The past decade has witnessed dramatic changes in the oil and gas industry with the drilling and production extending into progressively deeper waters and higher operating pressures, therefore making it essential to gain a better understanding of the behaviour of gas hydrate at high pressure conditions. New experimental 3-phase H−LW−V (Hydrate−Liquid Water−Vapour) equilibrium data for nitrogen and H−LW−V (Hydrate−Liquid Water−Vapour) and H−LW−LHC (Hydrate−Liquid Water−Liquid Hydrocarbon) data for ethane and propane simple clathrate hydrates were generated by a reliable fixed-volume, isochoric, step-heating technique. The accuracy and reliability of the experimental measurements are demonstrated by comparing measurements with reliable literature data from different researchers. Additional experimental data up to high pressure (200 MPa when available) for CH4, C2H6, C3H8, i-C4H10, N2, Ar, Kr, Xe, H2S, O2, CO and CO2 clathrates have been gathered from literature. The Valderrama modification of the Patel-Teja (VPT) equation of state combined with non-density-dependent (NDD) mixing rules is used to model the fluid phases with previously reported binary interaction parameters. The hydrate-forming conditions are modelled by the solid solution theory of van der Waals and Platteeuw. Langmuir constants have been calculated by both Kihara potential as well as direct techniques. Model predictions are validated against independent experimental data and a good agreement between predictions and experimental data is observed, supporting the reliability of the developed model.

In applied research, a lack of understanding of corner stall, i.e. the three-dimensional (3D) separation in the juncture of the endwall and blade corner region, which has limited the efficiency and the stability of compressors. Both Reynolds-averaged Navier-Stokes (RANS) and large eddy simulation (LES) still need to be calibrated for turbomachinery applications. In the fundamental research of the turbulent boundary layer (TBL), there are a lot of findings of the effects of curvature and pressure gradients, which also play an important role in physics of corner stall. The purpose of this thesis is (i) to carry out an experiment in a cascade, (ii) to gain a database that could be used to calibrate both RANS and LES, and (iii) to give some basic explanations of corner stall through investigating the TBL on the suction side at the mid-span which is more complex than those in the basic investigations but simpler than those in a real engine. A detailed and accurate experiment of 3D flow field through a linear compressor cascade has been set up. Experimental data were acquired for a Reynolds number of 3.82×10 ^5 based on blade chord and inlet flow conditions. Measurements have been achieved by hot-wire anemometry, pressure taps on blade and endwall, five-hole pressure probe, oil visualization, 2D particle image velocimetry (PIV),and two-component laser Doppler anemometry (LDA). An original and complete database was thus obtained. The TBL on the suction side at mid-span was investigated. The wall-normal negative pressure gradient restrains the separation, on the contrary to its influence in the corner stall. The streamwise adverse pressure gradient can be responsible for the development of Reynolds stresses. The remarkable phenomenon at measurement stations near the trailing edge of blade is that an inflection point occurs in each profile of the mean streamwise velocity. At this inflection point, the magnitudes of the Reynolds stresses reach their maximum values, and the direction of energy diffusion also changes. The velocity field in the corner stall was presented. Bimodal histograms of velocity exist in the experiment. The bimodal points mainly appear in the region around the mean interface of separated flow and non-separated flow. At a bimodal point the local two velocity components are non-independent from each other, due to the aperiodic interplay of two basic modes in the flow field. Two modes were proposed to interpret the physics of bimodal behaviour.

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Made available in DSpace on 2014-10-09T12:51:59Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T13:57:00Z (GMT). No. of bitstreams: 0 / Dissertação (Mestrado) / IPEN/D / Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP

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Vegetation is commonly modelled as emergent arrays of rigid, circular cylinders. However, the drag coefficient (CD) of real stems or trunks is closer to that of cylinders with a square cross-section. In this thesis, vegetation has been idealised as square cylinders in laboratory experiments with a turbulence intensity of the order of 10% which is similar to that of typical river flows. These cylinders may also represent other obstacles such as architectural structures. This research has determined CD of an isolated cylinder and cylinder pairs as a function of position as well as the average drag coefficient (CDv) of larger arrays. A strain gauge was used to measure CD whilst CDv was computed with a momentum balance which was validated by strain gauge measurements for a regularly spaced array. The velocity and turbulence intensity surrounding a pair of cylinders arranged one behind the other with respect to mean flow (in tandem) were also measured with an Acoustic Doppler Velocimeter. The isolated cylinder CD was found to be 2.11 in close agreement with other researchers. Under fixed flow conditions CD for a cylinder in a pair was found to be as low as -0.40 and as high as 3.46 depending on their relative positioning. For arrays, CDv was influenced more by the distribution of cylinders than the flow conditions over the range of conditions tested. Mean values of CDv for each array were found to be between 1.52 and 3.06. This new insight therefore suggests that CDv for vegetation in bulk may actually be much higher than the typical value of 1 which is often assumed to apply in practice. If little other information is available, a crude estimate of CDv = 2 would be reasonable for many practical applications. The validity of a 2D realizable k-epsilon turbulence model for predicting the flow around square cylinders was evaluated. The model was successful in predicting CD for an isolated cylinder. In this regard the model performed as well as Large Eddy Simulations by other authors with a significant increase in computational efficiency. However, the numerical model underestimates CD of downstream cylinders in tandem pairs and overestimates velocities in their wake. This suggests it may be necessary to expand the model to three-dimensions when attempting to simulate the flow around two or more bluff obstacles with sharp edges.

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Made available in DSpace on 2014-10-09T12:52:18Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T14:00:31Z (GMT). No. of bitstreams: 0 / Tese (Doutoramento) / IPEN/T / Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP