Spelling suggestions: "subject:"[een] MASS TRANSFER"" "subject:"[enn] MASS TRANSFER""
481 |
ON HEAT TRANSFER MECHANISMS IN SECONDARY COOLING OF CONTINUOUS CASTING OF STEEL SLABHaibo Ma (11173431) 23 July 2021 (has links)
<p>Secondary cooling during continuous casting is a delicate
process because the cooling rate of water spray directly affects the slab
surface and internal quality. Undercooling may lead to slab surface bulging or
even breakout, whereas overcooling can cause deformation and crack of slabs due
to excessive thermal residual stresses and strains. Any slab which does not
meet the required quality will be downgraded or scrapped and remelted. In order to remain competitive and continuously
produce high-quality and high-strength steel at the maximum production rate,
the secondary cooling process must be carefully designed and controlled. Efficient
and uniform heat removal without deforming or crack the slab is a significant
challenge during secondary cooling. In the meantime, the on-site thermal
measurement techniques are limited due to the harsh environment. In contrast, experimental measurements
are only valid for the tested conditions, and the measurement process is not
only labor-intensive, but the result might be inapplicable when changes in the
process occur. On the other hand, the high-performance computing (HPC)-powered
computational fluid dynamics (CFD) approach has become a powerful tool to gain
insights into complex fluid flow and heat transfer problems. Yet, few
successful numerical models for heat transfer phenomena during secondary
cooling have been reported, primarily due to complex phenomena. </p>
<p> </p>
<p>Therefore, the current study has proposed two
three-dimensional continuum numerical models and a three-step coupling
procedure for the transport of mass, momentum, and energy during the secondary
cooling process. The first numerical model features the simulation of water
spray impingement heat and mass transfer on the surface of a moving slab considering
atomization, droplet dispersion, droplet-air interaction, droplet-droplet
interaction, droplet-wall impingement, the effect of vapor film, and droplet
boiling. The model has been validated against five benchmark experiments in
terms of droplet size prior to impingement, droplet impingement pressure, and
heat transfer coefficient (HTC) on the slab surface. The validated model has
been applied to a series of numerical simulations to investigate the effects of
spray nozzle type, spray flow rate, standoff distance, spray direction, casting
speed, nozzle-to-nozzle distance, row-to-row distance, arrangement of nozzles,
roll and roll pitch, spray angle, spray water temperature, slab surface
temperature, and spray cooling on the narrow face. Furthermore, the simulation
results have been used to generate a mathematically simple HTC correlation,
expressed as a function of nine essential operating parameters. A graphic user
interface (GUI) has been developed to facilitate the application of
correlations. The calculated two-dimensional HTC distribution is stored in the universal
comma-separated values (csv) format, and it can be directly applied as a boundary
condition to on-site off-line/on-line solidification calculation at steel mills.
The proposed numerical model and the generic methodology for HTC correlations should
benefit the steel industry by expediting the development process of HTC
correlations, achieving real-time dynamic spray cooling control, supporting
nozzle selection, troubleshooting malfunctioning nozzles, and can further
improve the accuracy of the existing casting control systems.</p>
<p> </p>
<p>In the second numerical model, the volume-averaged
Enthalpy-Porosity method has been extended to include the slurry effect at low
solid fractions through a switching function. With the HTC distribution on the
slab surface as the thermal boundary condition, the model has been used to
investigate the fluid flow, heat transfer, and solidification inside a slab
during the secondary cooling process. The model has been validated against the
analytical solution for a stationary thin solidifying body and the simulation
for a moving thin solidifying body. The effects of secondary dendrite arm
spacing, critical solid fraction, crystal constant, switching function
constant, cooling rate, rolls, nozzle-to-nozzle distance, and arrangement of
nozzles have been evaluated using the validated model. In addition, <a>the solidification model has been coupled with the
predictions from the HTC correlations, and the results have demonstrated the availability
of the correlations other than on-site continuous casting control. </a>Moreover,
the model, along with
the three-step coupling procedure, has been applied to simulate the initial
solidification process in continuous casting, where a sufficient cooling rate
is required to maintain a proper solidification rate. Otherwise, bulging or
breakout might occur. The prediction is in good agreement with the
measured shell thickness, which was obtained from a breakout incident. With the help of
HPC, such comprehensive simulations will continue to serve as a powerful tool
for troubleshooting and optimization.</p>
|
482 |
EXPERIMENTAL AND NUMERICAL ANALYSIS OF ENVIRONMENTAL CONTROL SYSTEMS FOR RESILIENT EXTRA-TERRESTRIAL HABITATSHunter Anthony Sakiewicz (15339325) 22 April 2023 (has links)
<p> As space exploration continues to advance, so does the drive to inhabit celestial bodies. In<br>
order to expand our civilization to the Moon or even other planets requires an enormous amount of research and development. The Resilient Extra-Terrestrial Habitat Institute is a NASA funded project that aims to develop the technology needed to establish deep-space habitats. Deep-space inhabitation poses many challenges that are not present here on earth. The Moon, for example, has temperatures that range from -233−123°C. Aside from the extreme temperatures, a variety of thermal loads will need to be handled by the Environmental Control and Life Support System (ECLSS). Aside from the research and architecture of the International Space Station’s ECLSS, very little information is known about disturbances related to the thermal management of extra- terrestrial habitats.<br>
</p>
<p>RETHi is developing a Cyber-Physical Testbed (CPT) that represents a one-fifth scale<br>
prototype of a deep space habitat. In order to answer difficult research questions regarding ECLSS and thermal management of a deep-space habitat, a heat pump was modeled and validated with the physical part of the CPT. Once validated, the heat pump model is able to accurately predict the steady state behavior given the indoor and outdoor conditions of the testbed. When coupled with the interior environment (IE) model, it gives insight into the system’s requirements and response. Experimental testing was conducted with the heat pump in order to validate the model. After the model was validated, a series of parametric studies were conducted in order to investigate the effects of varying thermal loads and dehumidification. Since the groundwork was laid through model development and experimentation, future work consists of designing a more versatile heat pump to test a variety of disturbance scenarios. Although the heat pump model is specifically designed for the CPT, it proves to be versatile for other closed and pressurized environments such as aircraft and clean rooms according to the analysis of dehumidification and dependence on pressure. </p>
|
483 |
The Effect of Turbulent Flow on Corrosion of Mild Steel in High Partial CO<sub>2</sub> EnvironmentsMohammed Nor, Azmi 10 June 2013 (has links)
No description available.
|
484 |
3D PRINTING SUPPRESSORFOR SMALL ARMSUSING FUSEDDEPOSITIONMODELINGRichard Collin Sinclair (15349201) 29 April 2023 (has links)
<p> </p>
<p>Metal 3D printing is the industry standard for manufacturing experimental suppressors due to the limitations of conventional, subtractive machining methods. Long print times, difficulty sintering, and cleaning of metal 3D printed suppressor components limit the development time. Plastic printed components are able to be produced quicker, safer, and at a lower cost than their metal 3D printed counterparts. Reducing the time and cost of manufacturing will allow for an increased pace of innovations in suppressor design.</p>
<p><br></p>
<p>Utilizing Finite Element Analysis (FEA) in combination with Computational Fluid Dynamics (CFD) will expedite the process of designing 3D printed plastic suppressors. Solidworks FEA determined the maximum stress applied to the blast chamber of the plastic suppressor. ANSYS Fluent CFD simulations were used to qualitatively compare the sound pressure levels of an unsuppressed and suppressed 22LR pistol. Comparing the results of the CFD simulations gave insight into the effectiveness of the selected baffle structure.</p>
<p><br></p>
<p>A prototype 3D printed suppressor was optimized for strength according to manufacturing practices for printed plastic small arms. Testing occurred at an indoor range where peak impulse noise was measured for an unsuppressed 22LR pistol and a plastic printed suppressor. The printed suppressor reduced the small arms impulse noise from 150.5 dB(spl) to 132.4 dB(spl). Impulse noises below the pain threshold of 140 dB(spl) do not require hearing protection for operation. Utilizing FEA, CFD, and FDM prototyping methods in this work has laid the foundation for future works in the rapid prototyping and optimizations of suppressors for small arms.</p>
|
485 |
Characterization of Cathodic and Anodic Processes Associated with Crevice Corrosion under Thin Electrolyte FilmsAgarwal, Arun Sureshchandra 03 August 2009 (has links)
No description available.
|
486 |
The Dissolution of Iron from Automotive Steel Sheets in a Molten Zinc Bath and the Kinetics of the Nucleation and Growth of Dross ParticlesLin, Kang-Yi 19 September 2011 (has links)
No description available.
|
487 |
Vaibhav_Rajora_Thesis_2024_Corrections_V3.pdfVaibhav Rajora (20371659) 03 December 2024 (has links)
<p dir="ltr">An adaptive mesh refinement strategy for shock dominated flows encompassing multiple types of fluids and fluid features. </p>
|
488 |
Investigating the effect of coarse particle addition on the measured rheological parameters of fine clay slurriesPaulsen, Eric 12 1900 (has links)
Thesis (MScIng)--University of Stellenbosch, 2007. / ENGLISH ABSTRACT: Due to economic and environmental constraints mining operations are placed under
increasing pressure to effectively manage and operate tailings disposal operations.
Restrictions imposed on water usage and tailings operations footprint have led to
higher density and wider particle size distribution slurries conveyed to tailings areas.
One means of efficiently disposing the tailings is co-disposal. In this method a
concentrated fine vehicle slurry is used to convey a coarser fraction. This produces a
higher density of tailings, with a number of advantages both upstream and downstream
of the tailings process. Limited research has been conducted on the effect of coarse
particles on the non-Newtonian rheological properties of these slurries. This lack of
information complicates the design and reliable operation of these systems.
This project aims at gaining a clearer understanding as to the mechanisms involved in
the addition of coarse particles to a fine clay slurry vehicle; and to provide a means of
estimating the measured slurry rheological properties. A number of experiments were
designed to test the slurry (both Kaolin only, and Kaolin-coarse particle mixtures)
rheological properties using a Couette viscometer (for the dynamic flow properties of
yield stress and plastic viscosity) and a vane instrument (for the static yield stress
measurements).
The slurries were prepared in varying Kaolin clay solids concentrations with reverse
osmosis water. Glass beads and two types of industrial sand were used as the coarse
fractions. All of the coarse particles had a similar size but varied significantly in shape.
Slurry pH and temperature readings were monitored throughout the tests.
Tests were done initially on clay only slurries. The rheological properties of these
slurries were repeatable, and no noticeable variations of properties with time were
observed. The yield stress (both static and dynamic) and plastic viscosity data were
well correlated with established relationships.
Coarse particles were added to the clay only slurries, and then removed. The
remaining clay only slurry exhibited the same rheological properties as the initial clay only slurry. The presence of coarse particles increased all the measured rheological
properties (i.e. dynamic yield stress, Bingham viscosity, and static vane yield stress) in
a fashion resembling the effect of adding clay to a clay only slurry. In addition, the
change in measured rheological property by addition of coarse particle was
independent of the clay fraction in the clay slurry. Furthermore, with both the clay only
slurries and clay and coarse sand slurries, a constant linear relationship existed
between the static and dynamic yield stress.
Several correlations from the literature were found to provide reasonable prediction of
the rheological property variations observed. These empirical and semi-empirical
models however did little to explain the mechanisms involved in coarse particle
addition. A new correlation has been proposed, Residual Clay Concentration, which
predicts the change in rheological property based on an additional clay concentration,
which in turn is a linear function of the coarse particle concentration. The accuracy of
this model further strengthens the belief that the coarse particle acts in a similar
fashion to a floc.
By means of a case study example the importance of selecting an appropriate model
for design was illustrated. The Residual Clay Concentration method provided the most
conservative results. This combined with its theoretical basis strengthens the models
recommendation for use in design. / AFRIKAANSE OPSOMMING: As gevolg van ekonomiese en omgewings beperkinge word mynwese nywerhede
onder toenemende druk geplaas om doeltreffende afvalstroom bestuur en operasie toe
te pas. Beperkinge geplaas op water gebruik en afvalstroom area-groote ly tot hoër
digthede en wyer partikel-grooteverspreidings van flodders vervoer na afval areas.
Een manier om van die afval doeltreffend ontslae te raak en te berg is deur medeberging.
In die metode word ‘n gekonsentreerde fyn flodder gebruik as draer van ‘n
growwer partikel-fraksie. Dit ly tot ‘n hoër digtheid flodder, met verskeie voordele in
beide die op – en afstroom prosesse. Beperkte navorsing is gedoen op die effek van
growwe partikels op die nie-Newoniese rheolgiese eienskappe van hierdie flodders.
Hierdie tekort aan informasie maak die effektiewe, betroubare bedryf en operasie van
die sisteme meer ingewikkeld.
Hierdie projek is daarheen gemik om ‘n beter begrip te ontwikkel met betrekking tot
die meganismes betrokke in die byvoeging van growwe partikels aan ‘n fyn klei-agtige
flodder draer; en om ‘n manier te voorsien wat die rheologiese eienskappe kan beraam.
Verskeie eksperimente was ontwerp om die flodders (beide slegs Kaolien, en Kaoliengrowwe
partikel mengsels) se rheologiese eienskappe te toets deur die gebruik van ‘n
Couette-viskometer. Die Couette viskometer was gebruik om die dinamiese
eienskappe (van grens-spanning, en plastiese viskositet) te meet. ‘n Vaan apparaat is
gebruik om die eienskap van statiese grens-spanning te meet.
Die flodders was voorberei in verskeie Kaolien konsentrasies met tru-osmosis water.
Glas krale en twee tipes industriële sand is gebruik as die growwe fraksies. Al die
growwe partikels het soortgelyke groottes gehad, maar het grootliks verskil in vorm.
Die flodder pH en temperatuur lesings is deurentyd nagegaan.
Toetse was aanvanklik gedoen op die klei-alleenlike flodders. Die gemete reologiese
eienskappe van die flodders was herhaalbaar, en geen opmerkbare veranderinge van
die eienskappe met betrekking tot tyd is gemeet nie. Die grens-spanning (beide statiese
en dinamiese) en plastiese viskositeit is goed gekorrelleer met gevestigde verhoudinge. Growwe partikels is aan die klei-alleenlike flodders bygevoeg, en daarnae verwyder.
Die oorblywende klei-alleenlike flodder het dieselfde gemete rheologiese eienskappe
getoon as die oorspronklike klei-allenlike flodder. Die teenwoordigheid van growwe
partikels het na ‘n toename van al die gamete rheologiese eienskappe gelei wat fisies
baie soortgelyk is aan die byvoeging van klei tot ‘n klei-alleenlike flodder. Verder, met
beide die klei-alleenlike en klei-growwe partikel flodders het ‘n konstante liniëre
funksie tussen die statiese en dinamiese grens-spannings bestaan.
Verskeie verhoudings uit die literatuur het goeie korrelasie bewerkstellig met die
waargenome rheologie veranderinge. Hierdie empiriese en semi-empiriese modelle
doen egter min om die megansimes betrokke in die toevoeging van growwe partikels
te verduidelik. ‘n Nuwe korrelasie is voorgestel, naamlik die Residu Klei Konsentrasie.
Hierdie model voorspel die verandering in reologiese eienskappe gebaseer op ‘n
addisionele klei konsentrasie, wat ‘n liniëre funkise is van die growwe partikel
konsentrasie. Die goeie korrelasie gesien met die model versterk die idée dat die
growwe partikel in ‘n soortgelyke manier as ‘n flok gedra in die teenwoordigheid van
ander flokke.
Deur middel van ‘n tipiese industriële voorbeeld is die belangrikheid in die keuse van
die regte korrelasie geillustreer. Die Residu Klei Konsentrasie metode het die mees
konservatiewe resultate gelewer. Hierdie feit gekombineerd met die model se soliede
teoreitiese beginsels versterk dit as voorgestelde korrelasie vir ontwerp.
|
489 |
Vapour phase mass transfer coefficients in structured packingVan der Westhuizen, Francois Erasmus 12 1900 (has links)
Thesis (MScEng (Process Engineering))--Stellenbosch University, 2008. / Please refer to full text to view abstract.
|
490 |
Reactive absorption kinetics of CO2 in alcoholic solutions of MEA: fundamental knowledge for determining effective interfacial mass transfer areaDu Preez, Louis Jacobus 04 1900 (has links)
Thesis (PhD)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: The reactive absorption rate of CO2 into non-aqueous solvents containing the primary amine,
mono-ethanolamine (MEA) is recognised as a suitable method for measuring the effective
interfacial mass transfer area of separation column internals such as random and structured
packing. Currently, this method is used under conditions where the concentration of MEA in
the liquid film is unaffected by the reaction and the liquid phase reaction is, therefore, assumed
to obey pseudo first order kinetics with respect to CO2. Under pseudo first order conditions,
the effect of surface depletion and renewal rates are not accounted for. Previous research
indicated that the effective area available for mass transfer is also dependent upon the rate of
surface renewal achieved within the liquid film. In order to study the effect of surface depletion
and renewal rates on the effective area, a method utilising a fast reaction with appreciable
depletion of the liquid phase reagent is required.
The homogeneous liquid phase reaction kinetics of CO2 with MEA n-Propanol as alcoholic
solvent was investigated in this study. A novel, in-situ Fourier Transform Infra-Red (FTIR)
method of analysis was developed to collect real time concentration data from reaction
initiation to equilibrium. The reaction was studied in a semi-batch reactor set-up at ambient
conditions (T = 25°C, 30°C and 35°C, P = 1 atm (abs)). The concentration ranges investigated
were [MEA]:[CO2] = 5:1 and 10:1. The concentration range investigated represents conditions
of significant MEA conversion. The reaction kinetic study confirmed the findings of previous research that the reaction of CO2
with MEA is best described by the zwitterion reactive intermediate reaction mechanism. Power
rate law and pseudo steady state hypothesis kinetic models (proposed in literature) were found
to be insufficient at describing the reaction kinetics accurately. Two fundamentally derived rate
expressions (based on the zwitterion reaction mechanism) provided a good quality model fit of
the experimental data for the conditions investigated. The rate constants of the full
fundamental model were independent of concentration and showed an Arrhenius temperature dependence. The shortened fundamental model rate constants showed a possible
concentration dependence, which raises doubt about its applicability.
The specific absorption rates (mol/m2.s) of CO2 into solutions of MEA/n-Propanol (0.2 M and
0.08 M, T = 25°C and 30°C, P = ±103 kPa) were investigated on a wetted wall experimental setup.
The experimental conditions were designed for a fast reaction in the liquid film to occur
with a degree of depletion of MEA in the liquid film. Both interfacial depletion and renewal of
MEA may be considered to occur. The gas phase resistance to mass transfer was determined to
be negligible. An increase in liquid turbulence caused an increase in the specific absorption rate
of CO2 which indicated that an increase in liquid turbulence causes an increase in effective mass
transfer area. Image analysis of the wetted wall gas-liquid interface confirmed the increase in
wave motion on the surface with an increase in liquid turbulence. The increase in wave motion
causes an increase in both interfacial and effective area.
A numerical solution strategy based on a concentration diffusion equation incorporating the
fundamentally derived rate expressions of this study is proposed for calculating the effective
area under conditions where surface depletion and renewal rates are significant. It is
recommended that the reaction kinetics of CO2 with MEA in solvents of varying liquid
properties is determined and the numerical technique proposed in this study used to calculate
effective area from absorption rates into these liquids. From the absorption data an effective
area correlation as a function of liquid properties may be derived in future. / AFRIKAANSE OPSOMMING: Die reaktiewe absorpsie van CO2 in nie-waterige oplossings van die primêre amien, monoetanolamien
(MEA) word erken as ‘n geskikte metode om die effektiewe massaoordragsarea
van gepakte skeidingskolomme te bepaal. Tans word die metode gebruik onder vinnige pseudo
eerste orde reaksietoestande met betrekking tot CO2. Die pseudo eersteorde aanname beteken
dat die konsentrasie van MEA in die vloeistoffilm onbeduidend beïnvloed word deur die reaksie
en effektief konstant bly. Onder pseudo eerste orde toestande word oppervlakverarming- en
oppervlakvernuwingseffekte nie in ag geneem nie, juis as gevolg van die konstante konsentrasie
van MEA in die vloeistoffilm. Daar is voorheen bevind dat oppervlakverarming en
oppervlakvernuwing ‘n beduidende invloed het op die beskikbare effektiewe
massaoordragsarea. Hierdie invloed kan slegs bestudeer word met ‘n vinnige reaksie in die
vloeistoffilm wat gepaard gaan met beduidende oppervlakverarming van die vloeistoffase
reagens. Die homogene vloeistoffase reaksiekinetika van CO2 met MEA in die alkohol oplosmiddel, n-
Propanol, is in hierdie studie ondersoek. ‘n Nuwe, in-situ Fourier Transform Infra-Rooi (FTIR)
metode van analiese is ontwikkel in hierdie ondersoek. Die reaksie is ondersoek in ‘n semienkelladings
reaktor met MEA wat gevoer is tot die reaktor om met die opgeloste CO2 te
reageer. Die FTIR metode meet spesiekonsentrasie as ‘n funksie van tyd sodat die
konsentrasieprofiele van CO2, MEA en een van die soutprodukte van die reaksie gebruik kan
word om verskillende reaksiesnelheidsvergelykings te modelleer. Die reaksie is ondersoek
onder matige toestande (T = 25°C, 30°C and 35°C, P = 1 atm (abs)). Die konsentrasiebereik van
die ondersoek was [MEA]:[CO2] = 5:1 en 10:1. Hierdie bereik is spesifiek gebruik sodat daar
beduidende omsetting van MEA kon plaasvind. Die reaksiekinetieka studie het, ter
ondersteuning van bestaande teorie, bevind dat die reaksie van CO2 met MEA in nie-waterige
oplosmiddels soos alkohole, beskyf word deur ‘n zwitterioon reaksiemeganisme. Die bestaande
reaksiesnelheids modelle (eksponensiële wet en pseudo gestadigde toestand hipotese) kon nie
die eksperimentele data met genoegsame akuraatheid beskryf nie. Twee nuwe reaksiesnelheidsvergelykings, afgelei vanaf eerste beginsels en gebaseer op die zwitterioon
meganisme, word voorgestel. Hierdie volle fundamentele model het goeie passings op die
eksperimentele data getoon oor die volledige temperatuur en konsentrasiebereik van hierdie
studie. Die reaksiekonstantes van die fundamentele model was onafhanklik van konsentrasie en
tipe oplosmiddel en het ‘n Arrhenius temperatuurafhanklikheid. Die verkorte fundamentele
model se reaksiekonstantes het ‘n moontlike konsentrasieafhanlikheid gewys. Dit plaas
onsekerheid op die fundamentele basis van hierdie model en kan dus slegs as ‘n eerste
benadering beskou word.
Die spesifieke absorpsietempos (mol/m2.s) van CO2 in MEA/n-Propanol oplossings (0.2 M en
0.08 M MEA, T = 25°C and 30°C, P = ±103 kPa) is ondersoek met ‘n benatte wand (‘wetted wall’)
eksperimentele opstelling. Die eksperimentele toestande is gekies sodat daar ‘n vinnige reaksie
in die vloeistoffilm plaasgevind het, met beide beduidende en nie-beduidende MEA omsetting.
Die doel met hierdie eksperimentele ontwerp was om die invloed van intervlakverarming en
intervlakvernuwing op die spesifieke absorpsietempo te ondersoek. Gas fase weerstand was
nie-beduidend onder die eksperimentele toestande nie. Beide intervlakverarming en
intervlakvernuwing gebeur gelyktydig en is waargeneem vanuit die eksperimentele data. ‘n
Beeldverwerkingstudie van die gas-vloeistof intervlak van die benatte wand het bevind dat daar
‘n toename in golfaksie op die vloeistof oppervlak is vir ‘n toename in vloeistof turbulensie.
Hierdie golfaksie dra by tot oppervlakvernuwing en ‘n toename in effektiewe
massaoordragsarea. ‘n Numeriese metode word voorgestel om die effektiewe area van beide die benatte wand en
gepakte kolomme te bepaal vanaf reaktiewe absorpsietempos. Die metode gebruik die
fundamentele reaksiesnelheidsvergelykings, bepaal in hierdie studie, in a konsentrasie
diffusievergelyking sodat oppervlakverarming en vernuwing in ag geneem kan word. Daar word
voorgestel dat die reaksiekinetika van CO2 met MEA in oplossings met verskillende fisiese
eienskappe (digtheid, oppervlakspanning en viskositeit) bepaal word sodat die numeriese
metode gebruik kan word om ‘n effektiewe area korrelasie as ‘n funksie van hierdie eienskappe
te bepaal.
|
Page generated in 0.0671 seconds