Iron filled carbon nanotubes (FeCNT) can be described as carbon nanotubes which contain an iron nanowire of several micrometers length and a diameter of approximately 10-100 nm. The carbon shells protect the iron core from oxidation and mechanical damage thus enabling a wide range of applications that require a long-term stability. The magnetic properties of the enclosed nanowire are in part determined by its small size and elongated shape. Magnetic force microscopy (MFM) measurements show that the iron wire exhibits a single domain behavior. Due to the large shape anisotropy it is magnetized along the long wire axis in the remanent state. Two magnetic monopoles of opposing polarity are located at the wire extremities. Depending on the structure and geometry of the individual nanowire, switching fields in the range of 100-400 mT can be found when the external field is applied along the FeCNT’s easy axis. Cantilever magnetometry shows that the switching can be attributed to a thermally assisted magnetization reversal mechanism with the nucleation and propagation of a domain wall. The defined magnetic properties of individual FeCNT combined with their mechanical strength make them ideal candidates for an application as high resolution high stability MFM probes. The fabrication of such probes can be achieved with the help of a micromanipulation setup in a scanning electron microscope. FeCNT MFM probes achieve a sub 25 nm lateral magnetic resolution. MFM measurements with FeCNT MFM probes in external fields show that the magnetization of these probes is exceptionally stable compared to conventional coated MFM probes. This greatly simplifies the data evaluation of such applied field MFM measurements. The emphasis of this work was put on the calibration of FeCNT probes to enable straightforward quantitative MFM measurements. The defined shape of the magnetically active iron nanowire allows an application of a point monopole description. Microscale parallel current carrying lines that produce a defined magnetic field are used as calibration structures to determine the effective magnetic moment of different MFM probes. The line geometry is varied in order to produce multiple magnetic field decay lengths and investigate the influence on the effective probe moment. The results show that while the effective magnetic monopole moment of a conventional MFM probe increases with an increasing sample stray field decay length, the effective moment of a FeCNT MFM probe remains constant. This enables a MFM probe calibration that stays valid for a large variety of magnetic samples. Furthermore, the fitted monopole moment of a FeCNT probe (in the order of 10E-9 Am) is consistent with the moment calculated from the nanowire geometry and the saturation magnetization of iron.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:14-qucosa-72457 |
| Date | 20 October 2011 |
| Creators | Wolny, Franziska |
| Contributors | Technische Universität Dresden, Fakultät Mathematik und Naturwissenschaften, Prof. Dr. Bernd Büchner, Prof. Dr. Bernd Büchner, Prof. Dr. Chris Hammel |
| Publisher | Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | doc-type:doctoralThesis |
| Format | application/pdf |
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