Neste trabalho, foi estudado o desempenho de um sistema constituído de torres de resfriamento e a sua integração em uma planta industrial de hidrogenação de butadieno. Caracterizou-se o desempenho das torres de resfriamento com base em um modelo fenomenológico, cujos parâmetros foram obtidos a partir da medição de variáveis operacionais reais. O processo de hidrogenação foi configurado em um simulador de processos, sendo o caso base estabelecido nas condições de projeto. Elaborou-se um módulo específico referente às torres de resfriamento, que foi integrado ao processo configurado no simulador. Em seguida, analisaram-se as interações das condições operacionais da torre de resfriamento no desempenho do processo industrial. / In the present work, the performance of a system composed of a cooling tower integrated in butadiene hydrogenation plant was studied. An experimental investigation was made to characterize the cooling towers based on a phenomenological model and in real process conditions. The hydrogenation process was configured on a process simulator and design specifications were considered as base case. A cooling tower module was developed and integrated to the process simulator. The interaction of the cooling tower system and the plant operation was investigated.

Orientadores: Roger Josef Zemp, Flavio Vasconcelos da Silva / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Quimica / Made available in DSpace on 2018-08-14T20:37:56Z (GMT). No. of bitstreams: 1 Waki_Renata_M.pdf: 3835384 bytes, checksum: c0857e96e600a266ca359e3df135543d (MD5) Previous issue date: 2009 / Resumo: Esta dissertação descreve a montagem de um sistema de resfriamento deságua e as avaliações nele realizadas visando sua utilização para o ensino de sistemas de processos para alunos de graduação. O ensino de sistemas de processos restringe-se, normalmente, à modelagem e simulação computacional, sendo poucas as vezes que o aluno tem um contato com o processo real. Buscando contribuir para uma melhorar aprendizagem nesta área e aplicar conceitos teóricos na prática, estruturou-se o referido sistema. Este sistema foi construído em escala de planta-piloto e é formado pelos subsistemas trocador de calor e torre de resfriamento. Para medição das variáveis de processo, foi feita uma instrumentação industrial padrão nos subsistemas com sensores de temperatura, umidade, vazão e pressão diferencial. Estes instrumentos foram conectados a um módulo de aquisição e registro de variáveis (datalogger) que possui comunicação serial RS485 com protocolo MODBUS. O uso deste aparelho possibilita o envio dos parâmetros do processo a terminais de computadores para acompanhamento on-line ou para armazenamento e posteriores análises. Para melhor visualização do processo, foram feitas telas supervisórias utilizando-se para isso o software Indusoft Web Studio v6.1. Por fim, foram realizados testes no subsistema torre de resfriamento para verificação de seu funcionamento e correção dos erros encontrados. Neste projeto, foi desenvolvida também uma equação empírica para o cálculo direto da temperatura de bulbo úmido do ar, facilitando, assim, sua determinação principalmente quando se deseja fazer um monitoramento contínuo desta. / Abstract: This work describes proposal for complementing Process Systems Engineering (PSE) undergraduate learning. Traditional teaching of PSE is normally restricted to modeling and computer simulations, with very little contact with actual processes. We felt that applying theoretical concepts to practical problems would be very welcome by the students and improve their understanding of PSE. For this purpose we designed and built an experimental setup consisting of a process system (a heat exchanger) and a utility system (a cooling tower). A set of industrial-standard instrumentation was used for measuring process variables: flow, temperature, humidity and pressure drop sensors. All instruments are connected to an industrial data-logging device. The measured process parameters are sent from the datalogger to a computer using the MODBUS/RS485 standard, and displayed to the user as process flowsheets. The flowsheets and additional screens were developed using the industrial-standard supervisory control and data acquisition system InduSoft Web Studio v6.1. Data can be continuously monitored or stored in files for further off-line processing. Some tests were made on the cooling tower system to verify its behaviour and correct the problems found. In this work, it was also developed an empirical equation through which it is possible to calculate the air wet bulb temperature in a direct way. This is specially interesting in its continuous monitoring in a process. / Mestrado / Sistemas de Processos Quimicos e Informatica / Mestre em Engenharia Química

O segmento industrial é um grande usuário de água e, na maior parte das situações, está localizado junto a aglomerações urbanas, caracterizando situação de dificuldade na obtenção deste recurso para as suas operações. As fontes de água estão cada vez mais saturadas e os processos de tratamento mais sofisticados. O objetivo deste estudo foi avaliar a viabilidade técnico-econômica da implantação do tratamento eletromagnético para água de resfriamento em indústrias químicas, substituindo ou complementando o tratamento químico convencional. O texto descreve inicialmente os fundamentos do tratamento de água baseado na aplicação de campo eletromagnético e, em seguida, os efeitos do uso dessa tecnologia sobre custos anuais de resfriamento em um caso típico da indústria química. Neste estudo foi dada ênfase ao efeito sobre os custos anuais da menor adição de produtos químicos, redução na vazão de purga e de reposição de água, além da redução na frequência de limpeza dos equipamentos e redução da carga poluente nos efluentes líquidos. O estudo foi aplicado a uma torre de resfriamento industrial, para a qual foi elaborado um modelo matemático considerando as taxas de consumo e especificações de água de resfriamento, além de parâmetros do processo de tratamento de água convencional e eletromagnético. São apresentados resultados de um estudo de sensibilidade para diferentes cenários, em que são identificados os fatores com maior efeito sobre os custos. Além disso, na aplicação ao sistema proposto, são estimadas condições ótimas de operação, considerando os ciclos de concentração para os quais pode haver maior redução de custos. Utilizando-se o tratamento eletromagnético para a água de resfriamento, há uma economia significativa, pois o número de paradas para a manutenção dos equipamentos pode ser reduzido. Dessa forma, o produto final do trabalho constitui-se em uma estrutura de cálculo voltada à estimação de custo do tratamento físico de água de resfriamento, o qual pode ser aplicado a diferentes cenários e condições de operação industrial. / The industrial sector is a major water user and in most situations is located next to urban areas, in a situation of increasing difficulty in collecting and treating water resources for its operations. The water sources are becoming more saturated and thus demanding more sophisticated treatment processes. The aim of this study was to evaluate the technical and economic feasibility of the implementation of electromagnetic treatment of cooling water in chemical industries, thus replacing or complementing the conventional chemical treatment. The text initially describes the principles of the physical process for water treatment based on the application of an electromagnetic field, and then focuses on the effects of the use of this technology on the annual costs of cooling in a typical case of the chemical industry. The study is focused on the effects of the electromagnetic treatment on the annual cost of cooling in view of the reduced consumption of chemicals, as well as reduction in purge flow and water replacement, reduced frequency of equipment cleaning, and reduction of pollution load caused by wastewater. The study results were applied to an industrial cooling tower for which a mathematical model was developed by considering consumption rates and cooling water specifications, as well as parameters of the electromagnetic and conventional water treatment processes. A sensitivity study was carried out for different scenarios, in which the most important factors affecting the annual cost are identified, and optimal process conditions are estimated for maximum concentration cycles. The study shows that the use of electromagnetic treatment for cooling water results in significant savings due to the reduced number of maintenance periods. The final product of this study is a calculation structure for cost estimation related to the physical treatment of cooling water, which can be applied to different scenarios and industrial operation conditions.

This thesis deals with the problems of wounding of low potential transferred from steam turbine condenser. First, in the theoretical part variations of steam condenser design are described. Then there is a description of variations of cooling cycles and possibilities of their operation range. In second part of the thesis there are two common cooler options chosen. Those are wet cooling tower with natural draft and dry chiller with forced draft. Two types of cooling liquid are chosen to be used for dry cooling. These are water and the other one is 50 % mixture of water and propylene glycol. Based on the calculation results of both cooling cycle variations appropriate pumps are chosen, fan for forced convection respectively. Parts of the thesis are also projection drawings for both calculated variations.

The aim of diploma thesis is a processing of climate data and design of chiller. Chiller is proposed to two options: air-cooled chiller and chiller with open cooling tower.

M.Tech. (Department of Chemical Engineering, Faculty of Engineering and Technology), Vaal University of Technology / Corrosion responses of some carbon steels, stainless steel and copper alloys in the presence of a culture of bacteria (referred to as SRB-Sulphate-reducing bacteria) found in industrial heat exchangers, was studied to recommend best alloys under this service condition, with techno-economic consideration. Water from cooling towers in three plants in a petrochemical processing complex were analysed for SRB presence. Two of the water samples showed positive indication of SRB presence. The mixed cultures obtained from plant one were grown in prepared media and incubated at 35 °C for 18 days. Potentiodynamic polarisation studies in anaerobic conditions were done on the selected alloys in aqueous media with and without the grown SRB. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) were then used to study the corrosion morphology and corrosion products formation. The voltamograms show higher icorr for alloys under the SRB compared to the control media, indicating the SRB indeed increased the corrosion rates. The surface analysis showed pitting on steel alloy ASTM A106-B. Localised attack to the grain boundaries on a selective area, was seen on ASTM A516-70 dislodging the grains, and intergranular corrosion was seen throughout the exposed area of ASTM A179. Copper alloys showed pitting on ASTM B111 grade C71500 (70-30), and denickelification on ASTM B111 grade C70600 (90-10), and is a good alternative material for use apart from carbon steel alloys, recording a low corrosion rate of 0.05 mm/year. The EDS analysis supported the findings showing higher weight percent of iron and sulphur on surface of the alloys after exposure to the SRB media. This implies that the presence of the sulphur ion indeed increased the corrosion rate. ASTM A516-70 carbon steel was chosen as a suitable alternative material to the stainless steel in this environment. The Tafel plot recorded a corrosion rate of 1.08 mm/year for ASTM A516-70 when exposed to SRB media.

Zur Kühlung von Prozessströmen kommen aufgrund hoher Leistungsdichten häufig Verdunstungskühltürme zum Einsatz. Um die Übertragungsfläche für Wärme und Stoff zu vergrößern, werden in diesen Kühltürmen Struktureinbauten integriert. Die Weiterentwicklung von Kühlturmeinbauten und die Untersuchung der den Kühlprozess beeinflussenden Faktoren erfolgt empirisch, was eine Vielzahl von Versuchen notwendig macht. Eine numerische Simulation des Kühlprozesses kann diese Messungen unterstützen und so helfen eine Vielzahl an Versuchen einzusparen. Des Weiteren können bei versuchsbegleitender Simulation mit einem geeigneten Modell weitere Untersuchungen durchgeführt und Erkenntnisse gewonnen werden, die bei Messungen am Versuchskühlturm verborgen bleiben. In dieser Arbeit werden zwei Ansätze der numerischen Simulation eines Verdunstungskühlturms betrachtet. Es werden eine CFD-Simulation und ein vereinfachtes Modellkonzept hinsichtlich der Anwendbarkeit auf diese Problemstellung untersucht. Schwerpunkt der vorliegenden Arbeit ist die methodische Entwicklung eines solchen vereinfachten mathematischen Modells. Dieses beruht auf der physikalisch deterministischen Beschreibung der im Kühlturm ablaufenden Prozesse der Wärme- und Stoffübertragung unter Berücksichtigung des Stoffverhaltens. Aufgrund der Nichtlinearität des Stoffverhaltens und der erforderlichen Inkrementierung des Berechnungsgebiets ist ein methodisches Vorgehen erforderlich, um die Erstellung der Modellgleichungen und deren Lösung überhaupt realisieren zu können. Hierfür wird auf allgemeine Methoden der gleichungsorientierten Simulation technischer Systeme zurückgegriffen. Das entwickelte Modellkonzept wird für die Modellierung und Simulation eines Versuchskühlturms angewandt. Mit den so ermittelten Messdaten wird das Modell kalibriert und validiert. Es zeigt sich, dass mit dem erstellten Modell quantitativ und qualitativ valide Ergebnisse erzielt werden können. / Due to the high power density, the cooling of process streams is often done bei evaporative cooling towers. To enlarge the exchange area for the heat and mass transfer, these cooling towers contain integrated structural fills. The future development of cooling tower fills and the research regarding the cooling process and its influencing parameters will be carried out empirically, resulting in a large number of required experiments. A numeric simulation of the cooling process can support theses measurements and reduce the vast number of needed experiments. Furthermore, with the use of test-related simulations and adapted models, it will be possible to gain knowledge and do research in areas which are omitted during regular measurements on cooling towers. In this study it is looked to two different approaches of numeric simulation of a evaporative cooling tower. There will be an examination of a CFD-Simulation and a simplified model concept regarding their respective applicability for this problem. This work is focussed on the systematic developement of such simplified mathematical models, based on the physical deterministic description of the occurring processes of heat and mass transfer in cooling towers considering the stock behaviour. Due to the non-linearity of the stock behaviour and the required incrementation of the calculation area, a systematic approach is needed to model equations and their respective solutions. For this purpose it is necessary to access general techniques of equation-based simulations of technological systems. The developed model concept will be applied for the modelation and simulation of an experimental cooling tower. The model will be calibrated and validated with data from this experimental tower. It shows, that the results from this model are qualitatively and quantitatevily valid.

In the process industries, cooling capacity is an important enabler for the facility to manufacture on specification product. The cooling water network is an important part of the over-all cooling system of the facility. In this research a cooling water circuit consisting of 3 cooling towers in parallel, 2 cooling water pumps in parallel, and 11 heat exchangers in parallel, is modelled. The model developed is based on first principles and captures the dynamic, non-linear, interactive nature of the plant. The modelled plant is further complicated by continuous, as well as discrete process variables, giving the model a hybrid nature. Energy consumption is included in the model as it is a very important parameter for plant operation. The model is fitted to real industry data by using a particle swarm optimisation approach. The model is suitable to be used for optimisation and control purposes. Cooling water networks are often not instrumented and actuated, nor controlled or optimised. Significant process benefits can be achieved by better process end-user temperature control, and direct monetary benefits can be obtained from electric power minimisation. A Hybrid Non-Linear Model Predictive Control strategy is developed for these control objectives, and simulated on the developed first principles dynamic model. Continuous and hybrid control cases are developed, and tested on process scenarios that reflect conditions seen in a real plant. Various alternative techniques are evaluated in order to solve the Hybrid Non-Linear Control problem. Gradient descent with momentum is chosen and configured to be used to solve the continuous control problem. For the discrete control problem a graph traversal algorithm is developed and joined to the continuous control algorithm to form a Hybrid Non-Linear Model Predictive controller. The potential monetary benefits that can be obtained by the plant owner through implementing the designed control strategy, are estimated. A powerful computation platform is designed for the plant model and controller simulations. / Thesis (PhD)--University of Pretoria, 2019. / Electrical, Electronic and Computer Engineering / PhD / Unrestricted

There was solved reinforced concrete cooling tower in the diploma thesis. This is a rotationally symmetrical construction. The cooling tower is concrete shell on columns. The cooling tower was solved using the finite element method, computer program Midas FEA. The work includes: calculation using the program Midas FEA, comparison of load between eurocode and foreign literature, the design of shell and columns, drawings form

M.Tech. (Department of Chemical Engineering, Faculty of Engineering and Technology), Vaal University of Technology. / In the present study, the removal of Ca2+ and Mg2+ from cooling tower water using Amberlite IR120 and Amberjet 1200 was studied by the application of one factor at a time method (OFAT) and response surface modelling (RSM). The effect of operational parameters such as contact time (min), pH, dosage (mL), concentration (mg/L) and temperature (K) were investigated using central composite design. The regeneration of the Amberlite IR120 and Amberjet were also studied. The purpose of the study was to apply OFAT and RSM to investigate and optimize the ion exchange operating parameters. Furthermore, the second-order empirical model that was developed, using the analysis of variance (ANOVA), presented a sufficient correlation to the ion exchange experimental data. The optimal ion exchange operating conditions for Amberlite IR120 and Amberjet 1200 were found to be: contact time was 120 min, dosage of 150mL, initial pH level of 2, concentration of 400mg/L and temperature of 343K. Regeneration of Amberlite IR120 and Amberjet 1200 using 0.5 M NaCl stripping solution initially showed an increase in % Ca2+ and Mg2+ removal, then a decrease in subsequent cycles. The correlation coefficients (R2) of Langmuir, Freudlich and Tempkin isotherms were found to range from 0.92 to 1 and this suggest that experimental data best described the models. However correlation coefficients (R2) for Dubinin–Radushkevich (D-R) model were found to range between 0.5 to 0.8 and this means that experimental data does not fit the model. Thermodynamic functions such as entropy (Δ𝑆𝑜), enthalpy (Δ𝐻𝑜) and change of free energy (Δ𝐺𝑜) were obtained from the gradient and intercepts of straight line graphs. The positive values of ΔG° were found meaning that the adsorption is not spontaneous and positive values of ΔH° were found meaning the endothermic type of adsorption which indicate the chances of physical adsorption.The correlation coefficient (R2) values of pseudo-first-order, pseudo-second-order and intraparticle models were found to range from 0.89 to 1 on both metals as shown in table 4.4. This observation clearly indicates that pseudo-first-order, pseudo-second-order and intraparticle diffusion models best describe the experimental data in the removal Ca2+ and Mg2+ from cooling tower water.