In any underground facilities especially tunnels, it is essential to seal the area against water ingress and leakage of reserved materials. Grouting is a common method used to seal rocks around tunnels, successful grouting reduces the duration and cost of the construction, guarantees better working environment and higher safety, minimizes the maintenance and most important decreases the corresponding environmental hazards significantly. Achieving a sufficient grout spread is one of the prerequisites for a successful and efficient sealing, the penetration of a grout is defined as the length of how far grout penetrates in the rock through fractures from a bore hole. Chemical grouts and cement-based grouts are the prevailing ones among the grouting materials. Despite the better penetrability of chemical grouts, they are unfavorable to use due to environmental hazards associated to them, whilst cement-based grouts are more convenient to use because of their low cost and low environmental impact.The major drawback with cement-based grouts is their limited ability to penetrate the very narrow fractures which is directly related to their filtration tendency which is defined as the tendency of cement grains to agglomerate and build an impermeable filter cake during the flow. Many previous studies investigated the factors that affect the filtration tendency. They drew different conclusions and suggested various methods to improve the penetrability of cement-based grouts.The mixing method is one of the factors that have a great influence on the penetrability of the grout. An effective mixing method improves the dispersion of cement particles in the mixture, thus the penetrability of the grout. As it is known from previous studies, the finer the cement particles the harder to disperse. Grouts based on micro-fine cement (< 30 μm) are essential for the development of grouts that can seal very narrow fractures (20-50) μm compared to (70-80) μm at the present.In this study, the dispersion efficiency of three different mixing methods was evaluated, a conventional lab dissolver equipped with 90-mm disk, a conventional lab dissolver equipped with R/S system and an ultrasound UP400St device. Two cement types, INJ30 and UF12, that are similar in chemical composition but differ in degree of milling were tested. Dispersion was tested with filter pump.The results showed that the conventional lab dissolver equipped with 90-mm disk is ineffective method. The conventional lab dissolver equipped with R/S system is a better method compared to the 90-mm disk but still not effective enough especially when it comes to grouts based on ultra-fine cement (UF12). The ultrasound dispersion is not only the best method between the three methods in comparison, but even more stable and reliable. The best result obtained was grout based on UF12 passing through the 54 μm filter. This could mean that fracture aperture down to 55 μm now can be sealed. This is a significant improvement but there is still a marginal for further improvements. In combination with the dispersion efficiency of different dispersion methods, the study investigated the effect of additives on dispersion in particular and penetrability in general. Results showed that additives do not directly contribute to better dispersion, but they are necessary for better spread since they affect the flow properties.

Vid SSAB Europé i Luleå produceras höghållfaststål. För att uppnå sådan kvalité måste renligheten i stålet vara god i hela processen. Risken att få förhöjda värden av exempelvis vanadin efter LD-processen vid deoxidationssteget, då medföljande vanadininhållande slagg som återreduceras till stålet är hög. Det finns olika system som jobbar för att förhindra medföljande slagg vid tappning av LD-konvertern. På SSAB i Luleå används IR-kamera för att identifiera slagg vid tappning och en mekanisk slaggstoppare som blockerar tapphålet samt tvingar flödet tillbaka in i konvertern med hjälp av kvävgas. Ett annat möjligt system att använda skulle kunna vara slaggens viskositet, då en högviskös slagg skulle fungera som en vortexinhibitor och därigenom reducera mängden medföljande slagg. Målet med examensarbetet har varit att undersöka sena tillsatsers påverkan av medföljande slagg, där de sena tillsatserna syftar till att öka viskositeten på slaggen genom att skapa fasta partiklar. I daglig drift görs ingen uppskattning av mängden medföljande slagg eller hur sena slaggtillsatser påverkar detta. Genom slaggprovtagning samt stålprover innan och efter tappning av LD-konvertern kan en massbalans göras av mängden medföljande slagg. Beräkningsämnena som passade bäst i denna studie var kisel och vanadin, två ämnen som oftast återfinns endast i slaggen. Utifrån resultatet av proverna visade sena tillsatser inte ha någon påverkan av mängden medföljande slagg. Ingen påvisad skillnad av viskositetsberäkningarna kunde kopplas till de sena tillsatserna, där beräkningarna gjordes i FactSage. Studien visade att sena tillsatser inte har den önskade effekten på medföljande slagg som man tidigare trott och skulle kunna tas bort helt. Detta för att reducera kostnaderna för tillsatser och deponi. Slaggen fick flytegenskaper redan vid 72% andel fasta partiklar och en temperatur på 1379°C. Vid LD-processen har slaggen 8% andel fasta partiklar och temperatur på 1739°C. Detta påvisar att det blir praktiskt omöjligt att styva upp slaggen i LD-processen med hjälp av sena tillsatser. / SSAB Europé in Luleå produce high-strength steel. To reach this quality the purity must be good in the whole process. There is a risk to get a high value of for example vanadium in the steel after the LD-process at the deoxidations step. The carried-over slag from the LD-process has a high content of vanadium that may reduce back to the steel from the deoxidation agent.  Several process systems work to reduce the amount of carried-over slag at LD-converter. At SSAB in Luleå this system is an IR-camera that is used for detecting carried-over slag at the tapping of the converter and a mechanical slagblocker that block the tapping jet and blow back the slag using nitrogen.  Another possible system could be to use the slag viscosity. High viscous slag will work like a vortex inhibitor and reduce the amount of carried-over slag. The goal of this master thesis is to study late additives impact of the amount of carried-over slag, there the purpose of the late additives is to increase the viscosity of the slag through solve in solid particles.  In the daily operations SSAB doesn´t do an estimate of the amount of carried-over slag or how the late additives affect carried-over slag. By conducting slag and steel sampling before and after tapping the LD-converter a mass balance can be used to calculate the amount of carried-over slag. The base of the mass calculation that fit beast in this study was silicon and vanadium. Two substances that often occurs in the slag. From the results of the samples, the late additive didn´t do any impact on the amount of carried-over slag. No impact of the viscosity calculation could connect to the amount of carried-over slag. The calculation has been done in FactSage. The study shows that late additive don´t have any impact on the amount of carried-over slag and that is why it should be avoided. This could decrease the cost of additive and landfill. The slag gets flow properties as early as 72% share solid particles and temperature at 1379°C and in the LD-process the slag had 8% share solid particles and temperature at 1739°C. This shows that it´s practically impossible to stiff up the slag in the LD-process with help of late additive.