The vulnerability of the Arctic to climate change has been realized due to disproportionately large increases in surface air temperatures which are not uniformly distributed over the seasonal cycle. Effects of this temperature shift are widespread in the Arctic but likely include changes to the hydrological cycle and permafrost thaw, which have implications for the mobilization of organic carbon into rivers. The focus of this research was to describe the seasonal variability of the chemical composition of dissolved organic matter (DOM) in the six largest Arctic rivers (Yukon, Mackenzie, Ob, Yenisei, Lena and Kolyma) using optical properties (UV-Vis Absorbance and Fluorescence) and lignin phenol analysis. We also investigated differences between rivers and how watershed characteristics influence DOM composition. Dissolved organic carbon (DOC) concentrations followed the hydrograph with highest concentrations measured during peak river flow. The chemical composition of peak-flow DOM indicates a dominance of freshly leached material with elevated aromaticity, larger molecular weight, and elevated lignin yields relative to base-flow DOM. During peak flow, soils in the watershed are still frozen and snowmelt water follows a lateral flow path to the river channels. As the soils thaw, surface water penetrates deeper into the soil horizons leading to lower DOC concentrations and likely altered composition of DOM due to sorption and microbial degradation processes. The six rivers studied here shared a similar seasonal pattern and chemical composition. There were, however, large differences between rivers in terms of total carbon discharge reflecting the differences in watershed characteristics such as climate, catchment size, river discharge, soil types, and permafrost distribution. The large rivers (Lena, Yenisei), with a greater proportion of permafrost, exported the greatest amount of carbon. The Kolyma and Mackenzie exported the smallest amount of carbon annually, however, the discharge weighted mean DOC concentration was almost 2-fold higher in the Kolyma, again, indicating the importance of continuous permafrost. The quality and quantity of DOM mobilized into Arctic rivers appears to depend on the relative importance of surface run-off and extent of soil percolation. The relative importance of these is ultimately determined by watershed characteristics.

The origin of the Amerasia Basin, in the Arctic region, is nowadays a highly controversial topic due to the paucity of geophysical data available and the difficulties in interpreting possible seafloor spreading magnetic anomalies. The Chukchi Borderland, that extends into the Amerasia Basin north of the Chukchi Sea, has proven to be one of the more difficult features of the arctic to understand in any model for the tectonic evolution of the Amerasian Basin. In the summer of 2005, USCG Icebreaker Healy crossed the Arctic Ocean from Dutch Harbor, Alaska, to Troms�, Norway, to collect geophysical data and take shallow cores in an effort to gain greater insight into the paleo-oceanographic, depositional and tectonic history of the Arctic basins. 780 km of new seismic lines from the Chukchi Borderland are presented along with a preliminary interpretation of the tectonic evolution of the Amerasia Basin in light of the new observations. The data provide high quality images of the region down to the basement and, in areas, images below the basement. The pelagic sediment cover varies along the profiles with thicknesses ranging from less than 0.1 s to a maximum of 1.5 s TWT. Significant extensional normal faults, striking approximately north-south, are observed throughout the dataset with strong evidence of growth faults below a major unconformity. Along the reflection images oriented E-W, young sediments and possibly the seafloor show small offsets. While this may be due to differential compaction or fluid expulsion, the presence of low amplitude folds above the footwalls suggests a recent fault-propagation folding process. This may indicate recent reactivation and rotation of the crustal blocks, although the total amount of displacement and strain are very small. We do not observe compressional or inversion structures anywhere in the dataset. The orientation of the structures imaged is similar to those observed along the Mendeleev Ridge to the west, which may support recent models that propose the Chukchi Borderlands and Mendeleev Ridge comprise a single extensional province that rifted from the Siberian margin.

Thesis (Ph. D.)--Rutgers University, 2009. / Includes bibliographical references.

Thesis (Ph. D.)--University of Alberta, 2009. / A thesis submitted to the Faculty of Graduate Studies and Research in partial fulfillment of the requirements for the degree of Doctor of Philosophy, Dept. of Earth and Atmospheric Sciences, University of Alberta. Includes bibliographical references. Also available via the Internet.

Little is known about the factors driving the cycle of the climate-active gas dimethylsulfide (DMS) and of its precursor the metabolite dimethylsulfoniopropionate (DMSP) in sea ice. To date, studies have focused on biotic factors, linking high DMSP concentrations to the high biomass of sympagic communities, and to physiological adaptations to the low temperatures and high salinities of the brine habitat. This thesis presents an approach integrating biotic and abiotic factors, investigating the influence of ice growth processes and brine dynamics on the DMS cycle. First, brine dynamics from growth to melt are explored based on ice temperature and salinity profiles measured in the Arctic. A strong but brief desalination phase is identified in spring. Using calculated proxies of permeability (brine volume fraction) and of the intensity of brine convection (Rayleigh number), this phase is shown to correspond to full-depth gravity drainage initiated by restored connectivity of brines on warming. Full-depth gravity drainage is crucial for the vertical transfer of DMS-compounds at the ice-ocean interface. This physical background is then used to investigate the spatio-temporal variability of DMS in Arctic sea ice during a year-round survey in Amundsen Gulf. The influence of processes such as scavenging and brine convection on the DMS cycle is shown, and the first combined measurement of DMS, DMSP, and dimethylsulfoxide (DMSO), a compound acting as source/sink for DMS through photo-chemical and bacterial processes, is presented. DMSO is shown to dominate the dimethylated sulfur pool in surface ice when the snow cover is low. Based on correlations with irradiance, it is suggested that this DMSO originates from photo-chemical oxidation of DMS trapped in impermeable ice. Finally, the spatio-temporal variability of DMS in Antarctic sea ice is investigated during another year-round survey in McMurdo Sound. Platelet crystals growth under the influence of ice-shelf waters are shown to favor the incorporation of strong DMSP producers, to increase the environmental stress on cells, and to favor the accumulation of DMS,P by reducing permeability. The increase of permeability on warming is shown to trigger strong release of DMS in the ocean and a vertical redistribution of DMSP in the ice cover.

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Arctic ecosystems are experiencing rapid changes as a result of climate warming and more frequent natural and human-caused disturbances. Disturbances can have particularly large effects on high-latitude ecosystems because ecosystem structure and function is controlled by strong feedbacks between soil conditions, vegetation, and ground thermal regime. My MSc. research used fieldwork and broad-scale GIS data to investigate post-disturbance ecosystem recovery along roads in two permafrost zones (discontinuous and continuous). In the first of two case studies, I focussed on tall shrub proliferation along the Dempster Highway at the Peel Plateau, NT. To explore the drivers of tall shrub proliferation and to quantify shrub expansion in this region of continuous permafrost, greyscale air photos (1975) and Quickbird satellite imagery (2008) were used to map landcover change within a 1.2 km buffer next to the road and inside a buffer 500 m away from the road. Extensive tall shrub proliferation in the study area indicates that warming air temperatures and disturbance both facilitate vegetation change in tundra environments. My findings also indicate that accelerated shrub expansion adjacent to the road was caused by increased soil moisture. Tall shrub proliferation adjacent to the road occurred at lower elevation sites characterized by wetter soils with thicker organic layers. Areas that resisted tall shrub encroachment were located at higher elevations and had drier soils with thin organic layers. These observations also support previous work that illustrates that tall shrub expansion next to the highway promotes strong positive feedbacks to ongoing shrub growth and proliferation. In a second case study I examined ecosystem recovery in an area of discontinuous permafrost 30 years after construction and abandonment of a winter access road in Nahanni National Park Reserve. Ecosystem recovery was studied by comparing disturbed (road) and undisturbed (adjacent to the road) sites in spruce muskeg, black spruce parkland, deciduous forest, and alpine treeline terrain. Field data showed that disturbances to discontinuous permafrost terrain can lead to large and persistent changes to ecosystem composition and structure. In spruce muskeg, permafrost thaw triggered by road construction dramatically increased soil moisture and facilitated a transition from spruce muskeg to sedge wetland. At alpine treeline the removal of stabilizing vegetation and organic soil during construction slowed subsequent ecosystem recovery. These findings are consistent with resilience theory that predicts that changes to key environmental factors will increase the likelihood of regime shifts. In terrain types where disturbance fundamentally alters ecosystem processes, the management of disturbance impacts in NNPR will be extremely difficult. Overall, this thesis contributes to our understanding of effects of disturbance on vegetation and abiotic conditions, and provides insight into the future of high-latitude ecosystems in a warmer climate with increased disturbance. / Graduate

This work represents an analysis of the spatial and temporal variability of nitrate deposition and preservation recorded in multiple ice core and snow pit records from the Greenland ice sheet. The primary objective of this research was to develop improved estimates of variability in the preserved ice core record of nitrate to aid in the interpretation of paleoatmospheric concentrations of reactive nitrogen compounds. Three separate works are presented, each focusing on a unique component of variability. The first is a study related to the direct preservation of nitrate over a single year. The second and third topics are related to analysis of ice core records collected during NASA's Program for Arctic Regional Climate Assessment (PARCA) which was initiated in 1993 and continued through 2002.The first study of preservation demonstrated that nitrate, despite possible post-depositional cycling and alteration, was well preserved throughout the year, such that the total flux measured in a snow pit taken to represent the previous year, was representative of snow surface concentrations during the past year. The small difference in preserved concentrations from observed surface snow concentrations gives evidence of only 7% post-depositional loss at this site (mean annual accumulation ~23 g cm-2 yr-1). Results from these studies indicate that at this site accumulation is the most significant process affecting preservation of nitrate in the firn.In the second study, the temporal variability of preserved nitrate was evaluated through time series analysis and correlation studies with available paleoclimate proxy records. Six Greenland ice cores covering the period 1794-1995 show correlated co-variability of nitrate concentration for periods greater than ten years and a ~60% increase in average concentration during the last 75 years. The changes in concentration yield ~30% higher nitrate flux (2.5 to 3.2 g m-2 a-1) and ~11% greater variability during 1895-1994 period versus the prior 100 years. Nitrate trends in the cores during the last 100 years are also correlated with global nitrate emissions, with an average r-value of 0.93 for the six cores.The last study focused on spatial variability of nitrate, and the relation of deposition to components of the earth system including temperature and accumulation. The objective of the study was to assess the contribution of spatial (latitude, longitude, and elevation) and climate (accumulation and temperature) components to the preserved record. Furthermore, the study evaluated the influence of anthropogenic activities on the spatial distribution of nitrate of the Greenland ice sheet. Large scale spatial variability exists as a result of accumulation gradients, with concentration 5% greater in the northern plateau, yet flux over the northern plateau is 30% lower than the dry snow zone as a whole. While spatially, flux appears to be more dependent on accumulation, preservation of flux shows increasing dependence on concentration with increasing accumulation. The relationship between concentration and accumulation is non-linear, showing less dependence in the low accumulation regions versus high accumulation regions. Accumulation alone is insufficient to account for the observed variability in nitrate flux in the low accumulation regions, and evidence supports an additional component to a transfer function model for nitrate that includes photochemistry, temperature, and possibly sublimation. In high accumulation regions, evidence points to a dilution effect, with concentration decreases resulting from increased accumulation. Flux estimates over the ice sheet are compared with a GEOS-CHEM model estimate of reactive nitrogen vertical fluxes showing the model captures a significant component of the variability in the southern portion of the ice sheet, but under-represents the flux and variability in the northern half of the ice sheet by a factor of 4.

No description available.

Glaciated areas offer a unique opportunity to study the dispersal of animals . During glaciation the fauna of glaciated areas was either destroyed or forced into ungla iated refugia. ..When the icesheets retreated the glaciated regions were open to reinvasion.