京都大学 / 新制・課程博士 / 博士(工学) / 甲第23870号 / 工博第4957号 / 新制||工||1774(附属図書館) / 京都大学大学院工学研究科都市環境工学専攻 / (主査)教授 高岡 昌輝, 教授 藤原 拓, 准教授 大下 和徹 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

The production of municipal solid waste has continued to grow in recent years. In Italy, municipal solid waste production reaches about 29 million tons per year. The organic fraction of municipal solid waste (OFMSW), which accounts for 30-40% of the total waste, usually undergoes biological treatments such as anaerobic digestion or composting, or is incinerated or landfilled. Biological treatments are considered not economically viable due to the long processing time (20-30 days), while incineration and landfilling are considered as low cost but polluting processes. In contrast, Hydrothermal Carbonization (HTC) is a cost-effective process to treat organic waste especially for the shorter processing time (0.5-8 h) and the possibility to treat directly wet heterogeneous materials. This thesis aims to investigate the potential use of HTC to upgrade OFMSW and other biomasses to biofuels or valuable byproducts. Chapter 1 gives an overview on the state of the art of HTC technology applied to organic wastes, focusing both on mechanisms and on the characteristics of reaction products. Chapter 2 investigates the potential use of HTC to upgrade the organic fraction of municipal solid waste (OFMSW) into biofuel and byproducts. The impact of process conditions (process time, temperature and solid load) on the formation, chemical and energy properties of hydrochar was deeply investigated. To analyze the behavior of hydrochar as a solid biofuel, the combustion (oxidation) of hydrochar and the co-firing (co-oxidation) of hydrochars and coals was also investigated. The results show that, especially at HTC harsher conditions, hydrochar is a “coal-like” material, that can be used as a valuable solid biofuel. The results evidenced that hydrochar is composed of primary char and secondary char. Primary char (non-extractable with organic solvents) has characteristics similar to coal and could be recovered for combustion, while secondary char is an amorphous and more volatile solid, easily extracted with organic solvents, which found possible application as a source of biochemicals and liquid bio-fuel. Chapter 3 investigates the use of HTC as a promising pre-treatment to enhance the biomethane potential during anaerobic digestion of OFMSW. Anaerobic digestion experiments were carried out using the HTC process liquid and the entire HTC reaction mixtures. Results proved that, when compared to the raw OFMSW, the use of HTC liquid and HTC mixture into AD lead to an increase of biomethane production of up to 37% and 363% by volume, respectively. Chapter 4 reports an HTC kinetics study and a kinetic model, which accounted for reactions leading to the production of primary and secondary char, as well as the liquid and gas phases. The model was optimized using experimental data performed on a lignocellulosic feedstock (olive trimmings) and validated on two other types of biomasses (grape marc and Opuntia Ficus Indica) and was used as a reliable tool to predict the carbon distribution among HTC products. In this chapter an in-depth analysis was also carried out to understand the evolution of feedstock characteristics during the heat-up transient phase before reaching the HTC set-point temperature. The results show that during heat up, the feedstock carbonized to a considerable extent at 220-250 °C. Tests clearly show evidence of the transition between thermal hydrolysis and HTC. Chapter 5 presents a study conducted to evaluate the economic feasibility and the detailed energy and cost analyses of a hypothetical HTC plant transforming wet biomass into pelletized dry hydrochar. To achieve these goals, a model was developed on the basis of experimental results obtained previously on two other organic materials (grape marc and off-specification compost). The results show that, when operating the HTC plant with grape marc at the optimal HTC conditions (T=220 °C, t=1 h, dry biomass to water ratio=0.19), the production cost of hydrochar were determined to be 157 €/ton, competitive with the price of wood pellets (150-200 €/ton). This makes HTC a promising process for a large development at the industrial scale.

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Um dos principais problemas enfrentados atualmente pelo Poder Público e pela sociedade é a destinação adequada de resíduos sólidos. O objetivo principal deste trabalho é avaliar a gestão dos resíduos sólidos urbanos (RSU) implantada no Rio Grande do Sul e verificar a existência de melhorias após a promulgação da Política Nacional de Resíduos Sólidos (PNRS). Este trabalho ainda apresenta o gerenciamento de resíduos sólidos no Brasil e na Europa, as formas de tratamento e disposição final dos resíduos sólidos urbanos, os tipos de tratamento de lixiviados existentes, identifica alternativa de reuso do lixiviado após tratamento, analisa os tratamentos de lixiviado utilizados em Aterros Sanitários localizados no estado do Rio Grande do Sul (RS) e em Portugal, o cumprimento das metas estipuladas para RSU nos Planos de Resíduos Sólidos e identifica e compara a legislação existente em Portugal e no Brasil que regulamenta a instalação e operação dos Aterros Sanitários. Para a elaboração foram analisados dados de destinação de RSU no Brasil, com especial ênfase ao estado do Rio Grande do Sul, e em Portugal. Através dos dados obtidos verifica-se que houve melhorias na destinação final dos RSU no Brasil após a homologação da PNRS, por exemplo houve um aumento de 138% de municípios que implantaram a coleta seletiva após a PNRS. Verificou-se que a forma mais utilizada de destinação final dos RSU no país é por meio de aterro sanitário, porém havendo ainda disposição inadequada por meio de aterros controlados e lixões. No RS em 2015, observou-se que houve uma redução na disposição final adequada em comparação ao ano de 2014, devido à má operação dos aterros sanitários, porém foi atingida a Meta 1 do Plano Nacional de Resíduos Sólidos (PLANARES), uma vez que em 2015 não havia lixões em operação no RS. Foi possível observar que no RS a maioria das áreas classificadas como inadequadas são administradas pelos próprios municípios, isto se dá devido à falta de recurso financeiro para gerenciar e operar um aterro sanitário. Com relação ao tratamento de lixiviado gerado nos aterros sanitários do RS, verificou-se que estes não possuem implantado um sistema eficaz e acredita-se que somente um tratamento combinado, apresentando tratamento avançado, seja a forma mais adequada para tratar este efluente, devido à grande variabilidade de características e complexidade do lixiviado. Fazendo uma comparação da legislação referente à gestão de resíduos no Brasil e em Portugal, observa-se que em 1996 foi aprovado o Plano Estratégico Setorial dos Resíduos Sólidos Urbanos (PERSU) em Portugal, que promoveu uma grande alteração na gestão de RSU, havendo grandes investimentos em infraestrutura visando atender as metas do PERSU. Já no Brasil somente em 2010 foi proposta esta alteração por meio da PNRS, e é possível observar que não houve o atendimento das metas estipuladas nos Planos Nacionais e Estadual, no caso do RS, devido à falta de conscientização do Poder Público e investimentos nesta área, de forma a promover uma destinação final adequada para os RSU gerados no país. / One of the main problems currently faced by the Government and the society is the appropriate destination of solid waste. The main objective of this study is to evaluate the management of municipal solid waste (MSW) introduced in Rio Grande do Sul and to verify possible improvements achieved after the promulgation of the National Solid Waste Policy (NSWP). This paper also describes the management of solid waste in Brazil and Europe, the way of treatment and final disposal of municipal solid waste, the existing leachate treatment process, identifies leachate reuse alternatives, analyzes the leachate treatment operations used in landfills located in the State of Rio Grande do Sul (RS) and in Portugal, the achievement of goal set for MSW in Solid Waste Plans and identifies and compares the legislation existing in Portugal and Brazil which regulates the installation and operation of Landfills. For the work accomplishment, data of the MSW disposal in Brazil, with special emphasis on the State of Rio Grande do Sul, and Portugal were analyzed. Through the data obtained it appears that there were improvements in the final disposal of MSW in Brazil after the approval of NSWP, for example an increase of 138% of municipalities that have implemented selective collection after NSWP. It was found that the most used form of final disposal of MSW in the country is through landfill, but there is still inadequate disposal in controlled landfills and dumps. In RS in 2015, it was observed that there was a reduction in the number of adequate final disposal sites, compared to 2014, due to wrong operation of landfills. Nevertheless, Goal 1 of the National Plan of the Solid Waste (NPSW) was achieved, since in 2015 there was no dumps operating in RS. It was observed that in RS most of the areas classified as inadequate are administered by the municipalities themselves. This, is due to lack of financial resources to manage and operate a landfill. Regarding the treatment of leachate generated in landfills of RS, it was found that these have not implemented an effective system and it is believed that only a combined treatment, with advanced treatment, will be the best way to treat this effluent due to the large variability of characteristics and complexity of the leachate. Making a comparison of the legislation on waste management in Brazil and in Portugal, it is observed that in 1996 the Sector Strategic Plan for Municipal Solid Waste (SSPMSW) was approved in Portugal, promoting a major change in the MSW management, with large investments in infrastructure to deal the goals of the SSPMSW. On the other hand, in Brazil only in 2010 this change was proposed by NSWP. It is possible to observe that goals set in the National and State Plans were not met, in the case of RS, due to lack of awareness of the government and investments in this area in order to promote an appropriate final destination for the MSW generated in the country.

Um dos principais problemas enfrentados atualmente pelo Poder Público e pela sociedade é a destinação adequada de resíduos sólidos. O objetivo principal deste trabalho é avaliar a gestão dos resíduos sólidos urbanos (RSU) implantada no Rio Grande do Sul e verificar a existência de melhorias após a promulgação da Política Nacional de Resíduos Sólidos (PNRS). Este trabalho ainda apresenta o gerenciamento de resíduos sólidos no Brasil e na Europa, as formas de tratamento e disposição final dos resíduos sólidos urbanos, os tipos de tratamento de lixiviados existentes, identifica alternativa de reuso do lixiviado após tratamento, analisa os tratamentos de lixiviado utilizados em Aterros Sanitários localizados no estado do Rio Grande do Sul (RS) e em Portugal, o cumprimento das metas estipuladas para RSU nos Planos de Resíduos Sólidos e identifica e compara a legislação existente em Portugal e no Brasil que regulamenta a instalação e operação dos Aterros Sanitários. Para a elaboração foram analisados dados de destinação de RSU no Brasil, com especial ênfase ao estado do Rio Grande do Sul, e em Portugal. Através dos dados obtidos verifica-se que houve melhorias na destinação final dos RSU no Brasil após a homologação da PNRS, por exemplo houve um aumento de 138% de municípios que implantaram a coleta seletiva após a PNRS. Verificou-se que a forma mais utilizada de destinação final dos RSU no país é por meio de aterro sanitário, porém havendo ainda disposição inadequada por meio de aterros controlados e lixões. No RS em 2015, observou-se que houve uma redução na disposição final adequada em comparação ao ano de 2014, devido à má operação dos aterros sanitários, porém foi atingida a Meta 1 do Plano Nacional de Resíduos Sólidos (PLANARES), uma vez que em 2015 não havia lixões em operação no RS. Foi possível observar que no RS a maioria das áreas classificadas como inadequadas são administradas pelos próprios municípios, isto se dá devido à falta de recurso financeiro para gerenciar e operar um aterro sanitário. Com relação ao tratamento de lixiviado gerado nos aterros sanitários do RS, verificou-se que estes não possuem implantado um sistema eficaz e acredita-se que somente um tratamento combinado, apresentando tratamento avançado, seja a forma mais adequada para tratar este efluente, devido à grande variabilidade de características e complexidade do lixiviado. Fazendo uma comparação da legislação referente à gestão de resíduos no Brasil e em Portugal, observa-se que em 1996 foi aprovado o Plano Estratégico Setorial dos Resíduos Sólidos Urbanos (PERSU) em Portugal, que promoveu uma grande alteração na gestão de RSU, havendo grandes investimentos em infraestrutura visando atender as metas do PERSU. Já no Brasil somente em 2010 foi proposta esta alteração por meio da PNRS, e é possível observar que não houve o atendimento das metas estipuladas nos Planos Nacionais e Estadual, no caso do RS, devido à falta de conscientização do Poder Público e investimentos nesta área, de forma a promover uma destinação final adequada para os RSU gerados no país. / One of the main problems currently faced by the Government and the society is the appropriate destination of solid waste. The main objective of this study is to evaluate the management of municipal solid waste (MSW) introduced in Rio Grande do Sul and to verify possible improvements achieved after the promulgation of the National Solid Waste Policy (NSWP). This paper also describes the management of solid waste in Brazil and Europe, the way of treatment and final disposal of municipal solid waste, the existing leachate treatment process, identifies leachate reuse alternatives, analyzes the leachate treatment operations used in landfills located in the State of Rio Grande do Sul (RS) and in Portugal, the achievement of goal set for MSW in Solid Waste Plans and identifies and compares the legislation existing in Portugal and Brazil which regulates the installation and operation of Landfills. For the work accomplishment, data of the MSW disposal in Brazil, with special emphasis on the State of Rio Grande do Sul, and Portugal were analyzed. Through the data obtained it appears that there were improvements in the final disposal of MSW in Brazil after the approval of NSWP, for example an increase of 138% of municipalities that have implemented selective collection after NSWP. It was found that the most used form of final disposal of MSW in the country is through landfill, but there is still inadequate disposal in controlled landfills and dumps. In RS in 2015, it was observed that there was a reduction in the number of adequate final disposal sites, compared to 2014, due to wrong operation of landfills. Nevertheless, Goal 1 of the National Plan of the Solid Waste (NPSW) was achieved, since in 2015 there was no dumps operating in RS. It was observed that in RS most of the areas classified as inadequate are administered by the municipalities themselves. This, is due to lack of financial resources to manage and operate a landfill. Regarding the treatment of leachate generated in landfills of RS, it was found that these have not implemented an effective system and it is believed that only a combined treatment, with advanced treatment, will be the best way to treat this effluent due to the large variability of characteristics and complexity of the leachate. Making a comparison of the legislation on waste management in Brazil and in Portugal, it is observed that in 1996 the Sector Strategic Plan for Municipal Solid Waste (SSPMSW) was approved in Portugal, promoting a major change in the MSW management, with large investments in infrastructure to deal the goals of the SSPMSW. On the other hand, in Brazil only in 2010 this change was proposed by NSWP. It is possible to observe that goals set in the National and State Plans were not met, in the case of RS, due to lack of awareness of the government and investments in this area in order to promote an appropriate final destination for the MSW generated in the country.

Um dos principais problemas enfrentados atualmente pelo Poder Público e pela sociedade é a destinação adequada de resíduos sólidos. O objetivo principal deste trabalho é avaliar a gestão dos resíduos sólidos urbanos (RSU) implantada no Rio Grande do Sul e verificar a existência de melhorias após a promulgação da Política Nacional de Resíduos Sólidos (PNRS). Este trabalho ainda apresenta o gerenciamento de resíduos sólidos no Brasil e na Europa, as formas de tratamento e disposição final dos resíduos sólidos urbanos, os tipos de tratamento de lixiviados existentes, identifica alternativa de reuso do lixiviado após tratamento, analisa os tratamentos de lixiviado utilizados em Aterros Sanitários localizados no estado do Rio Grande do Sul (RS) e em Portugal, o cumprimento das metas estipuladas para RSU nos Planos de Resíduos Sólidos e identifica e compara a legislação existente em Portugal e no Brasil que regulamenta a instalação e operação dos Aterros Sanitários. Para a elaboração foram analisados dados de destinação de RSU no Brasil, com especial ênfase ao estado do Rio Grande do Sul, e em Portugal. Através dos dados obtidos verifica-se que houve melhorias na destinação final dos RSU no Brasil após a homologação da PNRS, por exemplo houve um aumento de 138% de municípios que implantaram a coleta seletiva após a PNRS. Verificou-se que a forma mais utilizada de destinação final dos RSU no país é por meio de aterro sanitário, porém havendo ainda disposição inadequada por meio de aterros controlados e lixões. No RS em 2015, observou-se que houve uma redução na disposição final adequada em comparação ao ano de 2014, devido à má operação dos aterros sanitários, porém foi atingida a Meta 1 do Plano Nacional de Resíduos Sólidos (PLANARES), uma vez que em 2015 não havia lixões em operação no RS. Foi possível observar que no RS a maioria das áreas classificadas como inadequadas são administradas pelos próprios municípios, isto se dá devido à falta de recurso financeiro para gerenciar e operar um aterro sanitário. Com relação ao tratamento de lixiviado gerado nos aterros sanitários do RS, verificou-se que estes não possuem implantado um sistema eficaz e acredita-se que somente um tratamento combinado, apresentando tratamento avançado, seja a forma mais adequada para tratar este efluente, devido à grande variabilidade de características e complexidade do lixiviado. Fazendo uma comparação da legislação referente à gestão de resíduos no Brasil e em Portugal, observa-se que em 1996 foi aprovado o Plano Estratégico Setorial dos Resíduos Sólidos Urbanos (PERSU) em Portugal, que promoveu uma grande alteração na gestão de RSU, havendo grandes investimentos em infraestrutura visando atender as metas do PERSU. Já no Brasil somente em 2010 foi proposta esta alteração por meio da PNRS, e é possível observar que não houve o atendimento das metas estipuladas nos Planos Nacionais e Estadual, no caso do RS, devido à falta de conscientização do Poder Público e investimentos nesta área, de forma a promover uma destinação final adequada para os RSU gerados no país. / One of the main problems currently faced by the Government and the society is the appropriate destination of solid waste. The main objective of this study is to evaluate the management of municipal solid waste (MSW) introduced in Rio Grande do Sul and to verify possible improvements achieved after the promulgation of the National Solid Waste Policy (NSWP). This paper also describes the management of solid waste in Brazil and Europe, the way of treatment and final disposal of municipal solid waste, the existing leachate treatment process, identifies leachate reuse alternatives, analyzes the leachate treatment operations used in landfills located in the State of Rio Grande do Sul (RS) and in Portugal, the achievement of goal set for MSW in Solid Waste Plans and identifies and compares the legislation existing in Portugal and Brazil which regulates the installation and operation of Landfills. For the work accomplishment, data of the MSW disposal in Brazil, with special emphasis on the State of Rio Grande do Sul, and Portugal were analyzed. Through the data obtained it appears that there were improvements in the final disposal of MSW in Brazil after the approval of NSWP, for example an increase of 138% of municipalities that have implemented selective collection after NSWP. It was found that the most used form of final disposal of MSW in the country is through landfill, but there is still inadequate disposal in controlled landfills and dumps. In RS in 2015, it was observed that there was a reduction in the number of adequate final disposal sites, compared to 2014, due to wrong operation of landfills. Nevertheless, Goal 1 of the National Plan of the Solid Waste (NPSW) was achieved, since in 2015 there was no dumps operating in RS. It was observed that in RS most of the areas classified as inadequate are administered by the municipalities themselves. This, is due to lack of financial resources to manage and operate a landfill. Regarding the treatment of leachate generated in landfills of RS, it was found that these have not implemented an effective system and it is believed that only a combined treatment, with advanced treatment, will be the best way to treat this effluent due to the large variability of characteristics and complexity of the leachate. Making a comparison of the legislation on waste management in Brazil and in Portugal, it is observed that in 1996 the Sector Strategic Plan for Municipal Solid Waste (SSPMSW) was approved in Portugal, promoting a major change in the MSW management, with large investments in infrastructure to deal the goals of the SSPMSW. On the other hand, in Brazil only in 2010 this change was proposed by NSWP. It is possible to observe that goals set in the National and State Plans were not met, in the case of RS, due to lack of awareness of the government and investments in this area in order to promote an appropriate final destination for the MSW generated in the country.

Solid Waste Management is one of the essential services provided by local bodies to keep the urban areas clean. Often it is poorly rendered as it is unscientific, out-dated and inefficient. With the rapid increase in population, livening standards, the generation rates of solid waste are increasing drastically. The landfill waste includes both organic and inorganic wastes as it is not often effectively segregated before disposal. The problem is acute in developing countries such as India. Bangalore city, with a population of about 10.18 million and more than 2000 industries, generates about 4,500 TPD of municipal solid waste. Of this Presently, various municipal solid waste processing units in Bangalore can handle only about 2100 TPD of waste. Mavallipura landfill developed and operated by M/s. Ramky Environmental Engineers, located 40 km away from Bangalore, is being used for disposing of about 1000 TPD, the installed capacity being only 600 TPD of waste. There are also a few dumps in around Bangalore due to historical reasons and insufficient capacity of various designated landfills. To reclaim the old dump sites/closed landfill sites for infrastructural development, it is necessary to know their geotechnical characteristics. Within the Landfill, the characteristics of the waste may change with depth due to degraded wastes as it has been dumped over a period of time. The physical parameters, chemical properties as well as the geotechnical behaviour of the waste change with depth. MSW is known to be a heterogeneous material of varying constituent types and dimensions, containing elements that degrade with time. To consider MSW as a geo-material to support the foundation of structures such as buildings and pavement, an analysis of the bearing capacity of the foundation and further long-term settlement of MSW is essential. The MSW samples are retrieved from a Mavallipura landfill site, Bangalore and analysed for important geotechnical properties such as compaction characteristics, shear strength, permeability, compressibility behaviour and dynamic properties of MSW using ultrasonic and cyclic triaxial tests. This research thus aims to provide valuable information about landfill sites for reclamation, closure and infrastructural development after the closure of landfills. Scanty data are available on the geotechnical properties of waste from landfill sites with varying degrees of degradation. This landfill site is selected as there is a huge environmental concern regarding the soil and groundwater contamination in the area and also can represent a typical landfill scenario in tropical regions. Quantification, quality assessment, consequent treatment and management of leachate have become a monstrous problem world over. In this context, the present study envisages to study the physicochemical and biological characterization of representative urban municipal landfill leachate and nearby water bodies and attempts to figure out relationships between the various parameters together with understanding the various processes for chemical transformations. The analysis shows intermediate leachate age (5-10 years) with higher nutrient levels i.e. 10,000 - 12,000 mg/l and ~2,000 - 3,000 mg/l of carbon (COD) and nitrogen (TKN) respectively. Elemental analysis and underlying mechanisms reveal chemical precipitation and co-precipitation as the vital processes in leachate pond systems resulting in accumulation of trace metals in these systems. The microbial analysis also correlated with specific factors relevant to redox environments that show a gradient in nature and the abundance of biotic diversity with a change in leachate environment. Finally, the quality and the contamination potential of the sampled leachate were performed with the help of potential leachate index (LPI) analysis and water quality index (WQI) analysis for surrounding water bodies (namely surface pond and open well) of Mavallipura landfill site. A geotechnical testing program has been drawn to evaluate the engineering properties of municipal solid waste samples retrieved from a landfill at Mavallipura at various depths through augur within the landfill dumped area. Laboratory studies included are composition, moisture content, particle size analysis, compaction, permeability, direct shear test, consolidation, triaxial compression test. For the laboratory tests, we had considered maximum particle sizes of less than 4.75 mm only. Standard Proctor Compaction tests yielded a maximum dry density of 7.0kN/m3 at 50% optimum moisture content. The permeability of MSW results shows in the range of 4x10-4 cm/sec. Compression index of MSW is 0.46980 and recompression index of MSW is 0.09454. Results obtained from the rectangular hyperbola method are compared with Casagrande and Taylor methods to prove that this method is reliable equally, and results are reasonably accurate. Based on direct shear tests, the MSW sample exhibited continuous strength gain with an increase in shear strain (16%) to define strength. The cohesion of MSW was 10kPa and friction angle is 34°. Based on the elastic constants results obtained from the direct shear test found to be very soft material. In the triaxial test, the MSW sample exhibited continuous strength gain with an increase in axial strain. The frictional component is increased due to sliding and rolling of fibrous particles over one another resulting in the development of apparent cohesion due to antiparticle bonds within the MSW material. Landfills are an integral part of waste management, and disastrous consequences can happen if seismic vulnerability of these landfills is not considered. Dynamic properties of MSW are required to perform seismic response analysis of MSW landfills, but there is no good understanding of the dynamic shear strength of MSW in literature. A comprehensive laboratory cyclic triaxial testing program has been taken up to determine the properties at different densities, confining pressures and shear strains. MSW degrades with time, and its shear modulus and damping are expected to vary with time and degradation. For the density of 6 kN/m3 the dynamic shear modulus values for MSW varied from 0.68 MPa to 5.38 MPa and damping ratio varied from 20% to 40% for MSW. For the density of 7 kN/m3 the dynamic shear modulus values for MSW varied from 1.8 MPa to 7.5 MPa and Damping ratio varied from 23% to 40% for MSW. For the density of 8kN/m3 dynamic shear modulus values for MSW varied from 2.46 MPa to 8.00MPa and damping ratio varied from 16% to 33% for MSW. Also, the ultrasonic testing method was used for determining the dynamic properties at low strains. The Ultrasonic test results indicated that with an increase in density of the sample and with decreased void ratio, the pulse propagation velocity (Vp) increases. With an increase in the density, the shear wave velocity and elastic constants (elastic modulus and shear modulus) increase. The elastic constant values obtained from the ultrasonic test are higher compared to values obtained from unconsolidated-undrained triaxial tests. Also, the carbon stored in the buried organic matter in Mavallipura landfill is estimated. Total organic carbon increases steeply with an increase in depth and is significantly high at a depth of 6 m. Subsurface properties cannot be specified but must be analysed through in-situ tests. The in-situ testing that are carried out in a landfill are boring, sampling, standard penetration test (SPT), dynamic cone penetration test (DCPT) and plate load tests (under static and cyclic condition). A correlation between corrected SPT ‘N’ values and measured using shear wave velocities has been developed for Mavallipura landfill site. Results show that the corrected SPT- N values increase with depth. Corrected N-values are used in the landfill design, so they are consistent with the design method, and correlations are useful. The results obtained from the dynamic cone penetration tests shows lower value when to compare with standard penetration test. The unit weight profile with depth ranged from a low unit weight of 2.48 kN/m3 near the surface to a highest value of approximately 9.02 kN/m3 at a depth of 6 m. The highest temperatures for landfills were reported at mid-waste elevations with temperatures decreasing near the top. The bearing pressure-settlement curves for plate size 75cm and 60cm presented similar behaviour while the plate size of 60cm curve presents a lesser settlement of 70mm, compared to with plate size of the 75cm curve with the settlement of 80mm and failure mode could be classified as punching shear. The cyclic plate load test with plate size of 60cm and 75cm were carried out on the soil cover. The elastic constants were found to be 73.87 and 96.84 kPa/mm and for 60 and 75cm plates respectively. Geophysical testing may not be as precise but has the benefit of covering large areas at small costs and sometimes can locate features that might be missing by conventional borings. Multichannel analysis of surface waves (MASW) is an indirect geophysical method used in the landfill for the characterization of the municipal solid waste site. The Mavallipura landfill was surveyed up to the length of about 35m at the top level. A series of one-dimensional and two-dimensional MASW surveys used active seismic sources such as sledgehammer (5kg) and propelled energy generator (PEG-40) was used. This hammer was instrumented with geophones to trigger record time. All the testing has been carried out with geophone spacing of 1m and recorded surface wave arrivals using the source to first receiver distance as 5m with recording length of 1000 millisecond and the recording sampling interval of 0.5 milliseconds (ms) were applied. Results shows that the PEG-40 hammer can generate the longest wavelength with a maximum depth of penetration. The shear wave velocity varies from 75 to 155 m/s with an increase in depth of about 27.5m. Based on the site characterization at the landfill site, it was found that the Mavallipura landfill site can be categorized as very loose, and it is still in a continued stage of degradation. Shear wave and P-wave velocity profile for eight major locations in the study area were determined and variation of waste material stiffness corresponding to the in-situ state with depth, was also evaluated. Also, MASW survey has been carried out to develop dispersion curve on another landfill site at Bhandewadi, Nagpur. MASW system consisting of 24 channels geode seismograph with 24 geophones of 4.5Hz capacity is used in this investigation. The seismic waves were created by sledgehammer with 30cmx 30cmx2cm size hammer plate with ten shots. These waves were captured by the geophones/receivers and further analyzed by inversion. The results indicated that near surface soils(less than 3m depth) approximately the to 5mm, and with 85% of dry weight basis of waste particles with sizes less than 10mm, the shear wave velocity varies from 75 to 140 m/s (frequency ranges from 30 to 23Hz). With the increase in 6.5m depth, the shear wave velocity ranged from 140 to 225m/s (frequency ranges 23 to 13Hz). Overall, the results of the study showed that seismic surveys have the potential to capture the changes in dynamic properties like shear wave velocity and Poisson’s ratio of the depth of MSW landfill to infer the extent of degradation and provide dynamic properties needed for seismic stability evaluations. Based on the in situ and laboratory results of this study and a review of the literature, the unit weight, shear wave velocity, strain-dependent normalized shear modulus reduction and material damping ratio relationships for Mavallipura landfill are developed and also validated using semi-empirical methods. Finally, seismic response analysis of Mavallipura landfill has been carried out using the computer programs like SHAKE 2000 and DEEPSOIL. Results show that the unit weight is increased with depth in response to the increase in overburden stress. The proposed material damping ratio and normalized shear modulus reduction curve lie close to the profile given in the literature for landfills composed of waste materials with 100% particles sized less than 20mm. Peak spectral acceleration at 5% damping value is 0.7g for 0.07 sec in SHAKE 2000 and peak spectral acceleration at 5% damping value is 0.63g for 0.04 sec in DEEPSOIL. Amplification ratio is 6.11 at 1.1l Hz in SHAKE2000 and 4.65 at 2.67Hz in DEEPSOIL. Peak ground acceleration (PGA) for the landfill site, it is observed PGA has decreased from 0.3g to 0.15g in DEEPSOIL and PGA has decreased from 0.33g to 0.15g in SHAKE2000. The studies presented in the thesis brought out the importance of characterization of municipal solid waste leachate regarding metabolism and treatment/degradation of Mavallipura landfill leachate. For municipal solid waste of with sizes ranging from 0.08 coefficient of permeability being about 10-4 cm/sec, the compression index was about 0.47. A more reliable method of calculating the coefficient of consolidation has been recommended. Correlations between shear wave velocity and SPT-N values has been developed for the Mavallipura landfill site. The results showed that the dynamic cone penetration tests values are lower than indicated by standard penetration tests. The cyclic plate load tests carried out with plate sizes of 75cm and 60cm showed that elastic constants of 96.84 kPa/mm and 73.87kPa/mm respectively. MSW properties evaluated in this thesis are compared with those of soft clays. The MSW properties showed higher values (strength and SBC) and lower values of compressibility, compared with those of soft clays. Thus foundation improvement on MSW is less challenging than foundations on soft soils. Also stabilization of MSW with other solid wastes such as fly ash can be considered as an economical option. Based on detailed studies the importance of unit weight, shear wave velocity, strain-dependent normalized shear modulus reduction and material damping ratio relationships for landfill waste have been developed. Based on the site characterization, the waste landfill has been categorized as very loose material, which is still in a degradation process. SHAKE2000 software shows higher PGA value comparing with DEEPSOIL.

The problems of formation and placement of municipal solid waste in the Perm Krai are considered. The lack of temporary storage of waste, the unreasonable organization of selective collection, the unsettled time for export, untimely disposal of waste generated have a negative impact on both the quality of life of the population and the quality of the environment. The problem of waste generation and disposal is considered to be the most acute in modern conditions. At the same time, there is a real opportunity to return them to production, contributing to the partial solution of many socio-economic issues. The paper analyzes the situation on waste management in the Perm Krai, considers various options for the rational use of MSO landfills, provides an ecological and economic assessment of the options for using MSO landfills in the Perm Krai. As scientific novelty of the work, it is possible to note the development of an algorithm for the adoption of organizational and managerial decisions for the selection of the direction of reclamation and use of the territories of MSO landfills. / В работе рассматриваются проблемы образования и размещения твердых коммунальных отходов в Пермском крае. Отсутствие мест временного складирования отходов, непродуманная организация селективного сбора, невыдержанные сроки вывоза, несвоевременное обезвреживание образующихся отходов отрицательно сказываются как на качестве жизни населения, так и на качестве окружающей среды. Проблема образования и размещения отходов считается наиболее острой в современных условиях. В тоже время существует реальная возможность возвращения их в производство, способствуя частичному решению многих социально-экономических вопросов. В работе проведен анализ ситуации по обращению с отходами в Пермском крае, рассмотрены различные варианты рационального использования полигонов ТКО, дана эколого-экономическая оценка вариантов использования полигонов ТКО в Пермском крае. В качестве научной новизны работы можно отметить разработку алгоритма по принятию организационно-управленческих решений по выбору направления рекультивации и использования территорий полигонов ТКО.

Tesis por compendio / [ES] La estrategia de la Unión Europea para la gestión de residuos se articula a través de una serie de directivas que toman como punto de partida la Directiva 2008/98/CE. En ella, se establece un marco jurídico para el tratamiento de los residuos diseñado para preservar el medio ambiente, poniendo el foco en la importancia del empleo de las mejores técnicas disponibles para la gestión, recuperación y reciclado de residuos, reduciendo así el uso de los recursos naturales. Ello ha derivado en diferentes normativas que obligan a las economías a ser más sostenibles, priorizando la minimización de residuos y, cuando no sea posible, favoreciendo su reutilización y reciclado. En España, todo ello ha sido traspuesto al ordenamiento jurídico a través de la reciente Ley 7 /2022, de 8 de abril, de residuos y suelos contaminados para una economía circular, en la que el papel protagonista recae en los municipios. La ciudad de Castelló de la Plana es una ciudad mediterránea de tamaño medio que dispone de un sistema completo de gestión de residuos sólidos urbanos y que, como todo sistema, presenta oportunidades de mejora. El objetivo fundamental de esta Tesis Doctoral es, por tanto, la mejora del sistema de gestión de residuos actual partiendo de un análisis detallado de sus principales dimensiones. Concretamente, se ha analizado la evolución histórica de las principales fracciones de residuos de la ciudad observando cómo los factores externos pueden afectar a su tendencia; se ha estudiado la composición de los biorresiduos recogidos selectivamente para ayudar al dimensionamiento de los servicios de recogida y de nuevas instalaciones de valorización provinciales; se ha propuesto la mejor tecnología de motorización disponible para la renovación de la flota de vehículos recolectores y se ha desarrollado una metodología para priorizar los planes de acción incluidos en el Plan Local de Residuos de la ciudad, a través de un análisis de sus principales indicadores. Estas propuestas de mejora están encaminadas al cumplimiento de los Objetivos de Desarrollo Sostenible fijados para el año 2030 y atienden, por tanto, a demandas de sostenibilidad y circularidad. En cuanto a la forma de presentación de este trabajo, debe reseñarse que ha sido elaborado mediante el compendio de publicaciones en las que se han evaluado las cuatro dimensiones del sistema citadas anteriormente. Para ello, se han analizado investigaciones anteriores y, utilizando los datos propios del municipio, se han realizado análisis estadísticos y de decisión multicriterio para obtener resultados que facilitan los procesos de toma de decisiones estratégicas, tácticas y operativas que mejorarán la gestión de los residuos sólidos urbanos. De estos análisis, se han extraído importantes conclusiones que permitirán manejar mejor futuras situaciones extraordinarias (como la reciente crisis sanitaria), realizar acciones encaminadas a la mejora en la separación en origen, mejorar las flotas de vehículos de recogida de residuos y optimizar los recursos municipales mediante la priorización de planes de acción. Estos resultados pueden suponer una aportación muy útil para los responsables municipales en gestión de residuos ya que, mediante el uso de los métodos aquí definidos, se proporcionan aportaciones teóricas y prácticas para la toma de decisiones, así como para el desarrollo de futuros trabajos de investigación. / [CA] L'estratègia de la Unió Europea per a la gestió de residus s'articula a través d'una sèrie de directives que prenen com a punt de partida la Directiva 2008/98/CE. En ella, s'estableix un marc jurídic per al tractament dels residus dissenyat per a preservar el medi ambient, posant el focus en la importància de l'ús de les millors tècniques disponibles per a la gestió, recuperació i reciclatge de residus, reduint així l'ús dels recursos naturals. Això ha derivat en diferents normatives que obliguen les economies a ser més sostenibles, prioritzant la minimització de residus i, quan no siga possible, afavorint la seua reutilització i reciclatge. A Espanya, tot això ha sigut transposat a l'ordenament jurídic a través de la recent Llei 7 /2022, de 8 d'abril, de residus i sòls contaminats per a una economia circular, en la qual el paper protagonista recau en els municipis. La ciutat de Castelló de la Plana és una ciutat mediterrània de grandària mitjana que disposa d'un sistema complet de gestió de residus sòlids urbans i que, com tot sistema, presenta oportunitats de millora. L'objectiu fonamental d'aquesta Tesi Doctoral és, per tant, la millora del sistema de gestió de residus actual partint d'una anàlisi detallada de les seues principals dimensions. Concretament, s'ha analitzat l'evolució històrica de les principals fraccions de residus de la ciutat observant com els factors externs poden afectar la seua tendència; s'ha estudiat la composició dels bioresidus recollits selectivament per a ajudar al dimensionament dels serveis de recollida i de noves instal·lacions de valorització provincials; s'ha proposat la millor tecnologia de motorització disponible per a la renovació de la flota de vehicles recol·lectors i s'ha desenvolupat una metodologia per a prioritzar els plans d'acció inclosos en el Pla Local de Residus de la ciutat, a través d'una anàlisi dels seus principals indicadors. Aquestes propostes de millora estan encaminades al compliment dels Objectius de Desenvolupament Sostenible fixats per a l'any 2030 i atenen, per tant, a demandes de sostenibilitat i circularitat. Quant a la forma de presentació d'aquest treball, ha de ressenyar-se que ha sigut elaborat mitjançant el compendi de publicacions en les quals s'han avaluat les quatre dimensions del sistema citades anteriorment. Per a això, s'han analitzat investigacions anteriors i, utilitzant les dades pròpies del municipi, s'han realitzat anàlisis estadístiques i de decisió multicriteri per a obtindre resultats que faciliten els processos de presa de decisions estratègiques, tàctiques i operatives que milloraran la gestió dels residus sòlids urbans. D'aquestes anàlisis, s'han extret importants conclusions que permetran manejar millor futures situacions extraordinàries (com la recent crisi sanitària), realitzar accions encaminades a la millora en la separació en origen, millorar les flotes de vehicles de recollida de residus i optimitzar els recursos municipals mitjançant la priorització de plans d'acció. Aquests resultats poden suposar una aportació molt útil per als responsables municipals en gestió de residus ja que, mitjançant l'ús dels mètodes ací definits, es proporcionen aportacions teòriques i pràctiques per a la presa de decisions, així com per al desenvolupament de futurs treballs de recerca. / [EN] The European Union's strategy for waste management is articulated through a series of directives that take Directive 2008/98/EC as a starting point. It establishes a legal framework for waste treatment designed to preserve the environment, focusing on the importance of using the best available techniques for waste management, recovery and recycling, thus reducing the use of natural resources. This has led to different regulations that oblige economies to be more sustainable, prioritizing waste minimization and, when this is not possible, favouring its reuse and recycling. In Spain, all this has been transposed into the legal system through the recent Law 7 /2022, of April 8, on waste and contaminated soils for a circular economy, in which the leading role falls to the municipalities. The city of Castelló de la Plana is a medium-sized Mediterranean city that has a complete system of solid urban waste management and that, like any system, presents opportunities for improvement. The main objective of this Doctoral Thesis is, therefore, the improvement of the current waste management system based on a detailed analysis of its main dimensions. Specifically, the historical evolution of the main waste fractions of the city has been analysed, observing how external factors can affect their trend; the composition of bio-waste collected selectively has been studied to help the sizing of collection services and new provincial recovery facilities; the best available motorization technology has been proposed for the renewal of the fleet of collection vehicles and a methodology has been developed to prioritize the action plans included in the Local Waste Plan of the city, through an analysis of its main indicators. These improvement proposals are aimed at meeting the Sustainable Development Goals set for the year 2030 and therefore address sustainability and circularity demands. With regard to the presentation of this work, it should be noted that it has been prepared by means of a compendium of publications in which the four dimensions of the system mentioned above have been evaluated. For this purpose, previous research has been analysed and, using the municipality's own data, statistical and multi-criteria decision analyses have been carried out to obtain results that facilitate the strategic, tactical and operational decision-making processes that will improve the management of urban solid waste. From these analyses, important conclusions have been drawn that will make it possible to better manage future extraordinary situations (such as the recent health crisis), carry out actions aimed at improving separation at source, improve waste collection vehicle fleets and optimize municipal resources by prioritizing action plans. These results can be a very useful contribution for municipal waste management managers since, by using the methods defined here, theoretical and practical contributions are provided for decision making, as well as for the development of future research work. / Moreno Solaz, H. (2023). Análisis y mejora del sistema integral de gestión de resíduos sólidos urbanos en la ciudad de Castellón de la Plana respondiendo a demandas de sostenibilidad y circularidad [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/199548 / Compendio