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Planting woody biomass for energy production can be used as a mine reclamation procedure to satisfy the Surface Mining Control and Reclamation Act of 1977 (SMCRA) and provide renewable energy for the United States.  This study examines the economic viability of bioenergy production on previously mined lands using multiple hardwood species and treatments.  Five species were planted at two densities; one-half of the trees were fertilized in year two.  Height and diameter of the trees were measured annually for five years; the first three years by cooperating researchers at Virginia Tech, the last two years specifically for this report.  Current and predicted mass of the species, effects of planting density and fertilizer application, and the land expectation value (LEV) of each treatment were summarized.  A sensitivity analysis was conducted to determine how changes in production costs, stumpage price, rotation length, and interest rate affect the economic feasibility of bioenergy production.  Renewable energy and mine reclamation policies were investigated and it was determined that woody bioenergy can be planted as a mine reclamation procedure and may receive financial incentives.  Production cost appears to have the largest impact on LEV and is often the difference between positive and negative returns for the landowner.  The extra cost of fertilization and high density planting do not increase LEV; the unfertilized, low density treatments have the best LEV in all examined scenarios.  In general, bioenergy was found to be economically viable as a mine reclamation procedure only in limited circumstances.  In low cost, high price scenarios, bioenergy crops could have the potential to reforest both active and abandoned mine lands throughout southern Appalachia. / Master of Science

Our American electric system doggedly follows the central station model developed in the late 1800s. Thomas Hughes says the system gained momentum by adding more alliances with educators, politicians, and other industries until the social network was so intertwined with the technology that deviating from the central station model would be extremely difficult. However, change can occur if a variety of components change, but Hughes does not specify which components. Another network model, actor-network theory, proposes that social relationships (the same ones that maintain system momentum) are actually dynamic relationships that either actively maintain or change the system configuration. But which relationships need to change in order for utilities to accept and interconnect renewable energy with their grid? This thesis focuses on the social relationships created around renewable technologies and the idea that they can be successfully integrated into the network. In each case, customers, utility executives, institutions, and technology worked together to bring about utility acceptance. Individuals, working within these institutions, can bring about change. In New York City, an urban windmill was installed atop an apartment building. In Sacramento, CA, the municipal utility, SMUD, broke from the system model to become a leader in energy efficiency and renewable energy programs. In Texas, their renewables portfolio standard has become a standard for others to follow. / Master of Science

Proton exchange membrane (PEM) fuel cells are considered one of the best potential alternative power sources for automobiles. For this application, high efficiency and high power density are required. Pressurizing the fuel cell system can give higher efficiency, higher power density and better water balance characteristics for the fuel cell, but pressurization uses a percentage of the fuel cell output power. The compressor used to elevate the pressure has a direct effect on the system efficiency and water balance characteristics. A variety of compressors are being developed for fuel cell applications. Two compressor and expander technologies are discussed in this paper: the Opcon 1050 positive displacement twin-screw compressor and expander, and a Honeywell turbocompressor and expander. The effect of these compressors and expanders on the system at maximum load, low load, and set minimum airflow are examined. The effects of ambient conditions, stack temperature, and increased twin-screw compressor pressure are also examined. The turbocompressor proves to be a superior machine in terms of efficiency, and therefore offers the most promising effect on system efficiency of the two compressors. The twin-screw compressor, on the other hand, offers more flexible pressure ratio and better water balance characteristics at low fuel cell loads, which is an important factor with PEM fuel cell systems. Increased ambient and stack temperature has a significant negative effect on the water balance and a small positive effect on efficiency. Increasing the pressure for the twin-screw compressor significantly improves the water balance characteristics with some loss in efficiency. These results show the importance of determining the system operating range and operating conditions in the choice of a compressor for a fuel cell system / Master of Science

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Doctor of Philosophy / Department of Grain Science and Industry / Sajid Alavi / The Renewable Fuel Standard (RFS) in the Energy Independence and Security Act of 2007 has set the goal of 36 billion gallons of annual ethanol production in the U.S. by 2022, which is equivalent to 17.5% of the current gasoline consumption in the U.S. However, corn ethanol is expected to plateau at a level of 7.3% of current gasoline consumption on an energy-equivalent basis. Thus, it is essential to utilize a variety of substrates including lignocellulosic biomass from perennial energy crops such as switch grass, crop residues such as corn and sorghum stover, and agri-industrial co-products such as soybean hulls and wheat bran. Lignocellulosic substrates have a recalcitrant nature and require a pretreatment step that is critical for efficient enzymatic hydrolysis of cellulose and hemicellulose to fermentable sugars. In this study, soybean hulls were used as a model substrate for cellulosic ethanol. A novel thermo-mechanical pretreatment process using extrusion was investigated and compared with two traditional pretreatment methods, dilute acid and alkali hydrolysis, with regard to structural changes in the lignocellulosic substrate, and glucose and ethanol yields. The effect of extrusion parameters, such as barrel temperature, in-barrel moisture and screw speed, on glucose yield from soybean hulls was determined. Optimum processing conditions were screw speed of 350 rpm, maximum barrel temperature of 80C and 40% in-barrel moisture content, resulting in 95% cellulose conversion to glucose. Compared with untreated soybean hulls, the cellulose to glucose conversion of soybean hulls increased by 69.5, 128.4 and 132.2% for dilute acid, alkali and thermo-mechanical pretreatments, respectively. Glucose and other hexose sugars such as mannose and galactose were effectively fermented by Saccharomyces cerevisiae, resulting in ethanol yields of 13.04–15.44 g/L. Fermentation inhibitors glycerol, furfural, 5-(hydroxymethyl)-2-furaldehyde (HMF) and acetic acid were found in the thermo-mechanically pretreated substrate, ranging in concentrations from 0.072–0.431, 0–0.049, 0–0.023 and 0.181–0.278 g/L, respectively, which were lower than those reported from acid hydrolyzed substrates. The economic feasibility of commercial cellulosic ethanol production processes employing dilute acid hydrolysis and thermo-mechanical pretreatment were compared using a system dynamics modeling approach. It was concluded that low feedstock cost and high sugar conversion are important factors that can make cellulosic ethanol production commercially viable. Thermo-mechanical pretreatment was a more promising technology as compared to dilute acid hydrolysis because of the lower capital and operating costs, and higher sugar conversion.

This research addresses the manufacturing problems of the fuel cell in an applied industrial approach with the aim of investigating the technology of manufacturing of Proton Exchange Membrane (PEM) fuel cells, and using this technology in reducing the cost of manufacturing through simplifying the design and using less exotic materials. The first chapter of this thesis briefly discusses possible energy alternatives to fossil fuels, arriving at the importance of hydrogen energy and fuel cells. The chapter is concluded with the main aims of this study. A review of the relevant literature is presented in chapter 2 aiming to learn from the experience of previous researchers, and to avoid the duplication in the current work. Understanding the proper working principles and the mechanisms causing performance losses in fuel cells is very important in order to devise techniques for reducing these losses and their cost. This is covered in the third chapter of this thesis which discusses the theoretical background of the fuel cell science. The design of the fuel cell module is detailed in chapter 4, supported with detailed engineering drawings and a full description of the design methodology. So as to operate the fuel cell; the reactant gases had to be prepared and the performance and operating conditions of the fuel cell tested, this required a test facility and gas conditioning unit which has been designed and built for this research. The details of this unit are presented in chapter 5. In addition to the experimental testing of the fuel cell under various geometric arrangements, a three dimensional 3D fully coupled numerical model was used to model the performances of the fuel cell. A full analysis of the experimental and computational results is presented in chapter 6. Finally, the conclusions of this work and recommendations for further investigations are presented in chapter 7 of this thesis. In this work, an understanding of voltage loss mechanism in the fuel cell based on thermodynamic irreversibility is introduced for the first time and a comprehensive formula for efficiency based on the actual operating temperature is presented. Furthermore, a novel design of a 100W (PEMFC) module which is apt to reduce the cost of manufacturing and improve water and thermal management of the fuel cell is presented. The work also included the design and manufacturing of a test facility and gas conditioning unit for PEM fuel cells which will be useful in performing further experiments on fuel cells in future research work. Taking into consideration that fuel cell technology is not properly revealed in the open literature, where most of the work on fuel cells does not offer sufficient information on the design details and calculations, this thesis is expected to be useful in the manifestation of fuel cell technology. It is also hoped that the work achieved in this study is useful for the advancement of fuel cell science and technology.