In the current work, two different coatings, nitrocarburised (CN) and titanium carbonitride (TiCN) on M2 grade high speed tool steel, were prepared by commercial diffusion and physical vapour deposition (PVD) techniques, respectively. Properties of the coating were characterised using a variety of techniques such as Glow-Discharge Optical Emission Spectrometry (GD-OES) and Scanning Electron Microscopy (SEM). Three non-commercial, oil-based lubricants with simplified formulations were used for this study. A tribological test was developed in which two nominally geometrically-identical crossed cylinders slide over each other under selected test conditions. This test was used to evaluate the effectiveness of a pre-applied lubricant film and a surface coating for various conditions of sliding wear. Engineered surface coatings can significantly improve wear resistance of the tool surface but their sliding wear performances strongly depend on the type of coating and lubricant combination used. These coating-lubricant interactions can also have a very strong effect on the useful life of the lubricant in a tribological system. Better performance of lubricants during the sliding wear testing was achieved hen used with the nitrocarburised (CN) coating. To understand the nature of the interactions and their possible effects on the coating-lubricant system, several surface analysis techniques were used. The molecular level investigation of Fourier Transform Infrared Spectroscopy (FTIR) revealed that oxidative degradation occurred in all used oil-based lubricants during the sliding wear test but the degradation behaviour of oil-based lubricants varied with the coating-lubricant system and the wear conditions. The main differences in the carbonyl oxidation region of the FTIR spectra (1900-1600 cm-1) between different coating-lubricant systems may relate to the effective lifetime of the lubricant during the sliding wear test. Secondary Ion Mass Spectrometry (SIMS) depth profiling shows that the CN coating has the highest lubricant absorbability among the tested tool surfaces. Diffusion of chlorine (C1), hydrogen (H) and oxygen (O) into the surface of subsurface of the tool suggested that strong interactions occurred between lubricant and tool surface during the sliding wear test. The possible effects of the interactions on the performance of whole tribological system are also discussed. The study of Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) indicated that the envelope of hydrocarbons (CmHn) of oil lubricant in the positive TOF-SIMS spectra shifted to lower mass fragment after the sliding wear testing due to the breakage of long-chain hydrocarbons to short-chain ones during the degradation of lubricant. The shift of the mass fragment range of the hydrocarbon (CmHn) envelope caries with the type of both tool surface and lubricant, again confirming that variation in the performance of the tool-lubricant system relates to the changes in surface chemistry due to tribochemical interactions at the tool-lubricant interface under sliding wear conditions. The sliding wear conditions resulted in changes not only in topography of the tool surface due to mechanical interactions, as outlined in Chapter 5, but also in surface chemistry due to tribochemical interactions, as discussed in Chapters 6 and 7.

This study explores the application, benefits, and challenges associated with the implementation of Slippery Liquid-Infused Porous Surfaces (SLIPS) technology with additive manufacturing, with a particular focus on healthcare highlighting its potential to enhance the performance and safety of medical devices and implants by preventing biofouling and bacterial colonization. Challenges in the complex process of manufacturing implantable devices, requiring specialized equipment and expertise, present a significant barrier to widespread use, particularly in resource-limited settings. These delicate implants are then used to perform regenerative, therapeutic, and diagnostic functionalities in patients, significantly advancing the healthcare practice. On the other hand, most of these implants experience the biofouling issue caused by a complex of bacteria and protein on the surface of the implants during operation. In this study, we developed a durable yet practical antifouling strategy by integrating SLIPS coating technique – a bioinspired ultra-repellent surface – with an advanced additive manufacturing technique. SLIPS technology utilizes a mechanism where a stable, immiscible lubricant layer is infused into a porous or textured solid substrates. The embedded lubricant layer is specifically designed to be immiscible with other liquids, preventing liquids from wetting the SLIPS-treated surface and allowing them to simply glide off. The lubricant's creation of a liquid-liquid interface, which greatly lowers adhesion and friction between the surface and any touching materials, is what causes this effect. Integrating SLIPS with 3D printing technology enables the creation of a complex, customizable surface with enhanced antifouling and self-cleaning properties. 3D structures were printed using after meticulous designing process and printing parameters so that the designs had a 200-300µm of pore size and could give a capillary wicking action. This process can streamline the overall process by providing rapid prototyping, design flexibility, customization and personalization, and integration of complex features. The fabrication process of this involves chemical vapour deposition of Trichloro (1H, 1H, 2H, 2H – Perfluorooctyl), which is a fluorinated silane compound, making the surface molecule hydrophobic and oleophobic and immersing the silanized devices into Perflourodecalin (PFD). The PFD often used in healthcare industry, acts as the lubricant layer and forms SLIPS. Our approach to characterize the SLIPS-modified samples involved testing the samples for the sliding angle defined as minimum angle of inclination at which a droplet on the surface begins to move or slide off serving as a critical measure of the surface’s repellency and effectiveness in minimizing adhesion. To further quantify our study, we inoculated the samples with S.aureus bacterium for 1, 2, 5, and 7 days and analysed them for the formation of biolfilm. Our study successfully integrates the SLIPS technology into additive manufacturing and validates the claims of SLIPS technology for its antiadhesive and antifouling properties. Additionally, long-term durability and the performance of SLIPS in real-world applications are areas of active research, with the stability and longevity of the lubricant layer being critical for maintaining its unique properties over time alongside the need for periodic maintenance. In healthcare, the biocompatibility and safety of the lubricants used in SLIPS coatings are paramount, demanding thorough testing to ensure patient safety and regulatory compliance. Moreover, the mechanical durability and resistance to wear of SLIPS coatings are crucial for their sustained effectiveness in medical applications. This study emphasizes the need for collaborative research, clinical trials, and regulatory dialogue to overcome these challenges and fully realize the potential of SLIPS technology in 3D printed implants improving medical device performance and patient safety.

Embodiment grows out from deep concerns about the body and embodied knowledge across disciplines. As both subject and object, the body demands explorations that move beyond the dichotomy of body and mind, surface and depth, outside and inside. The interaction, intensity, and interstanding in the middle activate the body to move, to feel, and to be with other bodies. In the information age, with the rapid change in digital, computerized, and networkable technology, coupled with our growing concerns about the environment, embodiment becomes more complex and shatters the boundaries between human and nonhuman. In a sense, embodiment becomes posthuman by extending itself to interactions and interstandings with other species. In this dissertation, I extend embodiment into aesthetics and media by thickening the notion of surface in all of its profundity, contentious forces, and intertextuality. I emphasize as well its significance in exploring what an embodied curriculum and pedagogy could become for schools and society. This dissertation points toward the interaction and interstanding between philosophy, art, and technology. It encourages a notion of experience that engages readers/viewers viscerally with a technically manipulated surface. The readers/viewers not only encounter the theoretical mapping of the content of this dissertation, but also imagine and investigate the metaphorical and metaphysical possibilities of curriculum and pedagogy.

This exam report includes a survey of surface treatment materials and their associated surface treatment methods for application in a tissue machine commissioned by Valmet AB. The tissue machine produces 24 hours a day in a demanding environment consisting of water, heat, oils, glue, dust and various chemicals. The demanding environment makes it difficult to maintain the machine clean due to the limited access at various machine parts when the machine is operating, which can lead to both personal risks and risks for production stoppages. These factors form the basis for the build-ups that takes place at various machine parts. Mostly, it’s about paper fibres that either are loose and dry or clustered into lumps. They also appear as lumps of fibres held together by oil, glues or other chemicals. Over time, they can loosen and, in the worst case, are due to breakages and production failures. The build-ups can also destroy the function of moving machine parts or lead to corrosion. The commission was assigned by Bengt O Andersson and Mickey Lindevall at Valmet AB. The project was conducted as the examining part in the course Degree Project for the Bachelor of Science in Mechanical Engineering, MSGC17, at the faculty of health, science and technology at Karlstad university. The project was carried out individually by a student at the Bachelor of Science program in Mechanical Engineering at Karlstad university. This degree project has taken precedence where the previous degree project at Valmet AB completed its work. The previous degree project has served as a reference document in this report to work out a requirement specification and identifying machine parts that are desired to undergo some form of surface treatment. The acting environments that exist at the various machine parts that are desired to be surface treated have also been examined from the previous degree project. This report has taken a different approach compared to the previous thesis work and is instead directed towards finding suitable surface treatment materials and associated application methods using the material database, CES EduPack. The purpose of the degree project has been to present suitable surface treatment materials and associated surface treatment methods. These are to solve the existing problems, thus facilitating cleaning and maintenance of the tissue machine. To achieve this, a list of suitable materials and associated surface treatment methods has been presented. From this list, conclusions are drawn to find as good surface treatment materials and its associated application methods as possible. With these, the problem should be eliminated or reduced drastically for the number of build-ups regarding the treated machine parts. The objective for this project thesis has been to analyse and proposing suitable methods and materials for surface treatments. With the chosen method and material for the surface treatment, the surfaces upon application are to achieve such properties that build-ups do not adhere to them. The project also contains a requirement specification that has been translated into restriction terms that all investigated material candidates have had to fulfil to be classified as suitable material candidates. The report has also taken a stand to the literature and theory available in the subject area to further investigate what materials are currently used in similar industrial applications. The information that has been processed has, in a final phase, been used as a basis for the list of suitable surface treatment materials and their associated surface treatment methods presented in the report. / Denna examensrapport innefattar en undersökning av ytbehandlingsmaterial samt tillhörande ytbehandlingsmetoder för applicering i en mjukpappersmaskin på uppdrag av Valmet AB. Mjukpappersmaskinen producerar 24 timmar om dygnet i en krävande miljö bl.a. bestående av vatten, värme, oljor, lim, damm samt diverse kemikalier. Den krävande miljön gör att det är svårt att hålla maskinen ren eftersom att det är svårt att komma åt överallt under drift, vilket kan medföra både personrisker och risker för produktionsstopp. Dessa faktorer ligger till grund för att uppbyggningar uppstår vid diverse maskindelar. Mestadels handlar det om pappersfibrer som endera är lösa torra eller fasttorkade i klumpar men de förekommer även som klumpar av fibrer som hålls ihop av olja, lim eller andra kemikalier. Med tiden så kan dessa lossna och ligger i värsta fall till grund för banbrott och produktionsbortfall. Uppbyggningarna kan även förstöra funktionen på rörliga maskindelar eller leda till korrosion. Uppdraget är utgivet av Bengt O Andersson och Mickey Lindevall på Valmet AB. Projektet utförs som den examinerande delen i kursen Examensarbete för högskoleingenjörsexamen i Maskinteknik, MSGC17 vid fakulteten för hälsa, natur- och teknikvetenskap vid Karlstads universitet. Projektet har utförts enskilt av studerande vid Högskoleingenjörsprogrammet i Maskinteknik vid Karlstads universitet. Detta examensarbete har tagit vid där föregående examensarbetare vid Valmet AB avslutade sitt arbete. Dennes examensrapport har fungerat som ett referensdokument i denna rapport för att kunna arbeta fram en kravspecifikation samt identifiera maskindelar som önskas genomgå någon form av ytbehandling. De verkande miljöerna som existerar vid de maskindelar som önskas ytbehandlas har även undersökts från det tidigare examensarbetet. Denna rapport har tagit ett nytt tillvägagångssätt gentemot föregående examensarbetare och riktas istället mot att identifiera lämpliga ytbehandlingsmaterial samt tillhörande applikationsmetoder med hjälp av materialdatabasen, CES EduPack. Syftet med detta examensarbete har varit att presentera lämpliga ytbehandlingsmaterial samt tillhörande ytbehandlingsmetoder som löser de befintliga problemen och därmed underlättar rengöring och underhåll av mjukpappersmaskinen. För att kunna göra detta har en lista av lämpliga material samt tillhörande ytbehandlingsmetoder tagits fram. Ur denna lista med material och ytbehandlingsmetoder dras slutsatser för att hitta ett så bra ytbehandlingsmaterial och tillhörande ytbehandlingsmetod som möjligt. Med dessa skall problemet elimineras eller minskas drastiskt gällande antal uppbyggningar vid behandlade maskindelar. Examensarbetet har som mål att analysera och ge förslag på lämpliga metoder och material för ytbehandlingar. Med vald metod och material för ytbehandling skall ytorna vid applicering få en sådan egenskap att uppbyggningar inte vidhäftar vid dessa. Projektet innehåller även en kravspecifikation som översatts till restriktionsvillkor som samtliga undersökta materialkandidater varit tvungna att passera för att klassas som lämpliga materialkandidater. Rapporten har även tagit ställning till den litteratur och teori som funnits tillgänglig inom ämnesområdet för att vidare undersöka vilka material som används i dagsläget inom liknande industriella tillämpningar. Informationen som tagits fram har i ett slutskede legat som grund för den lista av lämpliga ytbehandlingsmaterial samt dess tillhörande ytbehandlingsmetoder som presenteras i rapporten.

High strength aluminum alloys have for a long time been a popular material utilized in the automotive and aerospace sector due to coveted mechanical properties in terms of weight, strength, fatigue, and corrosion. However, tribological mechanisms such as tribo-film formation and material transfer during the metal cutting manufacturing process of aluminum impose significant reduction of machining and tool-life performance. Additionally, environmental aspects associated with metal cutting manufacturing has got more interest and pushed cutting tool development in new directions to meet increased customer demands. One possible way of achieving this, is the implementation and utilization of diamond based cutting tools which has been shown to perform well in machining of high strength aluminum. However, in depth knowledge regarding the tribological properties of diamond based cutting tools is currently lacking. Thus, the aim of this master thesis has been to investigate the refined tribological characteristics and properties of WC-Co cemented carbide cutting tools coated with synthetically grown CVD diamond. Tribological testing methods, such as frictional scratch/sliding, pin-turning, contact-zone temperature measuring, and longitudinal turning have been conducted to acquire extensive amount of research material in the form of test samples and data information. Furthermore, pin-turning tests were performed using a newly developed Tribojan pin-turning equipment and the performance of this was evaluated as a subgoal task. Specimen sample analysis have primarily been performed through LOM and SEM/EDS microscopy techniques. The results acquired from testing, microscopy analysis and data set evaluation have showed promising results in terms of frictional characteristic and material transfer properties regarding CVD diamond coated surfaces. The average CoF of CVD diamond sliding against an Alumec 89 aluminum alloy surface were somewhat lower as compared with similar sliding of a conventional uncoated WC-Co cemented carbide material. Furthermore, the frictional behavior and characteristic of CVD diamond appears to be more consistent and regular over longer sliding distances. The contact interaction between the CVD diamond coated surface and Alumec 89 appears to have a more abrasive nature due to the rough surface structure and material properties of the coating. The corresponding tribo-pair contact interaction with WC-Co cemented carbide shows more adhesive tendencies. Additionally, the contact-zone temperature development during pin-turning is shown to be somewhat lower during CVD diamond/Alumec 89 surface interactions. Regarding material transfer properties, CVD diamond are shown to perform well when interacting with high-strength aluminum. The amount of material adherence is significantly reduced on CVD diamond coated surfaces. During longitudinal turning using CVD diamond coated cutting tools, no significant wear was observed. On the other hand, evidence of both adhesive and abrasive wear was observed during turning using conventional uncoated WC-Co cemented carbide tools. Finally, tribological mechanisms acting during Tribojan pin-turning tests was shown to be relatively comparable with an actual machining operation, which indicate that the testing method perform well as compliment to standard frictional sliding and machining testing. / Höghållfasta aluminiumlegeringar har länge varit ett populärt material inom bil- och flygindustrin på grund av deras eftertraktade mekaniska egenskaper när det gäller vikt, styrka, utmattning och korrosion. Däremot medför tribologiska fenomen, så som tribofilmbildning och materialöverföring under metallskärande tillverkningsprocesser för aluminium, en betydande minskning av prestanda hos utrustning och skärverktygens livslängd. Dessutom har miljöaspekterna i samband med metallskärande tillverkning fått ökat intresse och därmed drivit utvecklingen av skärverktyg i nya riktningar för att uppfylla kundernas ökade krav. Ett möjligt sätt att uppnå detta är att införa och använda diamantbelagda skärverktyg, vilka har visat sig fungera bra vid bearbetning av höghållfast aluminium. Dock saknas det för närvarande djupgående kunskaper om de tribologiska egenskaperna hos dessa diamantbaserade skärverktyg. Syftet med detta examensarbete har därför varit att undersöka de förfinade tribologiska egenskaperna hos WC-Co skärverktyg av hårdmetall belagda med syntetiskt odlad CVD-diamant. Tribologiska testmetoder, så som friktionsskrapning/glidning, pinnsvarvning, temperaturmätning i kontaktzonen samt longitudinell svarvning, har genomförts för att samla in analysmaterial i form av prover och datainformation. Dessutom utfördes pinnsvarvningstesterna med hjälp av en nyutvecklad så kallad Tribojan-utrustning, vars prestanda har utvärderats som ett delmål i projektet. Analyser av provexemplar har huvudsakligen utförts med hjälp av mikroskopitekniker så som LOM och SEM/EDS. Resultaten från provning, mikroskopianalys och utvärdering av data har visat lovande resultat när det gäller friktions och materialöverföringsegenskaper för CVD-diamantbelagda ytor. Den genomsnittliga CoF för CVD-diamant som glider mot en yta av aluminiumlegeringen Alumec 89 var något lägre jämfört med motsvarande glidning av konventionellt WC-Co hårdmetallmaterial. Dessutom verkar friktionsbeteendet hos CVD-diamant vara mer konsekvent och regelbunden över längre glidsträckor. Kontaktinteraktionen mellan ytor av CVD-diamant och Alumec 89 verkar också ha en mer abrasiv karaktär på grund av diamantbeläggningens grova ytstruktur och materialegenskaper. Motsvarande kontaktinteraktion mellan Alumec 89 och obelagd WC-Co hårdmetall visar däremot mer adhesiva tendenser. Dessutom tenderar temperaturutvecklingen i kontaktzonen under pinnsvarvning vara något lägre vid ytinteraktioner mellan CVD-diamant och Alumec 89. När det gäller materialöverföringsegenskaperna visar sig CVD-diamant fungera bra vid interaktion med höghållfast aluminium. Materialets vidhäftning minskar betydligt på diamantbelagda ytor. Vid kontinuerlig longitudinell svarvning med diamantbelagda skärverktyg observerades inget betydande slitage. Å andra sidan hittades tecken på både adhesivt och abrasivt slitage under svarvning med konventionella obelagda WC-Co hårdmetallverktyg. Slutligen visade det sig att de tribologiska mekanismerna som verkade under Tribojan-pinnsvarvning vara relativt jämförbara med faktisk bearbetning, vilket tyder på att testmetoden fungerar bra som komplement till friktions och svarvtester.