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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
51

Transmission diffraction gratings for soft x-ray spectroscopy and spatial period division

Hawryluk, Andrew M January 1982 (has links)
Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science, 1982. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND ENGINEERING. / Includes bibliographical references. / by Andrew Michael Hawryluk. / Ph.D.
52

Analysis of Metallurgically Bonded Electrospark Deposited Coatings

Joyce, Anne-Marie 05 August 2019 (has links)
No description available.
53

Experimental and theoretical investigation of the coherent x-ray propagation and diffraction

Feng, Zhenxing, 1982- January 2006 (has links)
No description available.
54

Transition Metal Impurities in Semiconductors: Induced Magnetism and Band Gap Engineering

2013 August 1900 (has links)
The main subject of this thesis is the study of electronic and magnetic properties of materials containing 3d transition metal atoms. Our motivation stems mainly from the modern fields of spintronic computing and solar energy conversion. The two primary goals of this work are to determine (i) why certain transition metal impurities in certain semiconductors can induce magnetic properties suitable for spintronic computing applications, and (ii) how transition metal impurities can be used to modify the electronic band gaps of semiconductors and insulators in ways useful for harnessing solar energy and for other applications. To accomplish these goals, we have applied both experimental and theoretical tools. We studied high quality materials prepared by advanced synthesis techniques using x-ray spectroscopy methods at synchrotron light sources. The results of these experiments were interpreted using a variety of theoretical techniques, primarily using computational software developed as part of this thesis and discussed herein. Regarding the study of introducing transition metal impurities into semiconductors to induce magnetic properties, we first developed and demonstrated a method to determine the location of impurity atoms within the host semiconductor lattice. This allowed to us explain the presence and absence of ferromagnetism in samples prepared under only slightly different synthesis conditions, which helped to address some long--standing issues in the spintronics field. We then studied an advanced and promising material -- indium (III) oxide with iron impurities -- to determine how magnetic ordering was maintained up to room temperatures. Our techniques unveiled that a portion of the iron atoms were coupled to oxygen vacancies in the material to create conditions which propelled the observed magnetism. This finding confirmed some earlier theoretical predictions by others in the field. For the study of electronic band gap modifications in semiconductors and insulators via the incorporation of transition metal atoms, we investigated a wide range of materials synthesized using different techniques. Again, we used experimental techniques to determine the location of impurity atoms within the materials, and used this to understand how band gaps were modified upon the introduction of the impurities. For Ti implantation into SiO2, Ni substitution into ZnO, and a new material, MnNCN, we have determined the electronic band gaps and used our techniques to explain how the values for the gaps arise. Finally, an additional outcome of this thesis work is a software program capable of simulating x-ray spectra using various advanced quantum models. We rewrote and built upon powerful existing programs and applied the result to the above studies. Our software was further applied in a collaborative effort with other researchers at the Canadian Light Source to study the differences in two experimental techniques for measuring x-ray absorption: partial and inverse partial fluorescence yields. By using the proper absorption and scattering formalisms to simulate each technique, we were able to explain the differences between the experimental spectra obtained from each. We explain fluorescence yield deviations using an analysis based on the spin configuration of different states, suggesting that the technique can be further extended as a quantitative spin state probe. These results could have significant implications for the field of soft x-ray absorption spectroscopy.
55

Tube-based field-portable X-ray fluorescence (FPXRF) as a qualitative screening tool for Resource Conservation and Recovery Act (RCRA) metals in children's products and comparison to total metals analyses to predict hazardous waste metals toxicity characteristic /

Kohlbach, James M. January 2009 (has links)
Thesis (M.S.)--Rochester Institute of Technology, 2009. / Typescript. Includes bibliographical references (leaves 86-88).
56

Surface processes ruthenium film growth, silicon nanocrystal synthesis, and methylene partial oxidation /

Smith, Kristen Colleen. January 2001 (has links)
Thesis (Ph. D.)--University of Texas at Austin, 2001. / Vita. Includes bibliographical references. Available also from UMI Company.
57

Temperature, photon energy and thickness dependent studies of Cs 5p core-levels on Cu(100), development of photoemission equipment and the 6m-TGM at CAMD /

Koch, Kevin David, January 2001 (has links)
Thesis (Ph. D.)--University of Texas at Austin, 2001. / Vita. Includes bibliographical references (leaves 225-235). Available also in a digital version from Dissertation Abstracts.
58

Inelastic losses in x-ray absorption theory /

Campbell, Luke, January 2002 (has links)
Thesis (Ph. D.)--University of Washington, 2002. / Vita. Includes bibliographical references (p. 113-118).
59

Study of x-ray supernovae and supersoft/quasisoft x-ray sources with an automated source search program

Li, Kwan-lok., 李君樂. January 2011 (has links)
published_or_final_version / Physics / Master / Master of Philosophy
60

Structure and dynamics in solution – the core electron perspective

Josefsson, Ida January 2015 (has links)
This thesis is based on theoretical studies of the molecular and electronic structure of solvated ions and molecules. Very detailed information of the system can be obtained from theoretical calculations, but a realistic model is dependent on an accurate computational method. Accurate calculations of core level electronic spectra, and evaluation of the modeling against experiments, are central parts of this work. The main tools used for characterization of the systems are high-level quantum chemistry and molecular dynamics simulations.  Molecular components in solutions are involved in many key processes converting sunlight into chemical or electrical energy. Transition metal complexes, with their pronounced absorption in the visible light region of the electromagnetic spectrum, are core components in various energy conversion applications, and the iodide/triiodide redox couple is a commonly used electrolyte. The local structure of the electronic valence in transition metal complexes and the details of the solvation mechanisms of electrolyte solutions are investigated through the combination of computational modeling and core level spectroscopy. The studies of model systems show that interactions between the solute and solvent are important for the electronic structure, and knowledge of the details in model systems studied can be relevant for energy conversion applications. Furthermore, high-level quantum chemistry has been applied for interpreting time-resolved spectra, where the electronic structure of a metal complex is followed during a photoinduced chemical reaction in solution. With advanced modeling in combination with recent experimental developments, more complex problems than previously addressed can be dissected. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 3: Submitted. Paper 8: Manuscript.</p>

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