Historic mine tailings pose a significant health risk to surrounding ecosystems and communities because of high residual concentrations of contaminant metals. The initial tailings mineral assemblage, metal sulfides, silicates, and carbonates are unstable at earth surface conditions and undergo oxidative and proton-promoted weathering. The weathering of metal sulfides generally produces acid that, if not balanced by protonconsuming dissolution of silicates and carbonates, leads to progressive acidification. The Klondyke State Superfund Site in Graham County, Arizona contains high concentrations of Pb (up to 13 g kg⁻¹) and Zn (up to 6 g kg⁻¹), and remains unvegetated 50 years after mining cessation. Field-scale investigation revealed a wide range of pH (2.5-8.0) and plant-available (DTPA-extractable) metals in the near surface of the tailings pile. Four samples were chosen for in-depth characterization ranging in pH, as denoted by subscript, from 2.6 to 5.4. The mineral transformations occurring in these four samples were investigated using a variety of techniques and the data indicated an increase in tailings weathering extent with increasing acidification (decreasing pH). Lead speciation, studied by a combination of chemical sequential extraction and X-ray absorption fine structure (XAFS) spectroscopy, was found to vary with tailings depth. The principle lead-bearing mineral was plumbojarosite (PbFe₆(SO₄)₄(OH)₁₂), with smaller amounts of anglesite (PbSO₄) and lead-sorbed iron-oxide. Anglesite, the most bioavailable mineral form of Pb in the tailings, was found to accumulate at the tailings surface, which has important implications for health risks. Total Zn content decreased by an order of magnitude (from 6 to 0.4 g kg⁻¹) and showed a change in molecular speciation with decreasing pH. Zinc-rich phyllosilicates and Zn-containing manganese oxides predominate at high pH, whereas low pH samples contained principally Zn-sorbed iron oxides. One of the overarching goals of the project is to remediate the Klondyke site using phytostabilization to keep contaminant metals from eroding offsite either by wind or water transport mechanisms. However, the impacts of plant growth on metal bonding environment are unknown. To address that gap in knowledge, we have developed a technique for the study of root-microbe-mineral-metal interactions that occur in the rhizosphere, the volume of soil surrounding, and affected by, plant roots. This technique involves the conjunctive use of fluorescence in-situ hybridization, X-ray fluorescence elemental mapping, XAFS and Raman micro-spectroscopies, and electron microscopy on single roots. Manganese and iron root plaques collocalized with elevated Pb, Zn, and Cr demonstrate that the rhizosphere can affect metal speciation. Metal speciation is an important factor in determining metal bioavailability, and thus is critical for understanding the health risk associated with mine tailings. The results of this research provides site-specific information about Pb and Zn speciation, which will be used to evaluate the effectiveness of site remediation within the context of metal toxicity.

No description available.

This study aims to assess the potential environmental risks posed by sediments in five lakes affected by present or historical metallurgy. Special attention is paid to the lakes Dammsjön and Värlingen in mid Sweden, where the sediments were contaminated after a breach in a nearby tailings dam used for storing residue from a metal processing plant. The sediments were examined for their metal content by X-ray fluorescence spectroscopy (XRF) analysis of loose powder samples. A subset of the samples from Dammsjön and Värlingen was also used for a simple pH-analysis and an experimental XRF analysis of evaporated leachate. To obtain a larger variety of samples for the XRF analysis of evaporated leachate, loose powder sediment and leachate from three additional lakes affected by extractive metallurgy, Tisken, Gruvsjön and Storjuktan, were likewise examined with XRF. The sediments from all lakes contained high levels of metals, and environmental standards for Pb (in all lakes) and Cd (in Storjuktan) were exceeded. The leachate tests showed that metals can be extracted using this method, including Cu and Ni in lake Tisken. This might indicatehigher bioavailability, but further studies are needed to confirm this interpretation. Dammsjön andVärlingen are contaminated by several metals, including Hg and As. The pH-analysis indicated that the deposited sediment is not the source of the prolonged low pH in Dammsjön, and that another source, possibly continued leaks from the tailings dam, needs to be found. The results call for close environmental monitoring, to minimise further contamination and damage to the environment.

Phytostabilization is a remediation technology that uses plants for in-situ stabilization of contamination in soils and mine tailings. The objective of this study was to identify native plant species with potential for phytostabilization of the abandoned mine tailings in Nacozari, Sonora in northern Mexico. A flora of 42 species in 16 families of angiosperms was recorded on the tailings site and the abundance of the most common perennial species was estimated. Four of the five abundant perennial species showed evidence of regeneration: the ability to reproduce and establish new seedlings. A comparison of selected physicochemical properties of the tailings in vegetated patches with adjacent barren areas suggests that pH, electrical conductivity, texture, and concentration of potentially toxic elements do not limit plant distribution. For the most abundant species, the accumulation factor for most metals was <1, with the exception of Zn in two species. A short-term experiment on adaptation revealed limited evidence for the formation of local ecotypes in Prosopis velutina and Amaranthus watsonii . Overall, the results of this study indicate that five native plant species might have potential for phytostabilization of the Nacozari tailings and that seed could be collected locally to revegetate the site. More broadly, this study provides a methodology that can be used to identify native plants and evaluate their phytostabilization potential for similar mine tailings.

A dissertation submitted to the Faculty of Engineering and the Built Environment, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Master of Science in Engineering. / The reliability of using isotropically consolidated specimens in the laboratory determination of liquefaction characteristics of cohesionless sands, as is common practice today, is evaluated. Two series of triaxial tests involved the conventional undrained loading of isotropically and anisotropically consolidated specimens. The third series of tests utilized anisotropically consolidated specimens loaded by following special undrained stress paths. Test results revealed that liquefaction characteristics obtained from isotropically and anisotropically consolidated specimens are different. The effective angles of friction mobilized at peak shear stress and at steady state were greater for anisotropically consolidated specimens. Loading stress path is seen to have no effect on the liquefaction characteristics derived from conventional loading of anisotropically consolidated specimens. The critical stress ratio line is observed to be the line determining the initiation of liquefaction so that any stress path attempting to cross this line, regardless of direction of approach, immediately shows strain-softening behavior leading to liquefaction. / AC 2018

Erosion on the slopes of mine tailings represents one of the most important environmental problems arising from the disposal of mine tailings. Tailings dam erosion is the main source of pollution that contaminates agricultural land and streams around mining areas. There is an urgent need to reduce erosion of the slopes of mine tailings in-order to limit further devastation of natural ecology. The present study investigates the possible use of cement to reduce erosion of the slopes of mine tailings dams. The pinhole erosion test was used to measure erodibility of tailings stabilized with cement. The strength properties of cement-stabilized tailings have been evaluated by the unconfined compression test. Conbex and ordinary Portland cement have been used for tailings stabilization, with contents of 0, 3, 5, 7, and 10% by mass. It has been established that cement can be used to reduce erosion of the slopes of mine tailings dams. At least 3% by mass cement is required to produce zero erosion loss. The resistance of tailings to erosion can be enhanced by increasing compaction density, curing period and cement content. Ordinary Portland cement produced higher strengths and erosion resistance than Conbex, although Conbex may be useful for stabilizing fine tailings. Cement-stabilized tailings could be used to make bricks and rubble for use in reducing erosion of the slopes of mine tailings dams. As little as 10% of cement is necessary to produce unconfined compressive strengths of 1600- 2600 kPa.

Thesis (M. Environmental Science)--North-West University, Potchefstroom Campus, 2008.

A common challenge during deposition of slurries is segregation as large particles settle through the matrix of fines and water. Whether segregation occurs or not depends on the grain size distribution of the solids, the void ratio or solids content and the rheological properties of the fines-water matrix. The rheological characterization of slurry composed of different grain sizes and varying water chemistry was investigated. The vane yield stress was used to characterize different slurries composed of clay, silt and sand materials. Semi-empirical fractal theory showed good agreement with experimental data for fine slurry. Comparison of yield stress at same concentration but different composition showed a decreasing trend as the composition of either silt or sand material increases. The pore-water effect was studied for representative kaolinite slurry. The yield stress was insensitive for pH values in the acidic and neutral range, while in the basic range it showed significant response depending upon the type of the chemical used to achieve the pH: Ca(OH)2 and NaOH. A modified segmented standpipe was designed and used in a series of experiments to determine concentration profiles during the sedimentation processes. Analyses of the solid content profiles and sand content profiles in the standpipes indicated a capture of sand particles which could be correlated to the yield stress of the fines matrix. Theoretical calculations, however, showed over-prediction of the captured sand size. A correction factor of about 0.2 was applied. Flume test on a high solid content slurries showed that the dynamic segregation is governed by all the factors governing the static case. Beaching profile shapes were not a necessary indication of segregating and non-segregating type of slurries. Modified version plastic theory for flow slides was used to characterise profile shape. Computational fluid dynamics approaches based on kinetic theory and bi-viscous model analysis were implemented and showed a reasonable capability in modelling segregation when compared with experimental results. A statistical formulation for segregation index, SI, was proposed. The index accounts for variation in depth of samples. Finally recommendations for future research are proposed based on the observations and findings made from the study. / Geotechnical Engineering

Commercial Magnafloc 1011and in-house synthesized Al-PAM were used as flocculants for model tailings, laboratory extraction tailings and tailings from paraffin froth treatment unit. The polymers were tested for their flocculation ability in settling and filtration. For model tailings, both polymers showed excellent ability to improve the settling and filtration performance. Magnafloc 1011 is found sensitive to overdosing, but Al-PAM is not sensitive to the dosage within the tested range. For the laboratory extraction tailings, both polymers showed excellent ability to enhance settling. Al-PAM performed very well as a filtration aid. The moisture of the cake obtained from tailings derived from a low fines ore was 6.6 1.2wt% and that from a high fines ore was 16.9 0.8wt%. However, Magnafloc 1011 was found not effective as a filtration aid. For the froth treatment tailings, Al-PAM improved the settling and filterability dramatically. Although the moisture of the cake obtained was 42.5wt%, no free water is seen visually in the cake. The solid cake is self-supportive and remains intact. This class of Al-PAM polymers can provide an alternative approach for oil sands tailings disposal that can potentially eliminate tailings ponds. / Chemical Engineering

Modified cellulase enzyme assay methods were developed to determine the potential of using enzyme activities to evaluate the decomposition of organic matter in carbon amended mine tailings systems. Cellulase assays are commonly performed in soil science applications, industrial production and bio-energy research to determine organic matter response to physical, chemical or temporal variation but, they have not been applied in a mine waste environment. Heavy metal content is considered to be a potential inhibitor to cellulase enzyme activity. Using samples collected from Greens Creek Mine in Juneau, Alaska, USA, the modified assay was evaluated to develop a method that provided reproducible results. It was determined that a sample mass of three grams is sufficient to provide consistent enzyme measurements. Each sample location was characterized by four replicates to ensure statistically representative data. Matrix interferences were determined to be inconsequential in this system. Despite the low organic content amended to the tailings, heavy metal content and potentially low enzyme activity, the modified enzyme assay method provided reproducible enzyme measurements. Following the development of the cellulase assays, spatial and temporal variations in cellulase enzymes were investigated from carbon amended tailings samples collected at the Greens Creek Mine. Six test cells, containing a mixture of tailings and a combination of peat, spent brewery grain and/or municipal biosolids were sampled in the fall of 2005, 2007 and 2009. Exo-(1,4)-β-D-glucanase (EC 3.2.1.91), Endo-(1,4)-β-D-glucanase (EC 3.2.1.4) and β-glucosidase (EC 3.2.1.21) enzymes were assayed from core sections at five different depths. Enzyme activities were compared to sulfate reducing and acid producing bacterial enumerations, sulfide trends and carbon content. General trends were consistent between enzyme activity and SRB enumerations. The range of total carbon values fell between 3 and 5 wt % in each test cell while the average inorganic carbon content was 3.5 wt %. The range of organic carbon content was between 0.2 and 1.2 wt %. Total, inorganic and organic carbon values were more characteristic of test cell carbon distribution. Cellulase enzyme assays provide valuable information regarding the degradation of cellulose and hemi-cellulose. This study demonstrates that enzymes can be monitored in a tailings environment and that enzyme assays conducted for monitoring purposes may be a useful practice to indicate the sustained or declining performance of organic matter in a carbon amended remedial system.