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Investigation of the magnetic and electronic structure of Fe in molecules and chalcogenide systems

In this work the electronic and magnetic structure of the crystals Sr2FeMoO6,
Fe0.5Cu0.5Cr2S4, LuFe2O4 and the molecules FeStar, Mo72Fe30, W72Fe30 are investigated
by means of X-ray spectroscopic techniques. These advanced materials exhibit very interesting properties like magnetoresistance or multiferroic behaviour. In case of the molecules they also could be used as spin model systems. A long standing issue concerning the investigation of these materials are contradicting results found for the magnetic and electronic state of the iron (Fe) ions present in these compounds. Therefore this work focuses on the Fe state of these materials in order to elucidate reasons for these problems. Thereby the experimental results are compared to multiplet simulations.

Identiferoai:union.ndltd.org:uni-osnabrueck.de/oai:repositorium.ub.uni-osnabrueck.de:urn:nbn:de:gbv:700-201006096312
Date09 June 2010
CreatorsTaubitz, Christian
Contributorsapl. Prof. Dr. Manfred Neumann, Prof. Dr. Joachim Wollschläger
Source SetsUniversität Osnabrück
LanguageEnglish
Detected LanguageEnglish
Typedoc-type:doctoralThesis
Formatapplication/pdf, application/zip
Rightshttp://rightsstatements.org/vocab/InC/1.0/

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