This thesis is an investigation into the moisture performance of straw bales used in the construction of buildings. The principle of taking bales of straw off the field and stacking them up on themselves to form the walls of a simple building is a practise that started over a hundred years ago. The modern form of this building method is more sophisticated, and is spreading world wide from its origins in the arid regions of America. Despite advances in modern methods of construction there has been concern and doubt over the suitability of straw bale for use as a building material in a temperate maritime climate. The main concern being that the higher levels of environmental moisture will have the potential to damage the straw over time. In order to assess the moisture performance of the straw bales in the walls of a building in this damp climate, a simple and effective means of measuring the moisture in-situ has been developed as part of this research. The overarching methodology for this research is to develop a more accurate version of a probe that uses a block of wood to measure moisture. An environmental chamber in the laboratory has been used to establish the hygrothermal relationship between the timber to be used in the probe, and samples of the straw used in construction. This is the first time that a continuous set of sorption and desorption isotherms have been created for samples of straw and timber simultaneously, a process that took six months to complete. This data was used in the design of a new wood block probe, and examples of the new probes were installed in the walls of a straw bale house with a known moisture history. The resulting readings from the new probe were compared to those from a professional agricultural straw moisture probe. These results could be checked against the readings of the relative humidity and temperature in the wall. Forty-eight pairs of the new wood block probe were calibrated in the laboratory. Fourteen diverse examples of straw bale construction were selected as case study buildings. Having been surveyed for this research, a number were then selected to have the new probes installed, and evidence of their moisture performance was recorded. Sufficient data was acquired through this process to confirm the suitability of straw bales for use in the construction of buildings, in a temperate maritime climate.

Exposure of bare soil for long periods and onsite compaction create soil and water problems in asparagus production. This project aims to develop a cost effective and practical runoff and soil erosion management system. Two field trials (Phase 1 running from April - July 2012 and Phase 2 running from May - November 2013) tested different combinations of shallow soil disturbance (SSD) and mulch (straw and compost) application for soil erosion control. Cranfield University’s soil bin was used to test the effect of different tine configurations on soil disturbance. The results of this research corroborated observations that asparagus production can result in levels of unsustainable soil loss that will contribute to the degradation of the existing soil resource. The field trials demonstrated that a straw mulch applied at 6 t ha- 1 significantly improved key performance indicators (KPIs, i.e. runoff initiation, volume and rate; total soil loss; sediment concentration; total oxides of nitrogen; orthophosphate-P; and sediment-bound P) as compared with the Non-SSD Control. In general, SSD (irrespective of tine configuration) was ineffective at improving key performance indicators as compared with the Non-SSD Control. In the soil bin work, different tine configurations generated varying degrees and extent of SSD, with the modified para-plough giving the greatest soil disturbance for the least draught force. However, the differences in SSD observed in the soil bin had no effect on the KPI’s tested in the Phase 2 field trial. The effective treatments observed in the field trials only yielded cost savings to the farmer/grower when a high level of soil loss occurred. This research highlights the need to develop erosion control measures in asparagus fields, with wider implications to other row crops. However caution is needed, given the observed variation in effectiveness and reliability of in-field mitigation measures, especially during ‘extreme’ rainfall events.

No description available.

Nickel contaminated wastewater from plating industries is a major environmental concern. Current treatment methods are often expensive and can also create additional problems. Biosorption is an alternative treatment method that uses inexpensive biomaterials to sequester metals from aqueous solutions. In this study, acid washed barley straw (AWBS) was used for adsorbing nickel ions (Ni2+) from simulated nickel plating wastewater. The adsorption process was rapid and the equilibrium was reached in about an hour. An increase in the initial nickel concentration increased the equilibrium nickel uptake, and the maximum uptake was found to be 8.45 mg/g of AWBS when the initial nickel concentration was1000 mg/L at pH 5. Nickel adsorption was favorable at room temperature than 5oC and 40oC, better adsorption rate and equilibrium uptake was observed at 23oC. Increasing the pH from 3 to 7 increased the equilibrium nickel uptake and the maximum uptake was observed at pH 7, whilst the initial nickel ion concentration was 100 mg/L. The Freundlich isotherm model exhibited better fit with the equilibrium data than the Langmuir equation. Nickel was desorbed using hydrochloric acid solution at pH 2 and the desorption efficiency was 86%. FT-IR studies indicated the participation of hydroxyl, carboxyl and amide groups from cellulose, hemi-cellulose, protein and lignin of barley straw.

Nickel contaminated wastewater from plating industries is a major environmental concern. Current treatment methods are often expensive and can also create additional problems. Biosorption is an alternative treatment method that uses inexpensive biomaterials to sequester metals from aqueous solutions. In this study, acid washed barley straw (AWBS) was used for adsorbing nickel ions (Ni2+) from simulated nickel plating wastewater. The adsorption process was rapid and the equilibrium was reached in about an hour. An increase in the initial nickel concentration increased the equilibrium nickel uptake, and the maximum uptake was found to be 8.45 mg/g of AWBS when the initial nickel concentration was1000 mg/L at pH 5. Nickel adsorption was favorable at room temperature than 5oC and 40oC, better adsorption rate and equilibrium uptake was observed at 23oC. Increasing the pH from 3 to 7 increased the equilibrium nickel uptake and the maximum uptake was observed at pH 7, whilst the initial nickel ion concentration was 100 mg/L. The Freundlich isotherm model exhibited better fit with the equilibrium data than the Langmuir equation. Nickel was desorbed using hydrochloric acid solution at pH 2 and the desorption efficiency was 86%. FT-IR studies indicated the participation of hydroxyl, carboxyl and amide groups from cellulose, hemi-cellulose, protein and lignin of barley straw.

No description available.

Thesis (M.S.)--Oregon State University, 2010. / Printout. Includes bibliographical references (leaves 156-165). Also available on the World Wide Web.

No description available.

This thesis reports research work in the development of biocomposites based on whole utilisation of renewable wheat straw for industrial applications. The concept of “whole utilisation” is based on a previous work on a novel twin-screw extrusion technology for processing of feedstock in wheat straw reinforced bio-composites. It demonstrated that straw raw material could be restructurised into a feedstock with cellulose fibre finely dispersed in the non-cellulose matrix, which can be utilised as a bonding phase without having to be removed as in conventional processes to extract the cellulose. The whole straw can thus be utilised to avoid waste of materials and the negative impacts to environment associated with the extraction process. Raw wheat straw in this research was prepared in three ways: size reduction through mechanical milling, pre-treatment by aqueous NaOH solution and deep preparation with aqueous NaOH solution soaking followed by extrusion fractionation. Prepared wheat straws were processed into varieties of forms according to the applications. They were hot-compressed into self-reinforced composite with good flow ability and also processed through extrusion and compression moulding to compound with other biopolymers as good filler. The relationships of processing parameter and property, as well as formulation and property were established for each form of product, which provides a key understanding of the whole development circle of an end product. Through this research, scientific and technical problems has been addressed in materials formulation/processing, product design/manufacturing, enhancement of functionality/ performance as well as economical/environmental assessment so as to develop a series of cost-effective bio-composites and products, which satisfy diverse technical and environmental performance requirements in the industrial sectors across packaging, horticulture, building/construction and shooting sports.

No description available.