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Previous issue date: 2014-08-26 / The addition of inorganic fillers in polyurethane resins for use as coating has been of great technological interest because it leads to improvements in the properties and performance of existing materials, besides the possibility of reducing environmental impact and costs. In this context, this work presents the production of ternary composites with addition of commercial inorganics fillers, titanium dioxide (TiO2) and silica (SiO2), in aqueous polyurethane dispersions. These ternary composites were obtained from the addition of 1% of different combinations of proportion of fillers (TiO2: SiO2 = 0:100 25:75 50:50 75:25 to 100:0) in aqueous polyurethane dispersions (PUD) by the in situ polymerization process. The characteristics of the ternary composite were evaluated in the form of polymer dispersion (particle size, pH, viscosity and conductivity) and in the form of films (thermal, mechanical and morphological properties), as well as the study of degradation of these materials. The results show that the synergy resulting from the combination of the two fillers, SiO2 and TiO2, interferes with the formation of micelles in PUD colloidal system, changing the coalescence process in the formation of films and modifying light reflection and refraction in the composite making it opaque and matte. The presence of anatase crystalline phase in TiO2 particles provides better compatibility filler1-filler2-polymer increasing the tensile strength and thermal stability of the ternary composites. The presence of SiO2 retarded the degradation process in the soil of the ternary composites and they did not show biological material on the surface after degradation. / A adi??o de cargas inorg?nicas em resinas de poliuretano para aplica??o como revestimento tem tido grande interesse tecnol?gico, pois conduz a melhorias nas propriedades e no desempenho dos materiais j? existentes, al?m da possibilidade de redu??o de impacto ambiental e de custos. Neste contexto, este trabalho apresenta a produ??o de comp?sitos tern?rios com a adi??o de cargas inorg?nicas comerciais, di?xido de tit?nio (TiO2) e di?xido de sil?cio (SiO2), em dispers?es aquosas de poliuretano. Estes comp?sitos tern?rios foram obtidos a partir da adi??o de 1% de diferentes propor??es das cargas (TiO2:SiO2 = 0:100, 25:75, 50:50, 75:25 e 100:0) em dispers?es aquosas de poliuretano (DPU) pelo processo de polimeriza??o in situ. As caracter?sticas dos comp?sitos tern?rios foram avaliadas na forma de dispers?o polim?rica (tamanho de part?cula, pH, viscosidade e condutividade) e na forma de filmes (propriedades t?rmicas, mec?nicas e morfologia), bem como, o estudo de degrada??o destes materiais. Os resultados mostram que a sinergia resultante da combina??o das duas cargas, SiO2 e TiO2, interfere na forma??o das micelas no sistema coloidal DPU, alterando o processo de coalesc?ncia na forma??o dos filmes e modificando a reflex?o e a refra??o de luz no comp?sito deixando-o opaco e fosco. A presen?a da fase cristalina anatase nas part?culas de TiO2 propicia melhor compatibilidade carga1-carga2-pol?mero aumentando a resist?ncia a tra??o com altos percentuais de deforma??o e a estabilidade t?rmica dos comp?sitos tern?rios. A presen?a de SiO2 retardou o processo de degrada??o em solo dos comp?sitos tern?rios e estes n?o apresentaram material biol?gico na superf?cie depois da degrada??o.
| Identifer | oai:union.ndltd.org:IBICT/oai:tede2.pucrs.br:tede/3267 |
| Date | 26 August 2014 |
| Creators | Santos, Cl?udia Andr?a Batista dos |
| Contributors | Ligabue, Rosane Ang?lica |
| Publisher | Pontif?cia Universidade Cat?lica do Rio Grande do Sul, Programa de P?s-Gradua??o em Engenharia e Tecnologia de Materiais, PUCRS, BR, Faculdade de Engenharia |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/masterThesis |
| Format | application/pdf |
| Source | reponame:Biblioteca Digital de Teses e Dissertações da PUC_RS, instname:Pontifícia Universidade Católica do Rio Grande do Sul, instacron:PUC_RS |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | -7432719344215120122, 500, 600, -655770572761439785 |
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