Este estudo consistiu na investigação sobre a interação dos lubrificantes empregados na usinagem de metais com a matéria orgânica natural (substâncias húmicas), a sua mobilidade no solo, a degradação microbiológica e a remoção dos mesmos do solo. Realizou-se, também, um estudo sobre as mudanças nas características dos fluidos após a sua utilização. Para o processo de degradação das amostras de fluido, submetidos aos efeitos de diferentes fatores ambientais, foram utilizados quatro tratamentos : (i) microrganismos nativos, chamada amostra controle; (ii) amostra controle com matéria orgânica proveniente de turfa; (iii) amostra controle acrescida de microrganismos existentes nos efluentes de máquinas de corte; e (iv) amostra controle com adição de microrganismos de compostagem. Para a pesquisa da degradação sem o efeito dos parâmetros climáticos, foram utilizadas amostras de solo contaminadas mantendo-se em estufa, e a inoculação dos microrganismos em meios de cultura com e sem acréscimo de fonte alternativa de carbono. Como técnicas analíticas, foram utilizadas a CG-DIC e a CG-EM. Essas técnicas são indicadas tanto para estudar a composição dos fluidos quanto dos produtos de degradação microbiológica, tendo sido otimizados métodos analíticos para serem empregados no monitoramento ambiental e de estudos de degradação. As análises por IVTF e por EF também foram empregadas na identificação e quantificação dos fluidos. Observou-se uma considerável interação dos fluidos solúveis com a matéria orgânica do solo, embora tenham se apresentado com alta mobilidade para alguns constituintes, bem como um acelerado processo de degradação durante o uso. De outro modo, os fluidos insolúveis se apresentaram mais imóveis, ficando retidos na matéria orgânica do solo, entretanto, foram mais prontamente degradados no ambiente que os solúveis. A adição de matéria orgânica e de microrganismos de compostagem acelerou o processo de degradação para todos os fluidos de corte investigados. / This study is an investigation of the interaction of lubricants employed in metal machining and natural organic matter (humic substances), their mobility in soil, microbial degradation and their removal from the soil. Also, was performed study of changes in characteristic on fluids after their use. On degradation process from fluid samples, contaminated soils submitted to different environment factors, were used four treatments : (i) native microorganisms named control sample; (ii) control sample added by organic matter from peat; (iii) control sample added by microorganisms existing in flowing out from cutting machines; and (iv) control sample with addition of microorganisms from composting. For degradation research by no effect from climate parameters were used sample of contaminated soil been investigated in stove and microorganisms inoculation in culture mean with and without addition of alternative carbon source. As analytical techniques were used GC-FID and GG-MS. These techniques are both indicated for fluid composition studies and microbial degradation product. Analytic methods had been optimized to be employed on environmental monitoring and degradation studies. The FTIR and espectrofluorimetric methods were used for the fluid identification and quantification. Were observed a notable interaction between soluble fluids and soil organic matter, thought it had been verified high mobility for some compounds as well an accelerated process of degradation during their use. Otherwise, insoluble fluids were more immobile been restrained in soil organic matter, nevertheless, were readily degraded in environment than soluble ones. Organic matter and composting microorganisms\' addition accelerated the degradation process for all cutting fluids investigated.

A partir de considerações sobre interações entre pares de objetos dependentes apenas de suas orientações relativas, desenvolvemos um modelo discreto para cristais líquidos biaxiais. Representamos estes sistemas por um conjunto de partículas biaxiais localizadas nos sítios de uma rede cristalina e que se orientam somente ao longo dos três eixos cartesianos. O diagrama de fases, obtido na aproximação de campo médio, apresenta uma fase nemática biaxial, duas fases nemáticas uniaxiais, além da fase isotrópica. Estas fases se encontram em um ponto multicrítico em cuja vizinhança fazemos a expansão de Landau da Energia Livre. Finalmente analisamos a adição de um campo externo favorável ao ordenamento nemático uniaxial. / From considerations about the pair interaction of objects depending only on their relative orientations, we develop a discrete model for biaxial liquid crystals. These systems are represented by a set of biaxial particles localized on the sites of a crystal lattice and oriented only along the three Cartesian axes. The phase diagram, obtained in a mean field approximation, displays a biaxial nematic phase, two uniaxial nematic phases, beside the isotropic phase. These phases meet on a multicritical point about which we make the Landau expansion of the free energy. Finally, we analyse the case where an external field is applied to favour the uniaxial nematic ordering.

Cheung, Wai Ming Edwin. / Thesis (Ph.D.)--Chinese University of Hong Kong, 2013. / Includes bibliographical references (leaves 107-112). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Abstracts also in Chinese.

The better understanding of the behavior of emulsions and suspensions is important in many applications. In general, emulsions allow the delivery of insoluble agents to be uniformly distributed in a more efficient way. At the same time suspensions of rigid particles are used as “smart materialsâ€� as their properties can be changed by the interaction with a magnetic or electric field. In the first part of the talk we consider a periodic emulsion formed by two Newtonian fluids in which one fluid is dispersed under the form of droplets of arbitrary shape, in the presence of surface tension. We assume the droplets have fixed centers of mass and are only allowed to rotate. We are interested in the time-dependent, dilute case when the characteristic size of the droplets aε, of arbitrary shape, is much smaller than the period length ε. We obtain a Brinkman type of fluid flow for the critical size aε = O(ε3) as a replacement of the Stokes flow of the emulsion. Additionally, using Mosco convergence and semigroup theory we extend the convergence to the parabolic case. For the case when the droplets convect with the flow, it can be shown again using Mosco-convergence that, as the size of the droplets converges to zero faster than the distance between the droplets, the emulsion behaves in the limit like the continuous phase and no “strangeâ€� term appears. Moreover, we determine the rate of convergence of the velocity field for the emulsion to that of the velocity for the one fluid problem in both the H1 and L2 norms. Additionally, a second order approximation is determined in terms of the bulk and surface polarization tensors for the cases of uniform and non-uniform surface tension. The second part of the talk is devoted to the study of MR fluids. We consider a suspension of rigid magnetizable particles in a non-conducting, viscous fluid with an applied external magnetic field. Thus, we use the quasi-static Maxwell equations coupled with the Stokes equations to capture the magnetorheological effect. We upscale using two scale asymptotic expansions to obtain the effective equations consisting of a coupled nonlinear system in a connected phase domain as well as the new constitutive laws. The proposed model generalizes the model of Rosenweig by coupling the velocity of the fluid and the magnetic field intensity. Using the finite element method we compute the effective coefficients for the MR fluid. We analyze the resulting MR model for Poiseuille and Couette flows and compare with experimental data for validation.

Heat transfer fluids are materials responsible for heat distribution, transfer and storage. Their significance is undeniable - many technological processes cannot be carried out without using heat transfer materials (for example due to overheating). These are usually mixtures of many compounds, for example glycols, silicones or water. Today's technologies constantly require more efficient, environmentally- and economically-friendly solutions for heat transfer applications. It is necessary to know the full physicochemical characteristics to design a new heat transfer fluid (mainly density, heat capacity, viscosity and thermal conductivity). Nanofluids (mixture of a basefluid and nanoparticles) were proposed as a solution for many industrial issues due to their enhanced thermophysical properties (i.e. thermal conductivity) than pure liquids. Moreover, these enhancements exhibit unusual features which make this group of materials interesting from molecular and industrial point of view. Ionic liquids, task specific materials with tuneable properties were repeatedly recommended as heat transfer fluids due to their specific properties (mainly low vapour pressure, wide liquidus range, or non-flammability) caused by the ionic structure. A very interesting material can be obtained by mixing ionic liquids and nanoparticles where specific properties of ionic liquids are preserved, and thermophysical properties are enhanced due to nanoparticles dispersion. In this work, we investigated ionic liquid - based nanofluids from the experimental and theoretical point of view, including imidazolium-, pyrrolidinium- and phosphonium-based ionic liquids with several different anions, and multiwalled carbon nanotubes, graphite, boron nitride and mesoporous carbon as nanoparticles, and also in mixtures with water. As a final result, we assessed the molecular recognition of the thermophysical properties enhancements in ionanofluids, developed the predictive models for physical properties, compared all investigated systems to commercial heat transfer fluids. The project was supported by King Faisal University (Saudi Arabia) through a research fund from the International Cooperation and Knowledge Exchange Administration department at KFU. Cytec are thanked for the generous donation of the trihexyl(tetradecyl)phosphonium chloride sample.

Lau Yiu Kee. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2004. / Includes bibliographical references (leaves 142-146). / Abstracts in English and Chinese. / LIST OF TABLES --- p.viii / LIST OF FIGURES --- p.x / Chapter 1. --- INTRODUCTION --- p.1 / Chapter 1.1 --- Motivation --- p.1 / Chapter 1.2 --- Railway Vehicle Suspension --- p.2 / Chapter 1.3 --- Semi-Active Magnetorheological Fluid Damper --- p.3 / Chapter 1.4 --- Research Objectives --- p.4 / Chapter 1.5 --- Thesis Outline --- p.5 / Chapter 2. --- BACKGROUND --- p.7 / Chapter 2.1 --- MR Fluids --- p.7 / Chapter 2.1.1 --- Composition of MR fluids --- p.7 / Chapter 2.1.2 --- Properties and characteristics of MR fluids --- p.8 / Chapter 2.1.3 --- Literature review --- p.13 / Chapter 2.2 --- MR Devices --- p.13 / Chapter 2.2.1 --- Advantages of MR devices --- p.13 / Chapter 2.2.2 --- Common device geometries --- p.14 / Chapter 2.2.3 --- MR fluid based applications --- p.15 / Chapter 2.2.4 --- Literature review --- p.19 / Chapter 2.3 --- Overview of Railway Vehicles --- p.21 / Chapter 2.3.1 --- "Passive, active and semi-active suspensions" --- p.21 / Chapter 2.3.2 --- Basic railway vehicle structure --- p.23 / Chapter 2.3.3 --- Literature review --- p.25 / Chapter 2.4 --- Railway Vehicle Suspension Systems --- p.25 / Chapter 2.4.1 --- Primary vertical suspension --- p.25 / Chapter 2.4.2 --- Secondary vertical suspension --- p.27 / Chapter 2.4.3 --- Secondary lateral suspension --- p.27 / Chapter 2.4.4 --- Yaw suspension --- p.28 / Chapter 3. --- DESIGN CONSIDERATIONS FOR MR DAMPERS --- p.29 / Chapter 3.1 --- Overview of Existing MR Dampers --- p.29 / Chapter 3.1.1 --- Monotube MR fluid damper --- p.29 / Chapter 3.1.2 --- Double-ended MR damper --- p.31 / Chapter 3.1.3 --- Bellow type MR damper --- p.35 / Chapter 3.2 --- Optimal Design and Configuration of Magnetic Circuit --- p.35 / Chapter 3.2.1 --- Magnetic circuit and magnetic field orientation --- p.35 / Chapter 3.2.2 --- Physical dimension of MR damper --- p.38 / Chapter 3.2.3 --- Connection polarity of electromagnetic circuit --- p.40 / Chapter 3.3 --- Basic Geometry Design Considerations --- p.43 / Chapter 3.3.1 --- Controllable force and dynamic range --- p.43 / Chapter 3.3.2 --- Geometry constraints --- p.45 / Chapter 3.3.3 --- Magnetic circuit design --- p.47 / Chapter 4. --- DEVELOPMENT AND FABRICATION OF MR DAMPERS --- p.51 / Chapter 4.1 --- Pneumatic Air Cylinder --- p.51 / Chapter 4.2 --- Fabrication Process of Double-Ended MR Dampers --- p.55 / Chapter 4.2.1 --- Modifications on the pneumatic air cylinder --- p.55 / Chapter 4.2.2 --- Manufacturing processes of the piston sleeve --- p.56 / Chapter 4.2.3 --- Modification processes of the original piston rod --- p.59 / Chapter 4.2.4 --- Modification of the piston staging area --- p.60 / Chapter 4.2.5 --- Copper wire wrapping and damper assembling --- p.63 / Chapter 5. --- EXPERIMENTAL SETUP AND RESULTS --- p.66 / Chapter 5.1 --- Experimental Setup for the Double-Ended MR Damper --- p.66 / Chapter 5.1.1 --- Instron 8801 loading machine --- p.66 / Chapter 5.1.2 --- Experimental setup for testing the MR damper --- p.67 / Chapter 5.2 --- Force-Lag Phenomenon of MR Damper --- p.70 / Chapter 5.2.1 --- Force-lag phenomenon --- p.70 / Chapter 5.2.2 --- Reasons of the force-lag phenomenon --- p.73 / Chapter 5.2.3 --- Methods to eliminate the force-lag phenomenon --- p.76 / Chapter 5.2.4 --- Setup for hydraulic pump system --- p.77 / Chapter 5.2.5 --- Results and effects of the pressurized MR damper --- p.79 / Chapter 5.3 --- Experimental Results for Testing the MR Damper --- p.83 / Chapter 6. --- SIMULATION RESULTS OF SEMI-ACTIVE TRAIN SUSPENSION --- p.87 / Chapter 6.1 --- MR Damper Model --- p.87 / Chapter 6.2 --- Rail Vehicle Model --- p.92 / Chapter 6.3 --- Semi-Active Railway Suspension --- p.94 / Chapter 6.3.1 --- Lateral vibration on the train --- p.94 / Chapter 6.3.2 --- Semi-active control strategy --- p.95 / Chapter 6.4 --- Simulation Results --- p.98 / Chapter 6.4.1 --- Lower sway mode excitation --- p.99 / Chapter 6.4.2 --- Upper sway mode excitation --- p.105 / Chapter 6.4.3 --- Mixed sway mode excitation --- p.110 / Chapter 6.4.4 --- BR high speed assault course --- p.116 / Chapter 6.4.5 --- Discussions --- p.124 / Chapter 6.5 --- Effects of Vibration on Ride Comfort --- p.128 / Chapter 7. --- CONCLUSIONS --- p.134 / APPENDIX --- p.136 / BIBLIOGRAPHY --- p.142

This work investigates the hydrodynamics of the expansion of the bubbles of the broken symmetry phase during the electroweak phase transition in the early universe, in which SU(2) electroweak symmetry is broken and fundamental particles acquire mass through the Higgs mechanism. The electroweak phase transition has received renewed attention as a viable setting for the production of the matter-antimatter asymmetry of the universe. The relevant mechanisms are strongly dependent on key parameters like the expansion velocity of the walls of bubbles of the new phase. In addition, the key dynamical parameters of the phase transition may generate signatures (like gravitational waves) which may become detectable in the near future. This work builds on existing hydrodynamical studies of the growth of bubbles of the broken symmetry phase and adapts them to novel scenarios, producing predictions of the wall velocity. The early universe at the time of the electroweak phase transition is modelled as a perfect relativistic fluid. A fundamental problem is to account for the interaction between the so-called cosmic 'plasma' and the bubble wall, which may slow down wall propagation and produce a steady state with finite velocity. This 'friction' is accounted for by a separate term in the hydrodynamical equations. This work adapts existing microphysical calculations of the friction to two physical models chosen because of their suitability as regards producing the baryon asymmetry of the universe: 1) An extension of the Standard Model with dimension-6 operators (for which this is the first calculation of the wall velocity ever produced) and 2) The Light Stop Scenario (LSS) of the Minimal Supersymmetric Standard Model (MSSM) (for which this is the first 2-loop calculation). The predicted values of the wall velocity are coherent and consistent with previous studies, confirming, in particular, the prediction of a low wall velocity for the LSS.

A partir de considerações sobre interações entre pares de objetos dependentes apenas de suas orientações relativas, desenvolvemos um modelo discreto para cristais líquidos biaxiais. Representamos estes sistemas por um conjunto de partículas biaxiais localizadas nos sítios de uma rede cristalina e que se orientam somente ao longo dos três eixos cartesianos. O diagrama de fases, obtido na aproximação de campo médio, apresenta uma fase nemática biaxial, duas fases nemáticas uniaxiais, além da fase isotrópica. Estas fases se encontram em um ponto multicrítico em cuja vizinhança fazemos a expansão de Landau da Energia Livre. Finalmente analisamos a adição de um campo externo favorável ao ordenamento nemático uniaxial. / From considerations about the pair interaction of objects depending only on their relative orientations, we develop a discrete model for biaxial liquid crystals. These systems are represented by a set of biaxial particles localized on the sites of a crystal lattice and oriented only along the three Cartesian axes. The phase diagram, obtained in a mean field approximation, displays a biaxial nematic phase, two uniaxial nematic phases, beside the isotropic phase. These phases meet on a multicritical point about which we make the Landau expansion of the free energy. Finally, we analyse the case where an external field is applied to favour the uniaxial nematic ordering.

Ionic liquids are organic salts with room temperature melting points. Their unique physicochemical properties make them popular choices in the fields of tribology, energy storage and production, and extractions. Previous studies show that IL’s interfacial volume, extending some nanometers from an adjacent surface, is characterized by the self-assembly of IL molecules into ordered structures. This ordering imparts unique properties which often govern the properties of ILs and affect their application in the aforementioned areas. This thesis describes research conducted to understand the behaviors and interactions of ILs at interfaces, along with investigations of bulk IL structures and transitions in the presence of water. The findings reported will help the scientific community by giving insight into the physical and chemical processes surrounding IL behavior, allowing ILs’ physicochemical properties to be more accurately tailored, via judicious synthesis, to a desired application. Major findings of this work show that the ordered interfacial region may extend up to two orders of magnitude further from the interface than previously thought. Specifically, this thesis shows several examples of reversible IL self-assembly into long-range ordered films that extend up to ~ 2 μm from a surface. This is approximately twelve times the thickness of interfacial region previously reported. Temperature controlled studies on the bulk structure of an IL at its phase transition temperatures aid in understanding the structural arrangement of molecules in the bulk fluid as a function of temperature. Spectroscopic analyses of these bulk studies and the above interfacial systems showed no similarities, indicating that the self-assembled interfacial structures are, in fact, unique. Being hygroscopic in nature, water is the most common impurity found in ILs. Water can affect IL intermolecular forces and the resulting structures in bulk fluids as well as at the interface. One of the chapter of this thesis describes these interactions, and the variably hydrated IL structures for two classes of ILs via spectroscopic and electrochemical techniques. The outcomes of this thesis will aid the community in understanding interfacial and bulk structures of ILs, as well as influences of temperature and water on these structures. The description of extended IL structures provides valuable insights into new design principles for truly task-specific ILs.

Chemical and physical interactions play important roles in surface film formation and fluid slip at the fluid-solid interface. It has been shown that the fluid molecules at this solid interface behave differently than the molecules in the bulk. To investigate fluid film formation and the fluid’s transition between bulk and interfacial regions, a dynamic wetting technique is utilized. This technique allows the formation of variable thickness fluid films. When used in conjunction with vibrational spectroscopy and ellipsometry, direct analysis of variable thicknesses films, spanning the bulk to interfacial transition, can be obtained. Film thickness are predicted using the Landau-Levich model and the Lifshitz model, and comparisons generally agree with experimental results. According to hydrodynamic no slip boundary condition, fluid molecules near a solid surface can have no velocity with respect to the solid substrate. Recent theories state more specifically that, if a fluid comes in contact with an ultra-smooth surface (< 5-7 nm RMS roughness), the no slip boundary condition might be violated. We confirmed violation of the no slip boundary condition in two specific cases for fluid layers on SAM-modified substrates. To understand how the fluid/solid properties affect this condition, an acetophenone and bare silver surface was studied. Our results show that the structure and ordering of fluid molecules within these films are highly dependent on the film’s thickness and confinement. Temperature control wetting studies also corroborate with these results showing that as a frozen film of large thickness approaches the melting point, a molecular reorganization occurs creating a crystalline structure before the film melts into an isotropic bulk structure. Structure dependence on alkyl-chain length was then investigated using a series of trialkylamine fluids. Results show significant changes in the vibrational profile as a function of film thicknesses and rotational velocity as the alkyl-chains increase in length. These are ascribed to changes in primary carbon attached to the nitrogen as a function shearing and the rigidity of the molecule. These results reveal interactions taking place at the solid-liquid interface and have impacts on a broad spectrum of industrial, commercial, and research applications including lubrication and transportation vehicles.