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Recycling of Glass Fiber CompositesKrishnamoorthi, Ramesh, Shinzhao, Zhang January 2012 (has links)
Composites are the materials which can be used for a wide variety of applications andproducts such as sports equipment, aerospace and marine because of light and stiffnessproperties. Composites are often made from thermoset resin with glass fibers.In this study, two ways of recycling composites were evaluated, which are microwavepyrolysed composites (MGC) and mechanical composites (GC). These glass fibers weregoing to be compounded with Polypropylene (PP) or Maleic Anhydride ModifiedPolypropylene (MAPP) and then injection moulded the sample by Micro-compounder.In order to get better adhesion to the polymer, a coating was added. The Neoxil 5682-polypropylene water emulsion was evaluated.The samples were characterized by Tensile Testing, Thermogravimetric Analysis (TGA),Different Scanning Calorimetry (DSC), and Dynamic Mechanical Analysis (DMA) to find aoptimum combination of recycled glass fiber reinforced polymer.Microwave pyrolysis is a new research area. The glass fiber, polymer oil and gas can beobtained by heating the composite with microwaves to in an inert atmosphere. The polymeroil can be distillated and then evaluated with GC-MS; in order to obtain the chemicalcompositions.Keywords: Composites, grinded and microwave pyrolyse composites (MGC), grindedcomposites (GC), Polypropylene (PP), Maleic Anhydride Modified Polypropylene (MAPP),Micro-compounder, Tensile Testing, Thermogravimetric Analysis (TGA), Different ScanningCalorimetry (DSC), and Dynamic Mechanical Analysis (DMA), Microwave pyrolysis,polymer oil, distillation, GCMS Analysis. / Program: MSc in Resource Recovery - Sustainable Engineering
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Biodegradable Composites : Processing of thermoplastic polymers for medical applications.Damadzadeh, Behzad, Jabari, Hamideh January 2009 (has links)
Despite the recent development in PLA and PLGA based medical devices, there are still needs to further improve the mechanical performance of bioresorbable medical implants and their bioactivity. This is normally done by optimizing the filler compositions in selected groups ofbiodegradable polymer matrices. In this study, the effects of various filler levels on mechanical strength and thermal properties of PLA and PLGA composites were investigated. Composites containing different dosage of osteoconductive HAp with various particles size (0-5μm, 0-50 μm, nano size), β-TCP, bioactive glass and biodegradable Poly-L-lactide and Polylactide-glycolic acid was manufactured with melt blending, using a twin-screw extruder.The samples were investigated by Differential Scanning Calorimetry (DSC), thermo gravimetric analysis (TGA), Scanning Electron Microscopy (SEM), viscometer, three points bending machine, and Optical Microscopy (OM). The Extruder produced a porous profile. The result from TGA and SEM indicated that there was homogenous filler dispersion in the matrix after compounding.The result from DSC and Viscometer shows that there was some degradation duringcompounding. Mechanical properties of composites were modified by adding filler to matrix. The addition of Bioactive glass, as a filler, increases the degradation of the polymer matrix. The best filler that was applied is 0-5μm and nano HAp. Also in in-vitro degradation part of this thesis work, the effects of calcium phosphate materialsare investigated on degradation process.
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