The production of hydrogen gas, through the process of water splitting,is one of the most promising concepts for the production of clean andrenewable fuel.The introduction of this thesis provides a brief overview of fossil fuelsand the need for an energy transition towards clean and renewable energy.Hydrogen gas is presented as a possible candidate fuel with its productionthrough artificial photosynthesis, being described. However, the highlykinetically demanding key reaction of the process – the water oxidationreaction – requires the use of a catalyst. Hence, a short presentation of differentmolecular water oxidation catalysts previously synthesized is also provided.The second part of the thesis focuses on ruthenium-based molecularcatalysis for water oxidation. Firstly, the design and the catalytic performancefor a new series of catalysts are presented. Secondly, a further study onelectron paramagnetic resonance of a catalyst shows the coordination of awater molecule to a ruthenium centre to generate a 7-coordinated complex atRuIII state. Finally, in an electrochemical study, coupled with nuclear magneticresonance analysis, mass spectrometry and X-ray diffraction spectroscopy, wedemonstrate the ability of a complex to perform an in situ dimerization of twounits in order to generate an active catalyst.The final part of this thesis focuses on immobilisation of first rowtransition metal catalysts on the surface of electrodes for electrochemical wateroxidation. Initially, a copper complex was designed and anchored on a goldsurface electrode. Water oxidation performance was studied byelectrochemistry, while deactivation of the electrode was investigated throughX-ray photoelectron spectroscopy, revealing the loss of the copper complexfrom the electrode during the reaction. Finally, we re-investigated cobaltporphyrin complexes on the surface of the electrode. Against the backgroundof previous report, we show that the decomposition of cobalt porphyrin intocobalt oxide adsorbed on the surface is responsible for the catalytic activity.This result is discussed with regard to the detection limit of various spectroscopic methods. / <p>QC 20170529</p>

<p>Razvojem i testiranjem autentičnog modela dokazano je da se primenom multikriterijumske analize uz primenu PROMETHEE metode može kreirati funkcionalan, operativan i primenljiv alat za dizajniranje energetskih politika orijentisanih ka podršci razvoja obnovljivih izvora energije. Model je testiran na energetskom profilu Grada Novog Sada. Pretpostavljeno je da lokalne vlasti Grada Novog Sada imaju nameru da dizajniraju razvojnu politiku/meru sa ciljem da podstaknu korišćenje obnovljivih izvora energije za grejanje stambenih objekata (porodičnih kuća) i pripremu tople sanitarne vode.</p> / <p>Development and testing of an authentic model has proven that the application of multi-criteria analysis by applying the PROMETHEE method can create a functional, operational and applicable tool for designing energy policy oriented towards supporting the development of renewable energy sources. It is assumed that local authorities in Novi Sad have the intetion to design development policies / actions in order to promote the use of renewable source for heating residental buldings (family houses) and hot water.</p>

There is a vision in the EU for a transition to a low carbon society, including a carbon-neutral energy system, containing a high share of renewable energy. However, this vision is not isolated from other political goals, such as halting the loss of biodiversity by 2020. Both of these goals are accompanied by EU legislation promoting their respective aims. One of the central challenges, in light of this transition, is the very nature of the legal system – that it is rather fragmented – both regarding the substantive law applicable to renewable energy activities and the legal processes that renewable energy activities face. The aim is therefore to discuss certain challenges arising from the fragmented legal system applicable to renewable energy activities. The dissertation is based on EU and Swedish law. First, I investigate the EU’s competence in the field of renewable energy and address how such policy may better reflect the protection of biodiversity. Thereafter, in a Swedish context, I analyse the relationship between protection of biodiversity and promotion of renewable energy. Finally, I address the problems arising from the fragmented legal procedures of renewable energy activities, with the main example of wind power installations and new transmission lines. In general, this study suggests that the current system lacks consistency between renewable energy and nature protection legislation and there is a coordination problem with regards to the permit processes of the development of renewable energy activities. These conclusions point towards a need for a broader perspective on the development of renewable energy activities, which could include: a more integrated planning system for renewable energy activities; exploring the use of derogation rules from the Water Framework Directive; and a more integrated EU renewable energy policy with specific sustainability criteria.

Buildings both commercial and residential are the largest consumers of electricity. Integrating Photovoltaic technology in building architecture or Building Integrated Photovoltaics (BIPV) provides an effective means for meeting this huge energy demands and provides an energy hub at the place of its immediate requirement. However, this technology is challenged with problems like low efficiency and high cost. An effective way of improving the solar cell efficiency and reducing the cost of photovoltaic systems is either by reducing solar cell manufacturing cost or illuminating the solar cells with a higher light intensity than is naturally available by the use of optical concentrators which is also known as Concentrating Photovoltaic (CPV) technology. Integrating this technology in the architecture is referred as Building integrated Concentrating Photovoltaics (BICPV). This thesis presents a detailed performance analysis of different designs used as BICPV systems and proposes further advancements necessary for improving the system design and minimizing losses. The systems under study include a Dielectric Asymmetric Compound Parabolic Concentrator (DiACPC) designed for 2.8×, a three-dimensional Cross compound parabolic concentrator (3DCCPC) designed for 3.6× and a Square Elliptical Hyperbolic (SEH) concentrator designed for 6×. A detailed analysis procedure is presented showcasing the optical, electrical, thermal and overall analysis of these systems. A particular issue for CPV technology is the non-uniformity of the incident flux which tends to cause hot spots, current mismatch and reduce the overall efficiency of the system. Emphasis is placed on modelling the effects of non-uniformity while evaluating the performance of these systems. The optical analysis of the concentrators is carried out using ray tracing and finite element methods are employed to determine electrical and thermal performance of the system. Based on the optical analysis, the outgoing flux from the concentrators is predicted for different incident angles for each of the concentrators. A finite element model for the solar cell was developed to evaluate its electrical performance using the outputs obtained from the optical analysis. The model can also be applied for the optimization of the front grid pattern of Si Solar cells. The model is further coupled within the thermal analysis of the system, where the temperature of the solar cell is predicted under operating conditions and used to evaluate the overall performance under steady state conditions. During the analysis of the DiACPC it was found that the maximum cell temperature reached was 349.5 K under an incident solar radiation of 1000 W/m2. Results from the study carried on the 3DCCPC showed that a maximum cell temperature of 332 K is reached under normal incidence, this tends to bring down the overall power production by 14.6%. In the case of the SEH based system a maximum temperature of 319 K was observed on the solar cell surface under normal incidence. An average drop of 11.7% was found making the effective power ratio of the system 3.4. The non-uniformity introduced due to the concentrator profile causes hotspots in the BICPV system. The non-uniformity was found to reduce the efficiency of the solar cell in the range of 0.5-1 % in all the three studies. The overall performance can be improved by addressing losses occurring within different components of the system. It was found that optical losses occurred at the interface region formed due to the encapsulant spillage along the edges of the concentrator. Using a reflective film along the edge of the concentrating element was found to improve the optical efficiency of the system. Case studies highlighting the improvement are presented. A reflective film was attached along the interface region of the concentrator and the encapsulant. In the case of a DiACPC, an increase of 6% could be seen in the overall power production. Similar case study was performed for a 3DCCPC and a maximum of 6.7% was seen in the power output. To further improve the system performance a new design incorporating conjugate reflective-refractive device was evaluated. The device benefits from high optical efficiency due to the reflection and greater acceptance angle due to refraction. Finally, recommendations are made for development of a new generation of designs to be used in BiCPV applications. Efforts are made towards improving the overall performance and reducing the non-uniformity of the concentrated illumination.

Title: Legislation of renewable energy sources and their use Abstract The presented thesis deals with issues of legal regulation of renewable energy sources with target on legal regulation of system of support in the Czech Republic. The thesis contains the overview of documents and instruments from international enviroment. As a result of the Czech Republic membership in the European Union the thesis presents instruments of union legislation which due to integration of EU member states legislation and due to marking out obligatory goals aims to opened unified and liberal energy market. The thesis describes historical development of this phenomenon from partial legislation to complex and sophisticated legislation and artificially formed systems of support including and puts them into context with social economic aspects of pursued period of time. Due to comparative method the thesis brings not only comparation of legislation in the course of time in Czech and European background but also evaluate them and try to estimate progress and find possible solution. One of the thesis targets is to provide the comprehensive view on legislation of renewable energy sources from businessmen points of view and put this relationship into context with institute of environment protection.

Thesis title: Legal regulation of the use of alternative energy resources The goal of the paper is to analyze the legal regulation of the use of alternative energy sources and to provide a summary and logical overview of this matter that is closely related to environment and climate protection. The greenhouse effect is frequent topic of current debates regarding the climate changes that lead the international communities to decision on limitation of greenhouse gases emissions by using among others renewable energy sources. The reason for my research is a long-term interest in renewable energy sources. The thesis is composed of seven chapters, each of them dealing with different aspects of promotion of the use of alternative energy sources. Chapter One is introductory and provides the overview of the research topic. Chapter Two explains the term alternative energy sources and its relation to renewable energy sources. Chapter Three is divided into two subchapters dealing with international and European aspects of the climate protection and related law. History of the Czech legal regulation of promotion of renewable energy sources is provided in Chapter Four and the main issues are outlined. Chapter Five deals with current Czech legal regulation on promotion of renewable energy sources and provides...

This thesis is focused on the legislation on the renewable energy sources, especially on the mechanisms of promotion granted to the producers of the electricity and heat from the renewable sources of energy. The thesis describes the contemporary regulation in the Czech republic and compares it to the relevant German regulation.

Wind energy has been growing rapidly during recent years. This paper aims to estimate the impact of wind power generation on the Swedish wholesale electricity price, using monthly time series data over the periods 2000-2016. The error-correction model is used to measure the price effect by including other factors that influence the electricity supply and demand. Thefindings suggest that the impact of changes in wind power production on the wholesale priceof electricity is negative in the short-term. When the wind power production increases by 1%, the wholesale electricity price decreases with 0.08%. Furthermore, the magnitude of the coefficient increases to 0.10% in the long-term.

Around 770 million people lack access to improved drinking water sources (WHO 2013), urgently necessitating implementation of contaminant removal by e.g. desalination systems on a large scale. To improve water quality and enable use of brackish water sources for human consumption in remote arid areas, a directly coupled wind – electrodialysis system (Wind-ED) was developed. Modularity, sustainability and above all suitability for the practical use in off-grid locations were the main motivations and design objectives. The direct coupling of wind energy with membranes reduces the system costs as well as technical drawbacks associated with using intermediate energy storage systems. During this research, systematic experiments were performed using the Wind-ED system in order to determine desalination performance and clean water production, specific energy consumption (SEC) and current efficiency (ηc) under relevant conditions, such as varying: i) wind speed, ii) wind turbulence intensity, iii) oscillation periods, iv) varying NaCl concentrations and v) flow rates. Moreover, the competitive removal of four commonly available inorganic contaminants in brackish groundwater sources, nitrate (NO3-), fluoride (F-), sulphate (SO42-) and chloride (Cl-), were investigated. Firstly, to establish a systematic understanding of how and to what extent energy fluctuations influence the transport of the salt (i.e. NaCl) ions across the membranes, experiments were conducted using pulsed electric field assisted electrodialysis (pulsed-ED) over a wide range of frequencies (0.001 – 10 Hz) and duty cycles (20 – 80). The results showed that pulsation applied in the sub-limiting regime resulted in reduced water production, explained by the delays caused by the off-periods during the pulsed desalination process. At higher current densities, pulsation led to considerable improvements in current (e.g. up to 95%, for a feed solution of 500 mg/L and a pulse regime of 1 Hz at 50 V peak voltage) and significant reduction in water dissociation, explained by a reduction of concentration polarisation. Importantly, the pulsation had no significant effect on energy consumption or current efficiency suggesting that ED could be suitable for direct coupling to fluctuating energy sources such as wind energy. ED was consequently coupled to a wind turbine system and a series of desalination tests were performed over a wide range of wind speeds (2-10 m/s), turbulence intensities (TI of 0-0.6) and oscillation periods (0-180 s). Results showed that water production and SEC increased with wind speed. However, both the water production and SEC stopped increasing as the power output from the turbine levelled off at wind speeds above the rated value (vrated: 7.9 – 8.4 m/s). The impact of wind speed fluctuations on the system performance were insignificant up to a TI of 0.4. The desalination performance declined under high turbulence intensity fluctuations (TIs ≥ 0.5) and long periods of oscillation (> 40 s), as the wind-ED system periodically cycled off in response to operation below the cut-in wind speed of the wind turbine (vcut-in: ~ 2 m/s). The off-cycling of the system caused significant delays in the desalination process, and thus resulted in reduced water production. Further reduction in the water production resulted as the wind-ED system operated under intermittent wind speed conditions with off-wind periods longer than 10 s. It was concluded that the main challenge in direct coupling of ED to a wind resource was not the magnitude of the fluctuations but the impact of the power cycling off during long periods of oscillation and lengthy periods of no wind. Interestingly, the SEC of the process remained relatively unaffected by the fluctuations and intermittencies in the wind resource. The effect of energy fluctuations on the competitive transport of F-, Cl-, NO3- and SO42- from artificial brackish water (TDS ~4350 mg/L) was investigated using different sets of real wind data. The ion removal, independent of the wind regime tested, followed the order: NO3- ≥ Cl- > F- > SO42-. The competitive removal of the ions was linked to differences in physicochemical properties (i.e. hydration energy, ionic mobility and valence). The specific selectivity (e.g. preferential transport of NO3- over SO42- ions) was found to increase with concentration polarisation being either minimised (by lowering the mean wind speed) or disrupted (by fluctuations in the wind resource). The results from flow rate and feed concentration experiments, showed that power production of the wind turbine depended on not only the available wind energy but also the resistance of the load (i.e. the ED stack). Thus, increasing the feed concentration and the flow rate resulted in reduced resistance in the ED stack (Rstack), which inversely influenced the current induction counter torque force applied on the shaft of the wind turbine and caused the rotor to spin at a lower angular velocity. This led to increased sensitivity of the wind-ED system to wind speed fluctuations (e.g. system cycled off due to extreme fluctuations and intermittencies with low TDS feed concentration of 2400 mg/L) and hence a reduction of desalination performance. Impact of flow rate on the SEC was found to be negligible; this was attributed to the automatic voltage to current adjustments done by the wind turbine, in order to minimise the impacts of Rstack on the power production by the turbine at a given wind speed. Increased flow rate and resulting shrinkage of the boundary layer’s thickness, caused the concentration profiles at the solution-membrane interface to become steeper. This favoured the transport of ions with the highest diffusion coefficients in the mixture (i.e. Cl- and NO3-). Decreased flow rate favoured the transport of ions with larger valence numbers and higher electric mobility inside the electrolyte (i.e. SO42-); as the former property governed the faster migration of SO42- ions through the thick boundary layer and the latter property assisted with the improved affinity of the ion-exchange membrane to SO42- ions compared to the monovalent anions in the mixture. Increasing the feed concentration of Cl- from 500 to 2,550 mg/L led to reduced transport numbers for the other anions in the mixture and significantly reducing their removal rate. The results obtained from both the pulsed-ED and wind-ED experiments showed that, despite direct coupling to the fluctuating energy source the SEC of the process remained relatively unaffected by the energy fluctuations. Although the desalination process might require more time to be completed when operating under extreme wind speed fluctuations and intermittencies, the quality of the drinking water produced was always within the WHO standards. In conclusion, the findings from this research prove the wind-ED system to be an energetically robust and a reliable off-grid desalination technique suitable for the treatment of brackish groundwater in water stressed remote regions.

A photovoltaic thermal solar collector (PVT) produces both heat and electricity from a single panel. PVT collectors produce more energy, for a given area, than conventional electricity and heat producing panels, which means they are a promising technology for applications with limited space, such as building integration. This work has been broken down into 3 subprojects focusing on the development of PVT technology. In the first subproject an experimental testing facility was constructed to characterise the performance of PVT collectors. The collectors under investigation were assembled by combining bespoke thermal absorbers and PV laminates. Of the two designs tested, the serpentine design had the highest combined efficiency of 61% with an 8% electrical fraction. The header riser design had a combined efficiency of 59% with an electrical fraction of 8%. This was in agreement with other results published in literature and highlights the potential for manufacturers of bespoke thermal absorbers and PV devices to combine their products into a single PVT device that could achieve improved efficiency over a given roof area. In the second project a numerical approach using computational fluid dynamics was developed to simulate the performance of a solar thermal collector. Thermal efficiency curves were simulated and the heat removal factor and heat loss coefficient differed from the experimental measurements by a maximum of 12.1% and 2.9% respectively. The discrepancies in the findings is attributed to uncertainty in the degree of thermal contact between the absorber and the piping. Despite not perfectly matching the experimental results, the CFD approach also served as a useful tool to carry out performance comparisons of different collector designs and flow conditions. The effect of 5 different flow configurations for a header collector was investigated. It was found that the most efficient design had uniform flow through the pipe work which was in agreement with other studies. The temperature induced voltage mismatch, that occurs in the PV cells of PVT collector was also investigated. It was concluded that the temperature variation was not limiting and the way in which PV cells are wired together on the surface of a PVT collector did not influence the combined electrical power output.