Geological records of past sea ice, such as those contained in Arctic marine sediments, offer an opportunity to strengthen our understanding of long-term sea ice variability, provided unambiguous paleo-sea ice proxies can be developed. One such recently proposed proxy is IP₂₅, a highly branched isoprenoid alkene biosynthesized exclusively by sea-ice dwelling diatoms (Haslea spp.), which is well preserved in marine sediments and could be used to reconstruct past changes in spring sea-ice extent. However, little is known about regional-scale controls on IP₂₅ production in sea ice, limiting its wider applicability as a paleo-sea-ice proxy. To address this issue we examined the distributions of IP₂₅ and the marine productivity biomarkers dinosterol and brassicasterol in a suite of surface sediment samples distributed across the Arctic. We find a statistically significant, logarithmic relationship between IP₂₅ and spring sea ice cover in samples from arctic and subarctic sites in the Pacific (n = 96, r² = 0.67, P < 0.0001) and the Atlantic n = 25, r² = 0.50, P < 0.0001), though the absolute concentrations of IP₂₅ are generally higher in the Atlantic (1.6 - 166.4 [mu]g/g OC) than in the Pacific (0 - 38.5 [mu]g/g OC) for equivalent sea-ice cover, and there are regional and basin-specific differences in the slope of the IP₂₅ - sea ice relationship. After normalization of IP₂₅ concentrations to that of a productivity biomarker (e.g., dinosterol; the PDIP₂₅ index) the proxy-sea ice relationship in greatly improved for all regions (r² = 0.86 and r² = 0.75 for Atlantic and Pacific, respectively) and most of the basin specific differences in the rate of change of IP₂₅ with sea ice are removed. This suggests that productivity plays an important secondary role in controlling IP₂₅ concentrations. However, the use of the PDIP₂₅ index does not change the absolute differences in concentrations seen in the Atlantic and the Pacific, and previously published data from Fram Strait remain anomalous when compared to the rest of our data. This suggests that there are additional, yet unidentified controls on the IP₂₅ proxy - sea ice relationship, which may hinder the development of an Arctic-wide calibration but that the PDIP₂₅ index is a viable tool for local and regional sea ice reconstructions. / text

Understanding the paleoclimate of a region is important, especially when trying to determine the extent of natural climate variability within the context of anthropogenic impacts. Recent anomalous periods of climate change in the Late Holocene, including the Little Ice Age and Medieval Warm Period, could possibly repeat in the future, having significant worldwide consequences. This holds especially true for tropical and subtropical karst environments, where limited paleoclimate proxies provide minimal data regarding past climate change. An investigation into past climate change in Belize using fulvic acids from cave sediments shows periods of drought during the collapse of the Maya society around 1400 years ago. Comparison of changes in the carbon isotope data from the fulvic acids agree with speleothem records, but more closely reflect changes in the vegetation above the cave, showing Maya population decline through waning agriculture. Further investigation of using fulvic and other organics acids are examined from cave sediments in Florida. The data show fulvic acid carbon isotopes are the most robust recorders of climate change, agreeing with several nearby speleothem d¹8O and d¹³C records from west-central Florida. A more detailed record of climate change in Florida through a calibration study of precipitation and cave dripwater oxygen and hydrogen isotopes revealed that the amount effect dominates rainfall in west-central Florida. Homogenization of epikarst dripwater gives average d¹8O values representative of the annual amount-weighted average of precipitation d¹8O for the area, suggesting speleothem isotope records reflect changes in rainfall amount. Examination of two speleothems from west-central Florida show complex teleconnection and solar forcing mechanisms responsible for past climate changes. A high-resolution stable isotope, trace element, and time series analysis study for the last 1500 years shows variability during the LIA and MWP, pointing to a combined influence of Pacific and Atlantic teleconnection mechanisms, especially the ITCZ, NAO and PDO, being responsible for precipitation variability. Long-term reconstruction of the mid-Holocene and Late Pleistocene from another speleothem reveals differences in temperature and precipitation between glacial and interglacial conditions in Florida. Climate proxies from the tropics and subtropics provide additional clues to global climate change crucial to understanding future water availability.

The Helium isotopic system provides novel tools to probe the sedimentary record of the earth over the last few hundred million years. Radiogeneically derived \(^4He\) and solar wind implanted \(^3He\) is delivered to sediments by weathered continental material and interplanetary dust particles, respectively. The purpose of research presented in this thesis is to use \(^4He\) of terrestrial and \(^3He\) of extraterrestrial origins as tools to investigate the relationship between global climate and surface processes on earth. I measured \(^4He\) in annual growth bands in a Porites coral from the northern Red sea, lacustrine carbonate sediments from the Bahamas and marine sediments in the North Atlantic (Ocean Drilling Program site 1313). Terrestrially derived fraction of the measured \(^4He\) in the Red Sea Porites coral and carbonates of the Bahamas together provide accurate information about changes in dust export rates from North Africa over the last millennium; dust fluxes are intimately tied to droughts in North Africa at decadal to centennial time scales over the last millennium that in turn, appears to be modulated by sea surface temperatures (SSTs) in the Indian and the Atlantic Ocean. On the other hand, \(^4He\) content in marine sediments in the North Atlantic provide information about changes in sources of detrital over the last six million years that in turn appears to reflect changes in ocean circulation in the sub-polar north Atlantic. Accretion rates of solar wind implanted \(^3He\) provide independent constraints on time distribution and physical processes operational during the deposition of marine sedimentary sequences. I measured extraterrestrial \(^3He\) in sediments from the late Cretaceous through the early Danian at one site in the North Pacific (Ocean Drilling Program site 1209 on the Shatsky Rise) and in three sites from the South Atlantic (Deep Sea Drilling Projects sites 516F on Rio De Grande Rise and 528 on the Walvis Ridge). The high-resolution record of extraterrestrial \(^3He\) at the Shatsky Rise demonstrates that there was no increase in solar system dustiness associated with the meteorite impact thought to be responsible for the end cretaceous mass extinction. The assumption of constant delivery of extraterrestrial material therefore resulted in independent constraints on sediment accumulation rates and resultant age model through the early Danian, the latter marking the recovery of ocean system following the events of the end Cretaceous mass extinction. On the other hand, the extraterrestrial \(^3He\) derived mass accumulation rates in the south Atlantic sites demonstrate that carbonate-clay cyclicity in sediments—used by cyclostratigraphy to derive age models—are generated by different physical processes at different sites. It is therefore, crucial to understand processes underlying the carbonate-clay cyclicity before interpreting sediment couplets in terms of age model. / East Asian Languages and Civilizations

A dearth of reliably-dated paleolake records from the southern Basin and Range has limited knowledge of past water balance changes there, precluding a more complete understanding of late Pleistocene atmospheric circulation across western North America. Paleoshorelines in closed basins throughout the region can provide accurately dated records of local effective moisture variations, representing a largely untapped source of paleohydrologic information. This dissertation presents paleohydrologic reconstructions from depositional successions in two basins at 32°N, approximately 100 km apart: Willcox basin, in southeastern Arizona, and Playas Valley, in southwestern New Mexico. Also presented are the results of ¹⁴C dating of charcoal samples from the El Fin del Mundo Clovis archaeological site, in northwestern Sonora, Mexico. In depth analysis of these results allowed constraint of the "small sample effect" on the charcoal ages, found to be smaller than 1σ of analytical uncertainty. The magnitude of the problem in ages from miniscule shell samples in the Willcox and Playas chronologies was found to be similar. The successions record moist pluvial conditions from ~20-13 ka in Playas, and>37-11 ka in Willcox, with most dates younger than 19 ka--before which there is no solid evidence for lake transgressions. There is clear evidence for overlapping highstands between ~18.3 and 17.9 ka and a brief highstand of Cochise at ~12.9 ka, coinciding with Heinrich events H1b and H0, respectively. Temporal concordance between wet periods and perturbations in the North Atlantic ocean and/or southern Laurentide ice sheet supports the idea that abrupt paleoclimatic changes in the southwestern U.S. occurred in response to large-scale atmospheric linkages to the northern high latitudes. The H1b highstands fill a hiatus in ¹⁴C dates compiled from paleoshorelines throughout the western U.S., and correspond to the first part of a lowstand in paleo-Lake Estancia (35°N), in north-central New Mexico. Anti-phasing within New Mexico suggests that the newly documented highstands resulted from an increase in southerly-sourced precipitation. This is consistent with paleoenvironmental evidence from southern Arizona and New Mexico that points toward periodic intensification of the summer monsoon during the late Pleistocene.

The main objective of this dissertation is to improve the knowledge of glacial chronology and paleoclimate of Turkey during the Late Quaternary. The 36Cl cosmogenic exposure ages of moraines show that Last Glacial Maximum (LGM) glaciers were the most extensive ones in Turkey in the last 22 ka (ka=thousands years), and they were closely correlated with the global LGM chron (between 19&plusmn;23 ka). LGM glaciers started retreating 21.3&plusmn;0.9 ka (1&sigma;) ago on Mount Erciyes, central Turkey, and 20.4&plusmn;1.3 ka ago on Mount Sandiras, southwest Turkey. Glaciers readvanced and retreated by 14.6&plusmn;1.2 ka ago (Late Glacial) on Mount Erciyes and 16.2&plusmn;0.5 ka ago on Mount Sandiras. Large Early Holocene glaciers were active in Aladaglar, south-central Turkey, where they culminated at 10.2&plusmn;0.2 ka and retreated by 8.6&plusmn;0.3 ka, and on Mount Erciyes, where they retreated by 9.3&plusmn;0.5 ka. The latest glacial advance took place 3.8&plusmn;0.4 ka ago on Mount Erciyes. Using glacier modeling together with paleoclimate proxy data from the region, I reconstructed the paleoclimate at these four discrete times. The results show that LGM climate was 8-11oC colder than today (obtained from paleotemperature proxies) and wetter (up to 2 times) on the southwestern mountains, drier (by ~60%) on the northeastern ones and approximately the same as today in the interior regions. The intense LGM precipitation over the mountains along the northern Mediterranean coast was produced by unstable atmospheric conditions due to the anomalously steep vertical temperature gradients on the Eastern Mediterranean Sea. In contrast, drier conditions along the southern Black Sea coast were produced by the partially ceased moisture take-up from the cold or frozen Black Sea and prevailing periglacial conditions due to the cold air carried from northern hemisphere's ice sheets. Relatively warmer and moister air from the south and overlying cold and dry air pooled over the northern and interior uplands created a boundary between the wet and dry LGM climates somewhere on the Anatolian Plateau. The analysis of Late Glacial advances suggests that the climate was colder by 4.5-6.4oC based on up to 1.5 times wetter conditions. The Early Holocene was 2.1oC to 4.9oC colder on Mount Erciyes and up to 9oC colder on Aladaglar, based on twice as wet as today's conditions. The Late Holocene was 2.4-3oC colder than today and the precipitation amounts approached the modern levels. Glaciers present on Turkish mountains today are retreating at accelerating rates and historical observations of the retreat are consistent with the behavior of other glaciers around the world.

Holocene climate variability in the British Columbia Coast Mountains has resulted in repeated intervals of glacier expansion and retreat. Since reaching their late Holocene maximum positions in the late 20th century, glaciers in the region have experienced significant volumetric loss. The subsequent downwasting and frontal retreat has revealed forests buried by glacier advances throughout the Holocene, enabling description of significant intervals of ice expansion using dendroglaciology. This thesis characterizes dendroglaciological evidence as it relates to climate at two scales: (1) at Franklin Glacier in the Mt. Waddington area, and; (2) throughout the Coast Mountains. Dendroglaciological evidence from glacier forefields and lateral moraines in the Coast Mountains provides evidence for at least 11 intervals of glacier activity during the Holocene. The earliest record glacier activity is documented in the Pacific Ranges from 8.5 to 7.8 ka, after which glaciers in this region retreated during the early Holocene warm and dry interval. Following this a glacial advance from 6.7 to 5.6 ka was followed by a subsequent expansion episode from 5.1 to 4.6 ka in response to attendant cool and moist conditions in the Pacific Ranges. After 4.6 ka, glaciers in the Pacific and Boundary ranges advanced at 4.4 to 4.0 and 3.8 to 3.4 ka during intervals characterized wet conditions resulting from an intense, eastwardly positioned Aleutian Low pressure centre. Following 3.4 ka most glaciers retreated before expanded between 3.2 and 2.8 ka, retreated, and then advanced from 2.6 to 2.4 ka. Glacier advances from 1.8 to 1.1 ka occurred in response to a regional cooling event, and proceeded Little Ice Age advances from 0.6 to 0.4 ka. Franklin Glacier is an 18-km long valley glacier that originates below the west face of Mt. Waddington. Radiocarbon-dated wood samples from the proximal faces of lateral moraines flanking the glacier show that it expanded at least nine times since 13 ka. A probable Younger Dryas advance of Franklin Glacier at 12.8 ka followed the late glacial retreat and downwasting of the Cordilleran Ice Sheet from ca. 16.0 to 12.9 ka. During the succeeding early Holocene warm period, Franklin Glacier appears to have retreated significantly, leaving no record of glacial expansion until the mid-Holocene when it repeatedly advanced at 6.3, 5.4, and 4.6 ka in response to cool summer temperatures and generally moist conditions. Downwasting of the glacier surface after 4.6 ka was followed by intervals of expansion at 4.1, 3.1, and 2.4 ka contemporaneous with a period of increased precipitation. Following ice expansion at 2.4 ka into trees over 224 years in age, there is no record of the glacier activity until 1.5 ka when Franklin Glacier thickened and advanced into young subalpine fir trees, reflecting attendant cool and wet environmental conditions. During the Little Ice Age, advances at 0.8 and 0.6 ka preceded a mid-19th to early-20th century advance that saw Franklin Glacier attain its maximum Holocene extent in response to an extended interval of cold temperatures. The dendroglaciological record at Franklin Glacier is among the most comprehensive recovered from the British Columbia Coast Mountains and showcases the complexity of latest Pleistocene and Holocene glacier behaviour in the region. / Graduate / 0368 / bjmood@uvic.ca

A reconstruction of regional climate variability in southern West Virginia that spans the last glacial/interglacial transition is presented. Paleoclimate interpretations obtained from the 50-cm long stalagmite provide key insights regarding the timing, magnitude, and forcing mechanisms responsible for past climate variability. Stable isotopic (δ18O and δ13C) and trace element (Ba, Sr, Mg) signatures from samples contiguously milled along the growth-axis of a 230Th-dated stalagmite which grew between approximately 20 and 5 thousand years before present (kyr BP) provide critical constraints for above-cave mean annual temperature, seasonality of moisture mean annual precipitation, and potential vegetation shifts. Specifically, the stalagmite record reveals subcentennial-scale variations in the proxy records, and strong multimillennial-scale features that correlate to well-known patterns of sea-surface variability in the North Atlantic Ocean (i.e., Bond cycles). The large-scale glacial/interglacial transition is sufficiently resolved to show that regional climate changes largely paralleled climatic transitions preserved in low-latitude (Chinese monsoon records; Cariaco Basin) and high-latitude (Greenland Ice Sheet) paleo-archives. However, the Younger Dryas interval in the south-central Appalachian Mountains is not as prominent a feature as in other records.

In this study reef corals from two Caribbean and adjacent regions in different periods were investigated. Sclerochronological records of corals from well preserved Miocene to Pleistocene reefs were used to document potential changes in seasonal and interannual climate associated with CAS uplift and closure. In southern Florida the Plio/Pleistocene Caloosahatchee Formation is cropping out. During the deposition of this stacked shallow marine sediments at the Plio/Pleistocene Florida carbonate platform, a rich coral fauna existed. Corals from the Caloosahatchee Formation were investigated herein, regarding to reveal high resolution (bimonthly) climatic archives in their skeletons. The second region investigated herein is the Cibao Valley in the Dominican Republic, where sediments of the Neogene Yaque Group are outcropping. Corals from the Late Miocene Cercado Formation and the Mio/Pliocene Gurabo Formation (both upper part of the Yaque Group) are discussed here. Both formations are mixed carbonate-siliciclastic deposits of the prograding inner-shelf and contain a well preserved faunal record. Sclerochronological methods are used to identify seasonal and interannual climatic variability. Especially radiography, stable isotope analysis and laser ablation measurements (LA-ICP-MS) were used and discussed with a special focus on the pristine preservation of the analysed coralline material.

The triumvirate of tectonics, lithology, and climate control landscape evolution. This study quantifies how lithologic variation and climate-mediated changes in ecosystems perturb steady state processes in the unglaciated, soil-mantled Oregon Coast Range (OCR). I first demonstrate that minor grain-scale differences in rock properties in a seemingly uniform sandstone control differences in rock strength, biotic bedrock-to-soil production efficacy, and erosion rates and influence relief at the watershed scale. I then build on sedimentology, paleoecology, and isotopic-derived paleoerosion data I collected from a new 50 ka sediment archive at Little Lake, OR to explore climate controls on soil production and erosion rates 21 ka across the OCR and spanning 50 ky within a single watershed. In Chapter III, I combine a mechanistic frost weathering model with a regional Last Glacial Maximum (LGM) climate reconstruction and paleovegetation data to demonstrate that accelerated frost-driven erosion was pervasive across the OCR during the LGM. My findings provide a new framework to quantify how the late Pleistocene affects modern erosion and soil formation rates in unglaciated environments and implies that most landscapes reside in a transient state. In Chapter IV, I document climate-mediated ecosystem influence on erosion rates over 3 climatic intervals. 10Be-derived erosion rates increase 3x (from 0.6 mm/yr to 0.21 mm/yr) as the OCR transitioned from the open forest-dominated marine isotope stage (MIS) climate interval (50-26 ka) into the periglacial subalpine MIS 2 glacial interval (26-13 ka). Measured erosion rates fell by more than half as the subalpine ecosystem gave way to the modern MIS 1 closed canopy Douglas-fir forest. Coupling paleovegetation-derived climate information with core observations I model frost weathering intensity from ~ 43 ka to 21 ka and establish a correspondence with increasing frost weathering intensity and increasing 10Be-derived erosion rates. Utilizing a transient mixing depth and erosion rate model, I am able to broadly replicate measured erosion rates at Little Lake through time. My findings contradict previous work that suggests climate has only weak control on erosion rates. This dissertation includes previously published and unpublished co-authored material.

When measuring weathering intensity of paleosols there arevarious methods and ratios that can be used. This studyexamines several weathering indicators too see which are bestapplied and most effective on loess and paleosols from Yukon,Canada. This region today is considered sub-arctic, but duringpast time this area and its soils has been characterized byglaciations and interglaciations. These changes are the origin ofthe unweathered Kluane loess and the weathered Slims Soilthat are analyzed in the study. Methods used to determine themost sensitive weathering indicator was; CIA (the ChemicalIndex of Alteration), CPA (the Chemical Proxy of Alteration),oxide ratios ((CaO + Na2O + MgO)/TiO2 and (CaO + Na2O +K2O)/TiO2), and elemental ratios (Rb/Sr, Ba/Sr, Ti/Sr). Theresults from the CIA and oxide ratios show that calcium is thevarying factor, and thereby a good weathering indicator forthese samples. The elemental ratios showed a great variationbetween weathered and unweathered samples, and a cleardecrease strontium is apparent. These ratios would also beuseful indicators, but since Sr is associated with Ca, it isprobably calcium that is the main feature. The methods withoutcalcium as a factor did not give any clear separation betweenKluane loess and Slims Soil. Thereby it is concluded that proxyscontaining Ca are the most useful indicators of weathering inthis area.