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New applications of isoureas in synthesisCollingwood, S. P. January 1987 (has links)
No description available.
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Mechanistic and Synthetic Studies on Iron-Bisphosphine-Catalyzed Cross-Coupling Reactions of Alkyl Halides / ハロゲン化アルキルを用いる鉄触媒クロスカップリング反応の機構および開発に関する研究Nakajima, Sho 23 March 2017 (has links)
京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第20391号 / 工博第4328号 / 新制||工||1671(附属図書館) / 京都大学大学院工学研究科物質エネルギー化学専攻 / (主査)教授 中村 正治, 教授 辻 康之, 教授 小澤 文幸 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM
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Synthesis and Use of Chiral Surfactants.Yang, Xiaoye 01 August 2001 (has links) (PDF)
It has been previously shown that micelles formed from surfactants with chiral head groups serve to induce a chiral reaction medium, leading to enhanced enantioselectivities in the reaction products. This utilization of chiral surfactants will offer an economical alternative to traditional chial solvents while simultaneously reducing organic waste. We have successfully dimethlated S-leucinol in an 85% yield, and have synthesized a hydrocarbon-based surfactant with this molecule as a head group. We have also formed polymeric surfactants that have polydimethylsiloxane as the hydrophobic portion with the (S)-dimethylleucinol as a head group. Tests of the solubility of these surfactants have been conducted. We also have done a reduction of a ketone in 95% ethanol and 1.3%-4% (w/v) surfactants, resulting in ee. 5.4%-6.6%.
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Understanding the Solvent-free Nucleophilic Substitution Reaction Performed in the High Speed Ball Mill (HSBM): Reactions of Secondary Alkyl Halides and Alkali Metal-Halogen SaltsMachover, Sarah B. 20 September 2011 (has links)
No description available.
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Synthesis of Chiral Surfactants for Enantioselective Organic Synthesis.Mondal, Kalyan 11 August 2003 (has links) (PDF)
The first step of the synthesis of the hydrocarbon-based chiral surfactant (2) involved the methylation of (S)-leucinol to give (2S)-N-hexadecyl-N,N-dimethyl-(1-hydroxy-4-methyl-1-pentyl)-2-ammonium bromide (2.92g, 67%). The chiral surfactant was synthesized by reacting (2S)-N,N-dimethyl-2-amino-4-methyl-1-pentanol (1) with bromohexadecane (2.06g, 71%). The functionalized styrene for the polymer supported chiral catalyst (6) was synthesized by reacting (1) with 4-vinylbenzyl chloride. The polymerization was carried out with 10% of the functionalized monomer (5) (1.26g, 70.2%), 5% cross-linking agent divinylbenzene, and 85% of styrene with AIBN as the initiator. The structure of each of the products was confirmed by using FTIR and NMR spectroscopy. The activity of the hydrocarbon surfactant and polymeric catalyst were examined by using them as additives in a standard reduction of 2-pentanone with sodium borohydride to yield (R)- and (S)-2-pentanol (3) (4gm, 25%). The resulting alcohol was then esterified with (2S)-methylbutyric acid with iodine as the catalyst and the ester was characterized.
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Electrochemically Driven Functionalization of Alkyl HalidesTruesdell, Blaise L. 07 September 2022 (has links)
No description available.
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Photofragment velocity-map imaging of organic moleculesGardiner, Sara Heather January 2014 (has links)
Photofragment velocity-map imaging (VMI) has generally been employed to investigate the photodissociation dynamics of relatively small molecular systems (< 5 atoms). The work reported in this thesis focuses on the application of this technique for the investigation of the unimolecular photodissociation of larger chemical systems, which are of interest to a broad cross section of the chemical community. Typically, VMI studies involve state-selective detection of one particular fragmentation product, and so are often limited to the investigation of a single dissociation channel. By employing vacuum ultra-violet (VUV) photoionization, we are able to detect most, if not all of the fragments resulting from the dissociation of a neutral species, with ‘universal’ ionization being achieved in the ideal case when the fragment ionization energies are all lower than the VUV photon energy. This capability becomes particularly important when investigating larger systems, since these often display complex dynamics with multiple competing fragmentation pathways. Our approach allows us to investigate the different photofragmentation processes occurring for a particular system, to evaluate the relative importance of the active dissociation channels, and to gain insight into the energy partitioning amongst the fragments. A study of the UV photodissociation of two neutral alkyl iodide molecules demonstrates the first use in our laboratory of ‘universal’ ionization in combination with VMI. Studies into the photofragmentation processes resulting from 193 nm photoexcitation of neutral N,N-dimethylformamide, a small-molecule model for a peptide bond, and a number of neutral cyclic alkenes, which undergo the retro-Diels-Alder reaction, are also presented. The remaining studies presented in this thesis have investigated the photofragmentation processes of ionic species, generated by means of VUV photoionization. In the case of ion dissociation each fragmentation channel necessarily produces one charged species, which may be detected using the VMI technique. Therefore, such studies provide an insight into all of the active channels. An in-depth VMI study of the UV photodissociation of two ethyl halide cations is presented, which demonstrates the successful investigation of the multiple photofragmentation pathways of these ionic species. The remainder of the cation photodissociation studies are of relevance to a number of common processes known to occur in mass spectrometry, including the McLafferty rearrangement, the retro-Diels-Alder reaction, and ‘peptide’ bond fragmentation. By velocity-map imaging the products of these reactions, further information is obtained concerning these dissociation processes, which are no doubt of interest to the wider chemical community. This work forms part of the velocity-map imaging mass spectrometry (VMImMS) project. VMImMS involves imaging each of the fragmentation products that result from dissociation of a parent molecule of interest, with the aim of increasing the amount of information that can be obtained from a mass-spectrometry-type experiment. The work presented in this thesis demonstrates that VMImMS allows us to unravel details of the dissociation dynamics of both neutral and ionic species, and is potentially a powerful technique for investigating the fragmentation processes of increasingly complex systems.
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