by Sou Ka Hou. / On t.p. "2', "3", and "T" are subscript following "deposition of" in the title. / Parallel title in Chinese characters. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1992. / Includes bibliographical references (leaves [88]). / Chapter 1. --- Introduction --- p.1 / Chapter 2. --- Computer-controlled sputtering system for deposition of high Tc thin films --- p.10 / Chapter 2.1 --- Introduction --- p.10 / Chapter 2.2 --- Vacuum system --- p.12 / Chapter 2.3 --- Gas flow control --- p.16 / Chapter 2.3.1 --- Design --- p.16 / Chapter 2.3.2 --- Flow control --- p.18 / Chapter 2.4 --- Gas pressure control --- p.21 / Chapter 2.4.1 --- Gauges --- p.21 / Chapter 2.4.2 --- Control method --- p.21 / Chapter 2.5 --- "Sputtering, guns and deposition control" --- p.24 / Chapter 2.5.1 --- Types --- p.24 / Chapter 2.5.2 --- Orientation of the sputter gun --- p.26 / Chapter 2.5.3 --- Dual magnetron gun system --- p.26 / Chapter 2.5.4 --- Deposition control system --- p.27 / Chapter 2.6 --- Substrate holder and temperature control --- p.30 / Chapter 2.6.1 --- Substrate holder --- p.30 / Chapter 2.6.2 --- Substrate temperature control --- p.31 / Chapter 2.7 --- Interlock protection --- p.34 / Chapter 2.8 --- Control program --- p.35 / Chapter 3. --- The presputtering effect --- p.39 / Chapter 3.1 --- Presputtering effect (a review) --- p.39 / Chapter 3.2 --- Emission spectroscopy on sputtered materials --- p.48 / Chapter 3.3 --- Experimental --- p.49 / Chapter 3.4 --- Emission spectra --- p.53 / Chapter 3.4.1 --- Effect of sputter power source --- p.53 / Chapter 3.4.2 --- Effect of gas ratio --- p.58 / Chapter 3.4.3 --- Effect of gas pressure --- p.64 / Chapter 3.4.4 --- Study of presputtering effect --- p.67 / Chapter 3.4.5 --- Monitoring the evaporation rate by the spectral line intensities --- p.71 / Chapter 4. --- Conclusion and discussion --- p.75 / Chapter Appendix A. --- Motor control --- p.77 / Chapter Appendix B. --- Thin film deposition --- p.82

Thesis. 1978. Ph.D.--Massachusetts Institute of Technology. Dept. of Physics. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCE. / Vita. / Includes bibliographical references. / by William J. Gallagher. / Ph.D.

Iron-based high temperature superconductors are a large family of materials that exhibit unconventional superconductivity and arise from antiferromagnetically-ordered parent compounds. One of the grand challenges in understanding the behavior of these materials is determining the physical mechanisms responsible for the transition into the superconducting state. This thesis describes two recent investigations to explore the magnetic and superconducting properties of NaFeAs in response to changes in temperature and nickel dopants. The peculiar interplay of magnetism and superconductivity in nickel-doped NaFeAs is elucidated using muon spin rotation. Our experimental findings on this novel system are supported with both computational and theoretical calculations. The second investigation describes an improvement to the analysis framework to the scanning tunneling microscopy technique that leverages recent advances in nonconvex optimization. This novel approach is applied directly to microscopy images of NaFeAs to provide unprecedented phase-sensitive access to the quasiparticle scattering spectrum in the material. These results place constraints on theoretical models that describe the local electronic structure and physics of NaFeAs.

Ferromagnetism (FM) and superconductivity (SC) are traditionally thought of as competing states of matter, since the opposite-spin electron pairing mechanism required for conventional SC is rendered impossible by FM spin alignment. However, recently discovered heavy-fermion compounds UGe2 and URhGe are examples where SC and FM are cooperative, and rather than antagonistic the presence of FM is actually necessary for the occurrence of the SC phase. A cooperative state of FM and SC is a topic of interest because it presents a possible solution to one of the two main problems with present superconductors: technology inhibiting limits on the highest temperature and highest magnetic field to which the SC phase can exist. Although both UGe2 and URhGe cease to be superconductors before even reaching 1 K, unlike the various `high temperature' superconductors currently known that easily surpass 100 K, it is their magnetic properties that are interesting, the inherent FM ordering allowing them to exceed conventional limits on the maximum magnetic field that SC can withstand. For example, URhGe remains superconducting above 35 T and the upper limit is so high that it is still experimentally undetermined. How exactly the FM SC phase arises in these compounds is as yet unknown. The necessary opposite-spin pairing mechanism is theoretically provided by magnetic fluctuations in an easily polarizable system right on the edge of a magnetic phase transition, and indeed SC emerges in UGe2 and URhGe around a first-order quantum critical point (QCP) where the temperature of the transition to an FM phase is reduced to absolute zero, by application of pressure in the case of UGe2 and by application of a magnetic field for URhGe. The aim of the research detailed in this thesis is to probe the FM phase transition and the associated QCP related to the emergence of SC in these compounds, to gather more information about the precise nature of the phases either side of the transition and exactly what changes occur in the system crossing the QCP. Specifically, the main objective is to characterise the magnetic fluctuations at the phase boundary and determine whether, by current FM SC theory, these fluctuations could be responsible for SC or if instead other, modified, unconventional theories are required to explain the unconventional electron pairing. The probes of choice for this PhD were Hall effect and magnetoresistance measurements of UGe2, and capacitive torque magnetometry and simultaneous magnetoresistance measurements of URhGe. The main result of the UGe2 project is an observed order-of-magnitude change in the Hall coefficient crossing the FM transition as a function of temperature and a dramatic change, similar in magnitude but also accompanied by a sign reversal, crossing the QCP as a function of pressure. Furthermore, the sign reversal at the critical pressure persists up to roughly 12 K, far beyond the 7 K critical end point of the phase transition, suggesting that in fact three different phases converge at the QCP where fluctuations between them presumably lead to the emergence of SC. Further investigation of the Fermi surface, either by deeper analysis of the Hall effect results or by other experimental methods, will be required to complete the main objective and determine exactly what the differences are between these newly identified phases. The main result of the URhGe project is actually the successful development of the capacitive torque magnetometry technique itself and the proof of operation for simultaneous measurement of all the individual components of both the magnetization and differential susceptibility tensors in a high magnetic field, which is currently not possible by any other technique. Completing the main objective was hampered by the extremely high susceptibility components encountered in the vicinity of the QCP, which in itself could be considered evidence for the theoretical relationship between strong FM fluctuations and the emergence of SC in URhGe. A number of results incidental to the main aim of the URhGe project are also summarised in this thesis, including the characterisation of quantum oscillations frequencies not previously reported in scientific literature and a variety of subtle features in resistivity measurements, which could, in conjunction with evidence from the susceptibility measurements, suggest the presence of another superconducting state such as surface or domain wall SC.

Lai, Kwing To = 鐵基超導體的合成與分析 : 氟及釔合摻SmFeAsO / 黎烱韜. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2011. / Includes bibliographical references. / Abstracts in English and Chinese. / Lai, Kwing To = Tie ji chao dao ti de he cheng yu fen xi : fu ji yi he shan SmFeAsO / Li Jiongtao. / Abstract --- p.i / 摘要 --- p.iii / Acknowledgements --- p.v / Table of contents --- p.vii / List of table captions --- p.x / List of figure captions --- p.xi / Chapter Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Superconductivity --- p.1 / Chapter 1.1.1 --- Physical properties --- p.3 / Chapter 1.1.1.1 --- Zero resistance --- p.3 / Chapter 1.1.1.2 --- Meissner effect --- p.4 / Chapter 1.1.1.3 --- Josephson effect --- p.5 / Chapter 1.1.2 --- Type I and II superconductivity --- p.7 / Chapter 1.2 --- Iron-based superconductors --- p.7 / Chapter 1.2.1 --- Classifications and structures --- p.8 / Chapter 1.2.2 --- Physical properties --- p.12 / Chapter 1.2.3 --- Iron-based superconductors versus Cuprate superconductors --- p.13 / Chapter 1.2.4 --- Correlation between high-Tc superconductivity and magnetism --- p.14 / Chapter 1.2.5 --- Quantum phase transition by doping --- p.16 / Chapter 1.2.6 --- Sample preparation of undoped and doped iron-based superconductors --- p.17 / Chapter 1.3 --- Objectives of this research project --- p.18 / References --- p.20 / Chapter Chapter 2 --- Literature Review --- p.22 / Chapter 2.1 --- Theories of superconductivity --- p.22 / Chapter 2.1.1 --- London equation --- p.22 / Chapter 2.1.2 --- Ginzburg-Landau theory --- p.24 / Chapter 2.1.2.1 --- Mean-field theory and Landau theory --- p.24 / Chapter 2.1.2.2 --- Spatial varying order parameter and Gauge symmetry --- p.27 / Chapter 2.1.2.3 --- Applications --- p.31 / Chapter 2.1.3 --- BCS theory --- p.35 / Chapter 2.2 --- Magnetism in condensed matters --- p.39 / Chapter 2.2.1 --- Ferromagnetism and Antiferromagnetism from local moments --- p.40 / Chapter 2.2.1.1 --- Mathematical explanation in the mean-field approach --- p.40 / Chapter 2.2.1.2 --- Exchange interaction --- p.43 / Chapter 2.2.2 --- Antiferromagnetism in magnetic metals: Spin density wave --- p.45 / References --- p.52 / Chapter Chapter 3 --- Methodology and Instrumentation --- p.53 / Chapter 3.1 --- Sample preparation --- p.53 / Chapter 3.2 --- Characterization --- p.55 / Chapter 3.2.1 --- Scanning electron microscopy (SEM) and Energy dispersive X-ray spectroscopy (EDX) --- p.55 / Chapter 3.2.2 --- Transmission electron microscopy (TEM) and Electron diffraction --- p.55 / Chapter 3.2.3 --- X-ray diffraction (XRD) --- p.56 / Chapter 3.2.4 --- X-ray photoelectron spectroscopy (XPS) --- p.57 / Chapter 3.2.5 --- Physical properties measuring system (PPMS) --- p.58 / Chapter 3.2.5.1 --- Transport properties --- p.58 / Chapter 3.2.5.2 --- Magnetic properties --- p.60 / Chapter 3.2.6 --- Raman spectroscopy --- p.62 / Chapter 3.3 --- Precautions --- p.62 / References --- p.63 / Chapter Chapter 4 --- Results --- p.64 / Chapter 4.1 --- Fluorine-doped SmFeAsO --- p.64 / Chapter 4.1.1 --- Morphologies and microstructures --- p.67 / Chapter 4.1.2 --- Phase and composition --- p.69 / Chapter 4.1.3 --- Lattice constants --- p.72 / Chapter 4.1.4 --- Transport properties --- p.73 / Chapter 4.1.5 --- Magnetic properties --- p.74 / Chapter 4.2 --- Fluorine and Yttrium co-doped SmFeAsO --- p.78 / Chapter 4.2.1 --- Morphologies and microstructures --- p.79 / Chapter 4.2.2 --- Phase and composition --- p.82 / Chapter 4.2.3 --- Lattice constants --- p.84 / Chapter 4.2.4 --- Oxidation state --- p.85 / Chapter 4.2.5 --- Transport properties --- p.88 / Chapter 4.2.6 --- Magnetic properties --- p.89 / Chapter 4.3 --- Quality control of the superconducting products --- p.94 / Chapter 4.3.1 --- Intermediate product SmAs --- p.95 / Chapter 4.3.2 --- Intermediate product FeAs --- p.104 / Chapter 4.3.3 --- Effects of annealing temperature --- p.110 / Chapter 4.4 --- Summary --- p.112 / References --- p.112 / Chapter Chapter 5 --- Discussions --- p.113 / Chapter 5.1 --- Effects of F doping --- p.113 / Chapter 5.2 --- Effects of YF doping --- p.115 / Chapter 5.3 --- Improvements in the quality of the superconducting samples --- p.117 / Chapter 5.4 --- Summary --- p.124 / References --- p.125 / Chapter Chapter 6 --- Conclusions and Suggestions for Future work --- p.126 / Chapter 6.1 --- Conclusions --- p.'126 / Chapter 6.2 --- Suggestions for future work --- p.128 / References --- p.130 / Chapter Appendix A --- Sealing samples in small evacuated silica capsules for DTA measurements --- p.131 / Chapter Appendix B --- AC susceptibility measurement --- p.133 / Chapter Appendix C --- Suggested readings for beginners --- p.135 / Bibliography --- p.138

Yeung, Him Ching = 以粉末混合方法及夾心樣品方法製作的硼化鎂的特性研究 / 楊謙靖. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2008. / Includes bibliographical references. / Abstracts in English and Chinese. / Yeung, Him Ching = Yi fen mo hun he fang fa ji jia xin yang pin fang fa zhi zuo de peng hua mei de te xing yan jiu / Yang Qianjing. / Abstract --- p.i / 摘要 --- p.iii / Acknowledgments --- p.v / Table of contents --- p.vi / List of table captions --- p.viii / List of figure captions --- p.ix / Chapter Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Superconductors --- p.1 / Chapter 1.1.1 --- Classifications --- p.1 / Chapter 1.1.2 --- Conventional versus unconventional --- p.2 / Chapter 1.1.3 --- Type I and Type II superconductors --- p.4 / Chapter 1.1.4 --- Critical current Jc and the Bean´ةs Model --- p.5 / Chapter 1.2 --- Magnesium diboride --- p.8 / Chapter 1.2.1 --- Structure --- p.8 / Chapter 1.2.2 --- Physical properties --- p.8 / Chapter 1.2.3 --- Chemical properties --- p.9 / Chapter 1.2.4 --- Conduction mechanisms --- p.9 / Chapter 1.2.5 --- Fabrication methods --- p.9 / Chapter 1.3 --- Objectives of this work --- p.10 / References --- p.12 / Figures --- p.14 / Chapter Chapter 2 --- Methodology and instrumentation --- p.17 / Chapter 2.1 --- Experimental procedures --- p.17 / Chapter 2.2 --- Samples preparation --- p.17 / Chapter 2.2.1 --- Powder mixing approach --- p.17 / Chapter 2.2.2 --- Sandwich structure approach --- p.18 / Chapter 2.3 --- Samples fabrication --- p.18 / Chapter 2.4 --- Determination of compositions --- p.18 / Chapter 2.5 --- Characterization --- p.19 / Chapter 2.5.1 --- X-ray diffractometry (XRD) --- p.19 / Chapter 2.5.2 --- Microstructural analysis --- p.20 / Chapter 2.5.3 --- Magnetic measurements --- p.20 / Chapter 2.5.3.1 --- Setup for Jc measurements --- p.21 / Reference --- p.22 / Figures --- p.23 / Chapter Chapter 3 --- Powder mixing approach --- p.26 / Chapter 3.1 --- Results --- p.26 / Chapter 3.1.1 --- XRD results --- p.26 / Chapter 3.1.2 --- Compositions --- p.27 / Chapter 3.1.3 --- SEM results --- p.28 / Chapter 3.1.3.1 --- Sample sintered at 600°C --- p.28 / Chapter 3.1.3.2 --- Samples sintered at 700°C and 800°C --- p.28 / Chapter 3.1.3.3 --- Sample sintered at 900°C --- p.29 / Chapter 3.1.3.4 --- Sample sintered at 1000°C --- p.29 / Chapter 3.1.3.5 --- Sample sintered at 1050°C --- p.29 / Chapter 3.1.4 --- VSM results --- p.30 / Chapter 3.1.4.1 --- Tc measurements --- p.30 / Chapter 3.1.4.2 --- Hysteresis loops --- p.31 / Chapter 3.1.5 --- Jc measurements --- p.31 / Chapter 3.1.5.1 --- Direct measurement --- p.31 / Chapter 3.1.5.2 --- The Bean´ةs Model --- p.32 / Chapter 3.2 --- Discussions --- p.32 / Chapter 3.3 --- Summary --- p.35 / References --- p.36 / Figures --- p.37 / Tables --- p.47 / Chapter Chapter 4 --- Sandwich structure approach --- p.49 / Chapter 4.1 --- Results --- p.49 / Chapter 4.1.1 --- SEM results --- p.49 / Chapter 4.1.1.1 --- Surface of the Mg disk --- p.49 / Chapter 4.1.1.2 --- Inner region of the Mg disk --- p.50 / Chapter 4.1.2 --- XRD results --- p.50 / Chapter 4.1.2.1 --- Surface of the Mg disk --- p.50 / Chapter 4.1.2.2 --- Inner region of the Mg disk --- p.51 / Chapter 4.1.3 --- VSM results --- p.51 / Chapter 4.1.3.1 --- Tc measurement --- p.51 / Chapter 4.1.3.2 --- Hysteresis loops --- p.52 / Chapter 4.2 --- Discussions --- p.52 / Chapter 4.3 --- Summary --- p.54 / Reference --- p.54 / Figures --- p.55 / Tables --- p.61 / Chapter Chapter 5 --- Growth Mechanism --- p.62 / Chapter 5.1 --- Introduction --- p.62 / Chapter 5.2 --- Brief summary of results --- p.62 / Chapter 5.2.1 --- Powder mixing approach --- p.62 / Chapter 5.2.2 --- Sandwich structure approach --- p.63 / Chapter 5.3 --- Formation of the MgB2 platelets --- p.63 / Chapter 5.4 --- Size of the MgB2 platelets --- p.67 / Chapter 5.5 --- Summary --- p.68 / References --- p.69 / Figures --- p.70 / Tables --- p.75 / Chapter Chapter 6 --- Conclusions and suggestions of future work --- p.76 / Chapter 6.1 --- Summary --- p.76 / Chapter 6.2 --- Future work --- p.77 / Appendix 1 --- p.79 / Appendix 2 --- p.81

The gradual increase in global warming and environmental pollution has made low-carbon technologies an urgent need for the whole world. Superconducting technology, which is known for its extremely high conductivity and high power density, is capable enough to provide novel solutions, contributing to the future smart grid, thus aiding the power industry towards the realisation of a low-carbon and green planet. In recent decades, several industrial applications using superconducting technology have been developed. Of them, particularly in the power industry, a range of superconducting applications including superconducting magnetic energy storage (SMES), superconducting motors/generators, superconducting cables and superconducting fault current limiters (SFCLs) have been developed. Among them, SFCLs are one of the most promising and are successfully being implemented in power distribution networks. SFCLs exhibit low impedance during normal operation and gain considerable impedance under a fault condition, providing a new solution to the increasingly high fault current levels. However, most of the SFCL projects are limited to low-voltage and medium-voltage levels, there are very few successful operational trials of high voltage SFCLs. This thesis, for the first time, studies the comprehensive characteristics of solenoid type SFCLs based on second generation (2G) high temperature superconductors (HTS), which may be successfully implemented in power grids with high voltage levels. The main contributions of this work include three aspects: 1) proposing an innovative method for simulating the AC losses of the solenoid coils and an electro-magneto-thermal model for simulating the SFCL’s current limiting property; 2) comprehensive and in-depth comparison study concerning the application of the two types of non-inductive solenoid coils (braid type and non-intersecting type) in SFCLs both experimentally and numerically; and 3) the first and thorough discussion of the impact of different parameters such as pitch and radius of coils to the overall performance of braid type SFCLs and the validation of the braid type SFCL concept with a 220 V/300 A SFCL prototype. Based on these experimental and simulation works, the thesis provide strong guidance for the development of future non-inductive solenoid type SFCLs based on 2G HTS, which are promising for high voltage level power grid applications.

Graduation date: 1997

I. S?mon. / 3697726 RSC / "June 15, 1949." / Bibliography: p. 27. / Army Signals Corps Contract No. W36-039-sc-32037 Project No. 102B. Dept. of the Army Project No. 3-99-10-022.

E. Maxwell, P.M. Marcus, J.C. Slater. / "This paper is based on a thesis submitted in partial fulfillment of the Degree of Doctor of Philosophy at M.I.T." "May 2, 1949." / Bibliography: p. 55. / Army Signal Corps Contract No. W36-039-sc-32037 Project No. 102B Dept. of the Army Project No. 3-99-10-022