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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
101

Intramolecular cyclizations of substitutes 5-hexenyl radicals

Phillipou, George. January 1974 (has links) (PDF)
No description available.
102

Applying loop-mirror and ring resonator on Non- Alumium epi-layer in the fabrication and design Fabry-Perot laser of wavelength in 1.55£gm

Lin, Chia-yi 30 July 2007 (has links)
The purpose of this thesis is to develop ring resonators with simple processes and integration. We used loop mirror as a reflector in the semiconductor lasers. In the material, a 1.55£gm symmetric quantum well InGaAsP epi-layer is used to fabricate the lasers. In device design, we designed four kinds of semiconductor lasers by using loop mirror and cleaved facet. The curvature radiuses are 160 and 260£gm that are presented to investigate bending loss and material loss. In the input/output we had an inclined 7 degree to avoid interference. We also designed another two semiconductor lasers by using ring resonator and cleaved facet. Applying the resonance characteristic of ring resonator can achieve wavelength selection and filtering. In fabrication process, we developed new etching technique. The ICP-RIE dry etching and wet etching method were used in the process. Fist we etched half of the total depth by ICP-RIE dry etching. And then the multi-step technique was used to approach the expecting depth. Beside, we had extra deep wet etching process in MMI. Finally, we used the etching solution HBr:HCl:H2O2:H2O =5:4:1:70 to smooth the sidewall and reduce the scattering loss. In device characteristic, we obtained differential quantum efficiency of 20£gW/mA for the 1000£gm straight waveguide laser. We can not observe laser characteristics for the loop mirror laser, partly because of the high loss in bending section.
103

Ring Laser Integrated Taper-directional Coupler Using Deep Etching to Fabricate Total Internal Reflection Mirrors

Chen, Po-Cheng 09 September 2010 (has links)
The goal of the thesis is Ring Laser Integrated Taper-directional Coupler Using Deep Etching to Fabricate Total Internal Reflection Mirrors. In order to total internal reflection, we make deep etching for the total reflection mirror. We use the tapered waveguide coupler, if unidirectional traveling-wave oscillation can be achieved, spatial hole burning effects seen in DFB laser can be avoided. In this paper, two types of ring laser structures are fabricated and discussed, in which (1) 90 degrees total reflection mirrors and (2) circular retro-mirrors. In fabrication process, we get smooth waveguide and highly perpendicularity waveguide by Self-Alignement wet etch method. In order to reduce bending loss and waveguide loss, we make deep etching for the total reflection mirror and circular retro-mirrors.
104

Applying loop mirror and ring resonator in the fabrication and design of semiconductor laser

Huang, Tzu-chien 21 July 2005 (has links)
We present design and fabrication of ring cavity semiconductor lasers and single ring filter with simple fabrication processes. A 1.55-£gm symmetric quantum well InGaAlAs epi-layer wafer is used to fabricate the lasers. In device design, we apply loop mirror to obtain reflection instead of cleaved facet and take 1x2, and 2x2 Multi-Mode Interference (MMI) with different splitting ratio(50%:50%¡F15%:85%) as a coupler. Then we combine MMI couplers with ring cavities to control the output of specific wavelength. Therefore we can obtain filter and lasers with the property of wavelength selection. We also design two kinds of special waveguides to achieve low reflectivity. One is a tapered spiral waveguide tail. The other waveguide is expanded in a curve and then cut off at the Brewster¡¦s angle. In loop mirror, two curvature radius(260,160£gm) were introduced to study bending loss and material loss. In single ring filter, we design two kinds of resonator lengths(1479,1385£gm) and the corresponding Free Spectrum Range (FSR) are 63.4, 67.75GHz, respectively. In fabrication, owing to the unstable dry etch condition for InGaAlAs, we adopted multi-step etch technology. In the part of curved waveguide, we also use this method to make deep-etching to increase the difference of refractive index between waveguide and the outside part. Finally, we use the etch solution (HBr:HCl:H2O2:H2O=5:4:1:70) to smooth the sidewall of the waveguide, and to reduce scattering loss of the device.
105

Applying loop-mirror reflector in the fabrication and design of Fabry-Perot laser

Lai, Chun-ming 10 July 2006 (has links)
The purpose of this research is to present design and fabrication of resonant loop-mirror Fabry-Perot lasers. Single filter has simple fabrication processes and good potential for intergration. A 1.55-£gm symmetric quantum well InGaAlAs epi-layer wafer is used to fabricate the laser. In device design, we apply loop mirror to obtain reflection instead of cleaved facet and take 1x2, 2x2 Multi-Mode Interference (MMI) with different splitting ratio (50%:50%¡F15%:85%) as a coupler. Then we combine MMI couplers with ring cavities to reflect specific wavelength at particular position. Therefore we can obtain semiconductor laser with property of wavelength-selection filter. In this design of the mask, we add a mask of deep-etch around MMI in order to decrease the loss of higher mode inside MMI. In the part of devices design, we apply multi-step technology for wet etch to obtain necessary depth. Finally, we use the etch solution (HBr¡GHCl¡GH2O2¡GH2O¡×5¡G4¡G1¡G70) to smooth the sidewall of the waveguide, and to reduce scattering loss of the device. In the part of planarization, we can adhere dummy wafers to surround the main sample and extend the total area. If we can fill the gap flat, the problem of high edge by spinning will be solved. However, we were not able to fill the gap.
106

The Design and Fabrication of Ring Cavity Semiconductor Laser

Wang, Chun-Kai 24 June 2003 (has links)
This paper presents design and fabrication of ring cavity semiconductor lasers with simple fabrication processes and good potential for integration. A 1.55-£gm symmetric quantum well InGaAsP epi-layer wafer is used to fabricate the lasers. The fabrication processes involve a bi-level deep etching to reduce the bending losses. Two geometric types of ring cavity semiconductor lasers have been investigated. For the type 1 ring cavity in the form of race tracks, two different designs are presented. One has a single ring resonator (SRR) design and the other has a coupled double ring resonators (DRR) design. The resonator of the type 2 ring cavity is formed between a cleaved facet and a loop mirror. Both a single ring resonator (SRR) design and a double ring resonator (DRR) design are presented for this type of cavity also. The maximum saturation output light powers of 0.479 and 0.409 mW are observed in room temperature L-I measurements for type 1 and type 2 ring cavity semiconductor lasers respectively. The spontaneous emission spectra of the type 1 ring cavity semiconductor lasers show a red-shift phenomenon under increasing drive currents. The type 1 ring cavity semiconductor lasers with ring resonators of 100 and 200 £gm radii have also been found to exhibit an interesting wavelength clamping phenomenon of the output light.
107

Alleviation of effective permeability reduction of gas-condensate due to condensate buildup near wellbore

Carballo Salas, Jose Gilberto 12 April 2006 (has links)
When the reservoir pressure is decreased below dew point pressure of the gas near the wellbore, gas-condensate wells start to decrease production because condensate is separated from the gas around the wellbore causing a decrease in gas relative permeability. This effect is more dramatic if the permeability of the reservoir is low. The idea proposed for reducing this problem is to eliminate the irreducible water saturation near the wellbore to leave more space for the gas to flow and therefore increase the productivity of the well. In this research a simulation study was performed to determine the range of permeabilities where the cylinder of condensate will seriously affect the well’s productivity, and the distance the removal of water around the wellbore has to be extended in order to have acceleration of production and an increase in the final reserves. A compositional-radial reservoir was simulated with one well in the center of 109 grids. Three gas-condensate fluids with different heptanes plus compositions ( 4, 8 and 11 mole %), and two irreducible water saturations were used. The fitting of the Equation of State (EOS) was performed using the method proposed by Aguilar and McCain. Several simulations were performed with several permeabilities to determine the permeabilities for which the productivity is not affected by the presence of the cylinder of condensate. At constant permeability, various radii of a region of zero initial water saturation around the wellbore were simulated and comparisons of the effects of removal of irreducible water on productivity were made. Reservoirs with permeabilities lower than 100 mD showed a reduction in the ultimate reserves due to the cylinder of condensate. The optimal radius of water removal depends on the fluid composition and the irreducible water saturation of the reservoir. The expected increase in reserves due to water removal varies from 10 to 80 % for gas production and from 4 to 30% for condensate production.
108

Applying multimode interference couplers in ring resonators

Tsai, Yi-Lin 02 August 2009 (has links)
This study uses vertical mirror optical waveguide reflector and bending waveguide to fabricate semiconductor ring resonators. By using multimode interference couplers with specific width and length that generate distinctive energy distribution to achieve the power splitting of 85:15. We integrate vertically deep etching turning mirror to reflect optical mode, and reduce the component size to 37.6%. In fabrication process, this study applies multiple wet etching technique to form the waveguide structure. First, we use wet etching technique to etch ridge waveguide and turning mirror, and then perform deep etching in the periphery of bending and turning region to reduce the bending loss. Finally, the etching mask is lifted off, and the wafer is polished and sliced for measurement. After measuring the signal, we can compute waveguide loss by Fabry-perot resonant situation. The waveguide loss is 59.6dB/cm. Power splitting of 90:10 is achieved. The free spectral range (FSR) is 72GHz for the ring resonators.
109

Intermolecular [4+3] cycloaddition reactions using epoxy enol silanes

Lo, Tsz-kiu, Brian., 盧子翹. January 2011 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
110

Demographic and ecological approaches to understanding Ring Ouzel (Turdus torquatus) population declines

Sim, Innes M. W. January 2012 (has links)
Populations of many species are decreasing, but the underlying causes are often poorly understood, impeding effective conservation action. One useful approach is to determine which demographic rates drive variation in population growth rate () and identify ecological and environmental causes. I identified key demographic rates driving the decrease in Ring Ouzel (Turdus torquatus) population size, a species of high conservation concern in the UK, and explored underlying ecological and environmental causes. The number of breeding pairs decreased by 44-100% during 1979-2009 across 13 study areas throughout the UK. The population in my study area in Glen Clunie, Aberdeenshire, Scotland, decreased by 67%, from 39 to 13 breeding pairs, during 1998-2009. Mean  calculated from annual censuses was 0.91. I recorded reproductive success, and used re-sightings of marked individuals to estimate survival rates in each year, thus measuring the mean, variance and covariance among key demographic rates. Prospective elasticity analysis indicated that  was most sensitive to adult survival. However, integrated elasticity analysis, accounting for estimated demographic covariance, indicated that  was most sensitive to first-year survival. Retrospective decomposition of variance indicated that first-year survival contributed most to observed variation in . However, adult survival was low compared with species with similar life histories. Juveniles fledged from early-season broods had higher survival probability during each four-day period post fledging (0.952 ± 0.011) than juveniles fledged from late-season broods (0.837 ± 0.021). Predation was the main apparent cause of mortality. Juveniles foraged on invertebrates in grass-rich areas during June to mid-July, but then switched to feed mainly on moorland berries in higher-altitude, heather-rich, areas during mid-July to early-September. Thus, a variety of habitats providing different food types is required during the late summer. This thesis illustrates the value of integrating demographic and ecological studies to understand population change in species of conservation concern.

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