The title compounds, C23H25Br2NO2 (1) and C31H29BrN2O4 (2), crystallize in the space group P21/n with two (1-A and 1-B) and one molecules, respectively, in the asymmetric unit of the cell. The molecular conformation of these compounds is stabilized by intramolecular C—H⋯O hydrogen bonds and C—H⋯N or C—H⋯π interactions. The crystal structure of 1 features a relatively strong Br⋯O=C halogen bond, which is not observed in the case of 2. Both crystal structures are characterized by the presence of C—H⋯Br hydrogen bonds and numerous intermolecular C—H⋯O hydrogen-bonding interactions.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:92587 |
| Date | 12 July 2024 |
| Creators | Stapf, Manuel, Leibiger, Betty, Schwarzer, Anke, Mazik, Monika |
| Contributors | Technische Universität Bergakademie Freiberg |
| Publisher | International Union of Crystallography |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, doc-type:article, info:eu-repo/semantics/article, doc-type:Text |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | 2056-9890, https://doi.org/10.1107/S205698902100788X |
Page generated in 0.0022 seconds