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Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants

Articulated rigid-rod polymers asPBI were synthesized via polycondensation reaction. Using 2-sulfoterephthalic acid and 5-sulfoisophthalic acid in different ratios for copolycondensation reaction making the fully conjugated rigid-rod backbone became articulated. Both rigid-rod and articulated rigid-rod were further derivatized using alkane sulfonated pendants and became water-soluble rigid-rod and articulated rigid-rod polyelectrolytes.
Lithium salt doped cast films of the polyelectrolytes showed a root-temperature DC conductivity parallel to film surface (

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0215105-111443
Date15 February 2005
CreatorsDu, Yue-Lin
ContributorsJin-Long Hong, Ming Chen, Shih-Jung Bai
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageCholon
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0215105-111443
Rightsnot_available, Copyright information available at source archive

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