No description available.

There are far too many Information Systems (IS) projects which end in failure. It is widely recognised that the primary reasons for this are essentially human and organisational and rarely technical. Although it is found that the vast majority of IT specialists consider human and organisational issues to be of equal if not of greater importance than technical issues, in practice they are still focusing on technical aspects at the expense of human and organisational issues in Information Systems Development (ISD) and implementation. Despite the awareness of the importance of human and organisational issues in ISD, little is known about how these issues can actually be addressed. This study attempts to fill this gap by investigating empirically how, when and by tinhorn a set of 14 specific organisational issues are treated in practice, and explores whether the treatment of this set of issues is dependent upon the employment of specific Systems Development Methods (SDM) or the successful adoption of organisationally oriented best practice factors. In excess of 2,250 questionnaires were posted to IS/IT directors in different British organisations which had over 250 employees, and 344 valid responses were received. This mail survey was followed by a series of focus groups interviewees with IT practitioners. It was envisaged that the integration of the two strategies would provide a very effective mechanism for combining the complementary advantages of the qualitative and quantitative research approaches. The interviews provided a richer picture of the research statistical results and explored their meaning and implications. This research presents empirical evidence that the level of organisational issues consideration, the tinting of treatment, and the person/people responsible for the treatment during ISD significantly influence the overall level of systems' success. The findings also show that there is a significant correlation between the adoption of best practice factors and the overall success of IS and the treatment of organisational issues. There is, however, no significant relationship between the use of systems development methods and the overall success of IS or the treatment of organisational issues. These findings suggest that it is not the choice of a specific systems method that ensures the consideration of a wide range of organisational issues, but the successful adoption of the organisationally oriented best practices approaches.

A microwave assisted methodology was developed to modify Merrifield resins (1-2% cross-linked containing 1.0-3.5 mmol Cl-/g) with different nominal molecular weights PEG (200-1000). The synthesis was also carried out by conventional heating to assess the differences between the two procedures. The most efficient synthesis was achieved by using microwave and by using PEG with molecular weight 200 and MR 2% crosslinked containing 1.25 mmol Cl -/g. The structural elucidation was carried out using Fourier transform infrared (FTIR) spectroscopy and elemental analyses. Upon pyrolsis-GC/MS analysis of the PEGylated MR, the PEG showed the tendency to undergo thermal degradation by the loss of a smaller PEG fragments. This observed degradation of PEG was less prominent during microwave assisted synthesis compared to conventional heating, in addition to faster reaction rates and higher yields. As expected, the PEGylated MR showed improved swelling properties in polar solvents. The chemical reactivity of the PEGylated Merrifield resin was confirmed by the esterification with pyruvic acid and by the substitution of hydroxyl group using thionyl chloride. In addition, the PEGylated MR was converted into (1) polymer-supported acid/base or redox indicator by the attachment of a blue organic dye - 2,6-dichloroindophenol (DCIP) through a nucleophilic substitution reaction and (2) beta-cyclodextrin trap, a water insoluble inclusion-complex, by immobilization of beta-cyclodextrin through cross-linking with 1,6-hexamethylene diisocyanate reagent.

Gas hydrates are a topic of great interest and intense investigation. Traditionally, these compounds have been seen as a nuisance to the oil and gas industry, which can plug pipelines and cause hours of costly downtime. More recently, gas hydrates have been viewed as a possible energy source due to the vast amount of methane trapped in the form of gas hydrate. Many researchers have also proposed the possibility of transporting natural gas in the form of gas hydrate may be safer and more economical than using liquid or compressed natural gas. Gas hydrate may also offer the possibility of reducing greenhouse gas emissions via the sequestration of carbon dioxide. / Surfactants have been found to act as both promoters and inhibitors of hydrate formation. In the present study, the formation rate, solubility and mass transfer conductance of methane in the presence of Gemini surfactant, a new class of surfactants, was studied with varying concentration of Gemini surfactant. The experiments to determine the formation rates of methane hydrate were conducted at 4°C and 6500 kPa. While the experiments to determine solubility and mass conductance were carried out at 4°C and 3800 kPa. The resulting values were used to determine experimental accuracy and reproducibility by comparing the values obtained with literature values and by analyzing the distribution of the data obtained. Solubility measurements were extremely close to literature values with only a 1.4% difference. The distribution of solubility values and formation rates did not deviate significantly between replicates indicating a high degree of reproducibility; however, a lot of variability was observed in mass transfer conductance. This may be attributed to the fact that mass transfer was not determined experimentally by regressing a coefficient to fit a curve, which may be less accurate than other experimentally determined parameters. / In the second part of the study, the formation rate, solubility and mass transfer conductance of methane were determined using aqueous Gemini surfactant solutions. The experiments to determine the formation rates of methane hydrate were conducted at 4°C and 6500 kPa. While the experiments to determine solubility and mass transfer conductance were carried out at 4°C and 3800 kPa. The resulting values were used to determine the effect of Gemini surfactant on the properties of interest by comparing the values obtained with aqueous Gemini surfactant with the values previously obtained for pure water. The results obtained showed that solubility increased with increasing concentrations of Gemini surfactant with solubility increasing by up to 18% for higher concentration of Gemini surfactant. The mass transfer conductance was also found to increase by up to 49%; however other than the existence of an increase, no conclusive relationship could be determined between the concentration of Gemini surfactant and mass transfer conductance. / Finally, the formation rate of gas hydrates was found to decrease slightly, relative to water, at low concentrations, increased linearly at subsequently higher concentrations and ultimately plateau at a maximum. This trend was in agreement with similar experiments found in literature and the increase in formation rate may be attributed to the increase in both solubility and mass transfer conductance when using aqueous Gemini surfactant.

El presente trabajo surge como una necesidad en el Campus de la Universidad Nacional de Salta, de contar con herramientas que faciliten al Ingeniero de redes realizar tareas de administración desde cualquier punto de la red, independizándolo de esta manera de la plataforma necesaria para ejecutar aplicaciones de gestión. La Administración o Gestión basada en Web es la aplicación de la tecnología World Wide Web a redes y administración de dispositivos. Pretende aprovechar la amplia difusión de los navegadores como interfaz de usuario universal, para utilizarlos como interfaz para las aplicaciones de gestión. Debido a que esta tecnología es relativamente nueva, pocos investigadores se adentraron en el tema hasta ahora. El principal beneficio de los mecanismos de Gestión basados en Web es que los desarrolladores de aplicaciones no tienen por qué conocer los detalles de los protocolos de gestión para manejar dispositivos remotos. Adicionalmente esto permite abstraer los diferentes protocolos y unificarlos con una única visión. Este trabajo plantea por una parte inspeccionar el área de la Gestión basada en Web, y compararla con las Herramientas de Gestión tradicionales basadas en SNMP. Se hace énfasis en muchas características como seguridad, eficiencia, costo, interfaz amigable, etc. Por otro lado intenta desarrollar un conjunto de herramientas que sean rápidamente implementables y permitan al Ingeniero de red realizar algunas operaciones de administración en agentes del tipo pc/routers, ver estadísticas, estado y evolución de estos dispositivos.

The synergy of smartphone, mobile applications (apps) and Augmented Reality (AR) technology has the potential to mediate tourism experiences to great extents. The advent of AR apps on smartphones provides a dynamic solution for tourists by helping convey destinations’ meanings and creates positive experiences via interactive tourist information and services almost anywhere, anytime. As a result, tourists are increasingly using AR travel apps at destinations to create more memorable travel experiences. Despite vast literature on tourists’ experiences, there is limited research focusing on understanding the use of smartphones and AR apps for tourism. A critical review of the literature indicates that there is a need to develop a richer theoretical framework that describes the use of smartphones and AR apps for travel. In addition, there is a need to understand tourists’ experiences with smartphone-mediated technology. In particular, literature on understanding of the use of smartphones and apps for travel is largely established from a quantitative perspective, and it is argued that this perspective cannot provide an in-depth understanding of the mechanisms that affect the use of smartphones and travel apps, which in turn shapes the travel experience. The present qualitative study was designed to understand the current use and possible benefits of smartphone-mediated tourism experiences with AR apps. Specifically, the purpose of this study was to examine the influence of AR apps on tourists’ experiences. The study sought to understand how tourists used AR apps, which specific interactions with the mobile devices were afforded, what emotions were evoked through interaction with the AR technology, and how the technology mediated tourist’s experiences. Based on this notion, the study attempted to generate an inductive middle-range theory on smartphone-mediated tourism experiences using grounded theory method. An iPhone AR app was developed for the Texas A&M University campus to better understand how tourists used the AR app and how this use influenced their travel experiences. Forty-four participants inclusive of students, prospective students and visitors of Texas A&M University were recruited for the study. To aid theory building and enhance the solidity of the smartphone-mediated travel experience theory, the study included a control group, which involve individual, group and guided tours that only use a brochure/campus booklet or listen to a human tour guide. The AR app was tested on 10 individuals and 10 groups. For the control group, 6 individuals and 6 groups used brochure/campus booklet while touring the sites and 6 individuals and 6 groups listen to the tour-guide. This comparison provided detailed understanding of what happens in the absence of technology in travel experience, and a focus on apprehending what AR technology adds. Data were collected through face-to-face in-depth interviews with the participants and then transcribed and imported into ATLAS.TI 7.0 software for analysis. A grounded theory approach was used to analyze the data. The interview data were coded and presented in five major sections representing the research questions. The results of the study provided theoretical contributions in understanding the smartphone-mediated tourism experiences and offered practical implications for app design and interpretative services for tourist sites.

The resources and localization abilities available in modern smartphones have provided a huge boost to the popularity of location-based applications. In these applications, users send their current locations to a central service provider and can receive content or an enhanced experience predicated on their provided location. Privacy issues with location- based applications can arise from a central entity being able to store large amounts of information about users (e.g., contact information, attributes) and locations (e.g., available businesses, users present). We propose an architecture for a privacy-friendly location hub to encourage the development of mobile location-based social applications with privacy- preserving features. Our primary goal is to store information such that no entity in our architecture can link a user’s identity to her location. We also aim to decouple storing data from manipulating data for social networking purposes. Other goals include designing an architecture flexible enough to support a wide range of use cases and avoiding considerable client-side computation. Our architecture consists of separate server components for storing information about users and storing information about locations, as well as client devices and optional com- ponents in the cloud for supporting applications. We describe the design of API functions exposed by the server components and demonstrate how they can be used to build some sample mobile location-based social applications. A proof-of-concept implementation is provided with in-depth descriptions of how each function was realized, as well as experi- ments examining the practicality of our architecture. Finally, we present two real-world applications developed on the Android platform to demonstrate how these applications work from a user’s perspective.

Pulsed Electric Field (PEF) processing, a novel, non-thermal food preservation method, has been shown to inactivate both spoilage and pathogenic microorganisms, while minimizing changes in the physical and organoleptic qualities of the food, such as those observed under conventional thermal processing. An understanding of the inactivation mechanisms and kinetics of microorganisms exposed to lethal or sub-lethal PEF treatments would allow industry and consumers to better understand and evaluate the potential of PEF technology as an alternative or complement to traditional methods of food preservation. This study consisted of three sets of experiments which sought to determine: (i) the electrical conductivity (EC) of various liquid food products (apple, orange and pineapple juices, egg white, whole egg and egg yolk) at different temperatures (5--55°C); (ii) the capacity of PEF (15 kV cm-1, 0°C) to inactivate Escherichia coli O157:H7 in dialyzed liquid egg products; and (iii) the effect of PEF (20 or 30 kV cm-1) in combination with temperature (10--40°C) on the inactivation of E. coli and Salmonella Enteritidis in liquid egg yolk (EY), whole egg (WE), or egg white (EW). The treatment chamber design was based in part on regression equations of EC vs. temperature developed in the first set of experiments. After only 0.1 sec of PEF (15 kV cm-1) treatment, l, 3 and 3.5 log reductions of E. coli were noted in dialyzed egg white, egg yolk and whole egg, respectively. Kinetic models of bacterial inactivation were proposed. A 210 mus exposure to PEF (30 kV cm-1 ) resulted in log reductions of 5.0 and 5.0 in egg yolk, 3.9 and 3.6 in WE and, 2.8 and 3.6 in egg white, for E. coli and S. Enteritidis, respectively. A maximum energy of 914 J was required to inactivate S. Enteritidis in WE. In egg white, cells injured by PEF represented 0.9 and 0.4 log for S. Enteritidis and E. coli, respectively. An exponential decay model and an Arrhenius equation were

The resources and localization abilities available in modern smartphones have provided a huge boost to the popularity of location-based applications. In these applications, users send their current locations to a central service provider and can receive content or an enhanced experience predicated on their provided location. Privacy issues with location- based applications can arise from a central entity being able to store large amounts of information about users (e.g., contact information, attributes) and locations (e.g., available businesses, users present). We propose an architecture for a privacy-friendly location hub to encourage the development of mobile location-based social applications with privacy- preserving features. Our primary goal is to store information such that no entity in our architecture can link a user’s identity to her location. We also aim to decouple storing data from manipulating data for social networking purposes. Other goals include designing an architecture flexible enough to support a wide range of use cases and avoiding considerable client-side computation. Our architecture consists of separate server components for storing information about users and storing information about locations, as well as client devices and optional com- ponents in the cloud for supporting applications. We describe the design of API functions exposed by the server components and demonstrate how they can be used to build some sample mobile location-based social applications. A proof-of-concept implementation is provided with in-depth descriptions of how each function was realized, as well as experi- ments examining the practicality of our architecture. Finally, we present two real-world applications developed on the Android platform to demonstrate how these applications work from a user’s perspective.

No description available.