The present study investigates microcracking and damage progression in IM7/977-2, IM7/5555, and IM7/5276-1 [0/90/90/0] laminates. For each material system, seven to eight small coupons were axially loaded in a tensile substage. At increments of around 50 MPa the surfaces of the specimens were inspected via optical microscopy so that a history of microcracking damage as a function of applied loading could be charted. In the IM7/977-2 laminates microcracks were found to initiate on average at around 1050MPa; microcracking initiation for the other two systems was around 850 to 900 MPa. Also, the IM7/977-2 system displayed a steeper increase in crack density as a function of applied loading than the other two systems. The IM7/5555 system was the only system that achieved a microcracking saturation density; the saturation density was found to be around 17 cracks per centimeter. While the IM7/977-2 and IM7/5276-1 systems typically broke into two pieces at failure, the IM7/5555 specimens shattered into pieces. In addition, delaminations were observed in a majority of the IM7/5555 specimens at loadings 250MPa under the failure loads.

A madeira apresenta diferentes comportamentos, dependendo das solicitações às quais está sujeita. Em geral, a madeira pode resistir a solicitações de maior magnitude se a ação ocorre num curtíssimo intervalo de tempo. A propriedade mecânica envolvida nestes casos é a tenacidade, cujos valores são determinados em ensaios de impacto na flexão. Diversas aplicações relacionadas à madeira dependem da mencionada propriedade, não muito estudada para as madeiras usualmente empregadas no Brasil. Com o intuito de preencher tais lacunas o presente trabalho foi realizado para avaliar a influência da umidade e da orientação dos anéis de crescimento da madeira no valor da sua tenacidade. Para isso foram utilizadas as espécies Angelim Saia (Vatairea sp), Eucalipto Citriodora (Eucalyptus citriodora), Eucalipto Grandis (Eucalyptus grandis), Pinus Elliottii (Pinus elliottii), com corpos-de-prova convenientemente amostrados e climatizados. Além disso foram quantificadas as relações entre: a tenacidade e a densidade da madeira a 12% de umidade; a tenacidade e a resistência da madeira à compressão paralela às fibras; a tenacidade e a resistência convencional da madeira no ensaio de flexão estática. Para isto foram considerados os resultados obtidos para trinta e seis espécies tropicais brasileiras, sendo no mínimo doze amostras por espécie. / Wood often exhibits different behavior, depending on the kind of acting forces. Usually, wood can resist to greater solicitations if short time intervals are considered. The mechanical property involved in these situations is toughness, which values are determined in impact bending tests. Several basic uses of timber depend on the toughness, property not widely studied to tropical species grown in Brazil. This work, which was conducted to improve this situation, aimed to evaluate the influence of moisture content and grain angle in values of toughness. In order to reach these objects, species like Angelim Saia (Vatairea sp), Eucalipto Citriodora (Eucalyptus citriodora), Eucalipto Grandis (Eucalyptus grandis), Pinus Elliottii (Pinus elliottii), were employed, with well-sampled and climatized specimens. Besides, relationship between toughness and wood density at 12% of moisture, toughness and wood strength at compression parallel to the grain, toughness and modulus of rupture in static bending test were determined. To reach these subjects, results obtained for thirty six tropical species grown in Brazil, no less than twelve especimens for specie, were considered.

Durante os anos desde 1910, diversos trabalhos científicos foram desenvolvidos, tornando o processo de têmpera bem estabelecido nas plantas industriais. Atualmente, existem diferentes tipos de têmpera e mais técnicas estão sendo desenvolvidas para aumentar as propriedades de componentes de aço. Um deles é o de têmpera intensiva, que pode ser considerado como um processo relativamente novo. O método de têmpera intensiva visa otimizar o processo produtivo, ao mesmo tempo em que diminui consideravelmente o custo da etapa de tratamento térmico. Além disso, atualmente o uso de soluções ambientalmente amigáveis torna este processo bem menos agressivo ao planeta. Neste trabalho realizou-se a têmpera intensiva e a têmpera convencional em corpos de prova preparados para teste de tenacidade à fratura. Trata-se, porém, de um método alternativo de teste, relativamente recente, no qual são considerados parâmetros de fratura dúctil e fratura frágil para o cálculo de K1C. Estes ensaios de tenacidade foram feitos a partir de ensaios de tração em corpos de prova com pré-trinca. Embora as tensões residuais compressivas tenham atingido os valores mais altos na têmpera intensiva, os resultados de tenacidade à fratura foram mais positivos para as amostras com têmpera convencional. A junção e aplicação desses métodos pode trazer um novo parâmetro de fabricação e análise de materiais metálicos, em especial aços-mola, que foi o objeto de estudo deste trabalho. / Since the beginning of 20th Century, several scientific works were developed and conventional quenching process became well established into the industrial area. Nowadays new quenching process were introduced increasing mechanical properties of the heat treated components. Intensive quenching is one of these process which optimize the heat treatment process using also quenchants considered nontoxic to the environment. In this work it was made comparative studies in the SAE 5160 samples which were submitted to conventional quenching and intensive quenching. Toughness fracture were evaluated using an alternative test where are analyzed ductile fracture and brittle fracture parameters to calculate KIC. In this method tensile test are performed in pre-cracked samples. Residual stresses were also measured and although intensive quenching promoted highest compressive stresses in the surface, KIC obtained in such samples presented low values compared with conventional quenching. The presented method of analysis will bring a new parameter for production and analysis for metallic materials, particularly spring steel, where compressive stress and toughness are important as properties for suspension components.

This study reports a novel and simple technique for successfully coating multi-walled carbon nanotubes (MWCNTs) on to the surface of carbon fibre (CF) fabric for the production of multi-scale CF-epoxy composites. Initially, epoxy composites with multi-scale reinforcement were produced by resin infusion (RI) using woven CF fabric coated with a dispersion of 1 wt. % MWCNTs in an epoxy binder of low molar mass. The effects of this reinforcement on the CF-epoxy interface with MWCNTs was studied in mode I and mode II interlaminar fracture toughness (ILFT) using double-cantilever beam (DCB) and 4 point end-notch flexure (4ENF) tests, respectively. Relative to an equivalent composite reinforced with non-coated CF reinforcement, the binder/MWCNTs coating increased significantly the ILFT of the CF-epoxy composite; in mode I by 105% and in mode II by 50%. This increase in ILFT was attributed to two main effects: Firstly, the binder alone (without MWCNTs), which has a much lower glass transition temperature (Tg) than that the matrix (45 vs. 140 °C), hindered crack propagation and increased the ILFT of the epoxy matrix by 25% for mode I and 15% for mode II; Secondly, the energy absorbing mechanisms of MWCNTs during fracture particularly pull-out and crack bridging. However the Tg of the matrix epoxy of the multi-scale composites was reduced to 118 °C compared to 140 °C, for the unmodified composite, due to phase mixing with the low Tg binder. For RI processing, the CF volume fraction of the composites prepared using coated CF was ≈50% compare to at ≈55% for the composite with non-coated CF. Curing agents were added to the binder, which not only increased the Tg from ≈50 °C to ≈100 °C, but also increased the Tg of the matrix epoxy of the multi-scale composites to 154 °C. Relative to an equivalent composite reinforced with non-coated CF reinforcement, the curable-binder/MWCNTs coating increased the ILFT of the CF-epoxy composite; in mode I by 120% and in mode II by 90%. A hybrid RI-hot press (HP) process was used to prepare CF-epoxy composites from coated fabrics with CF volume fractions of ≈55%. The damping curves for the HP-composites consisted of a β-peak, due to the formation of a third mixed phase, in addition to a γ-peak (assigned to the Tg of the binder) and an α-peak (assigned to the Tg of matrix epoxy). The β-peak, and the uniformly distributed nodular particles observed on the fracture surface of the matrix, by SEM, for HP-composites, are indicative of the formation of mixed-phase particles due to reaction induced phase separation (RIPS). Relative to an equivalent RI-composite, the curable-binder/MWCNTs treatment increased the ILFT of the CF-epoxy multi-scale composite; in mode I by 134% and in mode II by 15% for HP-composites. Impact test results showed that HP-composites absorbed more energy, due to CF fracture, compared to equivalent RI composites, which showed larger delamination areas after 5 J and 10 J impact. The out-of-plane electrical conductivity and thermal conductivity of the HP-composite with CF coated with curable-binder/MWCNTs was increased by ≈38% and ≈50%, respectively, compared to the composite with non-coated CF, indicating formation of MWCNTs networks in the matrix rich areas of the multi-scale composite.

This thesis addresses the influence of veil architecture on interlaminar fracture toughness (IFT) of interleaved unidirectional (UD) carbon fibre-epoxy composites with the aim to provide insights. Two nonwoven veils sets formed from polyphenylene sulfide (PPS) fibres with different diameters, with a range of increasing areal density, and a sample of polyetheretherketone (PEEK) fibres, with comparable fibre diameter, are characterised gravimetrically and by tensile tests (long and zero span). Consequently, the anisotropy and maximum stress transfer efficiency (MSTE) parameters are shown by these veils. Subsequently, the veils are interleaved within UD composites and assessed for mode I and mode II IFT. In both modes the veils show a strong dependence on areal density before a plateau at high areal densities, although the lower diameter fibres showed higher IFT values. Interpretation of the results reveal that the difference is attributable to the coverage of veils and thus, to the fraction of fibres in the propagation of crack. However, the effect of fibres is quite evident through the fibre bridging mechanism in the propagation of cracks, more significantly in mode I than in mode II. Moreover, in mode I and mode II a linkage of MSTE of veils with low data variability in IFT is observed. With regard to the anisotropy, this is notably significant only for the PEEK sample, though a statistical analysis supports that the IFT values from both types of fibres are consistent. A comparison of data revealed a slight dependence of the ratio mode II/mode I on areal density only for the larger diameter PPS fibre and the anisotropy of PEEK sample has a strong influence on this ratio. In both modes, however, data presented by this study are consistent with data provided by previous work. Subsequently, mass distribution of veil handsheets is assessed for both modes of IFT into UD composites, revealing no significant dependence of mass distribution on mode I IFT, whereas for mode II this dependence is significant due to the effect a variety of fractional open area size and the floculatted fibres. Fractographic observations via SEM (Scanning Electro Microscope) from representative interleaved composites are analysed and discussed.

When a patient is diagnosed with various spinal injuries, deformities, or advanced degeneration, it is commonly suggested that he/she undergoes surgery for spinal fusion. Most current procedures in spinal fusion restrict mobility in one or multiple levels of the spine so that, over time, new bone will grow between the levels creating a single motionless unit of bone. The bilateral pedicle screw system (BPSS) has long been considered to be the "gold standard" in spinal fusion. However, for patients with osteoporosis, adequate fixation within the bone-screw interface has continuously been difficult to achieve or has come with high risk of other forms of catastrophic damage. Reflecting this, a new pedicle screw design was developed and evaluated against current standard pedicle screws commonly used in spinal surgery. All screw designs were also tested with a common cement augmentation technique surrounding the circumference of the screw. All tests measured pullout strength, stiffness, energy to failure, toughness, and the amount of destruction to the surrounding synthetic bone. While the newly designed pedicle screw failed to produce significantly stronger pullout forces in comparison to the standard screws, it did show evidence of a longer lasting residual axial resistance and a safer mode of failure than the standard screw, hinting that the design may benefit individuals who experience screw pullout and are awaiting reinstrumentation.

Hollow glass microspheres have been used extensively in the automotive and marine industries as an additive for reducing weight and saving material costs. They are also added to paints and other materials for their reflective properties. They have shown promise for weight critical applications, but have thus far resulted in materials with low fracture toughness and impact resistance when combined with thermosetting resins in syntactic foam. The advent of commercially available microspheres with a wide range of crushing strengths, densities and adhesive properties has given new impetus to research into syntactic foam with better fracture behaviour. Current research suggests that the beneficial effects on fracture and impact resistance gained by the addition of solid reinforcements such as rubber and ceramic particles are not seen with the addition of hollow glass microspheres. The research presented in this paper has examined the mechanisms for fracture resistance in glass microsphere filled epoxy (GMFE) syntactic foams, as well as determined the effect microsphere crushing strength and adhesion strength has on the material???s fracture toughness. The flexural properties of various GMFE have also been determined. GMFE were manufactured with varying microsphere volume fraction up to 50%, and with variances in microsphere crushing strength and adhesion. The specimens were tested for Mode I fracture toughness in a three point single edge notched bending setup as described in ASTM D5045 as well as a three point flexural setup as described in ASTM D790-3. Fracture surfaces were inspected using scanning electron microscope imaging to identify the fracture mechanisms in the presence of microspheres. Results indicate a positive effect on fracture toughness resulting from new fracture areas created as tails in the wake of the microspheres in the fracture plane. Results also indicate a negative effect on fracture toughness resulting from weak microspheres or from interfacial disbonding at the fracture plane. These two effects combine to show an increase in GMFE fracture toughness as the volume fraction of microspheres is increased to between 10 ??? 20% volume fraction (where the positive effect dominates), with a reduction in fracture toughness as microspheres are added further (where the negative effect dominates).

No description available.

The development of organic photovoltaics (OPVs) has attracted a lot of attention due to their potential to create a low cost flexible solar cell platform. In general, an OPV is comprised of a number of layers of thin films that include the electrodes, active layers and barrier films. Thus, with all of the interfaces within OPV devices, the potential for failure exists in numerous locations if adhesion at the interface between layers is inherently low or if a loss of adhesion due to device aging is encountered. To date, few studies have focused on the basic properties of adhesion in organic photovoltaics and its implications on device reliability. In this dissertation, we investigated the adhesion between interfaces for a model multilayer barrier film (SiNx/PMMA) used to encapsulate OPVs. The barrier films were manufactured using plasma enhanced chemical vapor deposition (PECVD) and the interfacial fracture toughness (Gc, J/m2) between the SiNx and PMMA were quantified. The fundamentals of the adhesion at these interfaces and methods to increase the adhesion were investigated. In addition, we investigated the adhesive/cohesive behavior of inverted OPVs with different electrode materials and interface treatments. Inverted OPVs were fabricated incorporating different interface modification techniques to understand their impact on adhesion determined through the interfacial fracture toughness (Gc, J/m2). Overall, the goal of this study is to quantify the adhesion at typical interfaces used in inverted OPVs and barrier films, to understand methods that influence the adhesion, and to determine methods to improve the adhesion for the long term mechanical reliability of OPV devices.

Metallic honeycomb structures are being studied for use as thermal protection systems for hypersonic vehicles and as structural panels in other aerospace applications. One potential concern is the growth of fatigue cracks in the thin face-sheets used for these structures. To address this concern, the fatigue behavior of thin aluminum base alloy sheets ranging from 30 m to 250 m in thickness was investigated. The effect of material roll direction was also considered at 30 m. In all cases, the fatigue crack growth rates were found to be one to two orders of magnitude higher than that of the same material of greater thickness. In addition to data for fatigue crack growth rate, data are also presented for the effect of thickness on the fracture toughness of these materials.