Steel industry is a highly polluted industry and one of the most important stationary sources in Kaohsiung City. The steel manufacturing process could emit a huge amount of particles, such as the sintering process, the blast furnace operation, and the raw material handling process. Suspended particles emitted from steel industry could deteriorate ambient air quality and cause adverse effects on human health.
In order to understand the impact of steel industry on ambient air quality in Siaogang District and to identify potential pollution sources, this study selected a integrated steel manufacturing plant located at Siaogang District to conduct a sampling protocol of suspended particulate matter (PM) at ambient sites (A1~A5) and sensitive sites (S1~S5) from July 2011 to March 2012. The size distribution of suspended particles in four seasons was measured with PM10 high-volume samplers, dichotomous samplers, and MOUDI for 3 days (24 hours for single sampling), and dustfall samplers for one month, to investigate the spatial distribution and temporal variation of PM concentration. After sampling, the physicochemical properties of PM, including mass concentration, particle size distribution, dustfall concentration, water-soluble ionic species, metallic elements, and carbonaceous contents, were further analyzed.
Field measurement of ambient PM showed that the averaged ambient PM10 concentration (53.54 - 203.56 £gg/m3) were higher than sensitive sites (55.06 - 140.07 £gg/m3) and the averaged ambient PM2.5 concentration of ambient (23.10 - 120.21£gg/m3) were higher than sensitive sites (12.52 - 65.62 £gg/m3). No matter ambient or sensitive sites, it showed a tendency of lower concentration in summer, indicating that concentration variation of PM10 and PM2.5 were highly affected by meteorological factors (such as wind direction, wind speed, and relative humidity) in Siaogang District. Furthermore, a t-test result showed that ambient and sensitive sites have similar pollution sources since the p-values were in significantly different.
Chemical analysis of PM results showed that the most abundant water-soluble ionic species of PM at the ambient and sensitive sites were secondary inorganic aerosols (SO42-, NO3-, and NH4+) and [NO3-]/[SO42-] showed that ionic species were mainly emitted from stationary sources. Fe, Al, K and Ca were the major metallic elements of this study, and the major pollution sources contain industries, traffics, and road dusts. Additionally, the raw material handling process was the major pollution source of PM. Correlation analysis of OC and EC showed that PM at ambient and sensitive sites were originated from primary sources, such as vehicles, industries, road dusts, and human activities.
Results obtained from PCA and CMB receptor modeling showed that both PM2.5 and PM10 highly correlated with wind direction in different season and the major pollution sources were industry pollution (including petroleum refineries, power plants, waste incinerators, consistent operating steel mills and electric arc furnace steel mills, etc.), followed by local traffics and derivative. Furthermore, marine aerosols were one of the important pollution sources at sensitive sites (S1, S4, and S5) where close to the ocean.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0824112-115817 |
| Date | 24 August 2012 |
| Creators | Liao, Chia-cheng |
| Contributors | Chin-Hsiang Luo, Yuan-Chung Lin, Chung-Shin Yuan, Jeng-Jong Liang |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0824112-115817 |
| Rights | user_define, Copyright information available at source archive |
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