methane and other higher order hydrocarbons, through C4, with interest in further developing reactions important to methane- and ethane-related chemistry. With the increased demand for energy and the declining conventional hydrocarbons worldwide, energy companies, both majors and independents, are turning to unconventional resources to produce the hydrocarbons required to meet market demand. From coalbed methane to low permeability (tight) gas reservoirs and gas shales, energy companies are making substantial progress in developing the technologies required to bring these unconventional reserves to the market. A common misconception is that there are not enough domestic oil and gas reserves to fuel our economy. The United States imports most of the oil used for transportation fuel and several TCF of natural gas annually. However, there is a very large resource of natural gas in unconventional reservoirs, with over 2,200 TCF of gas in place in just the gas shale formations that have been identified in the energy arena (Navigant Study 2008). There are still major gas shale plays and basins that have not been explored and are waiting to be evaluated and developed. The natural gas in shales and other unconventional reservoirs can be used to generate electricity, or it can be turned into liquids and used by the transportation industry. It is also misconstrued that gas shales are relatively new in our industry and something of the future. The first commercially viable gas shale well was drilled in the early 1920s in Pennsylvania, before the famous oil well drilled by Colonel Drake. The objectives of this study are to (1) complete literature review to establish which geologic parameters affect completion techniques in five emerging gas shales: the Antrium, the Barnett, the Haynesville, the Marcellus, and the Woodford; (2) identify the different completion methods; (3) create an economic model for the completion techniques discussed; (4) develop a sensitivity analysis on various economic parameters to determine optimal completion strategy; and (5) create completion flowcharts. Based on the literature review I have done for several gas shale basins, I have identified seven pertinent geologic parameters that influence completion practices. These are depositional environment, total organic content (TOC), average gas content, shale mineralogy, shale thickness, and reservoir pressure. Next, I identified different completion and simulation trends in the industry for the different shale plays. The results from this study show that although there are some stark differences between depths (i.e. the Antrim Shale and the Haynesville Shale), shale plays are very similar in all other geologic properties. Interestingly, even with a large range for the different geological parameters, the completion methods did not drastically differ indicating that even if the properties do not fall within the range presented in this paper does not automatically rule them out for further evaluation in other plays. In addition to the evaluation of geologic properties, this study looked at drilling cost and the production profile for each play. Due to the volatility of the energy industry, economic sensitivity was completed on the price, capital, and operating cost to see what affect it would have on the play. From the analysis done, it is concluded that horizontal drilling in almost any economic environment is economic except for one scenario for the Woodford Shale. Therefore, gas shales plays should still be invested in even in lower price environments and companies should try to take advantage of the lower cost environments that occur during these times. With continual development of new drilling and completion techniques, these plays will become more competitive and can light the path for exploration of new shale plays worldwide.

Texas water resources are under pressure due to population growth expected in the coming decades, increasing industrial demands, and frequent periods of drought. With this increasing demand for limited water resources it is important to explore alternative water sources within the State. One of those resources that can be developed is the many small aquifers which have never been well-characterized but could be an alternative source of fresh and brackish water for agriculture, municipal, and industrial applications. The natural gas industry’s demand for water is growing in Texas as new drilling techniques such a hydraulic fracturing have opened new reserves previously considered economically non-viable. The development of smaller aquifers containing brackish water is a viable alternative to the gas industry’s current reliance on fresh (potable) groundwater resources. The aquifer sections containing brackish water need to be mapped and characterized so they can be developed as an alternative water resource by the gas industry. The Barnett Shale in North-central Texas is one of the first major gas plays in the United States to use the technique of hydraulic fracturing in field development. This technique requires large quantities of water to create the required hydraulic pressure down the gas well to fracture the normally low permeability shale. A typical horizontal well completion consumes approximately 3.0 to 3.5 million gallons (11,400 to 13,200 m3) of fresh water. Projections of future groundwater demand for the Barnett Shale gas play total 417,000 AF (5.1x108 m3), an annual average of 22,000 AF (2.7x107 m3) over the expected 2007-2025 development phase. This level of water demand has the gas industry and groundwater managers exploring alternative sources of water for future development of the Barnett Shale. One alternative source of water for the expanding footprint of the Barnett Shale gas play are the smaller local Paleozoic aquifers on the western edge of the play. These small aquifers are underutilized and contain waters with higher levels of TDS. These levels are, however, acceptable to the drilling industry. In order to characterize theses aquifers, TWDB databases were utilized to analyze water chemistry and well productivity. / text

Frequently a discrepancy is found between the stimulated shale volume (SSV) estimated from production data and the SSV expected from injected water and proppant volume. One possible explanation is the presence of a fracture network, often termed fracture complexity, that may have been opened or reopened during the hydraulic fracturing operation. The main objective of this work is to investigate the role of fracture complexity in resolving the apparent SSV discrepancy and to illustrate whether the presence of reopened natural fracture network can be observed in pressure and production data of shale gas wells producing from two shale formations with different well and reservoir properties. Homogeneous, dual porosity and triple porosity models are investigated. Sensitivity runs based on typical parameters of the Barnett and the Horn River shale are performed. Then the field data from the two shales are matched. Homogeneous models for the two shale formations indicate effective infinite conductivity fractures in the Barnett well and only moderate conductivity fractures in the Horn River shale. Dual porosity models can support effectively infinite conductivity fractures in both shale formations. Dual porosity models indicate that the behavior of the Barnett and Horn River shale formations are different. Even though both shales exhibit apparent bilinear flow behavior the flow behaviors during this trend are different. Evidence of this difference comes from comparing the storativity ratio observed in each case to the storativity ratio estimated from injected fluid volumes during hydraulic fracturing. In the Barnett shale case similar storativity ratios suggest fracture complexity can account for the dual porosity behavior. In the Horn River case, the model based storativity ratio is too large to represent only fluids from hydraulic fracturing and suggests presence of existing shale formation microfractures.

In North Texas, the Barnett Shale underlies large areas of the Dallas-Fort Worth Metroplex (DFW), which magnifies debates about the externalities of shale gas development (SGD). Continued demand for natural gas and expansive urbanization in DFW will cause more people to come in contact with drilling rigs, gas transport, and other urban shale gas landscapes. Thousands of gas wells within the DFW region occupy a large, yet scattered land surface area. DFW city planners, elected officials, and other stakeholders must deal with current and future urban growth and the surface impacts that are associated with gas development. This research examines how shale gas landscapes affect urban land uses, landscapes, and patterns of development in DFW. The study focuses on multiple fast growing DFW municipalities that also have high numbers of gas well pad sites. This study asks what are the spatial characteristics of gas well production sites in DFW and how do these sites vary across the region; how do gas well production sites affect urban growth and development; and how are city governments and surface developers responding to gas well production sites, and what are the dominant themes of contestation arising around gas well production sites and suburban growth?

Municipalities protect human health and environmental resources from impacts of urban natural gas drilling through setback distances; the regulation of distances between well sites and residences, freshwater wells, and other protected uses. Setback distances have increased over time, having the potential to alter the amount and geographical distribution of drillable land within a municipality, thereby having implications for future land use planning and increasing the potential for future incompatible land uses. This study geographically applies a range of setback distances to protected uses and freshwater wells in the city limits of Denton, Texas to investigate the effect on the amount of land remaining for future gas well development and production. Denton lies on the edge of a productive region of the Barnett Shale geological formation, coinciding with a large concentration of drillable land in the southwestern region of the study area. This region will have the greatest potential for impacts to future municipal development and land use planning as a result of future gas well development and higher setback standards. Given the relatively high acreage of drillable land in industrially zoned subcategory IC-G and the concern regarding gas well drilling in more populated areas, future drilling in IC-G, specifically in IC-G land cover classes mowed/grazed/agriculture and herbaceous, would have the least impact on residential uses and tree cover, as well as decreasing the potential for future incompatible land uses.

The Barnett shale basin, the largest onshore gas field in the state of Texas, mainly produces natural gas. The basin’s oil and gas productions have dramatically increased over the past two decades with the enhancement via shale fracturing (fracking) technology. However, recent studies suggest that air emissions from shale fracking have significantly contributed to the growing air pollution problem in North Texas. In this study, air emissions from the Barnett shale basin during the production phase of the oil and gas activities (once the product is collected from the wells) are quantified. Oil and gas production data were acquired from the Texas Railroad Commission for the baseline years of 2010 through 2013. Methodology from prior studies on shale basins approved by the Texas Commission on Environmental Quality was employed in this study and the emission inventories from the production phase sources were quantified. Accordingly, the counties with the most gas operations in the basin, Tarrant, Johnson, Denton and Wise, were found to be the highest emitters of air pollutants. Tarrant County was responsible for the highest emitted NOx (42,566 tons) and CO (17,698 tons) in the basin, while Montague County released the maximum VOC emissions (87,601 tons) during the study period. Amongst the concerned emitted pollutants, VOC was the largest emitted pollutant during the study period (417,804 tons), followed by NOx (126,691 tons) and CO (47,884 tons). Significant Sources of air emissions include: storage tanks, wellhead compressor engines, and pneumatic devices. Storage tanks and pneumatic devices contributed to about 62% and 28% of the total VOC emissions, respectively. Whereas, wellhead compressor engines are primarily responsible for about 97% of the total NOx emissions. Finally, in Tarrant, Wise and Denton counties, the emissions increased during the study period due to increase in the oil and gas production, while Johnson County’s emission contribution declined throughout the study period.

The effect of shale gas activities on ground-level ozone pollution in the Dallas-Fort Worth area is studied in detail here. Ozone is a highly reactive species with harmful effects on human and environment. Shale gas development, or fracking, involves activities such as hydraulic fracturing, drilling, fluid mixing, and trucks idling that are sources of nitrogen oxides (NOX) and volatile organic compounds (VOC), two of the most important precursors of ozone. In this study two independent approaches have been applied in evaluating the influences on ozone concentrations. In the first approach, the influence of meteorology were removed from ozone time series through the application of Kolmogorov-Zurbenko low-pass filter, logarithmic transformation, and subsequent multi-linear regression. Ozone measurement data were acquired from Texas Commission on Environmental Quality (TCEQ) monitoring stations for 14 years. The comparison between ozone trends in non-shale gas region and shale gas region shows increasing ozone trends at the monitoring stations in close proximity to the Barnett Shale activities. In the second approach, the CAMx photochemical model was used to assess the sensitivity of ozone to the NOX and VOC sources associated with shale oil and gas activities. Brute force method was applied on Barnett Shale and Haynesville Shale emission sources to generate four hypothetical scenarios. Ozone sensitivity analysis was performed for a future year of 2018 and it was based on the photochemical simulation that TCEQ had developed for demonstrating ozone attainment under the State Implementation Plan (SIP). Results showed various level of ozone impact at different locations within the DFW region attributed to area and point sources of emissions in the shale region. Maximum ozone impact due to shale gas activities is expected to be in the order of several parts per billion, while lower impacts on design values were predicted. The results from the photochemical modeling can be used for health impact assessment and air quality management purposes. Both studies in this research show that the impact of shale gas development on local and regional level of ozone is significant, and therefore, it should be considered in the implementation of effective air quality strategies.

Conventional sources of emissions have been a prime target for policymakers in designing pollution control strategies. However, the evolution of shale gas activities is a growing concern over the impact of unconventional sources on urban and regional air quality. Owing to the development of Barnett Shale production, the fast-growing Dallas-Fort Worth (DFW) metroplex has encountered both types of these emissions. Oil and gas activities result in emissions of ozone precursors, notably volatile organic compounds (VOC). The major objective of this study was to evaluate the spatio-temporal distribution of VOC in order to highlight the influence of unconventional emissions. The study utilized measurements from automated gas chromatography (AutoGC) monitors to analyze the patterns of the total non-methane organic compounds (TNMOC) and relative contributions from marker species of traffic versus oil and gas activities. In this study, data from 2001-2014 was obtained from the Texas Commission on Environmental Quality (TCEQ) for fifteen monitoring sites within the North Texas region. With over a thousand wells in a 10 mile radius, two of the rural sites measured twice as much TNMOC as compared to the urban site in Dallas. Source apportionment analysis was conducted using Positive Matrix Factorization (PMF) technique. The target site located in the urban zone resolved an eight factor model. Natural gas signature was the dominant source of emission with a 52% contribution followed by 31% from two separate traffic-related sources. Considering ethane to be the dominant species in oil and gas emissions, it was observed that the rising ethane/NOx ratio correlated with increasing annual average ozone post-2007. In this period, higher concentration of ozone was found to be associated with stronger winds from the Barnett Shale area – a region that did not seem to contribute to high ozone during 2001-2007. With traffic emissions having flattened over the years, the recent increase in oil- and gas-related emissions has a negative impact on the air quality in this area. Results indicate that the area has failed to observe a declining trend in ozone despite effective reductions in NOx and traffic-related VOC emissions. The findings of the study would be helpful in proper evaluation of the ozone-forming potential of unconventional VOC emissions. Although these emissions may not be strong enough to cause harm through direct exposure, underestimating their potential towards ozone formation could hinder the progress in ozone attainment in growing urban areas. After all, a major portion of the study area continues to be in nonattainment of the EPA designated ozone standards. The study therefore draws the attention of policymakers towards the new influx of emissions that have emerged as a powerful source within the DFW metropolitan area.