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Surface pasting is an interactive hierarchical modelling technique used to construct surfaces with varying levels of local detail. The concept is similar to that of the physical process of modelling with clay, where features are placed on to a base surface and attached by a smooth join obtained by adjusting the feature. Cylindrical surface pasting extends this modelling paradigm by allowing for two base surfaces to be joined smoothly via a blending cylinder, as in attaching a clay head to the body using a neck. Unfortunately, computer-based pasting involves approximations that can cause cracks to appear in the composite surface. In particular this occurs when the pasted feature boundary does not lie exactly over the user-specified pasting region on the base surface. Determining pasted locations for the feature boundary control points that give a close to exact join is non-trivial, especially in the case of cylinders as their control points can not be defined to lie on their closed curve boundary. I propose and compare six simple methods for positioning a feature cylinder's control points such that the join boundary discontinuities are minimized. The methods considered are all algorithmically simple alternatives having low computational costs. While the results demonstrate an order of magnitude quality improvement for some methods on a convex-only curved base, as the complexity of the base surface increases, all the methods show similar performance. Although unexpected, it turns out that a simple mapping of the control points directly onto the pasting closed curve given on the base surface offers a reasonable cylindrical boundary pasting technique.

Surface pasting is an interactive hierarchical modelling technique used to construct surfaces with varying levels of local detail. The concept is similar to that of the physical process of modelling with clay, where features are placed on to a base surface and attached by a smooth join obtained by adjusting the feature. Cylindrical surface pasting extends this modelling paradigm by allowing for two base surfaces to be joined smoothly via a blending cylinder, as in attaching a clay head to the body using a neck. Unfortunately, computer-based pasting involves approximations that can cause cracks to appear in the composite surface. In particular this occurs when the pasted feature boundary does not lie exactly over the user-specified pasting region on the base surface. Determining pasted locations for the feature boundary control points that give a close to exact join is non-trivial, especially in the case of cylinders as their control points can not be defined to lie on their closed curve boundary. I propose and compare six simple methods for positioning a feature cylinder's control points such that the join boundary discontinuities are minimized. The methods considered are all algorithmically simple alternatives having low computational costs. While the results demonstrate an order of magnitude quality improvement for some methods on a convex-only curved base, as the complexity of the base surface increases, all the methods show similar performance. Although unexpected, it turns out that a simple mapping of the control points directly onto the pasting closed curve given on the base surface offers a reasonable cylindrical boundary pasting technique.

The goal of this thesis is to define and study the Fourier algebra A(G) of a locally compact groupoid G. If G is a locally compact group, its Fourier-Stieltjes algebra B(G) and its Fourier algebra A(G) were defined by Eymard in 1964. Since then, a rich theory has been developed. For the groupoid case, the algebras B(G) and A(G) have been studied by Ramsay and Walter (borelian case, 1997), Renault (measurable case, 1997) and Paterson (locally compact case, 2004). In this work, we present a new definition of A(G) in the locally compact case, specially well suited for studying locally trivial groupoids. Let G be a locally compact proper groupoid. Following the group case, in order to define A(G), we consider the closure under certain norm of the span of the left regular G-Hilbert bundle coefficients. With the norm mentioned above, the space A(G) is a commutative Banach algebra of continuous functions of G vanishing at infinity. Moreover, A(G) separates points and it is also a B(G)-bimodule. If, in addition, G is compact, then B(G) and A(G) coincide. For a locally trivial groupoid G we present an easier to handle definition of A(G) that involves "trivializing" the left regular bundle. The main result of our work is a decomposition of A(G), valid for transitive, locally trivial groupoids with a "nice" Haar system. The condition we require the Haar system to satisfy is to be compatible with the Haar measure of the isotropy group at a fixed unit u. If the groupoid is transitive, locally trivial and unimodular, such a Haar system always can be constructed. For such groupoids, our theorem states that A(G) is isomorphic to the Haagerup tensor product of the space of continuous functions on Gu vanishing at infinity, times the Fourier algebra of the isotropy group at u, times space of continuous functions on Gu vanishing at infinity. Here Gu denotes the elements of the groupoid that have range u. This decomposition provides an operator space structure for A(G) and makes this space a completely contractive Banach algebra. If the locally trivial groupoid G has more than one transitive component, that we denote Gi, since these components are also topological components, there is a correspondence between G-Hilbert bundles and families of Gi-Hilbert bundles. Thanks to this correspondence, the Fourier-Stieltjes and Fourier algebra of G can be written as sums of the algebras of the Gi components. The theory of operator spaces is the main tool used in our work. In particular, the many properties of the Haagerup tensor product are of vital importance. Our decomposition can be applied to (trivially) locally trivial groupoids of the form X times X and X times H times X, for a locally compact space X and a locally compact group H. It can also be applied to transformation group groupoids X times H arising from the action of a Lie group H on a locally compact space X and to the fundamental groupoid of a path-connected manifold.

When the tensor product of two irreducible representations contains multiple copies of some of its irreducible constituents, there is a problem of choosing specific copies: resolving the multiplicity. This is typically accomplished by some ad hoc method chosen primarily for convenience in labelling and calculations. This thesis addresses the possibility of making choices according to other criteria. One possible criterion is to choose copies for which the Clebsch-Gordan coefficients have a simple form. A method fulfilling this is introduced for the tensor product of three irreps of $su(2)$. This method is then extended to the tensor product of two irreps of $su(3)$. In both cases the method is shown to construct a full nested sequence of basis independent highest weight subspaces. Another possible criterion is to make choices which are intrinsic, independent of all choices of bases. This is investigated in the final part of the thesis with a basis independent method that applies to the tensor product of finite dimensional irreps of any semisimple Lie algebra over $\mathbb{C}$.

When the tensor product of two irreducible representations contains multiple copies of some of its irreducible constituents, there is a problem of choosing specific copies: resolving the multiplicity. This is typically accomplished by some ad hoc method chosen primarily for convenience in labelling and calculations. This thesis addresses the possibility of making choices according to other criteria. One possible criterion is to choose copies for which the Clebsch-Gordan coefficients have a simple form. A method fulfilling this is introduced for the tensor product of three irreps of $su(2)$. This method is then extended to the tensor product of two irreps of $su(3)$. In both cases the method is shown to construct a full nested sequence of basis independent highest weight subspaces. Another possible criterion is to make choices which are intrinsic, independent of all choices of bases. This is investigated in the final part of the thesis with a basis independent method that applies to the tensor product of finite dimensional irreps of any semisimple Lie algebra over $\mathbb{C}$.

The goal of this thesis is to define and study the Fourier algebra A(G) of a locally compact groupoid G. If G is a locally compact group, its Fourier-Stieltjes algebra B(G) and its Fourier algebra A(G) were defined by Eymard in 1964. Since then, a rich theory has been developed. For the groupoid case, the algebras B(G) and A(G) have been studied by Ramsay and Walter (borelian case, 1997), Renault (measurable case, 1997) and Paterson (locally compact case, 2004). In this work, we present a new definition of A(G) in the locally compact case, specially well suited for studying locally trivial groupoids. Let G be a locally compact proper groupoid. Following the group case, in order to define A(G), we consider the closure under certain norm of the span of the left regular G-Hilbert bundle coefficients. With the norm mentioned above, the space A(G) is a commutative Banach algebra of continuous functions of G vanishing at infinity. Moreover, A(G) separates points and it is also a B(G)-bimodule. If, in addition, G is compact, then B(G) and A(G) coincide. For a locally trivial groupoid G we present an easier to handle definition of A(G) that involves "trivializing" the left regular bundle. The main result of our work is a decomposition of A(G), valid for transitive, locally trivial groupoids with a "nice" Haar system. The condition we require the Haar system to satisfy is to be compatible with the Haar measure of the isotropy group at a fixed unit u. If the groupoid is transitive, locally trivial and unimodular, such a Haar system always can be constructed. For such groupoids, our theorem states that A(G) is isomorphic to the Haagerup tensor product of the space of continuous functions on Gu vanishing at infinity, times the Fourier algebra of the isotropy group at u, times space of continuous functions on Gu vanishing at infinity. Here Gu denotes the elements of the groupoid that have range u. This decomposition provides an operator space structure for A(G) and makes this space a completely contractive Banach algebra. If the locally trivial groupoid G has more than one transitive component, that we denote Gi, since these components are also topological components, there is a correspondence between G-Hilbert bundles and families of Gi-Hilbert bundles. Thanks to this correspondence, the Fourier-Stieltjes and Fourier algebra of G can be written as sums of the algebras of the Gi components. The theory of operator spaces is the main tool used in our work. In particular, the many properties of the Haagerup tensor product are of vital importance. Our decomposition can be applied to (trivially) locally trivial groupoids of the form X times X and X times H times X, for a locally compact space X and a locally compact group H. It can also be applied to transformation group groupoids X times H arising from the action of a Lie group H on a locally compact space X and to the fundamental groupoid of a path-connected manifold.

In this thesis, we study the representation theory of Lie colour algebras. Our strategy follows the work of G. Benkart, C. L. Shader and A. Ram in 1998, which is to use the Brauer algebras which appear as the commutant of the orthosymplectic Lie colour algebra when they act on a k-fold tensor product of the standard representation. We give a general combinatorial construction of highest weight vectors using tableaux, and compute characters of the irreducible summands in some borderline cases. Along the way, we prove the RSK-correspondence for tableaux and the PBW theorem for Lie colour algebras.

The field of theoretical chemistry has provided undeniably useful insights about molecular systems that otherwise, through experiment, would not be obtainable. We are constantly developing new and improved methods to fill in the gaps about how various factors including the electronic structure can affect the chemistry seen experimentally. The goal of most quantum chemistry methods is to develop a method that is widely applicable, has low computational costs, but with as much accuracy as possible. Some of the most challenging systems in our field include those that are considered strongly correlated. Strong correlation is usually referring to the need for a large number of configurations to properly model the chemistry. These systems can not be solved exactly, thus various approximations must be made. A set of methods that take advantage of truncating only the unimportant configurations to solve these challenging systems are selected configuration interaction methods. Even though these selected CI methods can often provide accurate results, their general application is limited by memory bottlenecks. In 2020, our group developed the Tensor Product Selected Configuration Interaction (TPSCI) method to overcome these memory bottlenecks. We take advantage of the local character of these strongly correlated systems by doing a change of basis into tensor products, then do a selected CI algorithm in that basis. In this dissertation, we discuss how we have extended TPSCI to compute excited states. We first test on a set of polycyclic aromatic hydrocarbons that were previously studied with TPSCI. We find very high accuracy and dimension reduction as compared to state of the art selected CI approaches. We then validate TPSCI's ability to study the electronic structure involved in the singlet fission process in tetracene tetramer with extending analysis using a Bloch effective Hamiltonian. This effective Hamiltonian allows for intuitive analysis of the singlet fission process. We also show how accurate and interpretable TPSCI can be on an open-shell biradical transition bimetallic complex, in addition to, hexabenzocoronene that is not straightforward clustering due to the conjugated benzene rings. To alleviate the previous system size limitations, we recently implemented a Restricted Active Space Configuration Interaction as a local solver for clusters. We present novel results of using this new solver on a tetracene dimer. We comment on specific coupling strengths and show the electronic dynamics of our TPSCI effective Hamiltonian which support a CT-mediated mechanism for the tetracene dimer singlet fission. / Doctor of Philosophy / The field of theoretical chemistry has used some of the fundamental principles in quantum mechanics to study the electronic structure of molecular systems for many years. The power of computational resources has increased over the years, facilitating the increased complexity and accuracy of quantum chemistry methods. This dissertation lies in the realm of pushing past previous molecular system computational limits with rewarding accuracy and increased interpretability. We achieve these goals by taking advantage of the localized nature in most of our chemistry vocabulary by using tensor product methods. Tensor product methods are able to separate a large problem into smaller units to overcome previous system size limitations while maintaining the desired accuracy. The main method focused on in this dissertation is a tensor product method called Tensor Product Selected Configuration Interaction (TPSCI) established by our research group in 2020. This dissertation covers the required background information including basic terminology and previously developed methods then presents very recent and novel research using TPSCI. We first focus on extending TPSCI to excited states since excited states are extremely important for many photochemical processes, spectral analysis, and chemical sensing. We then test TPSCI on a spectrum of systems that range from very local character (separated molecular units) to bimetallics to very delocalized (carbon-based conjugation) chemistry. We find TPSCI is able to handle this variety of systems with very high accuracy and allows for very in-depth qualitative analysis. Finally, we present novel results incorporating an additional approximation in the local solver to further extend TPSCI's applicability. To test this new local solver, we focus on a process called singlet fission which is promising to help overcome solar cell efficiency limits. We are able to match previously reported results for the tetracene dimer which supports the use of TPSCI to study larger singlet fission systems in future work. With the work presented in this dissertation, we have aimed to highlight the potential utility of TPSCI, motivating further developments and research in this direction.

x, 81 p. : ill. A print copy of this thesis is available through the UO Libraries. Search the library catalog for the location and call number. / We give an exposition of Deligne's tensor category Rep(St) where t is not necessarily an integer. Thereafter, we give a complete description of the blocks in Rep(St) for arbitrary t. Finally, we use our result on blocks to decompose tensor products and classify tensor ideals in Rep(St). / Committee in charge: Victor Ostrik, Chairperson, Mathematics; Daniel Dugger, Member, Mathematics; Jonathan Brundan, Member, Mathematics; Alexander Kleshchev, Member, Mathematics; Michael Kellman, Outside Member, Chemistry