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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Characterization of Cu-mineralized carbonate veins in the Alta-Kvænangen Tectonic Window, Norway

Svens, Ellen January 2024 (has links)
The Alta-Kvænangen Tectonic Window is part of a regional greenstone belt that formed around 2.3 Ga – 2.0 Ga. The Bergmark anticline in the area has gone through greenschist to amphibolite facies metamorphism and hosts Cu, Co and Au mineralizations in hydrothermal veins, albite felsite and chemical traps. The area was mined during the late 19th century mostly in trenches but it has still got exploration potential. This project will classify carbonate veins that are hosted within two gabbro units, compare orientations between the barren and mineralized veins as well as discuss the origin of the veins.  The study area has been affected by multiple extensional and compressional events during the Svecokarelian orogeny (1.9 – 1.8 Ga) and regional hydrothermal alterations including an influx of Na + Ca ± K ± Fe. Major shear zones were activated and used for transporting fluids which are thought to have controlled the formation of mineralization in second- or even third-order structures. The veins were studied using field work, detailed mapping, optical microscopy as well as scanning electron microscopy (SEM) and structural analysis. Results gave three different types of hydrothermal veins: 1) Fe oxide veins, 2) calcite veins and 3) dolomite-plagioclase-quartz veins. All of them show strong signs of deformation and recrystallization all while the chalcopyrite mineralization is heterogeneously distributed and commonly more or less bornite-altered. The veins pinch and swell over short distances and are sinuous but with a general orientation. Albite haloes are common for the veins but far from all veins have haloes. There are at least two generations of veins as some were found to have offset others. Brecciation, tension gashes and faults are also found in the area apart from veins. From the field measurements, two groups of orientations could be determined: one with a SW-NE direction and the other in NW-SE direction, both with relatively steep dips. Considering all downhole measurements, no conclusive results could be revealed, however, the optical televiewer results showed that the area has gone through a N-S compression giving a fold axis towards the west. In the end the orientations of the larger veins were found to either run parallel to the gabbro units or are connected to the NW-SE directed main brittle faulting in the Fennoscandian Shield. Smaller, surrounding veins having more diverse orientations. There are multiple signs of deformation and recrystallization in the mafic host rock but no fabric development can be seen. Its appearance varies locally depending on which alterations are dominating. It exhibits sodic-calcic, potassic and leucoxene alteration as well as albitization and carbonatization. The grain size varies from fine-grained to medium-grained which is more typical with a dolerite or basalt, even though it has been previously mapped as a gabbro. No pyroxene was found in the host rock and the plagioclase was Na-rich instead of the expected Ca-rich.  The Bergmark anticline has multiple similarities with the Gällivare-Kiruna area in Sweden which include 1) high-temperature, low-pressure metamorphism resulting in regional alterations such as albitization, carbonatization, amphibole and magnetite alteration. 2) The mineralization consists of Cu, Co, Au, Fe and minor P. 3) The mineralization can be found disseminated in albite felsite, in chemical traps and in first to third order structures (e.g., faults or hydrothermal veins) in brittle, deformed rocks. 4) The mineralization is structurally controlled to the vicinity of major fault zones. 5) In both places, greenstone belts are important for the formation of mineralization. 6) Reactivation of brittle structures, similar to those in the Kiruna area during the second phase of subduction during the Svecokarelian orogeny (D2), is likely the cause for the veining in the Bergmark anticline. 7) A younger N-S compression is recorded in the area. Differences between the Bergmark anticline and the Gällivare-Kiruna area include the lack of intrusions in the vicinity to the Bergmark anticline.
2

Petrography and Thermodynamic Modelling of Svecofennian Arsenic-bearing Metasupracrustal Rocks in the Arlanda Area, West-Central Fennoscandian Shield / Petrografi och termodynamisk modellering av Svekofenniskasuprakrustalbergarter i Arlanda-området, Bergslagen

Skoog, Klara January 2022 (has links)
The Arlanda area is a construction intensive area facing problems with risk of leaching of arsenic (As) from the bedrock to surface- and groundwater. Construction projects in the area have had problems with high levels of As in the bedrock and the risk of leaching increases through processing of aggregates and blasting of the bedrock. Additionally, there are high concentrations of As in potable water and elevated concentrations are correlated with occurrences of metasedimentary rock, but may also be related to other rock types. The existing geological information of the area was collected in the 1960´s and modern petrographic information as well as modelling of P-T and redox conditions are needed to understand the As mineralogy of the bedrock. Methods used in this project include field work, optical microscopy, electron microprobe analyses, geothermometry calculations, pseudosection modelling in Perple_X and geochemical modelling in PHREEQC. The results indicate that the As-rich bedrock domain include rocks of both igneous and sedimentary origin. As-bearing minerals löllingite and arsenopyrite were found in the matrix of two of the metasedimentary rock samples, while no As-minerals were found in metavolcanic samples. P-T estimates from several geothermobarometry models all suggest amphibolite facies metamorphism for the area, with pressure of 3.0-5.5 kbar and temperature of 490-640 °C. Simple modelling of equilibration of löllingite and arsenopyrite in pure water indicate that As(III) is the dominating oxidation state of As and that the molality of As increases with increasing T and decreasing pH. The results of this thesis provide new information on the petrography and P-T conditions for metamorphism of As-bearingsupracrustal rocks in the Arlanda area, but future research is needed to be able to predict the spatial occurrence of As in the bedrock. / Arlandaområdet är ett av de mest expansiva områdena i Sverige där en stor mängd infrastrukturprojekt är planerade under de närmaste 5-20 åren. Tidigare byggnadsprojekt i området har dock stött på problem med höga bakgrundshalter av arsenik (As) i berggrunden och det finns även en risk för urlakning av As från berggrunden till både yt-och grundvatten. Denna risk ökar under byggnadsarbeten i och med till exempel sprängning av berg. Ytterligare ett problem är att det i området runtomkring Arlanda ofta är höga halter av arsenik i dricksvattenbrunnar. Från data över As-halter i bergborrade brunnar har man kunnat se att höga halter av As ofta förekommer i metasedimentära bergarter, men även kan uppträda i andra bergarter. Den tillgängliga geologiska informationen över området är insamlad på 60-talet och ny petrografisk information, samt modellering av tryck- och temperaturförhållanden är nödvändig för att förstå förekomst av As i berggrunden. Målet med detta projekt är att med hjälp av fältarbete, optisk- och elektronmikroskopering, samt termodynamisk modellering få djupare kunskap kring ytbergarterna i området och utvärdera förekomsten av arsenik i dessa. Under vilka tryck- och temperaturförhållanden som de metamorfa bergarterna omvandlats studeras genom beräkningar från mineralsammansättningar samt modellering i programmet Perple_X. Resultatet från projektet visar att bergarter i As-anrikade zoner är av både magmatiskt och sedimentärt ursprung. Arsenikmineralen löllingit och arsenikkis dokumenterades endast i bergarter av sedimentärt ursprung. Bergarternas kemiska sammansättning tyder också på att de högsta As-halterna finns i de metasedimentära bergarterna. Modellering i PHREEQC visar att As(III) är den dominerande formen av As när löllingit och arsenikkis reagerar med vatten. Tryck- och temperaturberäkningar samt tryck- och termodynamisk modellering tyder på metamorfos under amfibolitfacies, med tryck omkring 3.0-5.5 kbar och temperatur omkring 490-640 °C. Resultaten från detta projekt ger ny information om de metamorfa bergarterna i Arlanda området och förekomst av As i dessa. Vidare studier är nödvändiga för att kunnaförutse i vilken form och i vilka bergarter As förekommer.
3

Pressure-Temperature Constraints on Garnet-Spinel-Sillimanite-Bearing Leucogranite in Sörfjärden, Sweden / Tryck-temperaturförhållanden hos granat-spinell-sillimanitförande leukogranit i Sörfjärden, Sverige

Roos, Antonia January 2024 (has links)
Despite extensive previous studies, the peak metamorphic conditions within the 2.0-1.8 Ga Svecokarelian orogen remain unclear, particularly regarding the deformation and migmatization events occurring between 1.87-1.80 Ga within the Ljusdal lithotectonic unit. While earlier observations indicate granulite facies metamorphism, the exact metamorphic conditions and nature of these events are still unclear. This thesis aims to determine the pressure-temperature range associated with the peak metamorphic conditions by analyzing mineral assemblages in the leucogranite of Sörfjärden, located east of Gnarp, Sweden. Through optical microscopy and electron microprobe analysis, a complex mineral assemblage was identified, including alkali feldspar, plagioclase, garnet, quartz, biotite, sillimanite, and Fe-Zn-rich spinel, with accessory minerals such as monazite, zircon, and rutile. Secondary chlorite and kaolinite were also observed. Ternary-feldspar thermometry revealed crystallization temperatures of 750 ˚C. Thermobarometric modeling of the bulk rock chemical composition, using the software GeoPS, indicated peak pressure-temperature conditions of 2.0–2.4 kbar and 740–770 ˚C, defined by the peak mineral assemblage garnet, plagioclase, quartz, sillimanite, and spinel. Melt structures on biotite and alkali feldspar were inferred to have formed during the second migmatization event, suggesting that granulite facies conditions were reached during the first migmatization event. While these findings provide insights into the metamorphic history of the Svecokarelian orogen, further investigations into the influence of Zn on the produced models are warranted. Addressing the limitations of current thermodynamic models would improve our understanding of this complex geological system. / Trots omfattande tidigare studier är de metamorfa förhållandena i den Svekokarelska orogenesen (2.0–1.8 Ga) fortfarande oklara, särskilt gällande de deformations- och migmatiseringsprocesser som inträffade mellan 1.87–1.80 Ga. Även om tidigare observationer tyder på metamorfos med granulitfacies är de exakta metamorfa förhållandena hos och karaktären av dessa processer fortfarande osäkra. Denna studie syftar till att fastställa det tryck-temperaturintervall som är förknippat med de högsta graderna av metamorfos genom att analysera mineralsammansättningar i leukograniten i Sörfjärden, beläget öster om Gnarp, Sverige. Genom optisk mikroskopi och elektronmikrosonderingsanalys identifierades en komplex mineralsammansättning: alkalifältspat, plagioklas, granat, kvarts, biotit, sillimanit och Fe-Zn-rik spinell, där monazit, zirkon och rutil är accessoriska mineral. Klorit och kaolinit är sekundära. Ternär fältspatstermometri påvisade en kristalliseringstemperatur vid 750 ˚C. Termobarometrisk modellering av bergartens kemiska sammansättning med programmet GeoPS indikerade maximala tryck-temperaturförhållanden på 2.0–2.4 kbar och 740–770 ˚C; mineralsammansättningen under dessa förhållanden var granat, plagioklas, kvarts, sillimanit och spinell. Smältstrukturer på biotit och kalifältspat tolkades ha bildats under den andra migmatiseringen, vilket medför att granulitfacies uppnåddes under den första migmatiseringen. Fastän dessa resultat ger insikter i den Svekokarelska orogenesens metamorfa historia är det motiverat att vidare undersöka inverkan av Zn på de framställda modellerna. Att hantera begränsningarna i nuvarande termodynamiska modeller skulle förbättra vår förståelse av detta komplexa geologiska system.

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