The neutron Electric Dipole Moment Experiment at the Spallation Neutron Source requires an overall magnetic shielding factor of order 105 to attenuate external background magnetic fields. At present, the shielding design includes an external (room-temperature) multi-layer μ-metal magnetic shield, a cryogenic (4 Kelvin) Pb superconducting shield, and a cryogenic (4 Kelvin) ferromagnetic shield composed of Metglas ribbon. This research determined how to construct a Metglas shield using minimal material that produced axial and transverse shielding factors of ~267 and ~1500. In addition, the μ-metal and Metglas shields were modeled using finite element analysis. The FEA model includes external coils and their effect on the residual magnetic fields. This study will help with the design of the shielding.

RR Lyrae stars are old, iron-poor, Helium-burning variable stars. RR Lyraes are extremely useful for tracing phase-space structures and metallicities within the galaxy because they are easy to identify, have consistent luminosities, and are found in large numbers in the galactic disk, bulge, and halo. Here we present a new set of spectroscopic metallicity calibrations that use the equivalent widths of the Ca II K, Hγ, and Hδ lines to calculate metallicity values. Applied to spectroscopic survey data, these calibrations will help shed light on the evolution of the Milky Way and other galaxies.

Two measurements have been made, addressing gaps in knowledge for 235U(n,f) and 238U(n,f). The energy distribution for prompt fission neutrons is not well-understood below 1 MeV in 235U(n,f). To measure the 235U(n,f) prompt fission neutron distribution, a pulsed neutron beam at the WNR facility in Los Alamos National Laboratory was directed onto a 235U target with neutron detectors placed 1 m from the target. These neutron detectors were designed specifically for this experiment and employed a unique geometry of scintillating plastic material that was designed to reject backgrounds. Fission fragments were detected using an avalanche counter. Coincidences between fission fragment production and neutron detector events were analyzed, using a double time-of-flight technique to determine the energy of the prompt fission neutrons. A separate measurement was made, investigating the neutron-induced fission cross section for 238U(n,f). This measurement also used the pulsed neutron beam at the WNR facility. The neutron flux was normalized to the well-known hydrogen standard and the fission rate was observed for beam neutrons in the energy range of 130-300 MeV. Using an extrapolation technique, the energy dependence of the cross section was determined. These new data filled a sparsely populated energy region that was not well-studied and were measured relative to the hydrogen standard, unlike the majority of available data. These data can be used to constrain the fission cross section, which is considered a nuclear reaction standard.

The fact that loosely bonded DNA bases could tolerate large structural fluctuations, form a dissipative environment for a charge traveling through the DNA. Nonlinear stochastic nature of structural fluctuations facilitates rich charge dynamics in DNA. We study the complex charge dynamics by solving a nonlinear, stochastic, coupled system of differential equations. Charge transfer between donor and acceptor in DNA occurs via different mechanisms depending on the distance between donor and acceptor. It changes from tunneling regime to a polaron assisted hopping regime depending on the donor-acceptor separation. Also we found that charge transport strongly depends on the feasibility of polaron formation. Hence it has complex dependence on temperature and charge-vibrations coupling strength. Mismatched base pairs, such as different conformations of the G・A mispair, cause only minor structural changes in the host DNA molecule, thereby making mispair recognition an arduous task. Electron transport in DNA that depends strongly on the hopping transfer integrals between the nearest base pairs, which in turn are affected by the presence of a mispair, might be an attractive approach in this regard. I report here on our investigations, via the I –V characteristics, of the effect of a mispair on the electrical properties of homogeneous and generic DNA molecules. The I –V characteristics of DNA were studied numerically within the double-stranded tight-binding model. The parameters of the tight-binding model, such as the transfer integrals and on-site energies, are determined from first-principles calculations. The changes in electrical current through the DNA chain due to the presence of a mispair depend on the conformation of the G・A mispair and are appreciable for DNA consisting of up to 90 base pairs. For homogeneous DNA sequences the current through DNA is suppressed and the strongest suppression is realized for the G(anti)・A(syn) conformation of the G・A mispair. For inhomogeneous (generic) DNA molecules, the mispair result can be either suppression or an enhancement of the current, depending on the type of mispairs and actual DNA sequence.

There have been very few measurements of the total cross section for n-p scattering below 500 keV. In order to differentiate among NN potential models, improved cross section data between 20 and 600 keV are required. We measured the n-p and n-C total cross sections in this energy region by transmission; a collimated neutron beam was passed through CH2 and C samples and transmitted neutrons were detected by a BC-501A deuterated liquid scintillator. Cross sections were obtained by taking the ratios of normalized neutron yields with the samples in the beam and with no sample in the beam. Both better precision and larger range between 90 keV and 1.8 MeV results are presented. The parameters resulting from fitting effective range theory to the data for n-p scattering are in good agreement with parameters determined from previous fits.

Fourier transform infrared difference spectroscopy (FTIR DS) is widely used to study the structural details of electron transfer cofactors in photosynthetic protein complexes. In photosynthetic proteins quinones play an important role, functioning as a cofactor in light-driven electron transfer. In photosystem I (PS I) phylloquinone (PhQ) functions as an intermediary in electron transfer. To investigate the properties of PhQ that occupies the, so called, A1 binding site in PS I, time-resolved step-scan FTIR DS, with 5µs time resolution at 77K has been used. By replacing PhQ in the A1 binding site with specifically isotope labeled version, information on the vibrational frequencies associated specifically with the quinone in the binding site were obtained, which could be compared to the vibrational properties of quinone in solution or quinones in other protein binding sites. To further aid in assessing the origin of bands in the spectra, quantum mechanics /molecular mechanics (QM/MM) ONIOM type calculations were undertaken. ONIOM is an acronym for Our own N-layered Integrated molecular Orbital and molecular Mechanics. We find that the phytyl tail of PhQ does not play an important role in the orientation of PhQ in the A1 binding site. We also find that PhQ, in both neutral and reduced states, is strongly hydrogen bonded. To test and verify the applicability of our QM/MM approach, ONIOM calculations were also undertaken for ubiquinone and a variety of other quinones incorporated into the, so called, QA binding site in purple bacteria photosynthetic reaction centers. The calculated and experimental spectra agree well, demonstrating the utility and applicability of our ONIOM approach. Hydrogen bonding to the carbonyl groups of quinones in the QA binding site was shown to be relatively weak, and it was found that hydrogen bonding to neutral ubiquinone in purple bacterial reaction centers can be considered in purely electrostatic terms, contrary to the widely held belief that the hydrogen bonding amino acids should be treated quantum mechanically.

A broad near-infrared photometric survey is conducted of 1678 stars in the direction of the $\rho$ Ophiuchi ($\rho$ Oph) star forming region using data from the 2MASS Calibration Database. The survey involves up to 1584 photometric measurements in the \emph{J}, \emph{H} and \emph{K$_{s}$} bands with an $\sim$1 day cadence spanning 2.5 years. Identified are 101 variable stars with $\Delta$\emph{K$_{s}$} band amplitudes from 0.044 to 2.31 mag and $\Delta$(\emph{J}-\emph{K$_{s}$}) color amplitudes ranging from 0.053 to 1.47 mag. Of the 72 $\rho$ Oph star cluster members, 79$\%$ are variable; in addition, 22 variable stars are identified as candidate members. The variability is categorized as periodic, long timescale, or irregular based on the \emph{K$_{s}$} time series morphology. The dominant variability mechanisms are assigned based on the correlation between the stellar color and single band variability. Periodic signals are found in 32 variable stars with periods between 0.49 to 92 days. The most common variability mechanism among these stars is rotational modulation of cool starspots. Periodic eclipse-like variability is identified in 6 stars with periods ranging from 3 to 8 days; in these cases the variability mechanism may be warped circumstellar material driven by a hot proto-Jupiter. Aperiodic, long time scale variability is identified in 31 stars with time series ranging from 64 to 790 days. The variability mechanism is split evenly between either variable extinction or mass accretion. The remaining 40 stars exhibit sporadic, aperiodic variability with no discernible time scale or variability mechanism. Interferometric images of the active giant $\lambda$ Andromedae ($\lambda$ And) were obtained for 27 epochs spanning November. 2007 to September, 2011. The \emph{H} band angular diameter and limb darkening coefficient of $\lambda$ And are 2.777 $\pm$ 0.027 mas and 0.241 $\pm$ 0.014, respectively. Starspot properties are extracted via a parametric model and an image reconstruction program. High fidelity images are obtained from the 2009, 2010, and 2011 data sets. Stellar rotation, consistent with the photometrically determined period, is traced via starspot motion in 2010 and 2011. The orientation of $\lambda$ And is fully characterized with a sky position angle and inclination angle of 23$\degree$ and 78$\degree$, respectively.

Recent experimental studies point to the notion that the brain is a complex dynamical system whose behaviors relating to brain functions and dysfunctions can be described by the physics of network phenomena. The brain consists of anatomical axonal connections among neurons and neuronal populations in various spatial scales. Neuronal interactions and synchrony of neuronal oscillations are central to normal brain functions. Breakdowns in interactions and modifications in synchronization behaviors are usual hallmarks of brain dysfunctions. Here, in this dissertation for PhD degree in physics, we report discoveries of brain oscillatory network activity from two separate studies. These studies investigated the large-scale brain activity during tactile perceptual decision-making and epileptic seizures. In the perceptual decision-making study, using scalp electroencephalography (EEG) recordings of brain potentials, we investigated how oscillatory activity functionally organizes different neocortical regions as a network during a tactile discrimination task. While undergoing EEG recordings, blindfolded healthy participants felt a linear three-dot array presented electromechanically, under computer control, and reported whether the central dot was offset to the left or right. Based on the current dipole modeling in the brain, we found that the source-level peak activity appeared in the left primary somatosensory cortex (SI), right lateral occipital complex (LOC), right posterior intraparietal sulcus (pIPS) and finally left dorsolateral prefrontal cortex (dlPFC) at 45, 130, 160 and 175 ms respectively. Spectral interdependency analysis showed that fine tactile discrimination is mediated by distinct but overlapping ~15 Hz beta and ~80 Hz gamma band large-scale oscillatory networks. The beta-network that included all four nodes was dominantly feedforward, similar to the propagation of peak cortical activity, implying its role in accumulating and maintaining relevant sensory information and mapping to action. The gamma-network activity, occurring in a recurrent loop linked SI, pIPS and dlPFC, likely carrying out attentional selection of task-relevant sensory signals. Behavioral measure of task performance was correlated with the network activity in both bands. In the study of epileptic seizures, we investigated high-frequency (> 50 Hz) oscillatory network activity from intracranial EEG (IEEG) recordings of patients who were the candidates for epilepsy surgery. The traditional approach of identifying brain regions for epilepsy surgery usually referred as seizure onset zones (SOZs) has not always produced clarity on SOZs. Here, we investigated directed network activity in the frequency domain and found that the high frequency (>80 Hz) network activities occur before the onset of any visible ictal activity, andcausal relationships involve the recording electrodes where clinically identifiable seizures later develop. These findings suggest that high-frequency network activities and their causal relationships can assist in precise delineation of SOZs for surgical resection.

The photoionization cross sections of small fullerenes (C28, C32, C40, C44, and C50), and the outer and near-outer shells of atoms (noble gases, alkaline earth) confined endohedrally inside a C60 molecule are calculated employing a time-dependent local density approximation formulation. Plasmon and confinement resonances are found to be a general feature of these cross sections, and dramatic interchannel coupling effects, significantly increasing the atomic cross sections, are exhibited in all cases in the vicinity of the C60 plasmons. Hybridization effects, the mixing of the atomic and cage bound state wave functions, are also found, but no systematics of the hybridization present themselves. Also, in the case of Ar@C60, Inter-atomic Columbic decay (ICD) has been found and studied.

This dissertation summarizes three research projects related to microwave radiation induced electron transport properties in the GaAs/AlGaAs two dimensional electron systems. In chronological order, the projects are: a microwave reflection and electron magneto-transport correlation study, the combined microwave power and polarization dependence on microwave radiation induced magneto-resistance oscillations study, and a comparative study about the effect of circularly polarized and linearly polarized microwaves radiation on magneto-resistance oscillations induced due to the microwave. These three research projects experimentally address many interesting issues in the non-equilibrium low dimensional electron transport under microwave irradiation and provide potential applications of utilizing microwave radiation induced magneto-resistance oscillations in two dimensional electron systems as a method to detect different qualities of microwaves or terahertz waves.