Master of Science / Department of Geology / Matthew Kirk / Groundwater from the High Plains aquifer is vital for food production and a growing human population in the Great Plains region of the United States. Understanding how groundwater quality is changing in response to anthropogenic and natural processes is critical to effectively managing this resource. Our study considers variation in groundwater geochemistry in the Great Bend Prairie aquifer, a portion of the High Plains aquifer in southcentral Kansas. We collected samples during summer 2016 from 24 monitoring wells and compared our results to data collected previously from the same wells from 1979 to 1987. We sampled 13 wells screened in the upper portion of the aquifer (avg. depth 72 ft), 10 wells screened near the aquifer base (avg. depth 141 ft), and one well screened in underlying bedrock. Compared to initial samples, samples we collected tended to have higher total dissolved solids (TDS) and nitrate content, particularly those we collected from the upper aquifer. Compared to initial samples, TDS was 78 mg/L higher in samples we collected from the upper aquifer and 373 mg/L lower in samples we collected from the aquifer base on average. Nitrate exceeded the U.S. standard for public supplies of drinking water (10 mg/L as N) in seven of the samples we collected, compared to only two samples collected previously. Compared to previous samples, nitrate concentrations were 9.5 and 3.9 mg/L as N higher on average in samples collected from the upper aquifer and aquifer base, respectively. Based on a mixing analysis, variation in the salinity of our samples primarily reflects the dilution of natural Permian brines by freshwater recharge throughout the area. However, salinity decreases observed in four samples reflects flushing of initial oil brine contamination over time, salinity increases in two samples may be due to evapotranspiration, and salinity increases in two samples may reflect migration of oil-brine contamination towards the site. Stable nitrogen (15N/14N) and oxygen (18O/16O) isotope ratios in our samples primarily fall within the range typical of nitrification of ammonium-based fertilizers with potential contributions from manure or sewage. In our analysis of the microbial community, we observed groups capable of denitrification, including genera within Nitrospirae, Firmicutes, and Proteobacteria. Despite their presence, our results demonstrate that water quality in the aquifer has degraded over the past 30 to 40 years due to nitrate accumulation.

Philosophiae Doctor - PhD / The Table Mountain Group (TMG) Aquifer is a huge aquifer system which may provide large bulk water supplies for local municipalities and irrigation water for agriculture in the Western Cape and Eastern Cape Provinces in South Africa. In many locations, water pressure in an aquifer may force groundwater out of ground surface so that the borehole drilled into the aquifer would produce overflow without a pump. Appropriate testing and evaluation of such artesian aquifers is very critical for sound evaluation and sustainable utilization of groundwater resources in the TMG area. However, study on this aspect of hydrogeology in TMG is limited. Although the flow and storage of TMG aquifer was conceptualised in previous studies, no specific study on artesian aquifer in TMG was made available. There are dozens of flowing artesian boreholes in TMG in which the pressure heads in the boreholes are above ground surface locally. A common approach to estimate hydraulic properties of the aquifers underneath is to make use of free-flowing and recovery tests conducted on a flowing artesian borehole. However, such testing approach was seldom carried out in TMG due to lack of an appropriate device readily available for data collection. A special hydraulic test device was developed for data collection in this context. The test device was successfully tested at a flowing artesian borehole in TMG. The device can not only be used to measure simultaneous flow rate and pressure head at the test borehole, but also be portable and flexible for capturing the data during aquifer tests in similar conditions like artesian holes in Karoo, dolomite or other sites in which pressure head is above ground surface. The straight-line method proposed by Jacob-Lohman is often adopted for data interpretation. However, the approach may not be able to analyse the test data from flowing artesian holes in TMG. The reason is that the TMG aquifers are often bounded by impermeable faults or folds at local or intermediate scale, which implies that some assumptions of infinite aquifer required for the straight-line method cannot be fulfilled. Boundary conditions based on the Jacob-Lohman method need to be considered during the simulation. In addition, the diagnostic plot analysis method using reciprocal rate derivative is adapted to cross-check the results from the straight-line method. The approach could help identify the flow regimes and discern the boundary conditions, of which results further provide useful information to conceptualize the aquifer and facilitate an appropriate analytical method to evaluate the aquifer properties. Two case studies in TMG were selected to evaluate the hydraulic properties of artesian aquifers using the above methods. The transmissivities of the artesian aquifer in TMG range from 0.6 to 46.7 m2/d based on calculations with recovery test data. Storativities range from 10-4 to 10-3 derived from free-flowing test data analysis. For the aquifer at each specific site, the transmissivity value of the artesian aquifer in Rawsonville is estimated to be 7.5–23 m2/d, with storativity value ranging from 2.0×10-4 to 5.5×10-4. The transmissivity value of the artesian aquifer in Oudtshoorn is approximately 37 m2/d, with S value of 1.16×10-3. The simulation results by straight-line and diagnostic plot analysis methods, not only imply the existence of negative skin zone in the vicinity of the test boreholes, but also highlight the fact that the TMG aquifers are often bounded by impermeable faults or folds at local or intermediate scale. With the storativity values of artesian aquifers derived from data interpretation, total groundwater storage capacity of aquifers at two case studies was calculated. The figures will provide valuable information for decision-makers to plan and develop sustainable groundwater utilization of artesian aquifers in local or intermediate scales. With the hydraulic test device readily available for data collection, more aquifer tests can be carried out in other overflow artesian boreholes in TMG. It becomes feasible to determine the hydraulic properties of artesian aquifers for the entire TMG. Thereof quantification of groundwater resources of artesian aquifers in TMG at a mega-scale becomes achievable. This would also contribute towards global research initiative for quantification of groundwater resources at a mega-scale.

No description available.

Soil aquifer treatment (SAT), the removal of contaminants during percolation through soil, is a strategy employed in managed aquifer recharge (MAR), one method of indirect potable water reuse. As part of Hampton Roads Sanitation District's (HRSD) MAR project, The Sustainable Water Initiative for Tomorrow (SWIFT), a soil column study was performed using four columns filled with sand taken from the Potomac Aquifer System (PAS) as well as water from various stages in SWIFT's 1MGD demonstration facility. Two pairs of two columns were operated in series, simulating 3 days and 1 month of travel time through aerobic to anaerobic conditions. During Phase 1 of testing, each pair of columns was fed from different stages in the SWIFT treatment process. During Phase 2 of testing, one set of columns was spiked with a conservative tracer bromide, and several contaminants of emerging concern (CECs). The contaminants monitored during both phases included total organic carbon (TOC), nitrogen species, and the disinfection byproducts bromate and NDMA. During Phase 2 of testing, CECs, iron, arsenic, bromide, and sulfate were monitored in addition to those monitored during Phase 1. About 50% of the TOC was removed within 3 days of travel time, with no additional removal observed in 1 month. Nitrate was conserved in the 3-day columns, but completely removed after 1 month, indicating denitrification. Bromate and NDMA were reduced significantly in the 3-day columns and mostly non-detect in the 1-month effluent. Many of the spiked CECs were reduced significantly in the 3-day column indicating degradation. Three compounds exhibited some retardation through both columns but were not degraded. A few compounds, notably perfluorooctanoic acid (PFOA), showed no retardation or degradation. / Master of Science / In order to continue to meet the water demands of the future, potable reuse is a necessary and effective solution. HRSD's SWIFT project aims to create a sustainable source of drinking water through advanced treatment of its wastewater effluent and subsequent recharge of the Potomac Aquifer in a process known as managed aquifer recharge (MAR). During MAR, chemical and biological contaminants are attenuated or removed through a process known as soil aquifer treatment (SAT). HRSD installed pilot-scale soil columns at their 1MGD SWIFT demonstration facility to evaluate the potential removal of contaminants. During the study, removal of contaminants, both regulated and unregulated, was observed. This study demonstrated that SAT provides an effective environmental barrier against many contaminants and helped to inform the level of treatment necessary to protect public health during MAR potable reuse projects.

Soil aquifer treatment (SAT) during managed aquifer recharge has been studied as a method of providing additional environmental barriers to pathogens and contaminants in indirect potable reuse (IPR) applications. A soil column study was conducted by Hampton Roads Sanitation District in order to evaluate the effectiveness of SAT, as a component of its IPR project involving the replenishment of the Potomac Aquifer System (PAS), in providing a sustainable source of drinking water. Four packed soil columns were constructed with sand from the PAS and were designed to simulate the travel time of 3 days and 30 days. The tests conducted aimed at evaluating pathogen removal (MS2, E. coli and Cryptosporidium oocysts); evaluating attenuation of regulated (nitrate, nitrite, bromate, trihalomethane (THM), haloacetic acids (HAA), organic carbon) and unregulated contaminants of concern that affect drinking water quality. Effective pathogen removal was observed with 6 to 7-log removals of MS2 and E. coli and 3 to 5-log removals of microbeads, used as a surrogate for Cryptosporidium. Removal across 3 day columns was comparable to 30-day columns but the potential to achieve higher removal with longer retention time was acknowledged. Nitrate, bromate, THMs and HAAs were completely reduced in 30-day columns. Total organic carbon was removed at 25 – 35% in all four columns. Seven out of the 106 contaminants of emerging concern (CEC) tested were consistently detected in the column feed and effluent at concentrations greater than 100 ng/L; some compounds showed potential for removal while no conclusive results were drawn for the remaining compounds. / MS / Potable reuse is a sustainable solution to the increasing water demands of the present and more so the future. Hampton Road Sanitation District (HRSD) aims to treat effluent from its wastewater treatment plants using advanced treatment process for direct recharge of the Potomac aquifer system. This is a method of indirect potable reuse termed as managed aquifer recharge (MAR). MAR can provide additional environmental barriers to contaminants present in water through a process of natural attenuation called soil aquifer treatment (SAT). A soil column study was conducted at HRSD’s pilot scale facility in order to asses SAT under controlled conditions at a meaningful scale. Attenuation of pathogens; regulated contaminants (nitrate, nitrite, bromate, etc.) and contaminants of emerging concern was evaluated through the soil columns. The results showed effective removal of most contaminants of interest which demonstrated that SAT potentially improves water quality and meets public health standards in potable reuse applications.

The use of cross-correlation analysis on spring discharge and precipitation data in karst aquifer basins has been used for many years to develop a conceptual understanding of an aquifer and estimate aquifer properties. However, to this point, the application of these processes has relied on gaged precipitation at discrete locations. The use of spatially varying precipitation data and cross-correlation analysis provides a means of spatially characterizing recharge locations on a karst aquifer. NEXRAD provides a spatial estimate of precipitation based by combining reflectivity measurements from radar stations and traditional precipitation gages. This study combines NEXRAD precipitation data with spring discharge data to develop maps of contributing areas for two karst springs in Central Texas. By calculating the cross-correlation of each NEXRAD measurement to spring flow data for the same period of time a map showing the locations hydraulically connected to the spring can be developed. Both numerical experiments and field applications were conducted as part of the study. The numerical experiments conducted by Padilla and Pulido-Bosch are revisited using the numerical groundwater model MODFLOW. This allowed the introduction of spatially varying parameters into the model. The results show that spatially varying parameters can be inferred based on the results cross-correlation of spatially varying precipitation with respect to a single spring discharge location. Also, contributing area maps are prepared for both Barton Springs and Jacob’s Well. Barton Springs has a precise estimate of the recharge area. The current map of the recharge area and the NEXRAD derived map show good agreement with the cross-correlation results. Conversely, Jacob’s Well has not been sufficiently studied to delineate a contributing area map. This study provides an preliminary estimate of the area contributing to flow at Jacob’s Well. Finally, the development of these maps can also be applied to the construction of regional groundwater models. An application of this methodology with the groundwater availability model for the Barton Springs portion of the Edward’s aquifer is introduced. The application of spatial cross-correlation analysis to constrain recharge in the model showed a reduction in the objective function with respect to discharge at Barton Springs of 15%. / text

Masters of Science / The thesis investigates the potential of the Rietfontein and Spitskop aquifer to meet a demand of 1000 m3/d (12 Lis) as an alternative water resource for the Rietfontein and Spitskop Community. Increasing demand for clean and hygienic drinking water puts more pressure on one of our most valuable resources and supplying all communities with surface water is an extremely difficult and costly task in rural areas like Rietfontein and Spitskop in South Africa. Therefore it is necessary that interim water supplies be found from local aquifers and be utilized to address water supply challenges. Groundwater may serve as a short-term and an interim water supply which may be useful during future dry periods. Abstraction of groundwater is sensitive to recharge. Due to semi-arid conditions in Rietfontein and Spitskop area, there is high rainfall variation and disparity each year. During the research, hydrocensus was carried out. Water samples for chemistry analysis were taken. Literature review and pumping test data was utilized from the previous studies done by different consultants (Botha, 2000, Vivier and Pretorius, 2003). A numerical groundwater flow model for the local aquifers in the area and surroundings was constructed focusing on recharge and abstraction scenarios for the water supply from the local aquifers. For Rietfontein and Spitskop area, the mean annual precipitation (MAP) is 617mm/year. To be assured and rational in determining aquifers ability to meet the required demand a recharge with ninety-five (95th ) percentile was recommended, which estimates the MAP of 308mm/year which is 50% lower than the average MAP of 617mm/year. For a period of ninety six (96) years, the data indicates a severe drought occurred four (4) times where the rainfall was even lower than 95th percentile level of assurance of recharge estimated. This gives a comprehensible indication that average mean is not ideal or steadfast stature when building a water supply numerical groundwater flow modelling. These aquifers can only be exploited and managed if a reliable method can be obtained to estimate their long-term sustainable potential, since the sustainable potential of these aquifers to supply the communities is dependent upon the recharge from rainfall. The results from a numerical groundwater flow model indicated that a combined potential from the local aquifer from eighteen (18) boreholes is sufficient to meet the required demand and a total of 2600m3 Id can potentially be abstracted from the aquifer. With ninety-five (95th ) percentile recharge rate of 308mm/year a numerical groundwater flow model shows that the rate of abstraction is 80% far less than recharge, which gives high level of assurance in terms of local aquifer water supply demand. The abstraction of the boreholes confirmed by a numerical groundwater flow model shows the least impact on the surrounding aquifer for an extended period of time. In the event of drought, the boreholes will see a decline in water level after two (2) months of pumping local aquifer. The water level will decline steadily from two (2) months to two (2) years with a change in water levels of up to 40m. The impact of the drought is minimal compared to recharge rate, which verifies less depletion of the aquifer. The local aquifer shows the potential of 3MLld can be supplied to the communities with an assurance level of 95th percentile of rainfall. Reliable quantification of groundwater recharge rate remains the main challenges the hydrologist experienced and further research is essential for improvement of groundwater management for the area concerned.

Master of Science / Department of Civil Engineering / David R. Steward / A one-dimensional model was developed to study the flow of groundwater in the sloping Ogallala Aquifer at a steady state during predevelopment condition. The sloping base was approximated using a stepping base model. GIS applications were applied during data collection and preparation, and later during interpretation of model results. Analytical and numerical methods were employed in the development of this model which was used to try to understand long-term water balance in the study region. The conservation of mass was achieved by balancing groundwater input, output, and storage; this led to understanding the interactions of groundwater and surface water in the predevelopment conditions. The study resulted in identification of where natural discharge from groundwater to surface water occurred, and the quantity of these flows was obtained. The Ogallala Aquifer is thick in the south western part of Kansas, this region had an average saturated thickness of 100m during predevelopment conditions. The model found that groundwater flowed at a discharge per width of approximately 17 m[superscript]2/d in this region. The aquifer thickness tends to gradually decrease from west to east and from south to north. The northern part had an average saturated thickness of 40m during predevelopment conditions; the model found that groundwater flowed at a discharge per width of approximately 3 m[superscript]2/d in this region. It was also found that groundwater leaves the Ogallala Aquifer on the eastern side with discharge per width between 0-3 m[superscript]2/d. The discharge from groundwater to surface water was summed over contributing areas to river basins. The discharge to streams necessary to satisfy long-term conservation of mass computed by the model showed that Cimarron River has total baseflow of about 5.5 m[superscript]3/s; this was found to be almost 100% of the total streamflow recorded during predevelopment conditions. The Arkansas River was found to have total baseflow of about 0.97 m[superscript]3/s, which is approximately 14.3% of the total streamflow recorded during predevelopment conditions. The Smoky Hill River was found to have total baseflow of about 1.7 m[superscript]3/s, which is approximately 73.9% of the total streamflow recorded during predevelopment conditions. The Solomon River was found to have total baseflow of about 0.95 m[superscript]3/s, which is approximately 41.1% of the total streamflow recorded during predevelopment conditions. The Saline River was found to have total baseflow of about 0.25 m[superscript]3/s, which is approximately 62.5% of the total streamflow recorded during predevelopment conditions. The Republican and Pawnee River was found to have total baseflow of about 0.38 m[superscript]3/s and 0.22 m[superscript]3/s, which is approximately 18.5% and 12.6% of the total streamflow in the predevelopment conditions respectively. The model was found to be always within -16 to +12 meters between observed values and the model results, with an average value of 0.15m and a root mean square error of 1.98m. Results from this study can be used to advance this study to the next level by making a transient model that could be used as a predictive tool for groundwater response to water use in the study region.

Seepage from steelmaking coal mine waste rock dumps in the Elk Valley, British Columbia, Canada can contain selenium (Se), cadmium (Cd), and sulfate (SO42-) from the oxidation of sulfide minerals, and nitrate (NO3-) from blasting. The impact of these constituents of interest (CIs) on receiving groundwater systems and the potential for their natural attenuation is investigated. A 10.7 km2 mine-impacted research catchment (West Line Creek) was instrumented with 13 monitoring wells and 8 drivepoint wells to characterize the hydraulics and geochemistry of the aquifer system downgradient of the waste rock dump. These data were augmented with geophysical surveys and by characterizing the lithology, geotechnical properties, and geochemistry of core samples obtained during drilling. Furthermore, the groundwater monitoring program also facilitated the development of a conceptual model of hydrogeology in a small montane valley. An unconfined aquifer at the overburden/fractured bedrock interface, i.e. the basal alluvial aquifer was identified as the primary groundwater conduit for the migration of water and solutes from the waste rock dump toward Line Creek. Vertical and horizontal dispersion of CIs was confirmed with porewater analysis of core samples, with Se concentrations exceeding the BC water quality guideline (2.0 µg/L) in 98% of samples (n = 223). Residence time for groundwater in the overburden aquifers was determined using 3H/3He age dating (n = 3) and estimates of groundwater velocity to be less than three years across the 650 m study site. The chemistry of groundwater was compared with rock drain water samples to evaluate CIs from their source through to identified discharge locations. Linear correlation of CI concentrations with SO42- concentrations in water samples showed that Se and NO3- were conservative solutes, whereas Cd was non-conservative and may be undergoing mineral precipitation or adsorption reactions in the groundwater system. The distribution of CIs in the overburden aquifers was seasonally variable and dilution was determined to be the dominant mechanism controlling the concentrations of conservative CIs (Se, SO42- and NO3-) away from the toe of the waste rock dump and during the spring freshet. The basal alluvial aquifer downgradient of the waste rock dump was estimated to annually discharge 16% of the water and 7% of the SO42- load from the catchment.

<p>Present master of science thesis has been carried out at the Swedish Road Administration consulting services (Vägverket Konsult) in Karlstad. The purpose of the study is to investigate how well the calculated drawdown of the groundwater table predicts the actual drawdown when the road and railway gates at the studied sites are built. For this purpose the groundwater levels at the three bridges were measured during 6 months. The bridges in question are two railway bridges situated in Ölme and Ulvåker and one road bridge crossing a pedestrian and cycling path in Lidköping.</p><p>In Ölme the calculated area of influence was smaller than the measured one. It differed up to 30 meters, i.e. 80 %.</p><p>In Lidköping the calculated area of influence agreed well with the measured one, but the groundwater level that the calculations were made from was more than one meter too low.</p><p>In Ulvåker the measured groundwater levels were influenced by other factors and no conclusions could be drawn.</p><p>When calculating how the groundwater level is affected from road and railway bridge constructions it is important to make sure to measure the groundwater level before the construction is made so that the unaffected level is known. Moreover the radius of the well should be set to a value less than 0.5 meters. It is also important that the conductivity is investigated thoroughly especially for confined aquifers. When measuring groundwater levels the examiner must make sure to plan the distances and depths of the piezometer wells, when to perform the measurements and how to protect the water in the wells from freezing.</p> / <p>Detta examensarbete är utfört på Vägverket Konsult i Karlstad. Syftet med arbetet är att med några exempel undersöka hur väl den beräknade permanenta grundvattensänkningen överensstämmer med den verkliga grundvattensänkning som görs vid byggen av vägportar. Arbetet utfördes genom att under 6 månader mäta grundvattennivåerna vid tre vägportar. De undersökta portarna är en väg – järnvägport i Ölme, en gång- och cykelväg – vägport i Lidköping och en väg – järnvägport i Ulvåker.</p><p>I Ölme framkom att den permanenta grundvattensänkningen har ett större influensområde än den beräknade. Differensen uppgick som mest till 30m vilket motsvarar en avvikelse på ca 80 %.</p><p>I Lidköping överensstämmer beräkningen av influensradierna väl med de uppmätta, medan grundvattennivån som beräkningarna gjordes från ligger drygt en meter för lågt.</p><p>I Ulvåker är den uppmätta avsänkningen påverkad av yttre faktorer och därför kan inga slutsatser dras.</p><p>Vid grundvattensänkningsberäkningar är det viktigt att den opåverkade grundvattennivån är känd, att brunnsradien sätts till ett tal mindre än 0,5 meter och att bestämningen av konduktiviteten är extra noga vid sluten akvifer. När grundvattennivåerna ska mätas bör avstånd och höjdnivå på grundvattenrören bestämmas noga, mätningarna utföras kontinuerligt under en längre tid och eventuell tillsats av frostskydd i grundvattenrören tänkas igenom.</p>