The purpose of this research was to determine uni-axial response of synthetic fibres required for structural design. The stress versus crack opening curves, required by RILEM for structural design of fibre reinforced concrete, were determined for each fibre type investigate and were used to compare the per fibre post-crack response, the pullout curves, and the flexural response. A study of the fibre distribution was conducted in order to determine the orientation factor required to predict the number of fibres expect in the tensile specimen crack face. The orientation factor, dosage, fibre geometry, and per fibre post-crack response were determined in order to predict the resulting tensile strength of a concrete mix. The tensile strength was compared to that of steel fibre currently being used in structural applications. The synthetic fibres tested only achieve a small percentage of their ultimate tensile strength; in order to produce synthetic fibres for structural applications, the bond strengths must be improved.

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A business application automates a collection of business processes. A business process describes how a set of logically related tasks are executed, ordered and managed by following business rules to achieve business objectives. An “online book purchase” business process contains several tasks such as buying a book, ordering a book, and sending out promotions. In this ever changing business environment, both of business applications and business processes are modified to accommodate changed business requirements and improve the performance of the organization. These continuous modifications introduce problems in the following two aspects: 1) Business process definitions are rarely updated to reflect the current business processes deployed in business applications. 2) Business processes may be cloned (e.g., copied and slightly modified) to handle special circumstances or promotions. Identifying these clones and removing them help improve the efficiency of an organization. However, business processes are defined with textual languages that cannot be automatically understood. To maintain business process definitions up to date, we present our techniques that automatically recover business processes from UIs of business applications and identify clones in the recovered business processes. We leverage UI design patterns, which present the best practices of UI designs, to capture business processes from UIs. To refine the recovered business processes and mark the functionally equivalent tasks, we use existing code clone detection tools, such as CCFinder and CloneDR, to detect clones in business applications, and lift clones from code level to business process level. The effectiveness of our techniques is demonstrated through a case study on 15 large open source business applications. / Thesis (Master, Computing) -- Queen's University, 2008-10-28 11:06:31.41

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This study was designed to develop some predictive models for the dielectric properties of the chemicals and chemical reactions and make use of dielectric properties and microwave irradiation in the chemical reactions. Specifically, the dielectric properties of the following systems were investigated at microwave frequencies of 2450 and 915 MHz: (1) C1--C5 alcohols, (2) glucose aqueous solutions, (3) lysine aqueous solutions, (4) mimicked esterification reaction model systems of parahydroxybenzoic acid with methanol, 1-propanol and 1-butanol in the presence of para-toluene sulfonic acid as a catalyst, (5) Maillard reaction model system consisting of glucose, lysine and water. / The dielectric properties of the model systems showed that they depended on the frequency applied, concentration of the material, and temperature. Most of the predictive models showed that there exists a linear or quadratic relationship between dielectric constant and concentration or temperature. However, the quadratic equation is better than the linear one to describe the variation of the loss factor with temperature or concentration. / Esterification showed great advantages for the use of microwave irradiation in chemical reaction. It included reduction in reaction time, and provided distinct temperature profiles due to microwave environment during chemical reactions. The reason for rate enhancement of this type of reaction was also demonstrated from the temperature profile. / Microwave-assisted solvent free Maillard reaction model system, consisting of glucose and lysine, demonstrated that the heating method applied was not one of the crucial factors, but the temperature level was important during the chemical reaction. / The relationship of loss factor with yield of reaction showed that it is possible to use dielectric data to analyze, and monitor the chemical reaction. It provided a new methodology to analyze the reaction. / The relationship between the loss factor, loss tangent and the reaction time, and concentration of the material showed that it is also possible to use dielectric data at microwave frequencies of 2450 and 915 MHz to study chemical reactions, especially the kinetics.

Cheese ripening is a costly and lengthy process. Increasing the enzyme pool in the cheese curd has been shown to accelerate the cheese ageing process, enhance flavour and texture. The characteristics of two lactic acid bacteria attenuated by pulsed electric fields were studied in a milk system and in cheese slurry. The potential of accelerating cheese ripening via the addition of starter cultures attenuated by pulsed electric fields (PEF) was studied. / Pulsed electric field treatment was performed in a static treatment chamber using bi-polar waveform with a field intensity of 20 kV and 2 mus pulse width. The number of pulses ranged from 10 to 500. Evaluation of the starter cultures was assessed through the analysis of acidifying abilities, survival fractions, enzymatic activities and proteolysis (RP-HPLC and Cd-ninhydrin) in water soluble nitrogen extracts following the different attenuation treatments. / Pulsed electric fields significantly affected the general viability of the cells through a delayed acidification and an inhibition of enzymatic activity. A study in cheese slurry systems showed that the cultures under investigation were not able to provide an increased proteolysis levels following PEF treatment. The results of this study also suggest that optimal PEF treatment varies for each LAB strain and that the Lactococcus strains do not possess high enough proteinase and peptidase activities to be beneficial for the acceleration of cheese ripening.

<p>In the natural decay series of 238U an inert radioactive gas, 222Rn (radon) is formed in the decay of 226Ra. Because radon is relatively soluble in water, it migrates from places of its generation in rocks and soils to other places either by soil air, or travels with underground water. Therefore, there is a growing interest among hydrogeologists in using radon as a natural tracer for investigating and managing fresh water reservoirs. This work is aimed at investigating and developing radon-in-water measuring techniques applicable to aquifers and rivers. A gamma-ray spectrometry method using a hyper-pure germanium (HPGe) detector, based at iThemba LABS, Cape Town and Marinelli beakers, has been optimized to measure radon in borehole water via the g-rays associated with the decay of radon daughters 214Pb and 214Bi (in secular equilibrium with their parent). An accuracy better than 5% was achieved. Moreover, long-term measurements of radon in water from an iThemba LABS borehole have been carried out to investigate the role of radon for characterizing aquifers. These investigations led to the development of a simplified physical model that reproduces the time-evolution of radon concentration with borehole pumping and may be used to estimate the time for representative sampling of the aquifer. A novel method is also proposed in this thesis to measure radon-in-water in the field after grab sampling - a so-called quasi in-situ method. The quasi in-situ method involves inserting a y-ray detector in a container of large volume filled with water of interest. The g-ray spectra are analyzed using an approach involving energy intervals on the high-energy part of the spectrum (1.3 &ndash / 3.0 MeV). Each energy interval corresponds to contributions from one of the major g-ray sources: 40K and the decay series of 238U and 232Th, and cosmic rays. It is assumed that the U interval will be dominated by g-rays emitted from the radon daughters (214Pb and 214Bi). Minor contributions to an interval with major radionuclide are corrected using an MCNPX simulated standard spectra. The two methods in this thesis make a significant contribution to measuring and modelling of radon in aquifers and surface waters. It forms a basis for further development in an interactive mode with hydrological applications.</p>