Due to the economic booms in Taiwan, huge buildings were constructed frequently and with more versatility in use. Which makes the fire protection and egress becoming a more important issue. In evaluating the smoke management and egress effectiveness, the method published by the Ministry of the Interior (MOI), or named as Route B, was widely adapted in Taiwan. However, when using this method in evaluating rooms with less than 200 square meters, difficulty existed due to the lower ceiling height and fixed internal heat released rate. It is the goal of this research to analyze the feasibility in adapting a ¡§Simplified Zone Model¡¨ for this purposes. In this research, various mathematical models were analyzed and compared first, followed by quantitative comparison with smoke descending rates calculated by both methods. It is concluded that the Simplified Zone model is suitable for evaluating rooms with floor area less than 200 square meters. Otherwise, the Route B method as proposed by the MOI is appropriate as expected.

L’objectif principal de ce travail est la compréhension des mécanismes qui gouvernent la fissuration assistée par l’hydrogène dans les métaux, en s’appuyant sur l’analyse expérimentale de la propagation des fissures en atmosphère hydrogénant et de l’interaction entre hydrogène et défauts cristallins, et sur le développement d’un modèle de zone cohésive influencé par l’hydrogène.Des essais de propagation de fissure de fatigue ont été réalisés sous haute pression d'hydrogène gazeux sur le fer de pureté commerciale Armco. Les résultats montrent une forte influence de la pression, de la fréquence et de la valeur de ΔK sur la modification des modes de rupture, et, par conséquent, sur les vitesses de propagation. Afin d’identifier les paramètres physiques pertinents qui gouvernent les modes de rupture, une étude sur l’interaction entre hydrogène et défauts cristallins développés lors d’une sollicitation cyclique a été réalisée. Nous avons observé une augmentation de l’absorption totale d’hydrogène avec la déformation plastique cumulée, qui peut être attribuée à l’augmentation du piégeage de l'hydrogène par les dislocations générées au cours de la déformation. Ces données seront ensuite introduites dans un modèle pour reproduire la modification de la diffusion de l’hydrogène en pointe de fissure, et son effet sur la plasticité.Par ailleurs, des mesures de la déformation plastique hors plan en pointe de fissure en présence d’hydrogène ont permis de proposer une amélioration d’un modèle de zone cohésive en introduisant un effet de l’hydrogène sur le comportement plastique des éléments de volume. De plus, l'étude des composantes de la loi de diffusion de Krom a montré l'importance du gradient de contrainte hydrostatique sur la diffusion et l'accumulation de l'hydrogène en pointe de fissure. Le modèle prédit une forte dépendance de la propagation de fissures vis-à-vis de la diffusion de l’hydrogène en pointe de fissure, et est capable de simuler la propagation de fissure sous chargement statique, validant ainsi la superposition d’une composante de fissuration cyclique et d’une contribution statique (due à la présence d’hydrogène), et expliquant la transition des vitesses de propagation observée expérimentalement. / The main purpose of this work is to understand the mechanisms that govern hydrogen assisted cracking in metals, based on the experimental analysis of crack propagation data under gaseous hydrogen and the interaction between hydrogen and lattice defects on the one hand, and on the development of a cohesive zone model influenced by hydrogen on the other hand.Fatigue crack propagation tests were performed under high pressure of gaseous hydrogen on the Armco iron. The results show a strong influence of the pressure, the frequency and the ΔK value, on the modification of the failure modes and on the fatigue crack growth rates. In order to identify the physical parameters that govern the changing of the failure modes, a study on the interaction between hydrogen and the crystallographic defects developed during a cyclic loading was performed. We observe an increase in the total absorption of hydrogen with the cumulated plastic deformation, which can be attributed to the increase in the hydrogen trapping by the dislocations generated during the cyclic deformation. These data have to be introduced into a numerical model to reproduce the modification of the hydrogen diffusion at the crack tip, and its effect on plasticity.Moreover, measurements of the out-of-plane plastic deformation at the crack tip in presence of hydrogen have conducted to an improvement of the cohesive zone model by introducing an effect of hydrogen on the plastic behavior of the volume elements. In addition, the study of Krom diffusion law components has shown the importance of the hydrostatic stress gradient on the diffusion and accumulation of hydrogen at the crack tip. The model predicts a strong dependence of the crack propagation with respect to the hydrogen diffusion at the crack tip, and it is able to simulate the propagation under static load, thus validating the cyclic cracking and static cracking superposition, and explaining the transient regime in fatigue crack growth rates experimentally observed.

An alternative point of view with regard to understanding the mechanism of energy transfer involved to create new surface is considered in this study. A combination of transport equation and cohesive element is presented. A practical demonstration in 1-D is presented to simulate the mechanism of energy transfer in a damage zone model for both elastic and elastic-plastic materials. The combination of transport and cohesion element shows the extent elastic energy plays to supply the energy required for crack growth. Meanwhile, plastic energy dissipation for an elastic-plastic material is shown to be well described by the transport approach. The cohesive zone model is one of many alternative approaches used to simulate fatigue crack growth. The model incorporates a relationship between cohesive traction and separation in the zone ahead of a crack tip. The model introduces irreversibility into the constitutive relationships by means of damage accumulation with cyclic loading. The traction-separation relationship underpinning the cohesive zone model is not required to follow a predetermined path, but is dependent on irreversibility introduced by decreasing a critical cohesive traction parameter. The approach can simulate fatigue crack growth without the need for re-meshing and caters for constant amplitude loading and single overloading. This study shows the retardation phenomenon occurring in elastic plastic-materials due to single overloading. Plastic materials can generate a significant plastic zone at the crack which is shown to be well captured by the cohesive zone model approach. In a cohesive zone model, fatigue crack growth involves the dissipation of separation energy released per cycle. The crack advance is defined by the total energy separation dissipated term equal to the critical energy release rate or toughness. The effect of varying toughness with the assumption that the critical traction remains fixed is investigated here. This study reveals that varying toughness does not significantly affect the stress distribution along the crack path. However, plastic energy dissipation can significantly increase with toughness. A new methodology called the fast-track method is introduced to accelerate the simulation of fatigue crack growth. The method adopts an artificial material toughness. The basic idea of the proposed method is to decrease the number of cycle for computation by reducing the toughness. By establishing a functional relationship between the number of cycles and variable artificial toughness, the real number of cycles can be predicted. The proposed method is shown to be an excellent agreement with the numerical results for both constant amplitude loading and single overloading. A new approach to predict fatigue crack growth curves is presented. The approach combines the fast-track method and an extrapolation methodology. The basic concept is to establish a function relationship using the curve fitting technique applied to data obtained from preliminary calculation of fast-track methodology. It is shown in this thesis that the new methodology provides excellent agreement with an empirical model. The methodology is limited to constant amplitude loading and small scale yielding conditions. It is shown in the thesis that fatigue crack growth curves for variable amplitude loading can be predicted by using the data set for fatigue crack growth rate for constant amplitude loading. A retardation parameter can be deduced from the number of cycles delayed using the cohesive zone model. The retardation parameter is established by performing calculation for different toughness. This methodology is shown to give good agreement with results from empirical models for different variable amplitude loading conditions.

A pre-flashover fire is very different from a post-flashover fire. The main difference is that in a pre-flashover fire the gas temperature and the radiation temperature differ. One thing that makes it a lot different is that the thermal exposure induced by a pre-flashover fire is largely affected by the smoke gas layer. These smoke gases can be very hot and therefore they emit heat radiation to their surroundings. The theory used, to calculate the thermal exposure of a pre-flashover fire, in this thesis relies on using thermal resistances to describe the heat transfer from the smoke gases. By doing so it is possible to calculate the temperatures of the smoke gases and the surfaces in touch with the smoke gases. Another approach is to use CFD software to numerically calculate the temperatures and in this thesis the two-zone model are compared to FDS, a CFD software. The two-zone model are also compared to a reduced-scale test. The comparisons gave good results, the two-zone model produced similar results compared to re reduced-scale test and FDS. This method of calculating thermal exposure can thereby be used to evaluate evacuation safety and save a lot of calculation time compared to calculating the thermal exposure with CFD software such as FDS.

Zone Models are a widely used tool in fire protection engineering to predict how fires will develop in compartments. Zone models use entrainment algorithms for plumes in the open and the effect of enclosures on the entrainment is currently unclear. This work was a systematic study of six global parameters that effect flame height and the enclosure effect on fire plume entrainment.

<p>Within the European space programme, a new upper stage engine (Vinci) for the Ariane 5 launcher is being developed, and the Volvo Aero Corporation (VAC) is contributing with tur-bines for the fuel turbopumps. This MSc thesis investigates the possibility of designing the Turbine Exhaust Duct (TED) of the Vinci-engine in a carbon fibre composite material with adhesively attached titanium flanges. The focus of the project has been on stress analyses of the adhesive joints using Finite Element Methods (FEM), more specifically by using a cohe-sive zone material (CZM) to model the adhesive layer. Analysing adhesive joints is complex and an important part of the work has been to develop and concretise analysis methods for future use within VAC.</p><p>To obtain the specialised material parameters needed for a CZM analysis, FE-models of ten-sile test specimens were analysed and the results compared to those of equivalent experimen-tal tensile tests. These parameters were then used when analysing the TED geometry with load cases specified to simulate the actual operation conditions of the Vinci engine. Both two-dimensional axisymmetric and fully three-dimensional models were analysed and, addition-ally, a study was performed to evaluate the effect of cryogenic temperatures on the strength of the joint.</p><p>The results show that the applied thermal and structural loading causes local stress concentra-tions on the adhesive surface, but the stresses are not high enough to cause damage to the joint if a suitable joint design is used. Cryogenic temperatures (-150 °C) caused a significant strength reduction in the tensile specimens, partially through altered adhesive properties, but no such severe effects were seen in the temperature-dependent FE-analyses of the TED. It should be pointed out however, that some uncertainties about the material parameters exist, since these were obtained in a rather unconventional way. There are also several other impor-tant questions, beside the strength of the adhesive joint, that need to be answered before a metal-composite TED can be realised.</p> / <p>Volvo Aero deltar i utvecklingen av Vinci, en ny motor till det övre steget i den europeiska Ariane 5-raketen. Detta examensarbete behandlar möjligheten att tillverka ett turbinutlopp (TED) till vätgasturbinen i Vinci-motorn i kompositmaterial med flänsar i titan för att på så sätt uppnå en viktbesparing gentemot den tidigare konstruktionen i gjuten Inconel 718. Fokus har legat på att analysera hållfastheten i de limfogar som är tänkta att sammanfoga huvudröret med flänsarna, genom analyser med finita elementmetoden (FEM). Ett viktigt syfte har även varit att, för Volvo Aeros räkning, samla praktiska erfarenheter angående numerisk analys av limfogar, särskilt med användning av kohesiva zon-element för att modellera limfogen.</p><p>FEM-analyser har gjorts av provstavsmodeller, där resultaten sedan jämförts med experimen-tella dragprovsresultat för att ta fram lämpliga material- och modelleringsparametrar för ana-lys med kohesiva zonelement. Därefter tillämpades dessa parametrar i analyser av den verkli-ga TED-geometrin med relevanta lastfall framtagna för att simulera driftsförhållandena i Vin-ci-motorn. Lastfallsanalyser med både tvådimensionellt axisymmetriska och tredimensionella geometrimodeller genomfördes, liksom uppskattningar av limfogens styrka vid kryogena driftstemperaturer.</p><p>Resultaten pekar entydigt mot att en limfog med en ändamålsenlig tvärsnittsgeometri skulle hålla för de angivna lasterna utan att ta skada. De spänningskoncentrationer som uppstår ger lokalt höga spänningar i limmet, men inte på nivåer som skulle kunna orsaka brott. Det finns dock en viss osäkerhet angående riktigheten i materialparametrarna då en något okonventio-nell metod användes för att ta fram dessa. Flera stora frågor finns fortfarande kvar att besvara innan en metall-komposit konstruktion kan realiseras, inte minst hur flödeskammarens kom-plicerade geometri skall kunna tillverkas i kompositmaterial.</p>

The purpose of this research is to develop a new approach to estimate the effective leakage area using the inverse modeling process as an alternative to the blower door test. An actual office building, which is the head quarter of Energy Efficiency Hub, was used as an example case in this study. The main principle of the inverse modeling process is comparing the real monitor boiler gas consumption with the result calculated from the EnergyPlus model with a dynamic infiltration rate input to find the best estimation of the parameter of effective leakage area (ELA). This thesis considers only the feasibility of replacing the blower door test with the calibration approach, so rather than attempting an automated calibration process based on inverse modeling we deal with generating a first estimate and consider the role of model uncertainties that would make the proposed method less feasible. There are five steps of the whole process. First, we need to customize our own actual weather data (AMY) needed by the energy model (EnergyPlus model), which can help increase our quality of the result. Second, create the building energy model in EnergyPlus. Third, create a multi-zone model using CONTAM with different ELA estimation of each facade to calculate the dynamic infiltration rate of each ELA estimate. Fourth, input the dynamic infiltration rate got from the CONTAM model to EnergyPlus model and output the boiler energy consumption. Fifth, compare the boiler gas consumption from the model and the real monitor data and find the best match between the two and the corresponding ELA, which gives the best estimate from the whole inverse modeling process. From the simulation result comparison, the best estimation of the total building ELA from the inverse modeling process is the 23437cm2 at 4pa, while the result from the blower door test is 10483cm2 at 4pa. Because of the insufficient information of the building and also the uncertainty of the input parameters, the study has not led to a definite statement whether the proposed calibration of the ELA with consumption data can replace a blower door test to get an equally valid or even better ELA estimate, but it looks feasible. As this this case study is done in a deterministic context, the full feasibility test should be conducted under uncertainty. A first step towards this will talk be discussed in chapter 4.

Within the European space programme, a new upper stage engine (Vinci) for the Ariane 5 launcher is being developed, and the Volvo Aero Corporation (VAC) is contributing with tur-bines for the fuel turbopumps. This MSc thesis investigates the possibility of designing the Turbine Exhaust Duct (TED) of the Vinci-engine in a carbon fibre composite material with adhesively attached titanium flanges. The focus of the project has been on stress analyses of the adhesive joints using Finite Element Methods (FEM), more specifically by using a cohe-sive zone material (CZM) to model the adhesive layer. Analysing adhesive joints is complex and an important part of the work has been to develop and concretise analysis methods for future use within VAC. To obtain the specialised material parameters needed for a CZM analysis, FE-models of ten-sile test specimens were analysed and the results compared to those of equivalent experimen-tal tensile tests. These parameters were then used when analysing the TED geometry with load cases specified to simulate the actual operation conditions of the Vinci engine. Both two-dimensional axisymmetric and fully three-dimensional models were analysed and, addition-ally, a study was performed to evaluate the effect of cryogenic temperatures on the strength of the joint. The results show that the applied thermal and structural loading causes local stress concentra-tions on the adhesive surface, but the stresses are not high enough to cause damage to the joint if a suitable joint design is used. Cryogenic temperatures (-150 °C) caused a significant strength reduction in the tensile specimens, partially through altered adhesive properties, but no such severe effects were seen in the temperature-dependent FE-analyses of the TED. It should be pointed out however, that some uncertainties about the material parameters exist, since these were obtained in a rather unconventional way. There are also several other impor-tant questions, beside the strength of the adhesive joint, that need to be answered before a metal-composite TED can be realised. / Volvo Aero deltar i utvecklingen av Vinci, en ny motor till det övre steget i den europeiska Ariane 5-raketen. Detta examensarbete behandlar möjligheten att tillverka ett turbinutlopp (TED) till vätgasturbinen i Vinci-motorn i kompositmaterial med flänsar i titan för att på så sätt uppnå en viktbesparing gentemot den tidigare konstruktionen i gjuten Inconel 718. Fokus har legat på att analysera hållfastheten i de limfogar som är tänkta att sammanfoga huvudröret med flänsarna, genom analyser med finita elementmetoden (FEM). Ett viktigt syfte har även varit att, för Volvo Aeros räkning, samla praktiska erfarenheter angående numerisk analys av limfogar, särskilt med användning av kohesiva zon-element för att modellera limfogen. FEM-analyser har gjorts av provstavsmodeller, där resultaten sedan jämförts med experimen-tella dragprovsresultat för att ta fram lämpliga material- och modelleringsparametrar för ana-lys med kohesiva zonelement. Därefter tillämpades dessa parametrar i analyser av den verkli-ga TED-geometrin med relevanta lastfall framtagna för att simulera driftsförhållandena i Vin-ci-motorn. Lastfallsanalyser med både tvådimensionellt axisymmetriska och tredimensionella geometrimodeller genomfördes, liksom uppskattningar av limfogens styrka vid kryogena driftstemperaturer. Resultaten pekar entydigt mot att en limfog med en ändamålsenlig tvärsnittsgeometri skulle hålla för de angivna lasterna utan att ta skada. De spänningskoncentrationer som uppstår ger lokalt höga spänningar i limmet, men inte på nivåer som skulle kunna orsaka brott. Det finns dock en viss osäkerhet angående riktigheten i materialparametrarna då en något okonventio-nell metod användes för att ta fram dessa. Flera stora frågor finns fortfarande kvar att besvara innan en metall-komposit konstruktion kan realiseras, inte minst hur flödeskammarens kom-plicerade geometri skall kunna tillverkas i kompositmaterial.

<p>An advanced bulk constitutive model is used with a new cohesive zone model that is stress state and rate-dependent in order to simulate the ductile to brittle failure transition in polycarbonate. The cohesive zone model is motivated by experimental evidence that two different critical energies per unit area of crack growth exist in glassy polymers. A higher energy state is associated with ductile failure (slow crack growth), while a lower energy state is associated with brittle failure (fast crack growth). The model is formulated so that as rate or stress state changes within a simulation, the fracture energy and thus fracture mode may also change appropriately. The ductile to brittle transition occurs when the cohesive opening rate is over a threshold opening rate and when the stress state is close to plane strain in a fracture specimen. These effects are coupled. The principal contribution of this work is that this is the first time a single set of material input parameters can predict the transition from slow to fast crack growth as test loading rate and sample thickness are varied. This result enlisted the use of an advanced constitutive model and the new cohesive zone model with rate and stress-state dependencies in three-dimensional finite element analysis.</p> / Dissertation

Studies show that the use of cleaning products is related to adverse respiratory health effects ranging from irritation to asthma. Yet exposure to these chemicals is poorly understood. This dissertation summarizes the current state of knowledge of inhalation exposure to toxic chemicals in consumer cleaning products. An improved two-zone model that treats personal air space as distinct from bulk room air is presented. The model accounts for air exchange between the two zones, dynamic source characteristics (i.e., the time-varying liquid concentrations and emission rates of pollutants within a mixture), and the characteristics of chemical use (e.g., how frequently a cleaning chemical is applied to a new area). To assess exposure to cleaning products and validate the improved two-zone model twenty-three experiments, encompassing six cleaning scenarios, were completed in an environmentally-controlled chamber with a thermal mannequin. Then, the model was used to predict exposure for four hypothetical cleaning scenarios and compared against other models. The model's applicability is restricted by limited data available for parameterization. At low air exchange rates gas-phase experimental results show concentrations in the breathing-zone of the mannequin exceeded concentrations predicted by the well-mixed model by factors up to 2.1. Breathing-zone concentrations also exceed those measured at centralized room monitors by factors up to 6.1. Thus, studies that use the centralized room monitors or the well-mixed model as a surrogate for breathing-zone concentrations could potentially underpredict exposure at low air exchange rates. The two-zone model provides the best prediction of exposure to cleaning tasks, at low air exchange rates. The next best model is the well-mixed model with an exponentially decreasing emission rate, followed by the well-mixed model with a constant emission rate. At high air exchange rates the well-mixed assumption appears to be valid. The inner-zonal volume and inter-zonal air exchange were independent of fresh air ventilation rate. But both were dependant on the mannequin's body position, with standing having the highest inner-zonal volume and lowest intra-zonal air exchange rate of the three body positions investigates (standing, bent over 45°, and hands and knees). / text