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Alkylation of planar chiral cationic pi-allylmolybdenum complexes : the total synthesis of cryptophycin 4Christopher, John Andrew January 2000 (has links)
No description available.
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The modification of supported palladium and nickel catalysts for asymmetric hydrogenationYoung, Nicola C. January 1995 (has links)
No description available.
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Aldohaloketenes and the Stereochemistry of Aldohaloketene CycloadditionsHoff, Edwin Frank 05 1900 (has links)
The objective of this research problem was to synthesize aldohaloketenes and investigate the chemistry of this new class of ketenes.
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Stereochemical aspects of the intramolecular Diels-Alder reactionGillis, Herbert Russell January 1982 (has links)
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 1982. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCE / Includes bibliographical references. / by Herbert Russell Gillis, Jr. / Ph.D.
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Experimental studies in the isomerism and structural variations in molybdenum and rhenium halo-compoundsAnderson, Ian Robert. January 1968 (has links) (PDF)
Includes bibliography.
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Total synthesis of (+)-bourgeanic acid and conformational analysis of its dilactoneJohnson, Alan T. (Alan Thomas), 1957- 15 November 1990 (has links)
Graduation date: 1991
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Theoretical studies of organometallic reactions in water and the mechanism and stereochemistry of hydrosilylation and hydroacylation reactions /Chung, Lung Wa. January 2003 (has links)
Thesis (M. Phil.)--Hong Kong University of Science and Technology, 2003. / Includes bibliographical references. Also available in electronic version. Access restricted to campus users.
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A study of the stereoelectronic factors influencing nucleophilic attack at phosphorusWickersham, Thomas Winder 08 1900 (has links)
No description available.
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Reactions of sodium metal and alkali amides with 2,2,2-triphenylethyltrimethylammonium iodide and 2,2-dimethylpropyltrimethylammonium iodideRogers, Lynn Calloway 12 1900 (has links)
No description available.
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RCHDCHDX compounds as stereochemical probes : INDO and UMINDO investigations of a test to distinguish erythro and threo diastereomersBloss, Richard E. January 1979 (has links)
This research has investigated the validity of a recently proposed test for distinguishing erythro and threo diastereomers of RCHDCHDX compounds on the basis of temperature dependent nmr spectra. INDO and UMINDO semiempirical molecular orbital calculations were used to calculate all nmr vicinal proton-proton coupling constants of a series of CH3CH2CH2X compounds (X = BH2, CH3, NH2, OH, F, PH2, SH, Cl). These data were used to predict the relative temperature dependence of the time-averaged vicinal proton-proton coupling constants of the corresponding CH3CHDCHDX` compounds.Standard bond lengths and angles were used for the input of trial geometries. Coupling constant data were obtained for molecules with no geometry optimization, optimization of the CH3CCX dihedral angle and total geometry optimization. All results suggest that the proposed test for distinguishing erythro and threo diastereomers of RCHDCHDX compounds is valid.
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