The exegesis accompanies a thesis, the latter being the portfolio of work consisting of two parts, each being a completed first draft of a novel written during the Masters of Creative Writing course: Part 1: ‘Sandcastles’ - a 'closed' text novel Part 2: ‘The Postmodern Rules For Family Living’ - an 'open' text novel These two works are separately bound with a thesis cover sheet and numbered. They are embargoed until 30 June 2011. The exegesis covers the writer’s motivation for writing these works, reflections on the course of development and changes in thinking that occurred during research and the act of writing. It shows the changing perspectives of the writer’s two thesis works in context and in contra-distinction to each other. It includes the writer’s academic and creative goals as they developed and the result achieved in terms of those goals. It highlights the writer’s developing interest in literary theory including suggesting an ephemeral adjunct to Reader-Response theory which is described as 'Collapse'. It shows the development of the writer’s deep interest in reality in fiction versus the lie in fiction and in the differences between writing and reading a creative work produced primarily for entertainment versus work of a literary nature, identifying some of the differences in features the writer has perceived.

The Microelectronics industry has continuously pushed the limit of critical dimensions to sub-20 nm. One of the challenges is pattern collapse, caused by unbalanced capillary forces during the final rinse and drying process. The use of surfactants offers a convenient method to reduce capillary forces but causes another deformation issue. This thesis work focuses on alternative approaches that are compatible with lithographic processes to mitigate pattern collapse. First, an e-beam lithography pattern with a series of varying line and space widths has been specifically designed in order to quantitatively study pattern collapse behavior. This pattern generates increasing stress in the pairs of resist lines as one moves across the pattern array and eventually a sufficiently small space value (critical space, S1c) is reached in each array such that the stress applied to the resist exceeds the critical stress (σc) required for pattern bending and subsequently feature deformation and collapse occurrs. The patterns we designed allow us to qualitatively and quantitatively study pattern collapse and obtain consistent, reproducible results. In the first part of the thesis work, a quick surface crosslink (called a reactive rinse) that involves the strengthening of the resist using crosslinking via carbodiimide chemistry while the resist structures are still in their wet state, has been developed and demonstrated. This technique provides efficient and significant improvement on the pattern collapse issue. In the second part of the thesis work, a triethoxysilane compound, vinyl ether silane (VE), has been successfully synthesized. It can be used to modify the silicon or silicon nitride substrates and form a covalent bond with the resist film instead of manipulating the surface energies using common HMDS. Compared to traditional Hexamethyldisilazane (HMDS) vapor primed surfaces, the implementation of the VE adhesion promoter resulted in a significant improvement in the adhesion and resistance to adhesion based pattern collapse failure in small sub-60 nm resist features. In the third part of the thesis work, the effect of drying rates and drying methods has been systematically studied. SEM analysis and critical stress results showed that fast drying appear to reduce the resist collapse. The line pair orientations in each pattern array with respect to the wafer radius reveal an apparent effect of fluid flow and centrifugal forces on collapse. Finally, a comprehensive pattern collapse model that incorporates adhesion based pattern failure and elastoplastic deformation-based failure, and dimensionally dependent resist modulus properties has been developed. This model provides such an excellent prediction of the experimental data and supports the idea that this level of combined adhesion-failure and elastoplastic-failure based pattern collapse modeling, where one explicitly considers the dimensionally dependent mechanical properties of the resist can be quantitatively predictive and useful for understanding the pattern collapse behavior of polymeric nanostructures.

This dissertation focuses on the study of inverse temperature transition processes of the poly(N-isopropylacrylamide) (PNIPAM) and the elastin-like polypeptides (ELPs). A novel temperature jump microfluidic system is introduced and this system shows the ability to measure the kinetics of the PNIPAM and the ELPs collapse without a heat transfer problem. The conformational change of the ELPs during the phase transition process is utilized as a nanoscale protein filter to modulate ligandreceptor binding events on supported lipid bilayers (SLBs). This research study is divided into three main parts. The first part is the development of the temperature jump microfluidics. The kinetics of PNIPAM collapse is used as a model system to show the capability of this new device to measure millisecond time scale phase transition processes. The effects of salts on the kinetics of PNIPAM collapse are also shown in this part. To our knowledge, this is the first study which shows the effects of salts on PNIPAM collapse kinetics. The second part of this research is the application of the novel temperature jump microfluidics. The hydrophobic collapse of ELPs composed of identical sequence but different chain length is investigated. By controlling the molecular weight of the ELPs, the thermodynamic contributions from intermolecular hydrophobic interactions, and intramolecular hydrophobic interactions could be calculated individually for this unique system. The third part is the application of the phase transition property of ELPs. The ELPs are conjugated on the surface of the SLBs as a nanoscale protein filter. The conformation of the ELPs can be modulated by ionic strength of the buffer solution or ambient temperature. The ELPs conjugated SLBs platform showed the ability to block IgG binding to biotin conjugated on the SLBs when the ELPs were in the extended coil state and open the access for protein to bind to biotin in compact globule conformation.

Thesis (Ph. D.)--University of Texas at Austin, 1999. / Vita. Includes bibliographical references (leaves 206-219). Available also in a digital version from Dissertation Abstracts.

Seismic code provisions are now adopting performance-based methodologies, where structures are designed to satisfy multiple performance objectives. Most codes rely on approximate methods to predict the desired seismic demand parameters. Most of these methods are based on simple SDOF models, and do not take into account neither MDOF nor degradation effects, which are major factors influencing structural behavior under earthquake excitations. More importantly, most of these models can not predict collapse explicitly under severe seismic loads. This research presents a newly developed model that incorporates degradation effects into seismic analysis of structures. A new energy-based approach is used to define several types of degradation effects. The research presents also an evaluation of the collapse potential of degrading SDOF and MDOF structures. Collapse under severe seismic excitations, which is typically due to the formation of structures mechanisms amplified by P-Delt a effects, was modeled in this work through the degrading hysteretic structural behavior along with P-Delta effects due to gravity loads. The model was used to conduct extensive statistical dynamic analysis of different structural systems subjected to a large set of recent earthquake records. To perform this task, finite element models of a series of generic SDOF and MDOF structures were developed. The degrading hysteretic structural behavior along with P-Delta effects due to gravity loads proved to successfully replicate explicit collapse. For each structure, collapse was investigated and inelastic displacement ratios curves were developed in case collapse doesn't occur. Furthermore, seismic fragility curves for a collapse criterion were also developed. In general, seismic fragility of a system describes the probability of the system to reach or exceed different degrees of damage. Earlier work focused on developing seismic fragility curves of systems for several values of a calibrated damage index. This research work focuses on developing seismic fragility curves for a collapse criterion, in an explicit form. The newly developed fragility curves represent a major advancement over damage index-based fragility curves in assessing the collapse potential of structures subject to severe seismic excitations. The research findings provide necessary information for the design evaluation phase of a performance-based earthquake design process.

During the last few decades Central Asia has experienced widespread changes in land cover and land use following the socio-economic and institutional transformations of the region catalyzed by the USSR collapse in 1991. The decade-long drought events and steadily increasing temperature regimes in the region came on top of these institutional transformations, affecting the long term and landscape scale vegetation responses. This research is based on the need to better understand the potential ecological and policy implications of climate variation and land use practices in the contexts of landscape-scale changes dynamics and variability patterns of land surface phenology responses in Central Asia. The land surface phenology responses - the spatio-temporal dynamics of terrestrial vegetation derived from the remotely sensed data - provide measurements linked to the timing of vegetation growth cycles (e.g., start of growing season) and total vegetation productivity over the growing season, which are used as a proxy for the assessment of effects of variations in environmental settings. Local and regional scale assessment of the before and after the USSR collapse vegetation response patterns in the natural and agricultural systems of the Central Asian drylands was conducted to characterize newly emerging links (since 1991) between coupled human and natural systems, e.g., socio-economic and policy drivers of altered land and water use and distribution patterns. Spatio-temporal patterns of bioclimatic responses were examined to determine how phenology is associated with temperature and precipitation in different land use types, including rainfed and irrigated agricultural types. Phenological models were developed to examine relationship between environmental drivers and effect of their altitudinal and latitudinal gradients on the broad-scale vegetation response patterns in non-cropland ecosystems of the desert, steppe, and mountainous regional landscapes of Central Asia.The study results demonstrated that the satellite derived measurements of temporal cycles of vegetation greenness and productivity data was a valuable bioclimatic integrator of climatic and land use variation in Central Asia. The synthesis of broad-scale phenological changes in Central Asia showed that linkages of natural and human systems vary across space and time comprising complex and tightly integrated patterns and processes that are not evident when studied separately.

Core-collapse supernovae are some of the most energetic events in the Universe, they herald the birth of neutron stars and black holes, are a major site for nucleosynthesis, influence galactic hydrodynamics, and trigger further star formation. As such, it is important to understand the mechanism of explosion. Moreover, observations imply that asymmetries are, in the least, a feature of the mechanism, and theory suggests that multi-dimensional hydrodynamics may be crucial for successful explosions. In this dissertation, we present theoretical investigations into the multi-dimensional nature of the supernova mechanism. It had been suggested that nuclear reactions might excite non-radial g-modes (the ε-mechanism) in the cores of progenitors, leading to asymmetric explosions. We calculate the eigenmodes for a large suite of progenitors including excitation by nuclear reactions and damping by neutrino and acoustic losses. Without exception, we find unstable g-modes for each progenitor. However, the timescales for growth are at least an order of magnitude longer than the time until collapse. Thus, the ε-mechanism does not provide appreciable amplification of non-radial modes before the core undergoes collapse. Regardless, neutrino-driven convection, the standing accretion shock instability, and other instabilities during the explosion provide ample asymmetry. To adequately simulate these, we have developed a new hydrodynamics code, BETHE-hydro that uses the Arbitrary Lagrangian-Eulerian (ALE) approach, includes rotational terms, solves Poisson’s equation for gravity on arbitrary grids, and conserves energy and momentum in its basic implementation. By using time dependent arbitrary grids that can adapt to the numerical challenges of the problem, this code offers unique flexibility in simulating astrophysical phenomena. Finally, we use BETHE-hydro to investigate the conditions and criteria for supernova explosions by the neutrino mechanism. We find that a critical luminosity/ mass-accretion-rate condition distinguishes non-exploding from exploding models in hydrodynamic 1D and 2D simulations. Importantly, the critical luminosity for 2D simulations is found to be ∼70% of the critical luminosity for 1D simulations. We identify the specifics ofmulti-dimensional hydrodynamic simulations that enable explosions at lower neutrino luminosities in 2D and discuss how these results might foreshadow successful explosions by eventual 3D radiation-hydrodynamic simulations.

In this study we generate the matching conditions for a spherically symmetric radiating star in the presence of shear. Two new exact solutions to the Einstein held equations are presented which model a relativistic radiating sphere. We examine the role of anisotropy in the thermal evolution of a radiating star undergoing continued dissipative gravitational collapse in the presence of shear. Our model was the first study to incorporate both shear and pressure anisotropy, and these results were published in 2006. The physical viability of a recently proposed model of a shear-free spherically symmetric star undergoing gravitational collapse without the formation of a horizon is investigated. These original results were published in 2007. The temperature profiles of both models are studied within the framework of extended irreversible thermodynamics. / Thesis (M.Sc.)-University of KwaZulu-Natal, Westville, 2008.

The exegesis accompanies a thesis, the latter being the portfolio of work consisting of two parts, each being a completed first draft of a novel written during the Masters of Creative Writing course: Part 1: ‘Sandcastles’ - a 'closed' text novel Part 2: ‘The Postmodern Rules For Family Living’ - an 'open' text novel These two works are separately bound with a thesis cover sheet and numbered. They are embargoed until 30 June 2011. The exegesis covers the writer’s motivation for writing these works, reflections on the course of development and changes in thinking that occurred during research and the act of writing. It shows the changing perspectives of the writer’s two thesis works in context and in contra-distinction to each other. It includes the writer’s academic and creative goals as they developed and the result achieved in terms of those goals. It highlights the writer’s developing interest in literary theory including suggesting an ephemeral adjunct to Reader-Response theory which is described as 'Collapse'. It shows the development of the writer’s deep interest in reality in fiction versus the lie in fiction and in the differences between writing and reading a creative work produced primarily for entertainment versus work of a literary nature, identifying some of the differences in features the writer has perceived.

The exegesis accompanies a thesis, the latter being the portfolio of work consisting of two parts, each being a completed first draft of a novel written during the Masters of Creative Writing course: Part 1: ‘Sandcastles’ - a 'closed' text novel Part 2: ‘The Postmodern Rules For Family Living’ - an 'open' text novel These two works are separately bound with a thesis cover sheet and numbered. They are embargoed until 30 June 2011. The exegesis covers the writer’s motivation for writing these works, reflections on the course of development and changes in thinking that occurred during research and the act of writing. It shows the changing perspectives of the writer’s two thesis works in context and in contra-distinction to each other. It includes the writer’s academic and creative goals as they developed and the result achieved in terms of those goals. It highlights the writer’s developing interest in literary theory including suggesting an ephemeral adjunct to Reader-Response theory which is described as 'Collapse'. It shows the development of the writer’s deep interest in reality in fiction versus the lie in fiction and in the differences between writing and reading a creative work produced primarily for entertainment versus work of a literary nature, identifying some of the differences in features the writer has perceived.