectres hors équilibre thermodynamique local est une approche potentiellement importante. Les effets hors ETL étant potentiellement fort, ils pourraient être en mesure de lever les problèmes de l'interprétation des raies de l'eau sans ajout de MOLsphère et impliquer un rôle important dans la dynamique de l'atmosphère. Pour cela, nous avons développé une méthode originale en mesure de résoudre l'équation de transfert pour les nombreuses transitions radiatives de l'eau sans approximationETL. Cette méthode a été mise en oeuvre via le développement d'un code de transfert radiatif parallèle. Les premiers résultats montrent que les effets hors ETL dans l'atmosphère des RSG, et leur impact sur le spectre comme sur certaines observables utilisées pour sonder ces étoiles, sont importants / Water is an important constituent of the atmosphere of red supergiant stars (RSG), which influence remains however poorly understood. The water spectrum of these stars can apparently be only reproduced through the addition of a detached shell of cool molecular gas, the so-called MOLspheres. However, this hypothesis is still cautious. In order to better interpret observed spectra, non local thermodynamic equilibrium (NLTE) spectrum synthesis may be potentially important. NLTE effects being potentially important, they may alleviate the problems in the interpretation of water spectra, and affect the atmosphere dynamics. We thus developed an original method to solve the radiative transfer equation, adapted to the numerous water transitions and without the LTE approximation. This method has been implemented in an original parallel code. Preliminary results show that NLTE effects in RSG atmospheres and their impact on observables such as the emergent spectrum are very important.

Central stars of planetary nebulae are low-mass stars on the brink of their final evolution towards white dwarfs. Because of their surface temperature of above 25,000 K their UV radiation ionizes the surrounding material, which was ejected in an earlier phase of their evolution. Such fluorescent circumstellar gas is called a "Planetary Nebula". About one-tenth of the Galactic central stars are hydrogen-deficient. Generally, the surface of these central stars is a mixture of helium, carbon, and oxygen resulting from partial helium burning. Moreover, most of them have a strong stellar wind, similar to massive Pop-I Wolf-Rayet stars, and are in analogy classified as [WC]. The brackets distinguish the special type from the massive WC stars. Qualitative spectral analyses of [WC] stars lead to the assumption of an evolutionary sequence from the cooler, so-called late-type [WCL] stars to the very hot, early-type [WCE] stars. Quantitative analyses of the winds of [WC] stars became possible by means of computer programs that solve the radiative transfer in the co-moving frame, together with the statistical equilibrium equations for the population numbers. First analyses employing models without iron-line blanketing resulted in systematically different abundances for [WCL] and [WCE] stars. While the mass ratio of He:C is roughly 40:50 for [WCL] stars, it is 60:30 in average for [WCE] stars. The postulated evolution from [WCL] to [WCE] however could only lead to an increase of carbon, since heavier elements are built up by nuclear fusion. In the present work, improved models are used to re-analyze the [WCE] stars and to confirm their He:C abundance ratio. Refined models, calculated with the Potsdam WR model atmosphere code (PoWR), account now for line-blanketing due to iron group elements, small scale wind inhomogeneities, and complex model atoms for He, C, O, H, P, N, and Ne. Referring to stellar evolutionary models for the hydrogen-deficient [WC] stars, Ne and N abundances are of particular interest. Only one out of three different evolutionary channels, the VLTP scenario, leads to a Ne and N overabundance of a few percent by mass. A VLTP, a very late thermal pulse, is a rapid increase of the energy production of the helium-burning shell, while hydrogen burning has already ceased. Subsequently, the hydrogen envelope is mixed with deeper layers and completely burnt in the presence of C, He, and O. This results in the formation of N and Ne. A sample of eleven [WCE] stars has been analyzed. For three of them, PB 6, NGC 5189, and [S71d]3, a N overabundance of 1.5% has been found, while for three other [WCE] stars such high abundances of N can be excluded. In the case of NGC 5189, strong spectral lines of Ne can be reproduced qualitatively by our models. At present, the Ne mass fraction can only be roughly estimated from the Ne emission lines and seems to be in the order of a few percent by mass. Furthermore, using a diagnostic He-C line pair, the He:C abundance ratio of 60:30 for [WCE] stars is confirmed. Within the framework of the analysis, a new class of hydrogen-deficient central stars has been discovered, with PB 8 as its first member. Its atmospheric mixture resembles rather that of the massive WNL stars than of the [WC] stars. The determined mass fractions H:He:C:N:O are 40:55:1.3:2:1.3. As the wind of PB 8 contains significant amounts of O and C, in contrast to WN stars, a classification as [WN/WC] is suggested. / Zentralsterne Planetarischer Nebel sind massearme Sterne kurz vor ihrer finalen Entwicklung zu Weißen Zwergen. Aufgrund ihrer Oberflächentemperatur von über 25 000 K sind sie in der Lage, durch Abstrahlung von UV-Licht das sie umgebende Material, welches in einer vorigen Phase ihrer Entwicklung abgestoßen wurde, zu ionisieren. Das solchermaßen zum Leuchten angeregte Gas bezeichnet man als Planetarischen Nebel. Etwa ein Zehntel der galaktischen Zentralsterne sind wasserstoffarm. Im Allgemeinen besteht die Oberfläche dieser Zentralsterne aus einer Mischung der Elemente Helium, Kohlenstoff und Sauerstoff, welche z.T. durch Heliumbrennen erzeugt wurden. Die meisten dieser Sterne haben darüberhinaus einen starken Sternwind, ähnlich den massereichen Pop-I-Wolf-Rayet-Sternen und werden in Analogie zu diesen als [WC] klassifiziert, wobei die eckigen Klammern der Unterscheidung von den massereichen WC-Sternen dienen. Qualitative Analysen der Spektren von [WC]-Sternen lassen eine Entwicklungssequenz dieser Sterne von kühleren sogenannten late-type [WC]-Sternen (kurz [WCL]) zu sehr heißen, early-type [WC]-Sternen (kurz [WCE]) vermuten. Mithilfe von Computerprogrammen, die den Strahlungstransport im mitbewegten Beobachtersystem zusammen mit den statistischen Gleichungen der Besetzungszahlen der Ionen im Sternwind rechnen können, wurden quantitative Untersuchungen der Winde von [WC]-Sternen möglich. Erste Analysen mit Modellen ohne Eisenlinien ergaben dabei systematisch unterschiedliche Häufigkeiten für [WCL]- und [WCE]-Sterne. Während sich für [WCL]-Sterne ein Verhältnis der Massenanteile von He:C von etwas 40:50 ergab, fand man für die [WCE]-Sterne ein mittleres Verhältnis von 60:30 für die He:C-Massenanteile. Dabei sollte die Entwicklung von [WCL] nach [WCE] innerhalb einer sehr kurzen Zeit durch Aufheizung infolge der Kontraktion der Hülle erfolgen und nicht mit einer wesentlichen Abnahme der Kohlenstoffhäufigkeit bei gleichzeitiger Zunahme der Heliumhäufigkeit an der Oberfläche einhergehen. Im Rahmen der vorgelegten Arbeit wird untersucht, ob sich mittels verbesserter Modelle für die Atmosphären von [WC]-Sternen das He:C-Häufigkeitsverhältnis der [WCE]-Sterne bestätigt. Elaboriertere Modelle, welche vom Potsdamer WR-Modelatmosphären-Code (PoWR) berechnet werden können, berücksichtigen Line-Blanketing aufgrund von Elementen der Eisengruppe, kleinskalige Windinhomogenitäten und die Elemente He, C, O, H, P, N und Ne. Unter Bezug auf Sternentwicklungsmodelle, die die Ursache der Wasserstoffunterhäufigkeit von [WC]-Sternen erklären, sind insbesondere die Neon- und Stickstoff-Häufigkeiten interessant. Von den drei möglichen Entwicklungskanälen für [WC]-Sterne führt lediglich das VLTP-Szenario zu einer Stickstoff-Überhäufigkeit von einigen Prozent bezogen auf die Masse. Bei einem VLTP, einem very late thermal pulse, handelt es sich um einen plötzlichen, starken Anstieg der Energieproduktion in der helium-brennenden Schale, während das Wasserstoffbrennen bereits zum Erliegen gekommen ist. Infolge eines VLTPs wird sämtlicher Wasserstoff kurz nach dem thermischen Puls in tiefere Schichten gemischt und in Anwesenheit von C, He und O verbrannt. Infolgedessen wird N und auch Ne erzeugt. Bei der Analyse von elf [WCE]-Sternen wurden für drei von ihnen, PB 6, NGC 5189 und [S71d]3, Stickststoffmassenanteile von 1,5 % bestimmt, während für drei andere Sterne solche hohen Stickstoffhäufigkeiten ausgeschlossen werden können. Für NGC 5189 gelang außerdem die qualitative Reproduktion der beobachteten, starken Ne-Spektrallinien mittels unserer Modelle. Zur Zeit lässt sich aus der Stärke der Ne-Emissionslinien der Ne-Massenanteil leider nur abschätzen, er scheint aber im Bereich einiger Prozent zu liegen. Mittels eines diagnostischen He-C-Linienpaares konnte das He:C-Massenverhältnis von 60:30 für [WCE]-Sterne bestätigt werden. Als Ergebnis der Analyse von PB 8 postulieren wir eine neue Klasse von wasserstoffarmen Zentralsternen, die in ihrer Elementzusammensetzung eher an massereiche WNL-Sterne als an [WC]-Sterne erinnern. Die ermittelten Massenanteile H:He:C:N:O betragen 40:55:1.3:2:1.3, der Wind von PB 8 enthält daher im Unterschied zu WN-Sternen signifikante Mengen von O und C. Es wird daher eine Klassifizierung als [WN/WC] vorgeschlagen.

Há uma concentração de aglomerados globulares moderadamente pobres em metais no bojo galáctico, e muitos deles mostram um Ramo Horizontal Azul (BHB). Essas características juntas apontam para uma idade antiga. Para entender melhor a origem desses aglomerados, o estudo de seu padrão de abundâncias pode ajudar a identificar o tipo das primeiras supernovas nas partes centrais da Galáxia. O NGC 6522 na janela do Baade é um representante desta classe de aglomerados. Análises de abundância de estrelas individuais nesses aglomerados confirmaram sua metalicidade de [Fe/H] -1.0, enriquecimento em elementos-$\\alpha$ e detectaram uma variação nas abundâncias dos elementos pesados de processo-s. Entre os maiores enriquecimentos em Y e Ba, a explicação usual da transferência de massa de uma companheira do ramo assintótico das gigantes pode não se aplicar, e um enriquecimento por estrelas massivas de alta rotação foi sugerido. A fim de estudar melhor as abundâncias em NGC 6522, obtivemos um programa com o FLAMES em 2012, a partir da qual, com os dados de UVES, mostramos que o enriquecimento em elementos-s ainda poderia ser acomodado com o modelo de transferência de massa de uma estrela companheira. Além disso, obtivemos novos dados com o FLAMES em 2016. No presente trabalho analisamos outras 6 estrelas observadas em alta resolução com UVES, e 32 estrelas em resolução média-alta observadas com GIRAFFE, onde foram selecionadas por suas velocidades radiais em torno de -14,3 km/s com uma abrangência de ±15 km/s. Os parâmetros atmosféricos e as abundâncias dos elementos leves C, N, O, elementos de Z ímpar Na e Al, elementos-$alpha$ Mg, Si, Ca, Ti, elementos de pico de ferro Mn, Cu, Zn, elementos de processo-s Y, Zr, Ba, La, Ce, Nd e o elemento de processo-r Eu são derivados para a amostra UVES e preliminarmente para a amostra GIRAFFE. Entre as estrelas UVES, duas delas mostram um enriquecimento significativo nos elementos do processo-s e uma com alto valor nas razões [Y/Ba] e [Zr/Ba], sugerindo um enriquecimento por estrelas massivas de alta rotação. / There is a concentration of moderately metal-poor globular clusters in the Galactic bulge, and many of them show a Blue Horizontal Branch (BHB). These characteristics together point to an old age. In order to better understand the origin of these clusters, the study of their abundance pattern can help identifying the kind of the earliest supernovae in the central parts of the Galaxy. NGC 6522 in Baades Window is a representative of this class of clusters. Abundance analyses of individual stars in this clusters have confirmed its metallicity of [Fe/H]-1.0, enhanced -elements, and detected a variation in the abundances of the s-process heavy elements. Among the highest enhancements of Y and Ba, the usual explanation of mass transfer from a companion in the Asymptotic Giant Branch might not apply, and an enrichment by early fast-rotating massive stars was suggested. In order to further study the abundances in NGC 6522 we obtained a run with FLAMES- UVES in 2012, from which with the UVES data we have shown that the enhancement in s-elements could still be accommodated with the companion transfer model. We further obtained new data with FLAMES-UVES in 2016. In the present work we analyze another 6 stars observed at high resolution with UVES, and 32 stars at medium-high resolution observed with GIRAFFE. The latter were selected from their radial velocities of -14.3±15 km/s. The abundances of the light elements C, N, O, odd-Z elements Na, Al, -elements Mg, Si, Ca, Ti, iron-peak elements Mn, Cu, Zn, s-process elements Y, Zr, Ba, La, Ce, Nd and r-process element Eu are derived. Among the UVES stars, two of them show a significant enrichment in s-process elements and one of them show high [Y/Ba] and [Zr/Ba] ratios, suggesting that an early enrichment by fast rotating massive stars is a probable scenario.

Há uma concentração de aglomerados globulares moderadamente pobres em metais no bojo galáctico, e muitos deles mostram um Ramo Horizontal Azul (BHB). Essas características juntas apontam para uma idade antiga. Para entender melhor a origem desses aglomerados, o estudo de seu padrão de abundâncias pode ajudar a identificar o tipo das primeiras supernovas nas partes centrais da Galáxia. O NGC 6522 na janela do Baade é um representante desta classe de aglomerados. Análises de abundância de estrelas individuais nesses aglomerados confirmaram sua metalicidade de [Fe/H] -1.0, enriquecimento em elementos-$\\alpha$ e detectaram uma variação nas abundâncias dos elementos pesados de processo-s. Entre os maiores enriquecimentos em Y e Ba, a explicação usual da transferência de massa de uma companheira do ramo assintótico das gigantes pode não se aplicar, e um enriquecimento por estrelas massivas de alta rotação foi sugerido. A fim de estudar melhor as abundâncias em NGC 6522, obtivemos um programa com o FLAMES em 2012, a partir da qual, com os dados de UVES, mostramos que o enriquecimento em elementos-s ainda poderia ser acomodado com o modelo de transferência de massa de uma estrela companheira. Além disso, obtivemos novos dados com o FLAMES em 2016. No presente trabalho analisamos outras 6 estrelas observadas em alta resolução com UVES, e 32 estrelas em resolução média-alta observadas com GIRAFFE, onde foram selecionadas por suas velocidades radiais em torno de -14,3 km/s com uma abrangência de ±15 km/s. Os parâmetros atmosféricos e as abundâncias dos elementos leves C, N, O, elementos de Z ímpar Na e Al, elementos-$alpha$ Mg, Si, Ca, Ti, elementos de pico de ferro Mn, Cu, Zn, elementos de processo-s Y, Zr, Ba, La, Ce, Nd e o elemento de processo-r Eu são derivados para a amostra UVES e preliminarmente para a amostra GIRAFFE. Entre as estrelas UVES, duas delas mostram um enriquecimento significativo nos elementos do processo-s e uma com alto valor nas razões [Y/Ba] e [Zr/Ba], sugerindo um enriquecimento por estrelas massivas de alta rotação. / There is a concentration of moderately metal-poor globular clusters in the Galactic bulge, and many of them show a Blue Horizontal Branch (BHB). These characteristics together point to an old age. In order to better understand the origin of these clusters, the study of their abundance pattern can help identifying the kind of the earliest supernovae in the central parts of the Galaxy. NGC 6522 in Baades Window is a representative of this class of clusters. Abundance analyses of individual stars in this clusters have confirmed its metallicity of [Fe/H]-1.0, enhanced -elements, and detected a variation in the abundances of the s-process heavy elements. Among the highest enhancements of Y and Ba, the usual explanation of mass transfer from a companion in the Asymptotic Giant Branch might not apply, and an enrichment by early fast-rotating massive stars was suggested. In order to further study the abundances in NGC 6522 we obtained a run with FLAMES- UVES in 2012, from which with the UVES data we have shown that the enhancement in s-elements could still be accommodated with the companion transfer model. We further obtained new data with FLAMES-UVES in 2016. In the present work we analyze another 6 stars observed at high resolution with UVES, and 32 stars at medium-high resolution observed with GIRAFFE. The latter were selected from their radial velocities of -14.3±15 km/s. The abundances of the light elements C, N, O, odd-Z elements Na, Al, -elements Mg, Si, Ca, Ti, iron-peak elements Mn, Cu, Zn, s-process elements Y, Zr, Ba, La, Ce, Nd and r-process element Eu are derived. Among the UVES stars, two of them show a significant enrichment in s-process elements and one of them show high [Y/Ba] and [Zr/Ba] ratios, suggesting that an early enrichment by fast rotating massive stars is a probable scenario.

No description available.

No description available.

Cette thèse présente une étude empirique et théorique approfondie de l'évolution spectrale des étoiles naines blanches, avec un accent particulier sur les naines blanches chaudes. La composition atmosphérique (et donc l'apparence spectrale) de ces cadavres stellaires peut changer drastiquement avec le temps à mesure qu'ils se refroidissent. Ce phénomène est généralement interprété comme le résultat d'une compétition entre divers mécanismes de transport des éléments dans l'enveloppe stellaire (tels que la diffusion, la convection, les vents et l'accrétion), mais demeure mal compris à plusieurs égards. Il est impératif de remédier à cette situation pour être en mesure d'exploiter le potentiel immense des naines blanches pour notre compréhension du passé de la Galaxie. Pour mieux caractériser l'incidence de l'évolution spectrale, nous effectuons tout d'abord une analyse spectroscopique exhaustive de près de 2000 naines blanches chaudes (Teff > 30,000 K) observées par le relevé SDSS. Nous déterminons les propriétés atmosphériques (notamment la température effective et la composition de surface) de ces objets à l'aide d'un nouvel ensemble de modèles d'atmosphère calculé spécifiquement à cet effet. En examinant la fréquence relative des étoiles riches en hydrogène et riches en hélium en fonction de la température, nous obtenons pour la première fois un portrait empirique détaillé de l'évolution spectrale des naines blanches chaudes. Plus spécifiquement, nous déduisons (1) qu'environ une étoile sur quatre arrive sur la séquence de refroidissement avec une atmosphère d'hélium, et (2) qu'environ deux tiers de ces objets développent ultérieurement une atmosphère d'hydrogène. En outre, nous accordons une attention particulière aux naines blanches hybrides (qui montrent à la fois des traces d'hydrogène et d'hélium) de notre échantillon et à ce que ces objets distinctifs nous apprennent sur l'évolution spectrale. Nous étudions ensuite l'évolution spectrale d'un point de vue théorique en modélisant les transformations chimiques qui s'opèrent dans les naines blanches. Pour ce faire, nous utilisons le code d'évolution stellaire STELUM, qui inclut un traitement cohérent et réaliste du transport des éléments et nous permet donc de réaliser les simulations numériques d'évolution spectrale les plus sophistiquées à ce jour. Nous modélisons la diffusion de l'hydrogène résiduel dans une enveloppe d'hélium à haute température, qui mène ultimement à la formation d'une atmosphère d'hydrogène. Nous simulons également le mélange convectif de cette couche superficielle d'hydrogène avec la couche sous-jacente d'hélium à basse température, qui produit à nouveau une surface dominée par l'hélium. En outre, nous étudions le transport du carbone dans les étoiles riches en hélium, incluant à la fois le tri gravitationnel à haute température et le dragage convectif à basse température. Ces calculs donnent lieu à plusieurs résultats astrophysiques d'intérêt. Nous obtenons notamment une contrainte inédite sur la quantité d'hydrogène résiduel contenue dans les naines blanches chaudes dominées par l'hélium. Nous démontrons aussi que la bifurcation observée dans le diagramme couleur-magnitude des naines blanches découvertes par le satellite Gaia est une signature du processus de mélange convectif à basse température. Par ailleurs, nos modèles fournissent de précieuses informations sur les propriétés des étoiles polluées par le carbone, en particulier sur leur masse et leur zone convective. Enfin, le résultat le plus important de cette thèse est la résolution définitive du problème le plus sérieux de la théorie de l'évolution spectrale, soit le problème de l'origine de l'hydrogène à la surface des naines blanches de type DBA. / This thesis presents an in-depth empirical and theoretical study of the spectral evolution of white dwarf stars, with a particular focus on hot white dwarfs. The atmospheric composition (and thus the spectral appearance) of these stellar remnants can change drastically over time as they cool. This phenomenon is generally interpreted as the result of an interplay between various element transport mechanisms in the stellar envelope (such as diffusion, convection, winds, and accretion), but remains poorly understood in several respects. It is imperative to remedy this situation to be able to exploit the immense potential of white dwarfs for our understanding of the past of the Galaxy. To better characterize the incidence of spectral evolution, we first carry out an exhaustive spectroscopic analysis of nearly 2000 hot white dwarfs (Teff > 30,000 K) observed by the SDSS survey. We determine the atmospheric properties (in particular the effective temperature and surface composition) of these objects using a new set of model atmospheres calculated specifically for this purpose. By examining the relative frequency of hydrogen-rich and helium-rich stars as a function of temperature, we obtain for the first time a detailed empirical picture of the spectral evolution of hot white dwarfs. More specifically, we infer (1) that about one in four stars enters the cooling sequence with a helium atmosphere, and (2) that about two-thirds of these objects eventually develop a hydrogen atmosphere. Furthermore, we pay special attention to the hybrid white dwarfs (which exhibit traces of both hydrogen and helium) in our sample and to what can be learned about spectral evolution from these distinctive objects. We then study spectral evolution from a theoretical point of view by modeling the chemical transformations that take place in white dwarfs. To do this, we use the stellar evolution code STELUM, which includes a consistent and realistic treatment of element transport and therefore allows us to perform the most sophisticated numerical simulations of spectral evolution to date. We model the diffusion of residual hydrogen in a helium envelope at high temperature, which ultimately leads to the formation of a hydrogen atmosphere. We also simulate the convective mixing of this superficial hydrogen layer with the underlying helium layer at low temperature, which once again produces a helium-dominated surface. Furthermore, we study the transport of carbon in helium-rich stars, including both gravitational settling at high temperature and convective dredge-up at low temperature. These calculations give rise to several astrophysical results of interest. In particular, we obtain an unprecedented constraint on the amount of residual hydrogen contained within hot helium-dominated white dwarfs. We also demonstrate that the bifurcation observed in the color-magnitude diagram of white dwarfs discovered by the Gaia satellite is a signature of the convective mixing process at low temperature. Furthermore, our models provide valuable information on the properties of carbon-polluted stars, in particular on their mass and convective zone. Finally, the most important result of this thesis is the definitive resolution of the most serious problem of the theory of spectral evolution, namely the problem of the origin of hydrogen at the surface of DBA-type white dwarfs.