Thesis: S.M., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2015. / Cataloged from PDF version of thesis. / Includes bibliographical references (pages 119-122). / The scattering of low-mode internal tides by ocean-floor topography is extensively studied through analytical models and field observations at the Line Islands Ridge (LIR). An existing Green function method is utilized to examine the generation of internal tides by idealized topographic shapes as well as realistic transects of the LIR. The method is also applied to examine the scattering of a mode-1 internal tide at these topographies to determine the relative high mode energy flux due to generated and scattered internal tides at the realistic transects. A method of determining the modal content of an internal wave field is advanced to account for arbitrary stratification and rotation. It is then adjusted to allow for image loss as is common to oceanographic studies. Its performance is compared to the existing regression method widely used by oceanographers to determine the modal content of internal tides. The results from this comparison are used to inform the analysis of the field observations. This thesis concludes by examining the modal content of the LIR as determined from measurements taken during the 150-day EXperiment on Internal Tide Scattering (EXITS) NSF field study. Motivated by satellite altimetry data and three-dimensional numerical model studies, the EXITS cruise sought to observe the internal tide scattering process in the ocean for the first time. The data from three moorings equipped with moored profilers, spanning total depths of 3000-5000 m is analyzed to determine the modal content of the southward propagating internal tide before and after it encounters the ridge for evidence of topographic scattering. / by Maha Niametullah Haji. / S.M.

Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2018. / Cataloged from PDF version of thesis. / Includes bibliographical references. / The biological carbon pump (BCP) helps to moderate atmospheric carbon dioxide levels by bringing carbon to the deep ocean, where it can be sequestered on timescales of centuries to millennia. Climate change is predicted to decrease the efficiency of the global BCP, however, the magnitude and timescale of this shift is largely uncertain and will likely impact some areas of the global ocean more significantly than others. Therefore, it is imperative that we (1) accurately quantify surface export and remineralization of particulate organic carbon (POC) via the BCP over large regions of the global ocean, (2) examine the factors controlling these POC fluxes and their variability, which includes the cycling of biologically-relevant trace metals, and (3) establish if and how the BCP is changing over time. This thesis focuses on addressing various aspects of these objectives using the 234Th- 238U method across basin-scale GEOTRACES transects. First, the export and remineralization of POC were examined across large gradients in productivity, upwelling, community structure, and dissolved oxygen in the southeastern tropical Pacific Ocean. Although low oxygen zones are traditionally thought to have decreased POC flux attenuation relative to other regions of the global ocean and the low oxygen Pacific locations followed this pattern, regions that were functionally anoxic had enhanced attenuation in the upper 400 m. Second, trace metal export and remineralization were quantified across the Pacific transect. Because many trace metals are necessary for the metabolic functions of marine organisms and can co-limit marine productivity, the controls on the cycling of trace metals in the upper ocean were examined. Lastly, POC export was determined across two transects in the Western Arctic Ocean, where light and nutrient availability drive the biological pump. Upper ocean export estimates in the central basin did not reflect a substantial change in the biological pump compared to studies from the last three decades, however, an extensive maximum in 234Th relative to 238U deeper in the water column indicated that rapid vertical transport had occurred, which could suggest a more efficient biological pump in the Arctic Ocean. / by Erin E. Black. / Ph. D.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, and the Woods Hole Oceanographic Institution), 2003. / Includes bibliographical references. / The presence of aqueous organic compounds derived from sedimentary organic matter has the potential to influence a range of chemical processes in hydrothermal vent environments. For example, hydrothermal alteration experiments indicate that alteration of organic-rich sediments leads to up to an order of magnitude more metals in solution than alteration of organic-poor basalt. This result is in contrast to traditional models for the evolution of vent fluids at sediment-covered mid-ocean ridge axis environments, and indicates the fundamental importance of including the effects of organic compounds in models of crustal alteration processes. However, in order to rigorously constrain their role in crustal alteration processes, quantitative information on the abundances and distributions of organic compounds in hydrothermal vent fluids is required. This thesis was undertaken to provide quantitative information on the distributions and stable carbon isotopic compositions of several low-molecular weight organic compounds (C1-C4 alkanes, C2-C3 alkenes, benzene and toluene) in fluids collected in July, 2000, at three sites on the northern Juan de Fuca Ridge: the Dead Dog and ODP Mound fields, which are located at Middle Valley, and the Main Endeavour Field, located on the Endeavour segment. At Middle Valley, the ridge axis is covered by up to 1.5 km of hemipelagic sediment containing up to 0.5 wt. % organic carbon. The Main Endeavour Field (MEF) is located approximately 70 km south of Middle Valley in a sediment-free ridge-crest environment, but previously measured high concentrations of NH3 and isotopically light CH4 relative to other bare-rock sites suggest that the chemical composition of these fluids is affected by sub-seafloor alteration of sedimentary material (LILLEY et al., 1993). / (cont.) Differences in the absolute and relative concentrations of NH3 and organic compounds and the stable carbon isotopic compositions of the C1-C3 organic compounds suggest that the three fields represent a continuum in terms of the extent of secondary alteration of the aqueous organic compounds, with the Dead Dog fluids the least altered, the MEF fluids the most altered and ODP Mound fluids in an intermediate state. At the two Middle Valley sites, the greater extent of alteration in the ODP Mound fluids as compared to the Dead Dog fluids is due either to higher temperatures in the subsurface reaction zone, or a greater residence time of the fluids at high temperatures. Higher reaction zone temperatures at the ODP Mound field than at the Dead Dog field are consistent with differences in endmember Cl concentrations between the two fields. The greater extent of alteration in the MEF fluids is caused by relatively oxidizing conditions in the subsurface reaction zone that promote faster reaction kinetics. Temperatures in the subsurface reaction zones calculated by assuming equilibrium among aqueous alkanes, alkenes and hydrogen are ... / by Anna M. Cruse. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2012. / Cataloged from PDF version of thesis. / Includes bibliographical references. / The Indian monsoon affects the livelihood of over one billion people. Despite the importance of climate to society, knowledge of long-term monsoon variability is limited. This thesis provides Holocene records of monsoon variability, using sediment cores from river-dominated margins of the Bay of Bengal (off the Godavari River) and the Arabian Sea (off the Indus River). Carbon isotopes of terrestrial plant leaf waxes ([delta]¹³Cwax) preserved in sediment provide integrated and regionally extensive records of flora for both sites. For the Godavari River basin the ([delta]¹³Cwax record shows a gradual increase in aridity-adapted vegetation from ~4,000 until 1,700 years ago followed by the persistence of aridity-adapted plants to the present. The oxygen isotopic composition of planktonic foraminifera from this site indicates drought-prone conditions began as early as -3,000 years BP. The aridity record also allowed examination of relationships between hydroclimate and terrestrial carbon discharge to the ocean. Comparison of radiocarbon measurements of sedimentary plant waxes with planktonic foraminifera reveal increasing age offsets starting -4,000 yrs BP, suggesting that increased aridity slows carbon cycling and/or transport rates. At the second site, a seismic survey of the Indus River subaqueous delta describes the morphology and Holocene sedimentation of the Pakistani shelf and identified suitable coring locations for paleoclimate reconstructions. The ([delta]¹³Cwax record shows a stable arid climate over the dry regions of the Indus plain and a terrestrial biome dominated by C₄ vegetation for the last 6,000 years. As the climate became more arid ~4,000 years, sedentary agriculture took hold in central and south India while the urban Harappan civilization collapsed in the already arid Indus basin. This thesis integrates marine and continental records to create regionally extensive paleoenvironmental reconstructions that have implications for landscape evolution, sedimentation, the terrestrial organic carbon cycle, and prehistoric human civilizations in the Indian subcontinent. / by Camilo Ponton. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2010. / Cataloged from PDF version of thesis. / Includes bibliographical references. / Volcanic accretion at the fast-spreading East Pacific Rise (EPR) occurs over a ~2-4 km wide neo-volcanic zone on either side of the axial summit trough (AST). Eruption ages are critical for understanding the distribution and timing of volcanic and magmatic activity. Uranium series nuclides are susceptible to fractionation by magmatic processes that occur beneath mid-ocean ridges, and the half-lives of 22 6Ra (1.6 kyrs) and 23Th (75 kyrs) make them ideally suited for determining eruption ages and placing constraints on eruption frequency and temporal changes in magma chemistry. Accordingly, major and trace element, and long-lived radiogenic and 2 8 U-2 Th-226Ra isotope compositions were measured in basalts from 9'-10 N EPR to determine eruption ages and to place temporal constraints on volcanic and magmatic processes. At 9030'N EPR, 238U-2 Th-2 26Ra compositions indicate that trace elementally and isotopically enriched mid-ocean ridge basalt (MORB) collected off-axis erupted >8 ka and that E-MORB magmatism is interspersed with normal, depleted MORB magmatism. Lava ages are consistent with eruption from the AST and flow down the ridge flanks, which is in contrast to previous studies that suggested E-MORB erupted from off-axis vents. At 9'50'N EPR, discrete eruptive units are distinguished by high precision 238U, 32 Th, and 226Ra sample concentrations, but because the resolution of the "2 Th-226Ra model age dating technique is ~±1 kyrs, the surprisingly young ages of these lavas prohibit the construction of an explicit, time-constrained lava stratigraphy. Nonetheless, seven different flows identified within 0.8-2.0 km west of the AST imply greater frequency of flows to these distances than previously recognized. Model age dating of ferrobasalts, basaltic andesites, andesites, and dacites sampled from the east limb of the overlapping spreading center at 9'03'N EPR is difficult due to uncertainties in magma residence times. However, (22 6Ra/23 Th) disequilibria indicate recent basaltic volcanism (<<8 ka) up to -4 km off-axis. The axial graben at the rise crest sources the most recent volcanic activity and is the dominant location for eruption of high-silica magmas. Major element, trace element, 87Sr/86Sr, and (3 4U/238U) isotope compositions are consistent with the formation of dacite magmas by extensive crystallization, and 238U-2Fh-226 Ra systematics imply crustal residence times of -8 kyrs. / by Christopher L. Waters. / Ph.D.

Thesis: Sc. D., Joint Program in Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2019 / Cataloged from PDF version of thesis. / Includes bibliographical references (pages 207-218). / Ocean surface transport is at the core of many environmental disasters, including the spread of marine plastic pollution, the Deepwater Horizon oil spill and the Fukushima nuclear contamination. Understanding and predicting flow transport, however, remains a scientific challenge, because it operates on multiple length- and time-scales that are set by the underlying dynamics. Building on the recent emergence of Lagrangian methods, this thesis investigates the present-day abilities to describe and understand the organization of flow transport at the ocean surface, including the abilities to detect the underlying key structures, the regions of stirring and regions of coherence within the flow. Over the past four years, the field of dynamical system theory has adapted several algorithms from unsupervised machine learning for the detection of Lagrangian Coherent Structures (LCS). The robustness and applicability of these tools is yet to be proven, especially for geophysical flows. / An updated, parameter-free spectral clustering approach is developed and a noise-based cluster coherence metric is proposed to evaluate the resulting clusters. The method is tested against benchmarks flows of dynamical system theory: the quasi-periodic Bickley jet, the Duffing oscillator and a modified, asymmetric Duffing oscillator. The applicability of this newly developed spectral clustering method, along with several common LCS approaches, such as the Finite-Time Lyapunov Exponent, is tested in several field studies. The focus is on the ability to predict these LCS in submesoscale ocean surface flows, given all the uncertainties of the modeled and observed velocity fields, as well as the sparsity of Lagrangian data. This includes the design and execution of field experiments targeting LCS from predictive models and their subsequent Lagrangian analysis. / These experiments took place in Scott Reef, an atoll system in Western Australia, and off the coast of Martha's Vineyard, Massachusetts, two case studies with tidally-driven channel flows. The FTLE and spectral clustering analyses were particularly helpful in describing key transient flow features and how they were impacted by tidal forcing and vertical velocities. This could not have been identified from the Eulerian perspective, showing the utility of the Lagrangian approach in understanding the organization of transport. / by Margaux Filippi. / Sc. D. / Sc.D. Joint Program in Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution)

Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2015. / Cataloged from PDF version of thesis. / Includes bibliographical references. / This thesis investigates lithospheric dynamics of Earth's subduction zones and Martian tectonic provinces on multiple time scales ranging from short-term earthquake deformation to long-term tectonic loading. In Chapter 2, I use geodetic observations to constrain the postseismic viscoelastic deformation following the 1960 M9.5 Valdivia, Chile earthquake and quantify its stress loading on the rupture zone of the 2010 M8.8 Maule, Chile earthquake. Results of analysis reveal that the post-1960 viscoelastic process might have contributed to the triggering of the 2010 earthquake. Chapter 3 presents numerical experiments to investigate elastoplastic deformation and faulting in the overriding plates of subduction zones caused by the movement of subducted seamounts. Numerical simulations show that a group of normal faults would first appear on the seaward side of a subducted seamount, followed by a group of thrust faults on the landward side of the seamount. In Chapter 4, I use the most recent Martian gravity and topography data to constrain spatial variations in lithospheric flexural deformation for various tectonic regions on Mars. The effective lithospheric thickness is estimated to be relatively small for the plain regions in the southern highland, but relatively large for the impact basins in the northern lowland as well as for volcanic montes in the Tharis province. The regional variations in the estimated effective lithospheric thickness might reflect both spatial and temporal changes in the thermal state of Mars. / by Min Ding. / Ph. D.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2009. / Includes bibliographical references (p. 101-107). / Marine mammal whistle calls present an attractive medium for covert underwater communications. High quality models of the whistle calls are needed in order to synthesize natural-sounding whistles with embedded information. Since the whistle calls are composed of frequency modulated harmonic tones, they are best modeled as a weighted superposition of harmonically related sinusoids. Previous research with bottlenose dolphin whistle calls has produced synthetic whistles that sound too "clean" for use in a covert communications system. Due to the sensitivity of the human auditory system, watermarking schemes that slightly modify the fundamental frequency contour have good potential for producing natural-sounding whistles embedded with retrievable watermarks. Structured total least squares is used with linear prediction analysis to track the time-varying fundamental frequency and harmonic amplitude contours throughout a whistle call. Simulation and experimental results demonstrate the capability to accurately model bottlenose dolphin whistle calls and retrieve embedded information from watermarked synthetic whistle calls. Different fundamental frequency watermarking schemes are proposed based on their ability to produce natural sounding synthetic whistles and yield suitable watermark detection and retrieval. / by Jared Severson. / S.M.

Includes bibliographical references (leaves 189-191). / Thesis (S.M. in Oceanographic Engineering)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2006. / (cont.) To that end, the space-time correlations of the error, turbulence, and wave processes are developed and then utilized to find the extent to which the environmental and internal processing parameters contribute to this error. It is found that the wave-induced velocities, even when filtered, introduce error variances which are of similar magnitude to that of the Reynolds stresses. / The challenge of estimating the Reynolds stress in an energetic ocean environment derives from the turbulence process overlapping in frequency, or in wavenumber, with the wave process. It was surmised that they would not overlap in the combined wavenumber-frequency spectrum, due to each process having a different dispersion relationship. The turbulence process is thought to obey a linear dispersion relationship, as the turbulent flow is advected with the mean current (Taylor's frozen turbulence approximation). However, the Acoustic Doppler Current Profiler (ADCP) looks at radial wavenumbers and frequencies, and finds overlap. Another approach is to exploit the physical differences of each process, namely that the wave induced velocities are correlated over much larger distances than the turbulence induced velocities. This method was explored for current meters by Shaw and Trowbridge. Upon adapting the method for the ADCP, it is found that the resulting Reynolds stress estimates are of the correct order of magnitude, but somewhat noisy. The work of this thesis is to uncover the source of that noise, and to quantify the performance limits of estimating the Reynolds Stress when using ADCP measurements that are contaminated with strong wave-induced velocities. / by Mark Rapo. / S.M.in Oceanographic Engineering

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2013. / In title on title page, "[delta]" appears as lower case Greek letters. Cataloged from PDF version of thesis. / Includes bibliographical references. / The stable isotopes, [delta]¹⁵N and [delta]¹⁸O, of nitrite and nitrate can be powerful tools used to interpret nitrogen cycling in the ocean. They are particularly useful in regions of the ocean where there are multiple sources and sinks of nitrogenous nutrients, which concentration profiles alone cannot distinguish. Examples of such regions are "oxygen deficient zones" (ODZ). They are of particular interest because they are also important hot spots of fixed N loss and production of N₂O, a potent greenhouse gas. In order to interpret these isotope profiles, the isotope systematics of each process involved must be known so that we can distinguish the isotopic signature of each process. One of the important processes to consider here is nitrification, the process by which ammonium is oxidized nitrite and then to nitrate. This thesis describes numerous experiments using both cultures of nitrifying organisms as well as natural seawater samples to determine the oxygen isotope systematics of nitrification. These experimental incubations show that the accumulation of nitrite has a large effect on the resulting [delta]¹⁸ONO3. In experiments where nitrite does not accumulate, [delta]¹⁸ONO3 produced from nitrification is between -1 to l%o. These values will be applicable for the majority of the ocean, but the nitrite isotopic exchange will be important in the regions of the ocean where nitrite accumulates, such as the base of the euphotic zone and oxygen deficient zones. [delta]¹⁸ONO2 was developed as a unique tracer in this thesis because it undergoes abiotic equilibration with water [delta]¹⁸O at a predictable rate based on pH, temperature and salinity. This rate, its dependencies, and how the [delta]¹⁸ONO2 values can be used as not only biological source indicators but also indicators of age are described. This method was applied to samples from the primary nitrite maximum in the Arabian Sea, revealing that the dominant source and sinks of nitrite are ammonia oxidation and nitrite oxidation with an average age of 37 days. Finally, using the isotope systematics of nitrification as well as the properties of nitrite oxygen isotope exchange described in this thesis, the final chapter interprets multiisotope nitrate and nitrite profiles in the Costa Rica Upwelling Dome using a simple ID model. The nitrite isotopes showed that there were multiple sources of nitrite in the primary nitrite maximum including (1) decoupling of ammonia oxidation and nitrite oxidation, (2) nitrate reduction during assimilation and leakage of nitrite by phytoplankton. In the oxygen deficient zone and secondary nitrite maximum, there were equal contributions of nitrite removal from nitrite oxidation and nitrite reduction. This recycling of nitrite to nitrate through oxidation indicates that the percentage of reduced nitrate fully consumed to N2 gas is actually smaller than previous estimates. Overall, this thesis describes new nitrogen and oxygen isotopic tracers and uses them to elucidate the complicated nitrogen biogeochemistry in oxygen deficient zones. / by Carolyn Buchwald. / Ph.D.