Sediment is a major source of water quality impairment in streams, rivers and lakes in the US. However, sediment fate and transport in small streams is poorly understood. Previous attempts to characterize sediment transport often insufficiently represented the physical and chemical sediment properties and lacked spatial and/or temporal resolution. Therefore, there is a need to develop better sediment tracers, for which rare earth element (REE)-labeled sediment is examined as an alternative. The objectives of this study were to: 1) assess the adsorption of REEs to natural soils and ensure their reliability as a tracer in a fluvial environment; and 2) evaluate the efficacy of utilizing REE-labeled sediment to quantify fate and transport in a second-order stream during a series of storm events. Two natural stream bank soils from Stroubles Creek in Virginia were labeled with the REEs lanthanum and ytterbium. The REEs adsorbed equally to both soils and had minimal desorption after several washes with stream water. This suggests that REEs form a dependable natural sediment tracer and sufficiently label natural soils for use in a sediment tracing study. During two storm events, two unique REE tracers were injected into Stroubles Creek. These tracers were detected at varying discharges and sediment loads in bed and suspended sediment samples up to 875 m downstream. REE tracers proved to be an ideal tracer for detecting sediment fate and transport in a small stream during a series of storm events and hold great potential for evaluating best management practices and sediment transport models. / Master of Science

No description available.

Preferential flow paths are areas of substantially higher permeability than surrounding media. Macropores and soil pipes are a type of preferential flow path where conduit-like voids in the subsurface are typically greater than three millimeters in diameter. They are known to occur in agricultural and forest soils, often as a result of biological and physical processes. Macropores also exist in stream banks and have the potential to enhance the exchange of water and solutes between the channel and riparian groundwater, yet the geographic distribution of bank macropores is unknown. Here we determined the abundance, distribution, and geometry of naturally occurring surface-connected macropores in the banks of 20 streams across five physiographic provinces in the Eastern United States. We identified a total of 1,748 macropores, which were present in all 20 streams, with 3.8 cm average width, 3.3 cm average height, 11.5 cm average depth, and 27.9 cm average height above water surface elevation. Macropore abundance, distribution and geometry were statistically different between physiographic provinces, stream orders, and soil textures, with the latter being the most important. Macropores tended to be larger and more abundant in soils with a high cohesiveness and a low hydraulic conductivity compared to soils with a low cohesiveness and high hydraulic conductivity. As a result, streams with greater longitudinal heterogeneity of soil texture also had greater heterogeneity of macropore density. However, macropore size and height above baseflow water surface elevation also increased with stream order and therefore stream size. This work represents the first attempt to characterize macropores across a variety of riverine systems and presents evidence that macropores may play an important role in hyporheic exchange within stream banks. These results may have water quality implications, where macropores may enhance hyporheic exchange yet reduce the filtering capacity of riparian buffer zones. / MS / Preferential flow paths are soil cavities or areas of highly permeable porous media surrounded by media with a significantly lower permeability. Macropores are a type of preferential flow path where conduit-like voids in the subsurface are typically greater than three millimeters in diameter. Their formation is often the result of biological processes, such as animal burrows and plant roots, erosive action in subsurface flow, or cracks in the soil, and can enable rapid movement of water. Macropores are known to exist in stream banks and have the potential to enhance the exchange of water and solutes between the stream channel and riparian groundwater, yet the geographic distribution of bank macropores is unknown. This research examines the distribution, abundance, and geometry of naturally occurring macropores in the banks of 20 streams across five physiographic provinces in the eastern United States. Macropores were present in all 20 streams despite variations in physiographic province, stream order, and soil texture. However, soil texture appeared to have the greatest influence on the distribution, abundance, and geometry of macropores. For example, soils primarily containing silt and clay had more macropores than soils consisting of sand or gravel. We suspect this is due to differences in soil cohesiveness and/or hydraulic conductivity. This work represents the first attempt to characterize macropores across a variety of riverine systems and presents evidence that macropores may play an important role in surface water and groundwater exchange within stream banks. These results may have water quality implications, for example, how macropores affect the pollutant filtering capacity of riparian buffer zones.

Riparian buffers are promoted for water quality improvement, habitat restoration, and stream bank stabilization. While considerable research has been conducted on the effects of riparian buffers on water quality and aquatic habitat, little is known about the influence of riparian vegetation on stream bank erosion. The overall goal of this research was to evaluate the effects of woody and herbaceous riparian buffers on stream bank erosion. This goal was addressed by measuring the erodibility and critical shear stress of rooted bank soils in situ using a submerged jet test device. Additionally, several soil, vegetation, and stream chemistry factors that could potentially impact the fluvial entrainment of soils were measured. A total of 25 field sites in the Blacksburg, Virginia area were tested. Each field site consisted of a 2nd-4th order stream with a relatively homogeneous vegetated riparian buffer over a 30 m reach. Riparian vegetation ranged from short turfgrass to mature riparian forest. Multiple linear regression analysis was conducted to determine those factors that most influence stream bank erodibility and the relative impact of riparian vegetation. Results of this research indicated woody riparian vegetation reduced the susceptibility of stream bank soils to erosion by fluvial entrainment. Riparian forests had a greater density of larger diameter roots, particularly at the bank toe where the hydraulic stresses are the greatest. These larger roots (diameters > 0.5 mm) provided more resistance to erosion than the very fine roots of herbaceous plants. Due to limitations in the root sampling methodology, these results are primarily applicable to steep banks with little herbaceous vegetation on the bank face, such as those found on the outside of meander bends. In addition to reinforcing the stream banks, riparian vegetation also affected soil moisture and altered the local microclimate. While summer soil desiccation was reduced under deciduous riparian forests, as compared to herbaceous vegetation, winter freeze-thaw cycling was greater. As a result, in silty soils that were susceptible to freeze-thaw cycling, the beneficial effects of root reinforcement by woody vegetation were offset by increased freeze-thaw cycling. Using the study results in an example application, it was shown that converting a predominately herbaceous riparian buffer to a forested buffer could reduce soil erodibility by as much as 39% in soils with low silt contents. Conversely, for a stream composed primarily of silt soils that are prone to freeze-thaw cycling, afforestation could lead to localized increases in soil erodibility of as much as 38%. It should be emphasized that the riparian forests in this study were deciduous; similar results would not be expected under coniferous forests that maintain a dense canopy throughout the year. Additionally, because dense herbaceous vegetation would likely not develop in the outside of meander bends where hydraulic shear stresses are greatest, the reductions in soil erodibility afforded by the herbaceous vegetation would be limited to areas of low shear stress, such as on gently sloping banks along the inside of meander bends. As the first testing of this type, this study provided quantitative information on the effects of vegetation on subaerial processes and stream bank erosion. It also represents the first measurements of the soil erosion parameters, soil erodibility and critical shear stress, for vegetated stream banks. These parameters are crucial for modeling the effects of riparian vegetation for stream restoration design and for water quality simulation modeling. / Ph. D.

The research focused on the assessment of the effectiveness of the methods used in the implementation of environmental legislation in the Mutasa district of Zimbabwe. Successful implementation of environmental legislation and any other legislation is determined by various factors. Some of the factors include environmental education, environmental awareness programmes, consistency in implementing environmental legislation, coordination of all stakeholders, willingness of communities to co-operate and the political will by political office bearers. This research revealed that the methods used to implement environmental legislation in the Mutasa district of Zimbabwe are ineffective. Poverty is the main reason for activities leading to environmental degradation. Communities in the Mutasa district of Zimbabwe are ignorant of environmental legislation which govern their activities. Environmental education and environmental awareness programmes are rarely carried out. The political office bearers in the Mutasa district lack the political will to ensure that environmental legislation are enforced. / Public Administration / MPA (Public Administration)

The research focused on the assessment of the effectiveness of the methods used in the implementation of environmental legislation in the Mutasa district of Zimbabwe. Successful implementation of environmental legislation and any other legislation is determined by various factors. Some of the factors include environmental education, environmental awareness programmes, consistency in implementing environmental legislation, coordination of all stakeholders, willingness of communities to co-operate and the political will by political office bearers. This research revealed that the methods used to implement environmental legislation in the Mutasa district of Zimbabwe are ineffective. Poverty is the main reason for activities leading to environmental degradation. Communities in the Mutasa district of Zimbabwe are ignorant of environmental legislation which govern their activities. Environmental education and environmental awareness programmes are rarely carried out. The political office bearers in the Mutasa district lack the political will to ensure that environmental legislation are enforced. / Public Administration and Management / MPA (Public Administration)