La présente étude vise à comprendre le comportement chimico-hydro-mécanique des argiles raides à travers deux formations géologiques, l'argile de Boom et les argiles yprésiennes, qui sont censées être des formations hôtes potentielles pour le stockage de déchets radioactifs en Belgique. Le comportement volumique a été étudié tant à l'état intact qu'à l'état reconstitué, et sous différentes conditions : K0 et isotrope, sous des boucles de chargement - déchargement. Les résultats obtenus montrent que le comportement volumique de ces argiles est gouverné par la compétition entre l'effet physico-chimique et l'effet mécanique, caractérisée par une contrainte seuil qui correspond à la contrainte de gonflement en termes de changements de structure. Une loi de comportement volumique a été ainsi développée afin de décrire cet aspect. La perméabilité a été déterminée, comparée avec les résultats dans la littérature et corrélée avec les paramètres comme l'indice des vides. La variation de la perméabilité avec la profondeur ont mis en évidence le rôle déterminant des macro-pores dans le transfert des fluides. Le comportement volumique et la perméabilité des argiles de Boom et yprésiennes intactes sont aussi influencés par la variation de la composition chimique de l'eau de pore, qui modifie la double couche diffuse et favorise l'agrégation des particules argileuses. Les caractéristiques élastiques, la surface de charge et l'enveloppe de rupture ont été identifiées pour le comportement déviatorique des argiles de Boom et yprésiennes. Un modèle élasto-plastique conceptuel a été développé permettant de tenir compte des effets du gonflement et de la compétition entre l'effet mécanique et l'effet physico-chimique / The present research aims to understand the chemo-hydro-mechanical behavior of stiff clays through two geological formations, the Boom Clay and the ypresian clays which are considered as possible host formations for the radioactive wastes disposal in Belgium. The volume change behavior was studied in both intact and reconstituted states, and under different conditions: under K0 and isotropic loading, under loading/unloading loops. The results show that the volume change behavior is governed by the competition between the physico-chemical effect and the mechanical effect, characterized by a threshold stress which corresponds to the swelling stress in terms of structure changes. A constitutive law was developed to capture this aspect. The permeability was determined, compared with the results in literature and correlated with the parameters as void ratio. The permeability variation with depth shows the important role of macro-pores in fluids' transfer. The volume change behavior and permeability of intact Boom Clay and ypresian clays are also influenced by pore water chemical composition changes which modify the diffuse double layer and give rise to the aggregation of clay particles. The elastic parameters, yield curve and failure envelope of Boom Clay and ypresian clays were identified. A conceptual elasto-plastic model was developed, accounting for the swelling effects and the competition between the physico-chemical effect and the mechanical effect

ABSTRACT The Eocene Roda Formation in northern Spain documents the deposits from a range of coastal depositional environments. These include alluvial plains, distributary channels, mouth bars, upper to lower-shorefaces, and tidal shelf ridges. Eighteen progradational sand tongues that are interpreted as parasequences compose two third-order sequences. Sequence 1 accumulated in an environment with strong tidal currents and high rates of progradation, while Sequence 2 was deposited under relatively weaker currents and higher rates of aggradation, which produced a higher mudstone:sandstone ratio. The stratigraphy highlights the transgressive origin of six tidal shelf ridges, three in each sequence, that overlie regressive deltaic tongues. Sequence 1 shelf ridges are composed almost entirely of cross-bedded sandstones, whereas Sequence 2 ridges are composed of a mixture of cross-bedded and ripple-laminated deposits. Ridges in both sequences contain bioturbation that is typical of the Cruziana Ichnofacies, and that indicates a marine origin. The tidal ridges are stratigraphically located at or near the point of maximum third-order regression, and are not found within early highstand or late transgressive deposits― times of high relative sea level when the deltaic shoreline did not protrude significantly. Tidal currents were accentuated at the coast when the delta complex had prograded several kilometres into the basin, while during times of high relative sea level, the basin was wider and tidal currents were weaker, consequently leading to a lack of tidal deposits. The tidal ridges are, thus, interpreted as being headland-associated deposits. / Thesis (Master, Geological Sciences & Geological Engineering) -- Queen's University, 2011-04-29 17:10:10.008