Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2009. / Includes bibliographical references (p. 88-91). / The work presented in this thesis addresses the problem of the detection, classification and localization of seabed objects in shallow water environments using a time reversal approach in a bistatic configuration. The waveguide is insonified at low frequency ('kHz) with an omnidirectional source and the resulting scattered field is sampled by a receiving array towed behind an Autonomous Underwater Vehicle (AUV). The recorded signals are then processed to simulate onboard the AUV, the time reversed transmissions which serve to localize the origin of the scattered field on the seabed and estimate the position of the targets present. The clutter rejection based upon the analysis of the singular values of the Time Reversal operator is investigated with simulated data and field measurements collected off the coast of Palmaria (Italy) in January 2008. / by Alexis J. Dumortier. / S.M.

Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2018. / Cataloged from PDF version of thesis. / Includes bibliographical references. / This thesis examines abiotic processes controlling the transformation and distribution of carbon compounds in seafloor hydrothermal systems hosted in ultramafic rock. These processes have a direct impact on carbon budgets in the oceanic lithosphere and on the sustenance of microorganisms inhabiting hydrothermal vent ecosystems. Where mantle peridotite interacts with carbon-bearing aqueous fluids in the subseafloor, dissolved inorganic carbon can precipitate as carbonate minerals or undergo reduction by H2(aq) to form reduced carbon species. In Chapters 2 and 3, I conduct laboratory experiments to assess the relative extents of carbonate formation and CO2 reduction during alteration of peridotite by C02(aq)-rich fluids. Results from these experiments reveal that formation of carbonate minerals is favorable on laboratory timescales, even at high H2(aq) concentrations generated by serpentinization reactions. Although CO2(aq) attains rapid metastable equilibrium with formate, formation of thermodynamically stable CH4(aq) is kinetically limited on timescales relevant for active fluid circulation in the subseafloor. It has been proposed that CH4 and potentially longer-chain hydrocarbons may be sourced, instead, from fluid inclusions hosted in plutonic and mantle rocks. Chapter 4 analyzes CH4-rich fluid inclusions in olivine-rich basement rocks from the Von Damm hydrothermal field and the Zambales ophiolite to better understand the origin of abiotic hydrocarbons in ultramaficinfluenced hydrothermal systems. Comparisons of hydrocarbon abundances and stable isotopic compositions in fluid inclusions and associated vent fluids suggest that fluid inclusions may provide a significant contribution of abiotic hydrocarbons to both submarine and continental serpentinization systems. / by Niya Gueorguieva Grozeva. / Ph. D.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2006. / This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections. / Includes bibliographical references (p. 89-96). / Blainville's beaked whales (Mesoplodon densirostris) use broadband, ultrasonic echolocation signals (27 to 57 kHz) to search for, localize, and approach prey that generally consist of mid-water and deep-water fishes and squid. Although it is well known that the spectral characteristics of broadband echoes from marine organisms are a strong function of size, shape, orientation and anatomical group, little is known as to whether or not these or other toothed whales use spectral cues in discriminating between prey and non-prey. In order to study the prey-classification process, a stereo acoustic tag was mounted on a Blainville's beaked whale so that emitted clicks and corresponding echoes from prey could be recorded. A comparison of echoes from prey selected by the whale and those from randomly chosen scatterers suggests that the whale may have, indeed, discriminated between echoes using spectral features and target strengths. Specifically, the whale appears to have favored prey with one or more deep nulls in the echo spectra as well as ones with higher target strength. A three-dimensional, acoustic scattering model is also developed to simulate broadband scattering from squid, a likely prey of the beaked whale. / (cont.) This model applies the distorted wave Born approximation (DWBA) to a weakly-scattering, inhomogeneous body using a combined ray trace and volume integration approach. Scatterer features are represented with volume elements that are small (less than 1=12th of the wavelength) for the frequency range of interest (0 to 120 kHz). Ranges of validity with respect to material properties and numerical considerations are explored using benchmark computations with simpler geometries such as fluid-filled spherical and cylindrical fluid shells. Modeling predictions are compared with published data from live, freely swimming squid. These results, as well as previously published studies, are used in the analysis of the echo spectra of the whale's ensonified targets. / by Benjamin A. Jones. / S.M.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Biology; and the Woods Hole Oceanographic Institution), 2008. / This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections. / Includes bibliographical references. / Ecological processes at deep-sea hydrothermal vents on fast-spreading mid-ocean ridges are punctuated by frequent physical disturbance. Larval dispersal among disjunct vent sites facilitates the persistence of sessile invertebrate species in these geologically and chemically dynamic habitats despite local extinction events. Regional population extension and rapid recolonization by the siboglinid tubeworm Riftia pachyptila have been well documented along the East Pacific Rise and the Galápagos Rift. To analyze spatial and temporal population genetic patterns and the processes governing them at ephemeral and disjunct habitats, a suite of 12 highly variable microsatellite DNA markers were developed for this species. Eight of these loci were used to assess the regional and within-ridge genetic structure of recent colonists and resident adults collected from nine sites in the eastern Pacific Ocean over period of three to seven years. A significant seafloor eruption during the seven-year sampling period allowed investigation into the role of local extinction in population genetic diversity at the Tica vent site at 9°N EPR, while collections within two and five years of an eruption that created the Rosebud vent field at 86°W GAR provided insights into genetic diversity input over population establishment. For the first time, this thesis demonstrated significant genetic differences between Riftia populations on the East Pacific Rise and Galápagos Rift. Moreover, the separate treatment of colonist and resident subpopulations revealed a high potential for local larval retention at vent sites. This mechanism for recruitment likely sustains disjunct populations and supports the recolonization of locally extinct areas after disturbance events, while episodic long-distance dispersal maintains genetic coherence of the species. / (cont.) Temporal population genetic consideration at the Tica site on the East Pacific Rise suggests that the 2005-2006 seafloor eruption had little to no discernable effect on local population genetic composition. Yet local populations appear to exhibit a small degree of genetic patchiness, with a high degree of relatedness (half-sibs) among subsets of individuals within both colonist and resident cohorts. This thesis broadens the application of recently developed molecular techniques to study the effect of ridge-crest processes and offers new perspectives into marine dispersal, gene flow, and population differentiation. / by Abigail Jean Fusaro. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2013. / Cataloged from PDF version of thesis. / Includes bibliographical references. / Pb and Pb isotopes in the ocean have varied on decadal to centennial time scales due to anthropogenic Pb inputs. Thus, tracing the temporal variation of Pb and Pb isotopes in the ocean provides information on the major sources of Pb and the transport of Pb from sources to the ocean surface and into the ocean interior. In this thesis study, first, a method was developed for the analysis of dissolved Pb and other trace elements in seawater using single batch nitrilotriacetate resin extraction and isotope dilution ICP-MS, which was applied in analyzing seawater Pb concentrations in the rest of the study. A -550 year history of the Pb and Pb isotopes in the deep North Atlantic Ocean is reconstructed using a deep-sea coral, showing the infiltration of anthropogenic Pb to deep sea. Comparing the results to the surface North Atlantic Ocean Pb record using a Transit Time Distribution model, the mean transit time of Pb is estimated to be -64 years. This is longer than the transit time estimate assuming simple advection from a source, showing the importance of advective-diffusive mixing in the transport of Pb to the ocean interior. The later part of the thesis investigates Pb in the Indian Ocean, where no useful Pb data have been previously reported. First, using annually-banded surface growing corals, I reconstruct variations of Pb and isotopes in the surface waters of the central and eastern Indian Oceans during the past half-century. Results of the study show the increase of Pb concentrations from the mid-1970s, and major sources of the Pb are discussed, including leaded gasoline and coal burning, based on their emission histories and Pb isotope signatures. Second, Pb concentration and isotope profiles are presented from the northern and western Indian Oceans. Higher Pb concentrations and lower Pb isotope ratios (206Pb/ 207Pb, 208Pb/207Pb) are found in the upper water column (<I 500m) as a result of anthropogenic Pb inputs, and their distributions are largely controlled by the water circulation in the Indian Ocean. / by Jong-Mi Lee. / Ph.D.

Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2016. / Cataloged from PDF version of thesis. Page 156/Figure B-1 contains text that runs off the edge of the page margin. / Includes bibliographical references. / Paleoclimate archives place the short instrumental record of climate variability in a longer temporal context and allow better understanding of the rate, nature and extent by which anthropogenic warming will impact natural and human systems. The ocean is a key component of the climate system and records of past ocean variability are thus essential for characterizing natural variability and quantifying climate sensitivity to radiative forcing. Coral skeletons are high-resolution archives of tropical sea surface temperatures (SSTs), but inconsistencies call the accuracy of existing coral proxy records into question. In this thesis, I first quantify the errors associated with the traditional coral thermometer, Sr/Ca, by comparing in situ logged SST with Sr/Ca-derived SST in four corals on the same reef. I show that intercolony disparities in mean Sr/Ca, amplitude of variability, and trend are not due to differences in water temperature, but rather to "vital effects" that result in a ±2° C uncertainty on reconstructed SST. I then expand, refine, and test a new paleothermometer, Sr-U, across multiple coral species and through time. I show that Sr-U captures spatial SST variability with an uncertainty of ±0.6° C. When applied to two corals outside of the calibration, Sr-U accurately captures the mean SST and the 20th century trend in the Western Tropical Atlantic. Finally, I apply Sr-U to a coral from the Little Ice Age (LIA) to address uncertainties in the magnitude of western tropical Atlantic cooling during a 95-year period spanning 1465-1560. Results suggest the region was 1.1° C±0.6°C cooler than the 1958-1988 mean, but within error of early 20th century SST at this site. Critically, several periods of warmth, equivalent to the 1958-1988 mean, occurred during a solar minimum that is widely believed to have been a cool period of the LIA. My results indicate that Sr/Ca exaggerates the actual cooling by almost 3° C. My record demonstrates the value of Sr-U and highlights the need for continuous accurate SST records to better constrain the amplitude, drivers, and mechanisms of LIA tropical climate change. / by Alice Elizabeth Alpert. / Ph. D.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2008. / Includes bibliographical references (p. 54-56). / Landmines and mine-like traps are effective weapons that are difficult to detect and discriminate from a safe distance. The ability to detect landmines in their host environment at a distance and to discriminate them from other objects would be valuable for countering the landmine threat. This paper explores a standoff acoustic/laser technique to discriminate landmines from other forms of man-made objects (clutter) in an urban environment. A novel approach currently under investigation by MIT Lincoln Labs, University of Mississippi, and other groups employs a non-contact acoustic/laser technique to detect landmines from a safe standoff range. This technique uses a sound source to excite vibrations in targets with an acoustic wave. These vibrations are in turn measured remotely with a Laser Doppler Vibrometer (LDV). In this thesis, the vibration responses of landmine variants are measured, analyzed, and compared to those of common urban objects likely to be found on a landmine field or roadside. The Fourier Transform of the vibration of the target as measured by the LDV is used to generate a target vibration spectrum. Target vibration spectra in response to a sound source were experimentally measured for 59 trials, 28 of which were of simulated landmine variants and the remaining trials were of urban clutter objects. Using an algorithm adapted from a methodology for mass spectral analysis, parameters of the target signatures are estimated; then individual target signatures are classified using a Support Vector Machine (SVM) with a training set composed of parameters from the remaining members of the total population. The best results obtained from this methodology had a 71% probability of detection and a 3% false alarm rate corresponding to 20 of 28 of the simulated landmine variants correctly identified and a single clutter object misidentified as a landmine variant. / by John Houston Doherty. / S.M.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2008. / Includes bibliographical references (p. 159-170). / This thesis formulates an estimation framework for Simultaneous Localization and Mapping (SLAM) that addresses the problem of scalability in large environments. We describe an estimation-theoretic algorithm that achieves significant gains in computational efficiency while maintaining consistent estimates for the vehicle pose and the map of the environment.We specifically address the feature-based SLAM problem in which the robot represents the environment as a collection of landmarks. The thesis takes a Bayesian approach whereby we maintain a joint posterior over the vehicle pose and feature states, conditioned upon measurement data. We model the distribution as Gaussian and parametrize the posterior in the canonical form, in terms of the information (inverse covariance) matrix. When sparse, this representation is amenable to computationally efficient Bayesian SLAM filtering. However, while a large majority of the elements within the normalized information matrix are very small in magnitude, it is fully populated nonetheless. Recent feature-based SLAM filters achieve the scalability benefits of a sparse parametrization by explicitly pruning these weak links in an effort to enforce sparsity. We analyze one such algorithm, the Sparse Extended Information Filter (SEIF), which has laid much of the groundwork concerning the computational benefits of the sparse canonical form. The thesis performs a detailed analysis of the process by which the SEIF approximates the sparsity of the information matrix and reveals key insights into the consequences of different sparsification strategies. We demonstrate that the SEIF yields a sparse approximation to the posterior that is inconsistent, suffering from exaggerated confidence estimates. / (cont) This overconfidence has detrimental effects on important aspects of the SLAM process and affects the higher level goal of producing accurate maps for subsequent localization and path planning. This thesis proposes an alternative scalable filter that maintains sparsity while preserving the consistency of the distribution. We leverage insights into the natural structure of the feature-based canonical parametrization and derive a method that actively maintains an exactly sparse posterior. Our algorithm exploits the structure of the parametrization to achieve gains in efficiency, with a computational cost that scales linearly with the size of the map. Unlike similar techniques that sacrifice consistency for improved scalability, our algorithm performs inference over a posterior that is conservative relative to the nominal Gaussian distribution. Consequently, we preserve the consistency of the pose and map estimates and avoid the effects of an overconfident posterior. We demonstrate our filter alongside the SEIF and the standard EKEF both in simulation as well as on two real-world datasets. While we maintain the computational advantages of an exactly sparse representation, the results show convincingly that our method yields conservative estimates for the robot pose and map that are nearly identical to those of the original Gaussian distribution as produced by the EKF, but at much less computational expense. The thesis concludes with an extension of our SLAM filter to a complex underwater environment. We describe a systems-level framework for localization and mapping relative to a ship hull with an Autonomous Underwater Vehicle (AUV) equipped with a forward-looking sonar. The approach utilizes our filter to fuse measurements of vehicle attitude and motion from onboard sensors with data from sonar images of the hull. We employ the system to perform three-dimensional, 6-DOF SLAM on a ship hull. / by Matthew R. Walter. / S.M.

Thesis (M.S.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences and the Woods Hole Oceanographic Institution), 2003. / Includes bibliographical references (p. 181-191). / In this thesis I have endeavored to determine the factors and physical processes that controlled SST and thermocline depth at 10⁰N, 125⁰W during the Pan Amer- ican Climate Study (PACS) field program. Analysis based on the PACS data set, TOPEX/Poseidon sea surface height data, European Remote Sensing satellite wind data, and model simulations and experiments reveals that the dominant mechanisms affecting the thermocline depth and SST at the mooring site during the measurement period were local surface fluxes, Ekman pumping, and vertical mixing associated with enhancement of the vertical shear by strong near-inertial waves in the upper ocean superimposed upon intra-seasonal baroclinic Rossby waves and the large scale zonal flow. / by J. Thomas Farrar. / M.S.

Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2017. / Cataloged from PDF version of thesis. / Includes bibliographical references. / The marine carbon cycle plays an important role in regulating Earth's climate. The vastness of the open ocean and the large variability in the coastal ocean provide obstacles to accurately quantify storage and transport of inorganic carbon within marine ecosystems and between marine and other earth systems. Thus far, the open ocean has been the only true net sink of anthropogenic carbon dioxide (Canthro) emissions. However, ocean storage of Canthro is not uniformly distributed. Changes in water chemistry in the Northeast Pacific were quantified to estimate the amount of Canthro stored in this region over the last decade. This additional Canthro was found to cause acidification and aragonite saturation horizon shoaling at rates towards the higher end of those found in Pacific and Atlantic Ocean basins, making the Northeast Pacific one of the most sensitive regions to the invasion of anthropogenic carbon dioxide. Due to large variability in biogeochemical signals in coastal oceans, it is challenging to accurately assess carbon fluxes across different boundaries, such as tidal exchange between coastal wetlands and coastal oceans. Coastal salt marshes have been suggested to be a large net CO₂ sink, thus designated as a type of "blue carbon." However, accurate and dynamic estimates of carbon fluxes to and from tidal marshes are still premature, particularly carbon fluxes from marshes to the coastal ocean via tidal exchange, often referred to as marsh lateral fluxes. In this thesis, lateral total alkalinity (TA) and dissolved inorganic carbon (DIC) export fluxes were realistically quantified using high frequency time-series, in situ data. High-resolution fluxes permitted a closer look at how marsh generated TA and DIC are being exported over diurnal, spring-neap, and seasonal scales. I investigated the best way to capture variability of marsh exports via traditional bottle sampling and assessed uncertainties associated with different sampling strategies. Marsh TA and DIC exports significantly modified buffering capacity of coastal waters. This work contains the first realistic estimate of TA exports from a tidal salt marsh. Accurate estimates of DIC and TA fluxes indicate the significance of salt marshes to the coastal carbon and alkalinity budgets. / by Sophie Ning-Shin Chu. / Ph. D.